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By D. Newman

Mineral production in the Highlands and Islands of Scotland during the last ten years has been confined to the sporadic production of industrial minerals—for example marble, anorthosite, limestone, talc and silica. From 1962 onwards there has been an upsurge in mineral exploration in the Highlands, increasing in tempo from 1966 onwards due to the efforts of the Institute of Geological Sciences, the Highlands and Islands Development Board, and private and public companies. Geological, chemical and economic aspects of some of the more interesting mineral prospects are discussed: these include anorthosite, feldspar, magnetite, quartzite and brucite marble. Reference is made to a geochemical survey undertaken in the Rosehall district of Sutherland, the results obtained being summarised. Problems that affect the future of mineral exploration in the Highlands are stated.

Dec 1, 1971

By B. W. Hester

Report of discussion at January, 1971, general meeting (Chairman: M. J. Cahalan, President) of the paper published in Transactions/Section B (Applied Earth Science), vol. 79, May, 1970, pp. B60-B67, and contributed remarks. Comments were made by Taylor J.T.M., James C.H., Lethbridge R.F. and Heath K.C.G.

Dec 1, 1971

By A. B. Holland-Batt

Two graphical techniques which are commonly used to assess batch separations are analysed in terms of reaction kinetics to provide a more powerful method of evaluation. An alternative and more general approach, based on the selection and application of suitable efficiency criteria, is also presented. The method proposed distinguishes between selection and collection efficiency in flotation and can be used to estimate the degree of liberation in the feed. Two examples are given: table concentration of monazite and ilmenite from a beach sand, and flotation of a pyrite-haematite ore

Dec 1, 1971

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By R. Phillips

The low concentration of diamond in workable deposits requires very large samples for grade estimation, and results, even then, may be erratic and difficult to interpret. Although the Poisson probability distribution cannot accurately describe the occurrence of diamond, it is suggested that it gives a better estimate of grade than conventional methods, even from single samples. Examples illustrate the simple calculation required.

Dec 1, 1971

By J. R. Hammond, I. C. Herbert

Report of discussion at October, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C128-36 and introduced by I.C. Herbert. Contributors were von Struve G., on the application of balling discs and the use of basic additives; Young P.A., asking for details of the drying, grinding, balling, induration and specification testing equipment and processes; Davison J. on pellet swelling properties and Carter G.C. on disc operation, refractories and green ball properties.

Dec 1, 1971

By M. G. Fleming

The professional mineral engineer is an individual of personal integrity who has undergone rigorous intellectual instruction in the scientific disciplines fundamental to his vocation; he has learnt to apply these disciplines to the discovery, mining and treatment of mineral resources and, through practical training and experience, has acquired competence and judgment to fulfil his undertakings. In the course of this development he has recognised and accepted a threefold responsibility to society, to his employer and to his profession

Dec 1, 1971

By D. W. Holliday

The major deposits of anhydrite and secondary gypsum in Jamaica occur discontinuously at a single horizon within the Lower Eocene succession of southeast Jamaica. They are not intruded from other horizons of different age, as has previously been supposed. The gypsum and anhydrite occur in a regressive sequence at the junction between marine (Richmond Formation, Halberstadt Volcanics, Halberstadt Limestone) and overlying non-marine (Wagwater Formation) sediments. They are thought to have been formed in an arid supratidal (sabkha) environment. A variety of 'nodular' structures occurs in the gypsum and anhydrite which can be related to early diagenetic processes and compaction effects. All gradations exist between single isolated anhydrite nodules and structureless anhydrite due to closer packing and coalescence of nodules. The structures and textures in the anhydrite are thought to be consistent with penecontemporaneous formation from gypsum crystals rarely more than 2 cm in diameter. Single anhydrite nodules are not usually larger than 2 cm; nodules of greater size are compound, due to the coalescence of several smaller nodules. Some large compound nodules may have developed from single sand crystals or rosettes. Compaction of anhydrite appears to have been largely mechanical, but some rocks have an aligned fabric, suggesting later flowage

Dec 1, 1971

By P. A. Wright

The note describes the steps involved in the combination of results reported by Shiraishi and Bell in 1968 and 1970 and by Mills and Turkdogan in 1964. Shiraishi and Bell derived from their vapour-pressure measurements an expression for the activity coefficient of tin implying that the miscibility gap in the two-liquid region is symmetrical about the N = 0-5 axis. The limits of the miscibility gap were reported by Shiraishi and Bell and measurements were reported graphically by Mills and Turkdogan. Least-square parabolas are fitted to the transformed results of Shiraishi and Bell and of Mills and Turkdogan for the miscibility gap in the liquid tin-iron system. Back-transformation from these curves gives limits at 1438 K and equations are derived that appear to be a fair average of existing data, although a third term for the activity coefficient equation needs to be investigated

Dec 1, 1971

By R. N. Pryor, S. H. Shaw, D. L. Dowie, S. H. U. Bowie, M. J. Cahalan, S. F. Gandar

It is concluded that land-based mineral resources will be adequate for most minerals in the immediate future, but in the long term more minerals will come from offshore locations. Because the oceans are international and can transport pollution, international control of offshore workings will be necessary. In the UK and similarly highly developed areas, the working of low-value bulk minerals will create increasing problems in urban development and countryside preservation. Much more information should be published on standards to be adopted and their costs, if emotional social pressures founded on ignorance are to be avoided. The Town and Country Planning Acts have greatly improved the environmental quality in Britain in relation to mineral working. In the long term conservation of some minerals in short supply may be necessary on a national or international basis. Much research is required for the determination of adequate criteria and standards for the preservation of environmental quality in the mineral industry. New local, national and international legislation will be required and the adoption of voluntary standards by trade associations should be encouraged wherever appropriate

