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By J. -P. Nepper

It has been possible to largely contain converter aisle emissions of SO2 and fumes in the case of batch-wise operated Peirce Smith converters during normal blowing periods with the help of suitably designed primary hoods. Controlling the escape of off-gas during the periods of turning the converter in or out of the stack has been problematic in the past. Effective automated contro1 systems have been deve1oped for the purpose and successfully applied in smelter operations in Spain, Taiwan and Germany. This has led not only to an effective reduction of emissions in the converter environment but also to an improvement in the converter operation.

Jan 1, 1992

By Richard F. McFarlin

INTRODUCTION Phosphate, one of the three major elements essential for all living plants and animals, has been mined in Florida for over a hundred years. Comprising roughly 80% of the U.S. total and 25% of the world's supply, the bulk of the 35 to 40 million annual ton output is converted to chemical fertilizers. With the exception of one mine in north Florida near the Georgia state line, today's mining activities are centered in the middle of the peninsula just east/southeast of Tampa in Polk, Hillsborough and Hardee counties. These "bone valley" deposits extend into Manatee and DeSoto counties, but there is little active mining there as yet. Because strip mining is, perhaps, the ultimate environmental insult and because Florida has a proactive environmental community, it is not surprising that the mining of phosphate rock has become increasingly controversial. This paper describes how phosphate rock is currently mined, the environmental problems presented by mining and processing the rock, and some mitigating technologies being employed to answer such problems. THE PHOSPHATE DEPOSIT AND ITS EXTRACTION Florida's phosphate deposits containing the calcium phosphate mineral, carbonate-fluorapatite, are between ten and fifteen million years old. The typical "bone valley" matrix is 15 feet thick and lies under 20 to 30 feet of overburden.(Fig. 1) Both the sandy overburden and matrix are unconsolidated and can be removed with standard 45 to 65 cubic yard, walking electric draglines. After removing the overburden, which is windrowed nearby, the dragline operator casts the matrix into a "slurry" pit where it is broken up by high pressure water monitors. Pit pumps (with boosters where necessary) transport the matrix slurry through 16 to 20 inch pipelines to a washer where the three components of the matrix (sand, clay and apatite) are separated. The phosphates contained in central Florida matrix are approximately half pebble/half flotation feed, through the pebble ratio decreases as the industry mines southward. Again, the matrix is roughly equally divided among sand, clays and apatite. The phosphatic clays, 75% of which are less than one micron in size, leave the washer as a 3 to 5% colloidal suspension. The impoundment of these waste clays is one of the environmental challenges to be discussed later. The sand (silica) is separated from the similarly sized phosphate particles by a double float process (fatty acid followed by a reverse mine or cleaner float), and the sand tailings are then pumped to disposal or reclamation sites. The apatite flotation product is combined with the screened phosphate pebbles and stacked to dewater before shipping.

Jan 1, 1992

By P. D. Rao

Although phosphorus is a very important biogenic element, its concentration in coal is generally low. Phosphorus concentrations typically range from 0.001 % to 0.229% in raw coals of the contiguous 48 states. Some Alaskan coals in the Cook Inlet region contain horizons unusually high in phosphorus. A foot by foot analysis of deep drill core, containing 70 ft. of sub bituminous 'C' coal from the Beluga coal field, Alaska, showed certain increments contained as high as 17.03% P2O5 in the coal ash; 1.01 % P on a moisture-free coal basis. Crandallite has been identified by electron microprobe analyses as a phosphorus numeral in these coals. The authors could quantify calcium, barium, strontium and phosphorus concentrations from the coal attributable to crandallite. These high phosphorus coals provided a unique opportunity to study the association of phosphorus in coals using chemical fractionation for exchangeable cations and acid extractable elements. Since the source of high phosphorous horizons in Cook Inlet coals is attributed to volcanic ash, it is suggested that the profiles of acid extractable phosphorous concentration may be useful for coal seam correlations.

