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By Munetaka Iwasaki

Nitrogen strongly affects mechanical properties of steel and therefore we may sometimes modify the various processes for its content. Numerous studies based on the results of chemical analysis of quenched samples were reported with a few exceptions of Hot Sievert method. The technique always poses a risk of uncertainty whether the true content of nitrogen in liquid metal is measured or not. In this study vacuum remelting under relatively low pressure was done to enhance gas phase mass transfer. Total pressure of the melt chamber was about 10-3 pa and electron beam heating was used. Mass spectroscopy was used for the direct observation of the rate of denitrization. Nitrogen molecules or atoms were detected by a mass spectrometer set above the melt. Continuous monitoring of the intensity of the fixed mass number may reflect the transfer of nitrogen from the melt to the vacuum. The results of the new and conventional techniques agree, both technique can be verified.

Jan 1, 1999

By G. E. S. Valadao

Filtration is an important solid liquid separation technology employed widely in the mineral processing industries. The effectiveness of the filtration operation can be influenced by numerous variables, related to the particulate phase, the slurry rheology and the equipment. The classical approach for analysis is based on Darcy's law. Knowledge of the cake pore microstructure and its correlation to macroscopic cake properties is required to model the filtration operation from a fundamental point of view. Since cake formation seems to occur randomly, a 3D Monte Carlo method was used to simulate cake formation. The configuration for simulation was a space with width of 500 µm, length of 500 µm and height of 4000 µm. Size distributions of five different industrial products whose particle size distributions follow the Rosin Rammler distribution function were used. The particle shape was assumed to be spherical. The simulated cake structures were described in terms of volume porosity (volume of pore space per unit volume of cake) and surface porosity (area of pore space per unit area of a cross section). The results indicate: I) it is possible to simulate 3D packing, which mimics cake structure, using the Monte Carlo method, 2) segregation phenomena occurs during simulated cake formation, 3) the values of calculated porosity for simulated samples B, C, D, and E were lower than those determined for corresponding industrial products Br, Cr, Dr, and Er, and 4) some structures of simulated samples seem to correlate with laboratory leaf test data obtained for different products from plant operations.

Jan 1, 1999

By C. Ottergren

A process does not have higher capacity than what can pass through its bottleneck. Acknowledging this, and with the goal to optimize production at a minimum investment, one can use existing equipment, modify the process flow and make a few strategic capital investments. Automatic setting regulation is a technology that allows balanced crusher performance matching minute changes in feed material characteristics. The system makes it possible to utilize the crushers fully at all times. It also continuously and completely compensates for manganese liner wear.

Jan 1, 1999

By M. A. van Nierop

The Discrete Element Method (DEM) is a model that is used to simulate the motion of the media in a grinding mill. The sum of the energy that is lost in inter-media and media-wall collisions represents the power drawn by the mill. The fact that the DEM predicts the power drawn by grinding mills over a large range of diameters has been used to show the validity of the DEM. However, the power drawn by a mill is a function only of the sum of forces of the load on the shell liners. A more accurate and detailed validation of the DEM would be to measure these forces as a function of angular position as the liner moves under the load, and to compare these measurements with predictions generated using the DEM. An experimental mill has been developed to reproduce exactly what the 2-dimensional DEM simulates. The 0,55 m diameter mill has a length of 0,023 m, which is fractionally larger than the diameter of the media used in the mill. One of the lifters in the mill has been instrumented so that the forces on the lifter can be measured as the mill rotates. The DEM simulation will be used to predict these forces. This will give experimental evidence of the validity of the DEM for modelling load behaviour in rotating grinding mills.

Jan 1, 1999

By S. Neven

The smelting of copper anode slimes, a material which contains mostly lead, silver, copper and selenium, has been practiced for many years with a view to recovering the silver and associated small amounts of gold. However, a theoretical understanding of the process has been lacking and this handicaps efforts to improve and intensify smelting operations. In the past few years work has been done in this area and this work will be reviewed in the paper. The underlying thermodynamics of the oxidation of silver-copper selenide mattes has been developed and used as a basis for the construction of a computational thermodynamics model which attempts to predict the composition of all condensed phases during the course of smelting. The model will be outlined and its successes in matching experimental data, as well as its current deficiencies, will be considered. Supporting work on the thermodynamics of silver solubility in slags, on activity-composition relationships in the Ag-Se system and work in progress on the oxidation state of copper in the slags will be reviewed. These projects are designed to provide further detailed data which will improve the robustness of the thermodynamic model.