Dec 1, 1971

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971

By A. W. Fletcher

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J, Cahalan President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, December, 1970, pp. C247-52, and contributed remarks. Contributions are included from: Cahalan M.J., giving figures related to leaching Cu from pyrite at Rio Tinto 1880-1910; Noakes F.D.L.; Embling P.M.K.; Bradshaw A.V.; Le Roux N.W.; Kelly D.P.; and Tuovinen O.H. Questions were raised regarding impurity removal, effects of light and ultraviolet light on the bacteria, the economics of solvent extraction and the possibilities for other organisms or other metals

Dec 1, 1971

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

By R. W. Schultz

Mineral exploration carried out in Ireland since the mid-1950s has resulted in the discovery of ore deposits that are now in production atTynagh (Pb-Zn-Cu-Ag), Silvermines (Zn-Pb) and nearby Ballynoe (barite), and Gortdrum (Cu-Ag-Hg); a major Zn-Pb deposit at Navan that is now being drilled prior to development; potentially productive deposits at Keel (Zn-Cd-Pb), Ballinalack (Zn-Pb) and Aherlow (Cu-Ag); and a number of interesting prospects, including one of spodumene. Underground exploration of a formerly extensively mined copper deposit at Allihies has outlined new, albeit currently uneconomic, reserves at depth. The copper and pyrite deposits at Avoca have in recent years been re-explored and are now again being worked. Most Irish ore deposits are in the lower half of the Lower Carboniferous succession of limestones and subordinate shales and sandstones, and this stratigraphic zone is being most intensively explored at present. Other geological units under active exploration are Ordovician sediments-volcanics belts, Caledonian granites, and parts of the Old Red Sandstone and Dalradian series. Surface prospecting is made difficult in many places by glacial and other superficial deposits, including peat and alluvium. Geochemical prospecting methods have been outstandingly successful and primarily responsible for most new discoveries. Boulder hunting and outcrop prospecting have proved effective in detailed investigations of geochemically anomalous areas. Some parts of the country have been covered by three separate airborne geophysical surveys, albeit without success so far. The induced polarisation technique, the most widely used ground geophysical method, has contributed to several discoveries. The scope of application of electromagnetic surveys is more restricted than that of induced polarisation, but the method has been effective in a few cases and has contributed to the Tynagh discovery. To date, the resistivity and self-potential methods have found little application. Magnetic surveys are not applicable directly in the search for ore deposits of the various known types, but can be helpful in outlining geological structures in some areas. The gravity method has been used successfully in a survey over the Zn—Pb deposit at Navan ; it has also proved effective in trials over a blind sulphide deposit at Tynagh that cannot be detected with geoelectrical methods. An appendix lists summary descriptions of 15 Irish deposits and occurrences

Dec 1, 1971

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By S. V. Shiraishi, H. B. Bell

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J. Cahalan, President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C120-C127, with a contribution by Wright P.A. on the miscibility gap

Dec 1, 1971

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

By W. E. Roscoe

The probability of making an exploration discovery in Canada can be calculated from Derry's (1970) data on exploration expenditures and number of discoveries over the last nineteen years. Considering an average exploration "try" to be $30,000, the probability of a discovery with one try has decreased tenfold from about 0.01 in 1951 to 0.001 in 1969. A plot of these probabilities can be extrapolated to the future, giving a 1969-71 three-year average probability of 0.00096 with 90 per cent confidence limits of 0.00042 and 0.00153. Using this probability, various calculations can be made, such as (1) the probability of making at least one discovery for any given exploration expenditure, (2) the probability of ultimate ruin or survival of the exploration investment process and (3) the expected value of an exploration investment. There is a critical minimum amount per discovery that must be re-invested in exploration, no matter how large the original investment is, for exploration to survive at all in the long run. Currently, this critical minimum is $31,200,000 with 90 per cent confidence limits of $19,600,000 and $71,400,000.

Jan 1, 1971

By N. R. Paterson

"More than a dozen AEM systems are currently being used in the routine exploration for massive sulphides. The systems differ from one another in minor respects, but fall into four main categories: rigid-coupled in-phase/quadrature systems; towed-bird, single-component systems; differential systems; and passive systems.Although field tests are important in demonstrating the performance characteristics of the AEM/airframe assembly (noise-levels, coupling effects, etc.), more meaningful evaluations can be made through physical or computer modelling. The latter approach has been used to compare the response of twelve AEM systems to both vertical and horizontal sheets, simulating a large orebody and a con-ductive overburden respectively. The effects of height changes are also studied.The results demonstrate that each AEM system has its own particular advantages and disadvantages. The relative importance of these is a matter for the geophysicist to judge, on the basis of specific geological and environ-mental information. Data currently available on AEM systems are adequate to permit an objective evaluation of the systems for a particular exploration program."

Jan 1, 1971

By John V. Beall

As Mother Nature arranged it, the hottest potential mineral target in the country today, the Stillwater complex had to occur in a spectacular natural setting-the north margin of the Bear Tooth Mountains of Montana. What more appropriate backdrop for the August 17-18 field hearings of Senator Frank E. Moss (D-Utah). His subcommittee, on Minerals. Materials and Fuels, heard 37 witnesses ponder the value of minerals vs esthetics or other uses of federal lands. On August 17, four Army Hueys swept the senatorial party, the press, Forest Service Officers and such distinguished witnesses as Montana Governor Forrest H. Anderson over the Custer-Gallatin National Forests, besting the thin air of 10,000 ft p1us, they set down on Iron Plateau.

Jan 1, 1971