Jan 1, 1992

By Violetta Pavlova

Knowledge of geometrical properties of blocks in a hard jointed rock among other things is of considerable importance for prediction of rock mass behavior and for its exploitation. This paper presents a new approach to obtain the information about percentage of blocks with desirable geometrical properties in a jointed rock mass extending through a large region of interest. A model of a rock mass separated by finite number of systems of parallel plane discontinuities which form discrete blocks is discussed. A computational procedure has been derived to analyze the volume and shape distribution of blocks in the rock mass.

Jan 1, 1992

By H. H. Law

Large amounts of waste material in the form of flue dust are generated in the operation of copper smelter furnaces. As a result of increasingly stringent disposal, it has become important to develop methods for treating such metallurgical wastes to extract metals and convert them into salable products. A two-step closed-loop hydrometallurgical process, has been developed: (1) extraction with sulfuric acid removes about 90% of zinc and decreases the dust volume by 50%; (2) extraction with hydrochloric acid dissolves the lead and further decrease the dust volume by 75%. A process scheme for generating salable products is proposed.

Jan 1, 1992

By Jon H. Gould

This paper describes the following at the new Advanced Solid Rocket Motor (ASRM) nozzle manufacturing facility, which is being constructed inside an existing manufacturing facility: 1) generalized subsurface conditions, 2) pile load test program and evaluation, 3) pile selection, 4) problems associated with pile driving operations, and 5) production pile installation. The poor subsurface conditions, known and unknown underground obstructions, and work environment inside the existing building, used to manufacture the Space Shuttle external fuel tanks, required special pile installation equipment, procedures, and work schedules to install the economical pile foundation system ahead of schedule and without a lost time accident. GEOTECHNICAL STUDIES In April and May 1990, 16 soil test borings were drilled inside the existing building with a truck-mounted drill rig. The borings extended to depths ranging from 60 to 65 ft (18.3 to 19.8 m) below the floor slab. Typically, the silty and clayey soils were sampled by pushing "undisturbed" Shelby tubes, and the more sandy soils were sampled by driving a Standard Penetration Test (SPT) split-spoon sampler. The unconfined compressive strength, water content, and unit weight of the Shelby tube samples were measured in the laboratory. A geotechnical report was issued in May 1990 presenting the results of the field and laboratory testing and foundation recommendations (Gilbert, 1990).

Jan 1, 1992

By Filippos Patsiogiannis

Laboratory size (4.5 kg) low carbon steel melts were deoxidized using Al and FeAl (33% Al), with and without synthetic fluxes, in alumina and zirconia crucibles. The dissolved oxygen, total oxygen, soluble aluminum, insoluble aluminum, silicon and carbon contents in the melt were determined as a function of refining time and temperature. It was observed that the reaction between aluminum and oxygen in solution closely follows thermodynamic equilibrium. Silica present in the alumina crucibles was found to be a source of oxygen for the melt, while this was not the case for zirconia crucibles. Reoxidation of the melt occurred through oxygen pick-up from the atmosphere. The extent of this reoxidation was found to be a function of oxygen content of the bath and the slag cover on the surface of the melt. The effectiveness of calcium-aluminate based fluxes in protecting the melt from the reoxidation and in increasing the rate of removal of inclusions was evaluated.

Jan 1, 1992

By Kal V. S. Sastry

Mineral processing simulation has come a long way since its beginning about thirty years ago. With our increased understanding of mineral process systems and the advent of new software and hardware technologies, we can visualize an ideal mineral processing simulator. This paper attempts to identify a number of desirable features of an ideal mineral process simulator and to describe the exciting trends in making such an ideal simulator a reality.