Jan 1, 1999

Giant gold deposits are considered products of crustal-scale systems. Reduced fluids stored in mid to lower crustal reservoirs were discharged into mid to upper crustal sites of deposition. Elements of the architecture include crustal-scale structures, reduced packages of rock and regional seals. Gas-rich aqueous fluids were common but non-aqueous fluids may have been significant in the deeper parts of the systems. Fluid fluxes in over pressured domains were maintained by porosity waves. Abnormal heat input from the mantle may not be required once the systems were perturbed. Fluid-mixing and hypogene enrichment were probably the most significant precipitation processes.

Jan 1, 1999

By Larry M. Southwick

The smelting of copper and other non-ferrous metals have made considerable advances over the last 125 years. Many of the ideas and processes currently in use were attempted early in the history of smelting and were unsuccessful. Often the cause was incomplete understanding of the metallurgy involved, inadequate refractories, poor materials of equipment fabrication or trying too many new ideas at once. With time, these problems get solved and the technologies become commercialized .These were processes whose time had not come when originally proposed, but did eventually. On the other hand, there have been some concepts whose time will never come. They were impossible then and they are impossible now. The people that dream these up were either crackpots (they didn't know what they were doing, but thought they did), or charlatans (they knew they didn't know what they were doing, but didn't care). Both rely on bad science to propose metallurgical absurdities. These too have their place in the development of technology, though mostly negative, and several examples will be discussed in this paper. Three from around the turn of the century will be covered, as well as one from this decade. The last demonstrates that the art of creating absurdities has not withered, even after ninety years of scientific sophistication, and some can even be patented. The first three reached field trials due to the gullibility of company management. The last arose from a fortuitous mis-operation of a plant which solved a problem, but the explanation and patent which arose are metallurgically impossible.

Jan 1, 1999

By Elmer Stewart, Richard May

"The Central Mukur deposit was discovered by the Semipalatinsk Geological Exploration Expedition (GEE) during detailed searches from 1977 to 1980. Andas Altyn Ltd., a Kazakhstanian gold mining company acquired the property and commenced mining in 1995. In 1998, Andas-Altyn Ltd. became a wholly owned subsidiary of Eurasia Gold Corporation.The Central Mukur gold project covers a linear series of parallel, discontinuous zones of near surface oxide gold mineralization that covers a distance of 7 kilometers and extends past the property boundaries. The oxide gold mineralization is a result of the regional oxidization of a primary sulfide gold mineralization emplaced in a series of shallow dipping thrust faults. Resources as calculated by the GEE are 3.45 mt at an average grade of 1.84 gmt Au in the C1 +C2 category and 7.52 mt at an average grade of 1.80 gmt Au in the P1 category. The Central Mukur Gold Heap Leach Mine consists of an open pit, heap leach pads, and an ion exchange resin gold recovery plant. Limited gold production (<2,500 ounces/year) has been achieved over the past three years leaching run of mine oxide gold mineralization. Gold recovery utiling cyanide to dissolve the Au and ionic resin technology to recover the Au for the leachate is approximately 60%. Loaded resin is shipped to a treatment plant at Almaty where the gold is stripped from the resin, refined and sold.This paper will describe the geology, mining, and processing of the Central Mukur ore. In addition, it will describe what it is like doing business in Kazakhstan and the transition from a Soviet style operation to a more western style operation.INTRODUCTIONThe Central Mukur Mine is owned and operated by Andas-Altyn Ltd. a Kazakhstanian gold mining company located in northeast Kazakhstan. Andas-Altyn is a wholly owned subsidiary of Eurasia Gold Corp., a Canadian public company listed on the Alberta Stock Exchange. The Central Mukur mine consists of a small open pit, and a heap leach operation that utilizes ion exchange resin to recover gold from pregnant solutions. In addition to the Central Mukur mine, Eurasia also owns the Myaly heap leach gold project which is also operated by Andas- Altyn Ltd."

Jan 1, 1999

By R. N. Powell

The Pipeline ore body was discovered in March 1991. The construction of the new mine and mill did not start until early March of 1996. Upon completion of permitting and corporate project approval, the 289 million USD project was “fast tracked”. The commissioning began 11 months after start of construction and the project ended 40 million USD under the budget figure. The objective of this paper is to review and highlight the Pipeline Project history from discovery, design, lawsuits, permitting, and re-design through to current - 1998operating practices. Particular emphasis will review the process design, design mistakes, and design successes. The paper will review project history, feasibility, design concepts, operator training, construction, financial and the current operation. Additional discussion will review what design features worked and which did not work within the process plant.

