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By Sam Tour

OF the new alloys achieving commercial prominence during the year, an aluminum-silicon magnesium casting alloy, which is similar in many respects to the 4 per cent copper alloy, developed about 1921, which has attained such a wide field of service, may be mentioned. The new alloy, like the old, is a heat-treatable type and develops about the same physical properties. The alloy casts easily and is relatively insensitive to high pouring temperatures. Its ability to produce substantially leak- proof castings is noteworthy. A second casting alloy development is the new Aluminum Co. of America No. 132, "Lo-Ex" piston alloy, a result of nearly eight years of research. The alloy contains about 14 per cent silicon and varying amounts of nickel, copper, and magnesium. It exhibits a low coefficient of expansion and thus permits small piston clearances. Its lower specific gravity is a further advantage.

Jan 1, 1932

By C. Babbitt, J. O’Green, N. I. Jayaraman

In many mines, dust-laden air from an entry being driven by a continuous miner will contaminate the intake air to the roof bolter operator and other downwind personnel. Through a US Bureau of Mines (USBM) contract, Foster-Miller Inc. has evaluated several control techniques to reduce the respirable dust exposures of downwind personnel. One fan and tubing technique consisted of bypassing the miner-generated dust directly to the section return. The results of the evaluation of this technique revealed that reductions in dust concentrations of 90% or more can be achieved at downwind roof bolter locations. A second method was to clean the dusty air from the upwind continuous miner by using a dust collector. The cleaned air was then supplied to the bolter through collapsible tubing. An underground evaluation showed reductions of 82% to 96% when the dust collector was operating. A third method was to reduce the quantity of dust contributed by the miner to the return airstream. A water-powered scrubber was installed over the throat area of the continuous miner. More than 1.18 m3/s (2500 cfm) of dusty air moved through five tubes with dust collection efficiency exceeding 75%. Underground evaluation results showed that return dust concentrations were reduced by about 60%. This paper discusses the ventilation and dust control techniques used for personnel downwind of the continuous miner.

Jan 1, 1987

By Abhirami B., V. Balakumar

Piled raft foundation system is an intelligent geotechnical concept, developed towards reducing the settlement of the raft and the footings by providing pile elements below the raft or footings, as the case maybe. Although a large volume of works has been done on the behaviour of piled rafts by observational studies, the effect of construction methodologies such as deep excavations, the installation methodologies used for piling etc appear to have not been covered adequately. This paper discusses the effect of deep excavations, pile installation techniques and the effect of adding structural elements, based on the data available from published literatures. Based on this study, the performance of the piled raft monitored by the author has been revisited and the results of such a study are discussed.

Nov 1, 2022

By D Blair, L Fergusson, G Barros

"The purpose of this paper is to present the findings of a waste rock remediation program conducted at a gold mine in New South Wales (NSW) over a six-year period. The treatment of waste rock dumps included the longitudinal results of one-off applications using: ViroMine Technology, including the application of a chemical reagent called Terra B, which is a benign, clay-like substance derived from processed bauxite and other sources lime and biosolids (added for nutrient value) clay capping and topsoil compared treatment outcomes from these three approaches to a control.Parameters measured in the program included leachate pH, total actual acidity (TAA) and chromium reducible sulfur (CRS), Al, Cd, Cu, Fe, Mn, Ni, Pb, Zn, and tree height and vegetative cover density with data collected at regular intervals over a six-year monitoring period. Findings over the life of the study indicated, for example, that leachate pH in the control area was 4.5 in year 1 falling to 4.0 by year 6; pH in the lime and capping treated waste rock was initially raised to about 5.5 after treatment but fell to 5.0 within 24 months and remained a low 4.7 by year 6; pH in the Terra B waste rock was 6.8 in year 1 immediately after treatment, and actually increased to 7.3 by year 6 with no further treatment. This finding is of relevance because it effectively profiles the acidity curves of waste rock control, lime, and capping applications, and shows that they decline over time, despite an initial æpH shockÆ to the solids as measured by TAA and CRS in the case of lime. Similar treatment curves were observed for heavy metal leachates. Tree height and vegetative cover density indicated that with increasing acidity in the waste rock dump, the lime and capping options did not allow healthy revegetation, but in the Terra B treated areas tree growth and density were comparable to background, undisturbed forest levels.is needed with respect to tailings management, based on a novel integrated research framework.CITATION:Fergusson, L, Blair, D and Barros, G, 2012. Sustainable waste rock remediation and revegetation - A real-world longitudinal study comparing ViroMine technology to standard applications and doing nothing, in Proceedings Life-of-Mine 2012 , pp 249-258 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 10, 2012

