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By E. James Quinn

Solvent extraction technology using EHEHPA (2-ethylhexyl phosphonic acid, 2-ethyhexyl mono ester) is the norm for industrial separations of rare earth elements. This process has some shortcomings, including a large number of stages compared to most SX processes and high acid requirement for stripping of the heavy rare earths. In this work, we examine a number of alternative mixed solvent extraction systems: (i) Mixtures of organophosphonic and phosphinic acids such as EHEHPA/Cyanex 272 or Cyanex 572; (ii) Ionic liquid mixtures of EHEHPA with quaternary ammonium chloride (Aliquat 336); and (iii) Mixtures of carboxylic acids for yttrium/lanthanide separations. We discuss and compare the efficacy of these systems with reference to the Nd/Sm separation, which is of industrial significance. Based on the extraction chemistry and the use of modelling tools to define the counter-current solvent extraction circuit, we present a techno-economic analysis of a separation plant and discuss the impact of various solvent systems on the capital expenditure (CAPEX) and operating costs (OPEX).

By David Heyl

"El presente texto señala la evolución de los modelos genéticos de geología económica del yacimiento minero Tres Cruces. Dicho yacimiento se encuentra localizado en el noreste del Perú, adyacente al distrito minero de Quiruvilca. A partir del año 1995 se le reconoció como el mayor productor de oro a través de un programa de exploración en la Formación volcánica Calipuy. Posteriormente, el yacimiento fue visitado por variosgeólogos que postularon diferentes modelos genéticos del yacimiento para así estimar su potencial económico -en tanto se incrementaron los datos geológicos del yacimiento. Por ello, el texto presenta el modelo genético de Tres Cruces, como el más adecuado, aunque la evaluación de su potencial econornica está aún en progreso."

Apr 26, 1999

By Robert J. Timko

Because of leakage through and around permanent stoppings in underground mines, more air must be forced into a mine than would otherwise be required for ventilation. As power costs increase, costs resulting from air leakage add increasingly to the operating costs of mining. The Bureau of Mines evaluated four different stopping construction techniques based on the ideas that (1) airtightness could be enhanced by brushing rather than troweling on mortar sealant and that (2) modified mortars (mortars containing glass fibers and other additives for increased strength and adhesion) would improve sealing performance. Air leakage tests comparing conventional to modified stoppings were done when the stoppings were built, after 6 months, after 1 yr, and following simple maintenance. It was found that stoppings can be built and maintained better if-- The area where a stopping is to be built is properly prepared. Stoppings are constructed using the techniques devised by the Bureau. Stoppings are periodically examined for leaks. Stoppings found to be leaking, especially at the perimeters, are resealed.

Jan 1, 1983

By E. T. Pecina

Bioleaching is a viable option for the processing of auriargentiferous refractory ores with high arsenic content. The application of mesophilic (A. ferrooxidans and ?L. ferrooxidans?) and thermophilic bacteria of the genus Sulfolobus (S. solfataricus and S. acidocaldarius) as oxidant treatment before the cyanidation of an industrial arsenical pyrite concentrate is presented. The results show that extraction of gold and silver increases due to bio-oxidation caused by mesophilic bacteria and results in a maximum gold recovery of 68%. In all strains studied, biooxidation resulted in an average silver recovery of 50%. The results showed that all evaluated strains were sensitive to solids content (5 to 20%) and average particle size (75 and 38 µm) of the concentrate.

Jan 1, 2010

By Raymond S. Shrode

Transportation is one of several important increments in the total market cost of most commodities. On a national average it has been reported that transportation accounts for about 25% of the total cost of a product at the market place. And industrial minerals are no exception. In fact, the proportionate cost frequently exceeds the 25% average. Further, it may actually determine the economic value of a deposit. Transportation may possibly be thought of as a specialized subject of concern only to a traffic manager and of only nominal interest to the mining engineer, the geologist or other technically oriented member of mineral producers' staff. However, in the industrial minerals field, interest is not commonly confined to exploration, development, production or marketing, but is in contrast an overlapping one. In a very real sense this broad area of interest in the total economics of the business is the specialty of the industrial minerals man. And transportation is a vital part of the total picture. Comments in this paper deal with rail transportation.