Jan 1, 1999

By M. E. Rossi

Reconciliation of production information is critical to evaluating the effectiveness of the predictive models, and to allow for optimization of mining operations. Whether mining open pit or underground, mine-to-mill reconciliations can be one of management&apos;s better tools to perform proper accounting, and a very useful evaluation and optimization tool. This paper proposes a set of criteria and objectives for a typical reconciliation program; also presents a stepwise, logic approach to performing reconciliations, and discusses the benefits and costs associated with the up-keeping of the information. It also highlights some of the potential pitfalls involved, and methods used to avoid collecting misleading information. These issues are illustrated with an example of a model-to-mine-to-mill reconciliation program being implemented at an operating mine; the program involves multiple predictive models (Long-term and Short-term block models), different open pit and underground mines, stockpiling, and at least 23 different mill streams. This paper presents the initial results of the program implemented at Minera Michilla S.A.

Jan 1, 1999

By M. M. Carpenter

Specialty chemicals are widely used in the industrial minerals process industry for many different purposes including beneficiation, filtration, flocculation, dispersion and biological control. Optimal use of such chemicals can confer benefits both in terms of cost efficiency and end product attributes. In this paper we will review recent progress in the fundamental understanding of mineral additive interactions and present data which show how optimization can lead to improved products.

Jan 1, 1999

By Mark Jolly

"Over the last ten years or so many man hours have been dedicated to developing methods for simulating shape casting processes. The majority of the methods developed have been devised by a combination of computer, mathematics and materials specialists often with limited knowledge of foundries and foundrymen. As a result of this it would appear that although there are many software packages for the foundryman to use there still exist fundamental misunderstandings as to their usefulness and suitability within the foundry.The paper aims to identify how well current software packages perform. The relationships between physical phenomena, practical defects and software capabilities are presented. Some discussion of the use of criteria functions is also presented. Finally issues arising from the postprocessing of results are discussed as the presentation of the results to the lay-person in simulation techniques is possibly one of the most important aspects in influencing the adoption of this type of software in the foundry community."

Jan 1, 1999

By J. Drelich

An improved experimental procedure to measure contact angle has been consolidated with coal surface preparation involving polishing with abrasive paper, alumina powder, and a cloth, followed by ultrasonic and mechanical cleaning. Specifically, the captive-bubble measuring technique has been compared with the sessile-drop technique and the former has been recommended for the examination of the hydrophobic properties of coal surfaces. Results of the research program, which is currently under way, on the examination of the effect of the nature, amount, size and distribution of mineral inclusions in coal on its wettability are briefly reviewed.

Jan 1, 1999

By F. J. Bruey

Refdist is a simple but valid approach to planning or analyzing a test-vs-control plant trial that uses accumulated plant performance data to calculate objective criteria for judging the trial outcome. Refdist calculations and results are explained and illustrated with data typical of the mining industry. Findings from a simulation study of Refdist statistical properties are reported. Suggestions for dealing with messy data situations are offered.

Jan 1, 1999

By G. Duncan

Distinct trends in grinding mill technology have emerged in recent years. In an effort to optimize overall mill performance for the needs of the End User, broad measures of logistical speed, process flexibility, operational risk, and overall costs now exert greater influence on the specification of grinding equipment. As a result, innovative alternatives to conventional grinding mill structures, supports, drives, feed, and discharge configurations are now being offered and selected with greater frequency. This paper investigates these trends in grinding mill technology, utilizing optimization and decision-theory techniques. In particular, the paper considers how specific advances in process design, product engineering, manufacturing techniques, and mining operations continue to relax technological constraints, enabling further mill innovation. In this context, a methodology is presented, illustrating how proper selection and specification of grinding mill components and configuration can target an optimization of the four End-User performance measures listed above..

Jan 1, 1999

By P. T. Craddock, H. V. Paliwal, L. K. Gurjar

The Indian cultural heritage of mining, smelting and the use of minerals and metals dates back to ancient times. Although the exact date of the commencement of such activities in India is not certain, Indians are known to have been familiar with gold, silver, copper, tin and lead and to a lesser extent with iron at least since the Vedic period (Table 1).