By W. G. Davenport

The remainder of this book develops and uses mass and heat balances to describe steady"state flash smelting. Its objectives are to: a) describe the many ways a flash furnace operator can produce specified products, e,g. 65% eu matte, 35% SiOz slag, 1500 K (b) determine the oxygen, air, flux and hydrocarbon fuel requirements of each method (c) show how the flash furnace can be controlled to give specified products with varying feed compositions (d) suggest how the flash furnace operator can maximize profitability while producing specified products. This chapter develops the basiC heat and mass balance equations of steady-state ?flash smelting. It then adapts the equations to industrial feed materials .and products. Lastly it determines the amounts of oxygen and flux needed to produce molten matte and 35% SiOz slag from chalcopyrite concentrate in an Inco oxygen flash furnace,

Jan 1, 2001

By Robert B. Johnson

The refraction seismic method has been used as an indirect means of exploring for fluorspar in southern Illinois by the Illinois State Geological Survey. Use of the method has been restricted to those areas where mineralization is associated with faults, a restriction necessitated by the operating principles of the refraction method. The seismic data enable the interpreter to locate fault zones in the subsurface and, under ideal circumstances, to make estimates of dip direction and magnitude and vertical displacement provided the local stratigraphic units are known and are geophysically recognizable. In this instance, refraction seismic exploration has been successful in the surface mapping of well-developed faults, both simple and complex with which fluorspar may or may not be associated. However, less clear results have been obtained where faulting has been less severe and where there are numerous accompanying mineralized joints.

Jan 1, 1964

By E. F. Vegman, Ndabezinhle Dube

"In the practice of conventional sintering, production is always afflicted with the problem of being unable to get a uniform quality of produced sinter in the bed. Invariably the top layer of the sinter cake is composed of weak but highly sinter, while the bottom layer is over-fused, forming a sinter that is very strong but less reducible. These symptoms point to a variable distribution of the heat balance in the process of sintering which results in a deficit of heat in the top layers of the sinter bed and an excess of heat in the bottom layers, due to an increasing input of regenerated heat in the heat balance down the bed. This causes losses in the productivities of the sinter machine and the blast furnace.The current work was designed to improve on the solution to the above problem through the establishment of a more accurate combustion zone heat balance of the sintering process. This development is mostly on the method of determining the regenerated heat input in the overall heat balance. Previous methods were based on the assumption that the width and the velocity of the combustion zone remain constant through out its whole life, which is not the case since tests have shown that both its width and velocity increase as the combustion zone moves down the bed. In this work, these factors have been taken into account. Tests and calculations using the model were carried out for haematite and limonitic ores. The high sensitivity of the model to changes in the sinter mix composition and sintering conditions was demonstrated.The results present the following prospects:• The minimum theoretically possible coke breeze consumption during the sintering of any type of iron ore fines, under any sintering conditions, can be established.• The model can be used to control the metallurgical quality of the sinter in any point in the sinter bed since calculation data includes desired basicity, combustion zone temperature and FeO content in the sinter produced."