Jan 1, 1992

By Simona Markic

With the aim of environment protection the program package HOMOGEN is used for realizing the planning and noxious components control in the coal produced. Using the program package PRIPREMA the division in levels and transformation (Hermite polynoms) in the N (0,1) distribution are made. By separated kriging 50 m x 50 m blocks are estimated on the levels and detailed distributions of the estimated component content are obtained. The face - longwall face is built in the blocks estimated in this way, and the direction of mining is determined. Using the stochastic simulation the distribution of the estimated production component (e.g. sulfur) on the face is obtained. Simulating the production of all faces in operation the distribution of the estimated daily mine production component is obtained. The estimated depot component is obtained in the same way. This procedure is used in the short-term planning of the estimated component movement for a given period in advance, and also in the daily production control in the case of changing conditions, e.g. the increased atmospheric pressure. The technology is successfully applied to the Velenje Lignite Mine Slovenia.

Jan 1, 1992

The bureaucracy in Victoria has worked against exploration and mining development. There is no doubt that the new Mineral Resources development Act has simplified matters on the mining side of the system. However, WMC's Bendigo and Deep Lead experiences demonstrate that other parts of the bureaucracy can cause serious delays. The mining industry continues to view the approval process causal of excessive costs and delays compared with other States (and countries) and prohibitive to investment in Victoria.

Jan 1, 1992

By D. Ince

Flotation of dolomite from apatite was investigated, using dodecylamine hydrochloride or sodium oleate as the collector, with and without inorganic modifiers such as sodium chloride. Separation of dolomite from apatite was anticipated from the single mineral experiments under various pH and collector concentration conditions. Flotation selectivity in the mixtures, however, was found to be limited. Attempts to control the flotation response of these minerals by addition of salts such as NaCl and KCI indicated that selectivity is possible. The presence of sodium chloride was determined to depress apatite flotation using sodium oleate, leaving dolomite flotation unaffected (Moudgil and Ince, 1989). In this paper, conditions for optimum separation and the effect of major parameters on the desired selectivity are discussed.

Jan 1, 1992

By H. William Zeller, T. E. Westpha1

The U.S. Bureau of Mimes evaluated the effects of two iron-based fuel additives on diesel particulate matter (DPM) emissions. The 5.6-L, six-cylinder test engine is typical of engines used in underground mines. One additive, ferrous picrate, did not measurably affect exhaust emissions. This report is mainly about a ferrocene-based additive that reduced DPM between 4 and 45 pct, depending on engine operating conditions. The report concludes that the DPM reductions were caused by the catalytic oxidation properties of a ferric oxide coating that developed inside the engine's combustion chamber. The ferric oxide coating also decreased gas-phase hydrocarbons and O, but it increased CO, and NO,. The increase in NO,, of about 12 pct, is considered the only adverse effect of the ferrocene-based fuel additive. The results suggest that the effectiveness of ferrocene was partially offset by increased sulfates because of the high-sulfur fuel used. Recommendations for continuing fuel additive research are presented.

Jan 1, 1992

In coal room and pillar, and pillar extraction panels, the sidewall conditions were investigated based on underground measurements and numerical simulations. Three-dimensional linear elastic models provided a useful and quick prediction of the amount of sidewall spalling. However, more complex constitutive models were required to simulate more accurately the extent of fracturing and its effect on the stress re-distribution. The input parameters of a Mohr-Coulomb model were determined by back-analysis of underground measurements, and the effect of the depth of the workings and the time dependent occcurrence of coal pillar fracturing were analyzed.

Jan 1, 1992

By E. H. Partelpoeg, B. G. Belew

In 1990, the Chino Smelter completed the construction of a plant designed to recover metal values and water from smelter scrubber effluent. Equipment was installed to maximize effluent recycling and minimize costs. The process utilizes magnesium hydroxide as a neutralizing agent which has the advantage of precipitating copper from solution with minimum generation of solid reaction products. The neutralized stream is clarified, with solids recycled to the smelter for metal recovery while the clarified effluent is recycled to the concentrator for use as process water.