Jan 1, 1999

By Y. Fautrelle, F. Felten, O. Metais, Y. Du Terrail

"We deal with the prediction of electromagnetically-driven turbulent flows by means of a Large-Eddy- Simulation method (LES). The model is applied in the case of a liquid metal pool submitted to a polyphase linear electromagnetic stirrer. We investigate two cases: (i) the frequency of the magnetic field is equal to 50 Hz; in that case the effects of the pulsating part of the Lorentz forces may be neglected; (ii) the frequency of the magnetic field is low (f= 1 Hz), then the oscillating part of the electromagnetic forces is taken into account. The LES predictions agree well with the mean velocity measurements, as does the standard k-a model. However, as for the turbulent kinetic energy predictions, there is a large discrepancy between the two models. When the oscillating part of the Lorentz forces is taken into account, the computations show that the fluid flow is sensitive to the unsteady part of the forces. We find that the mean velocity is not affected by the fluctuating component of the force. As for the turbulence parameters, the presence of the pulsating part leads to a significant reduction of the turbulent kinetic energy, whilst the turbulence length scale decreases.IntroductionElectromagnetic stirring is commonly used in various metallurgical processes. In continuous casting for example, it may improve the structure of the solidified metal products. Fluid flows generated by electromagnetic stirrers have been extensively investigated (1 ). As for numerical predictions, many works have been published on the subject. In most of the previous works, onepoint closure models have been used. The most used model is the well-known k-i:: model. Those models yield fairly good results as for the mean velocity prediction. However, it has two main drawbacks:(i) the turbulence is not predicted accurately,(ii) it is not well fitted for unstationary flows as well as transitional turbulent motions, where theReynolds number is moderate."

Jan 1, 1999

By Jorge Alberto Soares Tenório

Household zinc based batteries contain some heavy metals such as zinc, manganese and mercury. There is a large effort from manufacturers in order to eliminate the last one. As a municipal waste, the disposal of batteries has become an increasing worry. The aim of the present work was to characterize dry batteries scraps, and establish a flowsheet for their processing. This was done using unit operations of mineral processing and parameters and yields of each stage have been defined. Such procedures have been chosen due to their low cost. The operations were hammer mill grinding, size separation, magnetic separation and specific weight separation in water. The characterization step was done through chemical analysis and x-ray difiactometry. After size classification, it was verified that 76.6% of the total amount of zinc was over 1.70mm. This fiaction was constituted basically of zinc and some coarse pieces from the steel body, paper and plastics. This fraction was submitted to magnetic separation followed by specific weight separation in water. A visual examination showed that during the grinding process, graphite was concentrated in the finer fractions. Manganese concentration in the fractions over 6,35mm was less than 2%. This means that there was low contamination by the paste in this fraction. It was due to the entrapment of the paste by steel scraps (from the body) and zinc (from the cup) during grinding.

Jan 1, 1999

By F. G. Rinker

The world demand for metallized iron continues to increase, keeping pace with steelmaking requirements for lower cost hot metal. Virgin iron ore and in-plant oxide fines can be reduced to direct reduced iron (DRI) and hot briquetted iron (RBI). MR&E has developed an improved coal-based process for cost-effective production of either DRI or HBI. Starting with dry compaction, the process combines the latest technology for material preparation, rotary hearth furnace construction and environmental control. Coarse iron ore fines are blended with pulverized non-metallurgical coal to produce a highly metallized (>90%) product. This paper presents production and installation cost data based on operating and under-construction iron oxide reduction facilities.

Jan 1, 1999

By Sandra K. Zacharias

Brass, a deliberate alloy of copper and zinc, has been known since before Roman times. There are two main methods of making brass: (1) Cementation or calamine process - crushed zinc ore (calamine, ZnC03 , or calcined calamine, ZnO), is mixed with charcoal and small pieces of metallic copper and heated to about 900°C in a closed crucible, (2) Alloying - metallic copper and zinc are melted together in a reverberatory furnace. According to most modern authorities (e.g. Smith and Forbes 1955), the calamine process was the only one used in western Europe prior to the 18th century. At that time, the alloying technique began to take over, because metallic zinc was successfully produced on a large scale for the first time. Previously, this had been a problem because zinc vapourizes at 906°C or about the same temperature at which it can be reduced from its ore. Thus, some means had to be devised to collect and condense the zinc vapour (Tylecote 1976). Metallic zinc was known, however, earlier than the 18th century A.O. Several early finds have been made, including a rolled sheet of metallic zinc found in excavations at the Athens Agora dating to the 3rd to 2nd century B. C. (Farnsworth et al. 1949). The Chinese were producing zinc by at least the 10th century A. D. and, by the 17th century, Chinese zinc ingots were being imported into Europe by the Dutch East India Company (Needham 1974). Metallic zinc is also mentioned in several European documentary sources from the 16th century (e.g. Paracelsus, Agricola). This study traces the changes in Western brass making methods from Classical to Renaissance times by examining documentary and archaeological evidence.

Jan 1, 1999