Jan 1, 2001

By E. A. Sarver

The Fe(II) regeneration process is an important aspect of Alternate Anode Reaction Technology (AART) for copper electrowinning (EW). In AART, Fe(II) is oxidized to Fe(III) at the anode during EW, and it must be regenerated to maintain recyclable electrolytes. Regeneration is achieved via Fe(III) reduction by SO2(aq), and the reaction is catalyzed by activated carbon particles. To better understand this process, a kinetic model was developed and experimentally validated for the Fe(II) regeneration in the current work. The investigation focused on the primary reaction mechanism and the reaction rate dependence on four variables: carbon particle size, flow rate, initial Fe(III) concentration and initial SO2 concentration. The Fe(II) regeneration reaction is mass-transfer controlled in the presence of activated carbon. Carbon particle size and initial Fe(III) are the most influential factors under the conditions tested. Initial SO2 concentration is insignificant to the reaction rate.

Jan 1, 2007

By John Latilla

Exxaro Mining?s Matla Coal situated in Mpumalanga, South Africa operates two shortwall faces on the No 4 and No 2 seam while the No 5 seam has also been longwalled in the past. Severe strata loading events have lead to a number of serious roof falls on the wall face (facebreaks) resulting in safety threats as well as considerable production losses. In 2002 the No 4 seam shortwall suffered a facebreak restricted mainly to the tailgate side of the mining panel due to a thick, near surface dolerite sill not breaking properly. This was partly due to the premature suspension of longwalling in the overlying No 5 seam. The resultant overloading lead to severe pillar damage and subsequent bord collapse. Surface pre-split blasting was successfully used to relieve the pressure as well as to pre-condition the dolerite above the following two panels. The shortwall on the No 2 seam has experienced mid-face loading due to No 4 seam chain pillars lying over this area and creating a secondary cantilever effect. Pre-split blasting of the solid rock above the No 4 seam pillars has resulted in a significant reduction in the number of facebreaks. The panel layout of the No 2 seam was subsequently changed so that the chain pillars on both the No 4 and No 2 seam are superimposed whereas previously they were offset.

Jan 1, 2007

By V. Sheikhzadeh, M. Saghaeian, N. Esmaeili, R. Hejazi, A. Dehghani Ahmadabadi

High Pressure Grinding Rolls (HPGR) are mostly used prior to pelletising processes to increase the specific surface area (SSA) of iron ore concentrate. For expressing SSA, the Blaine index is utilised as one of the most important dimensional properties of iron ore pellet feed. ISO 21283 is a standard test method that explains the manual of Blaine air-permeability apparatus for determination of this parameter. In this standard, the disaggregation method is based on passing the minus of 1 mm samples from the 0.150 mm sieve. The disaggregation process has an effective role on the results of Blaine airpermeability test especially for regrinding HPGR products. In this research, firstly the Blaine index of samples was measured without disaggregation. Following this, disaggregation was done by passing the minus of 1 mm samples through three sieves with different dimensions, 0.150, 0.090 and 0.045 mm, separately, and the Blaine index was calculated for each one. Finally, lab-mill with rubber balls, called Jar mill, was investigated as another option. Screen analysis and image analysis with SEM were performed to evaluate the effects of the sample's disaggregation on the size distribution and agglomeration of samples. The results showed that the disaggregation method with sieve size 0.150 mm, according to ISO 21283, was not applicable for HPGR products because the particles were still stuck together. In addition, the disaggregation method with the sieve size 0.045 mm or with Jar mill offered reasonable results. Keywords: Disaggregation, Blaine index, specific surface area, regrinding HPGR, ISO 21283, Jar mill