Jan 1, 1992

By E. R. Bauer

This report presents the results of a cooperative study between BethEnergy Mines Inc., Ebensburg, PA, a central Pennsylvania coal mining company, and the U.S. Bureau of Mines to investigate longwall development entry roof instability. In-mine mapping of geologic and deformational features was conducted to reveal the major ground control problems encountered during gate road development. In addition, mining-induced pillar load monitoring was used to indicate development loading on variously dimensioned gate road pillars and to determine if pillar yielding occurred. Finally, visual observations of a variety of roof control methods were used to determine the most effective support elements for controlling cutter roof failure.

Jan 1, 1992

By R. K. Mehta

This paper presents the application of a simple genetic algorithm (SGA) to a coal slurry grinding process in order to find the optimum set of conditions under which the desired slurry properties can be attained. The operating parameters of the process were; slurry % solids, dispersant dosage, ball size, and mill speed. The optimization algorithm, which is based upon the mechanics of natural genetics, was used to find near-global optimum points specific to responses measured In terms of fineness, specific energy consumption, viscosity coefficient, and viscosity exponent. In order to minimize the viscosity of the slurry and simultaneously achieve a condition of maximum packing density, optimization was carried out by the penalty method using an overall objective function incorporating several responses. Computer results and analysis demonstrate the ability of the genetic algorithm to perform better than a traditional technique such as response surface methodology (RSM) and to rapidly locate "the global optimum".

Jan 1, 1992

By D. C. Azubike

Wolframite (FeWO4) usually having cassiterite (SnO2) as a major impurity is a primary source of tungsten. Its direct reduction/carburisation with carbon in the temperature range 1000-1400°C, and with hydrogen at 600-900°C followed by carburisation with CO at 900°C are described. Depending on the conditions and reactants employed, Fe, Fe2W, B-Sn,WC, W2C, Fe3W3C and Fe6W6C are the products. Tin was found to inhibit the overall reduction and carburisation reactions significantly. The potential for either efficient separation of iron and tungsten or a one-stage production of an iron-based metal carbide composite is discussed.

Jan 1, 1992

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992

By S. McCalpine, W. Muir, P. J. Downey

"Golden Bear Operating Company Ltd. (GBOC) was a joint venture between Chevron Minerals Ltd. and North American Metals Corp. that was formed for the development of the Golden Bear Project. The mine is located at Muddy Lake, Western British Columbia, approximately 80 km northwest of Telegraph Creek and 135 km west of Dease Lake (see Figure 1). Road access to the mine was developed by Golden Bear and consists of a radio controlled 155 km gravel road originating at highway 114.A feasibility study was completed in 1987 and project approval was finalized in 1988 with Golden Bear issuing a ""Request For Proposal"" for detailed engineering in May 1988. Golden Bear also commenced negotiating with vendors at this time for the supply of the two principal process equipment packages: the dry grinding and classification system and the whole ore roaster package.Process plant engineering and plant construction was completed in October 1989 with plant startup commencing in November 1989. Two months into the commissioning phase it became apparent that the plant, as designed, would not achieve the anticipated production targets.Kilborn Engineering Pacific were subsequently contracted by GBOC to review and modify the plant design, assist the operating personnel with plant commissioning and startup and provide operator training.This Paper describes some of the problems encountered during the startup and the plant modifications incorporated to achieve design parameters."

Jan 1, 1992

By P. Tsang, S. S. Peng

Mine floor failures, such as floor heave and floor buckling, occur frequently in underground coal mines where soft mine floor exists. The types of failure can usually be classified into two categories; shear punching failure and tensile failure. A model based on the Winkler's elastic foundation is proposed in this paper for floor stability analysis. The model considers material properties of floor strata, in-situ horizontal stress, pillar size, entry width, and configuration of multiple-entry system and predicts stress conditions in the mine floor based on given in-situ mining and geological conditions, as well as deformation of the mine floor. This information is used to predict possible failures of mine floor by comparing the strength of mine floor with its stress condition. The validity of the model is verified by in-situ data described in this paper.

Jan 1, 1992