Jan 1, 2020

By Jeff Jackson, Paul Axtell, David Graham

The Montana Department of Transportation recently awarded a contract to construct a replacement bridge across the Clark Fork River in Heron, MT. Both abutments and both intermediate bridge bents were to be founded on 6-ft and 8-ft diameter, permanently cased drilled shafts with rock sockets, respectively. Two drilled shafts per substructure location were designed for a total of eight drilled shafts. The original design included 6-ft diameter drilled shafts at the abutments but the Contractor elected to submit a Value Engineering proposal that increased them to 8-ft diameter. On the basis of the subsurface exploration program, extremely challenging subsurface conditions were known to exist, including the potential presence of large boulders within the predominantly sand and gravel soil matrix. The successful bidder elected to use an oscillator to install the permanent casing to the top of bedrock, while simultaneously removing the spoils from inside the casing with a clam-grab. On seven of the eight shafts, this approach worked well. Unfortunately, on one of the shafts, the casing met refusal on one or more boulders encountered in the predominantly sand and gravel soil overburden. Following several attempts, and despite several variations of approaches, it was determined that the casing could not be advanced beyond the obstruction without unacceptable risks to the pile-supported temporary work trestle (i.e., loss of soil and reduction in pile capacity for the foundations supporting the work trestle). To mitigate the problematic drilled shaft, a unique solution was designed and successfully constructed. The solution involved the construction of seven 16-in diameter micropiles constructed within the confines of the obstructed casing. The micropiles were drilled to bedrock through the sand, gravel, and boulders and include rock sockets to satisfy axial design requirements. The micropile casing thickness, grade and grout strength were designed to provide adequate flexural strength as well as to satisfy other design requirements. Upon completion of the micropile installation, the upper portion of the drilled shaft above the boulders and within the permanent casing was constructed as usual. This paper discusses the difficult subsurface conditions at the site, the drilled shaft construction difficulties, and the design and construction of the micropile solution.

Jan 1, 2018

By C. Samson, R. S. Smith, S. W. Hefford

"Abstract - Time-domain electromagnetic systems are most sensitive to highly conductive targets during the transmitter on-time. Data collected during the on-time is highly influenced by the geometric relationship between the transmitter and the receiver. Unless corrections can be applied for these geometric variations, the ability to correctly detect and identify highly conductive targets can not be fully realized. Variables affecting the relative position between the transmitter and receiver include changes in the position of the receiver with respect to the transmitter, variations in transmitter attitude, and transmitter loop deformation. The level of accuracy in the determination of the relative geometry required to permit complete removal of the effects due to geometric variations is different for each of the variables and is dependent on the depth of the target. The most influential geometric variation involves changes in the relative position of the receiver with respect to the transmitter along the direction of flight; this variable, therefore, requires the highest degree of accuracy. The accuracy required for receiver motions along the vertical direction is roughly one order of magnitude less, and in the lateral direction, several orders of magnitude less. The objective of this paper is to relate the sensitivity of the response to transmitter-receiver geometry to the ability of an airborne, time-domain electromagnetic system to resolve a highly conductive vertical target. This is achieved by a detailed analysis of the effect of the individual x, y, and z distances between the transmitter and the receiver, the transmitter attitude (roll, pitch, and yaw), and transmitter deformation.Sommaire - Les systèmes électromagnétiques en domaine temporel sont particulièrement sensibles aux cibles à forte conductivité durant le temps d’excitation. Les données collectées durant l’émission du transmetteur sont fortement affectées par les relations géométriques entre le transmetteur et le récepteur. Si un facteur de correction n’est pas introduit pour tenir compte de ces variations géométriques, la capacité de ces systèmes à détecter et identifier correctement les cibles fortement conductrices ne peut pas être pleinement réalisée. Les facteurs affectant les positions relatives du transmetteur et du récepteur comprennent les changements de position du récepteur relativement au transmetteur, les changements d’altitude du transmetteur et la déformation de la boucle du transmetteur. Le degré de précision requis pour déterminer la configuration nécesaire pour compenser complètement l‘effet des changements géométriques est différent pour chacune des variables et dépend de la profondeur de la cible. Les changements géométriques qui ont le plus d’influence sont ceux qui font varier la position du récepteur relativement au transmetteur dans l’axe de la ligne de vol; c’est donc cette variable qu’il faut contrôler avec le plus de précision. La précision requise pour le suivi des mouvements du récepteur le long de l’axe vertical est moindre d’environ un ordre de grandeur, tandis que selon l’axe latéral elle est diminuée de plusieurs ordres de grandeur. Le but du présent article est d’établir comment la susceptibilité de la réponse à la géométrie transmetteur-récepteur affecte la capacité d’un système électromagnétique en domaine temporel aéroporté à reconnaître une cible verticale fortement conductrice. Cet objectif est atteint par l’analyse détaillée de l’effet individuel des distances x, y, et z entre le transmetteur et le récepteur, l’attitude du transmetteur (lacet, roulis, tangage) et la déformation du transmetteur."

Jan 1, 2006

By J. C. Kerkering, J. C. Franklin, T. O. Meyer, R. W. McKibbin

A continuous survey of radon gas was made in two interconnecting stopes in a southwestern U. S. uranium mine to determine how the various phases of the mining cycle affected the radon concentration. The radon was monitored continuously with five detectors. One detector monitored the intake air, one the exhaust air, and three the stope air. The radon concentrations present during slushing, blasting, and exhaust fan shutoff were compared with concentrations on a nonwork day as a base level. Inside the stope, the radon concentration increased about 40% during slushing and 425% after blasting. Intake air radon increased 1600% and the stope air increased 550% while the surface exhaust fan was off.

Jan 1, 1979

By B. F. Naylor

"INTRODUCTION Investigation of the physical properties of electrolytic manganese and its alloys has constituted a part of the program of the Bureau of Mines for several years, and already extensive data have been reported. 3-14/ Heat-content measurements above 25° C. of pure manganese 15/ were completed recently at the Pacific Experiment Station of the Bureau, and the results obtained removed many of the inconsistencies in previously reported data. This paper reports heat-content data of seven manganese-copper alloys, varying in composition from 25 to 90 percent man-ganese. The alloys, obtained from the Salt Lake City Station, 16/ had been quenched from 850° C, and cold-worked. Without further heat treatment, heat-content measurements of each of these alloys were made at 100° or less temperature intervals from 450° to 850º C., as it was considered likely that any abnormal behavior of the specific heat would be found in this temperature range. Also, a portion of each alloy was heat-aged at given temperatures for periods of time thought sufficient to reach phase-equilibrium; then the heat-contents above 25° C. were determined at the aging temperatures. (Heat-aging was done at approximately 450°, 550°, 650°, 750°, and 850° C.)METHOD AND MATERIALSThe heat contents were determined by the ""drop"" method in a previously described apparatus. 17/ The calorimeter was cali-brated with electrical energy, measured in international joules, and the results were converted to the conventional thermochemical calorie by the relation, 1 cal. = 4.1833 int. joules."

Jan 1, 1946

By L. B. Slichter

Prospecting is certainly the world's biggest and best gambling business. It is a game where the chips cost many thousands and where many millions, even billions, can be won. An attractive feature of this gamble is the fact that the players are free to rig the odds as favorably as possible. Only the limited bounty of nature, the restrictions of the laws of the land, the competition from other players, the limited sagacity of the player himself— only these, and other factors, restrict the possibilities for large winnings. Today probably about half the land surface of the earth remains to be searched for signs of ore visible at the surface. It is fortunate that so much land still remains for exploration by relatively economical methods. Looking to the future, it is a good guess that the costs of finding ore will increase in response to increasing technical difficulties. To continue to achieve profits from prospecting, it will become necessary to analyze the business more skillfully, in a more and more sophisticated manner. Whenever feasible, qualitative concepts must be replaced by their quantitative equivalents, improvements, and extensions. THE GAMBLE The fact that prospecting is a gambling business reminds us at once of the elementary rule known as the law of gambler's ruin. I hesitate to mention so simple a rule in this company of experts. This rule expresses the rather serious chance of going broke when the odds for success are small, merely by a normal run of bad luck regardless of the long-run expectations of gain. The only sure way of avoiding this special risk of gambler's ruin is to have enough capital, and the will, to continue the play many times and thus ride out the inevitable runs of bad luck. For example, if the probability of success is one in ten for each venture, there is a 35 pct chance that ten successive ventures will fail in a row. But if one has the capital to continue the play through a run of 100 failures, then the chance of gambler's ruin is only 5 in 100,000. Almost any management, I suppose, would be under terrific pressure to cease the play during a long run of bad luck. To continue to prospect under such circumstances requires great confidence in the premises, and a firm conviction in the long-term expectation of profit. There is evidence which I shall mention that in the future even the strongest companies may not have the necessary capital to prospect on the ideal scale. Joint ventures will be very desirable as a means for extending the available venture

Jan 1, 1961

By Richard Mainiero, Donald A. Hurd, James H. Rowland

In previous conferences the authors have reported on toxic fumes generated by the detonation of ANFO. The research reported here extends the earlier work to include an emulsion blasting agent and ANFO/emulsion blends. Explosive mixtures were shot in 4-inch Schedule 80 steel pipe in a chamber in the experimental mine at the Pittsburgh Research Laboratory (PRL). Following each shot, the fumes in the chamber were analyzed using on-line instrumentation. A major goal of the research was to gain a better understanding of the factors that lead to the generation of toxic fumes in blasting operations. Earlier studies have suggested that the high nitrogen dioxide and nitric oxide concentrations in product clouds might be the result of the poor confinement provided by relatively weak ground strata or the exposure of the explosive to ground water prior to shooting the shot. Various mixtures of ANFO and emulsion were detonated in schedule 80 steel pipe and galvanized sheet metal pipe to evaluate the effect of confinement. Explosive mixtures were also allowed to soak in water for less than one day, one week, one month, and two months to determine which explosive mixtures would be degraded and observe what effect this degradation had on fume production. Results indicated that the production of nitrogen dioxide increased with low confinement of the detonating explosive and with exposure of the explosive to water.

By Luis Alva Saldaña

"Actualmente el método para descubrimiento de nuevos procesos y la elaboración de nuevas técnicas se ha modernizado. En ese sentido, el presente artículo señala la invención de estos procesos y técnicas a través del estudio de la Termodinámica. Esta ciencia trata de las relaciones entre las diversas formas de la energía, mostrando cuantitativamente los efectos que experimenta el complejo materia-energía cuando en él se realizaalgún cambio. Por ello, es fácil observar que muchos laboratorios tanto de Europa como de los Estados Unidos de Norteamérica, realizan estudios no sólo para completar las tablas de propiedades termodinámicas de las sustancias químicas, ya existentes, sino también para revisar los datos que antes se tenían de éstas."

Jul 1, 1955

By R. B. G. Yeo

The effects of alloy additions on the M, and A, temperatures of an Fe-22.5 pct Ni alloy have been determined. Increasing amounts of titanium, colum-bium, vanadium, and silicon raise and then lower M,while raising A, cmtinuously. Cobalt raises both M, and A,. Aluminum has little effect on Ms but raises A,. Chromium md nickel lower M, and A,. It is proposed that elements raise M, in accordance with their effect on the Ae3 temperature of iron until the lattice becomes stiffened against the shear transformation so that M, is then lowered. An anomaly, first pointed out by Zener,1 arises in steels when the addition of elements, such as molybdenum and tungsten, which raise the Ae3 temperature, also lower the M, temperature.2'3 During the development of a series of martensitic precipitation-hardening (maraging) steels, the effect of several elements on the transformation of austenite to martensite was studied. The results show that under suitable conditions several elements which raise Ae3 also raise the M, and A, temperatures. PREPARATION OF MATERIALS STUDIED A series of alloys was made in which cobalt, titanium, columbium, vanadium, silicon, aluminum, molybdenum, chromium, and nickel were added to an iron base containing 22.5 pct Ni. The compositions of the alloys prepared are given in Table I. The residual manganese contents of the heats were in the range of 0.030 to 0.35 pct, silicon 0.05 to 0.1 pct, carbon 0.0008 to 0.009 pct, and nitrogen from 0 to 0.004 uct. The allois were made as 50-lb induction heats starting with electro-iron and electro-nickel, melted in air to oxidize impurities. Additions of silico-manganese and ferro-silicon were made after which the power was turned off to allow the products of deoxidation to rise and be skimmed from the surface of the melt. The furnace chamber was pumped down to a pressure of 5 p and the charge was heated to 2900°F for the addition of other alloying elements. The heats were poured into five 10-lb ingots, making successive alloy additions to each. The ingots were soaked for 2 hr at 2300°F and hot-worked to 3/4-in.-diam bars. This stock was heated to 1500°F for 1

Jan 1, 1963

By C. Y. Wen, H. O. HOPMAN

l. INTRODUCTION. IN casting a thermal balance of the heat generated and absorbed in a blast-furnace treating lead-, copper- and similar non-ferrous ores, assumptions have always to be made for the values of the heat of formation of slag. ? Considering that the larger part of the charge introduced into the furnace comes out in the form of slag, the significance becomes apparent of a lack of heat-values for the singulo-silicate, which is the type of slags commonly made. The aim of the present investigation is to supply these heat-values as far as possible with the apparatus and the time available. The heats of formation of the ferrous and manganous bi-silicates have been determined by Le Chatelier; 1 those of some silicates other than iron and manganese by Tschernobaeff:2 finally Richards 3 gives a figure for a copper blast-furnace slag of known composition. The existing data and those resulting from the present investigation are assembled in Table VI. II. MATERIALS USED. The materials used in the experiments were silica, ferrous oxide, and calcium carbonate. Silica.-The silica sold in the market as chemically pure usually contains small amounts of magnesia, lime, and alumina, and is therefore not suited for the work. The pure material was obtained from clear quartz crystals from Arkansas, broken in a diamond mortar and ground in an agate mortar to pass 1 Comptes rendus, vol. cxx., p. 623 (1895); vol. cxxii., p. SO (1896). 2 Revue de Métallurgie, vol. ii., p. 729 (1905); Electrochemical and Metallurgical Industry, vol. iv., No. 2, p. 72 (Feb., 1906). 3 Electrochemical and Metallurgical Industry, vol. v., No. 7, p. 266 furls?, 1907;) ; Metallurgical Calculations, vol. iii.,.pp. 474, 475 (1908).

Jul 1, 1910

By Harold R. Larson, John F. Elliott

The standard free energies of formation of several nzetallic sulfides have been measured by a reversible electromotive-force cell employing stabilized zir-conia as the electrolyte. The oxygen potential at the cathode was fixed by the use of pure oxygen gas at 1 atm. It was established at the anode by bringing to equilibrium the reaction between the sulfide and oxide species present. Thus, Gf: for the sulfide could be obtained from the cell potential and the standard free energies of formation of the oxides participating in the reaction. The results in calories per cam rnole for the temperature range 850" to 1100°C are: Use of the reversible electromotive-force cell having an oxide-ion electrolyte to obtain the standard free energies of formation of some of the more stable metallic sulfides offers a convenient experimental method that is very productive. It also avoids some of the problems inherent in the experimental methods' for such studies which rely on precise determination of gas compositions, particularly if these compositions lie near the limits of our capabilities for accurate chemical analyses. The reaction equilibrium between the lowest sulfide of a metal, SO2 at a fixed pressure, and an oxide of the metal has a characteristic oxygen potential. For example: and for metals whose lowest sulfide is much more stable than the oxides of the metal, the equivalent reaction might be:

Jan 1, 1968