Jan 1, 1969

By Haragobinda Srichandan

The present study aimed to investigate the bioleaching efficiency of moderate thermophilic microorganism in a growth medium without Fe supplement on three different size fractions of spent catalyst obtained from petroleum refinery. All the experiments were conducted on shake flasks at a temperature of 65 °C and a pulp density of 10% (w/v) on three size fractions viz. 45-106 µm, 106-212 µm and >212 µm and a working volume of 100 ml comprising of 10 ml of microbial inoculums and 90 ml of Modified Kelly medium. The parameters like pH, redox potential, viable planktonic cell count and the amount of acid addition was measured and quantified on regular basis to follow the progress of the bioleaching. The pH varied much in the lag and logarithmic phase of the experiments but stabilized toward the stationary phase. The total acid additions in each batch experiment were determined the amount of Conc. H2SO4 requirement, which ranged between 683-757 kg/ton of spent catalyst. The redox potential values ranged between 625-650 mV, Ag/AgCl, but were very low ranging between 350-450 mV during initial period. The planktonic viable cell count ranged between 108-109 cells/ml active in the bioleaching system, without any toxic influence of the spent catalyst, but initially due to fall in redox potential and new environment for the microbes, their population was low. The leaching yield of Ni was found to be promising with very high leaching yield of 92-96% followed by Al as 61-62%, which means both Ni and Al leaching were favored by the moderate thermophilic bioleaching compared to the mesophilic bioleaching. There was very little difference in the leaching yield, when compared with different size fractions and hence grinding can be avoided prior to leaching. This process seems to be economical as no Fe source is supplemented together with no requirement of grinding and over all a biological process resulting for an eco-friendly process for future optimization of the metal recovery from petroleum refinery spent catalysts. Keywords: bioleaching, spent catalyst, thermophile, 9K medium

Sep 1, 2012

By H. Hejny

Economy needs mineral raw materials in almost each sector of modern life. They can only be provided by mining activities. An increasing share of the total mining production will be by underground mining. The mineral deposits will be found at gradually greater depths, including all problems associated with them. It involves an increase in overburden pressure with subsequent rock stability problems and risks of structural collapse. There is a need for new and safe technologies for almost all parts of a modern mine. The mining industry faces a number of challenges which require technical solutions that encompass the entire network and include the economic, social and environmental issues. The industry needs a new image based on pioneering solutions and a modern structure that can exploit minerals at greater depths and promote both high productivity and safe working conditions. Funding has been secured from the European Commission for the I²Mine project. Work started in November, 2011. This initiative is designed to focus on the technological challenges that the mining industry is currently facing including the exploitation of ever deeper deposits and the aspiration for an invisible, safe, zero impact mine. The project comprises a consortium of 27 organisations from 10 European countries. I²Mine marks the start of a series of development activities aimed at realising the concept of an invisible, zero impact, deep mine. The extractive sector, still seen as being old fashioned and environmentally unfriendly, will show that mineral extraction and processing can be done in a highly innovative and sustainable manner with low impact underground and zero impact above ground. The concept of I²Mine is to develop innovative methods, technologies, machines and equipment necessary for the efficient exploitation of minerals and disposal of waste, all of which will be carried out underground. This will dramatically reduce the volume of surface transportation of both minerals and waste, minimising above ground installations and reducing the environmental impact. New eco-efficient technologies will be applied in order to make the entire mining process more efficient and environmentally sound. The concept is for an integrated mine, with the majority of the installations underground, and only the final product will be transported above ground to be shipped to the customer. Production waste will be treated and stored underground and gaseous emissions will be managed underground as far as practical. I²Mine will also focus on ideas and concepts that increase energy efficiency and decrease waste. The core of the project will be to develop breakthrough technologies for autonomous, highly selective, continuous mineral extraction processes and machinery based on new sensor technologies, face front separation as well as innovative concepts for mass flow management and transportation integrating state of the art technologies. The concept of an invisible, zero impact mine requires a refined process underground that selectively extracts the mineral thereby reducing waste. For this reason, improved extraction machines and near to face processing methods, including backfill procedures, need to be developed. These developments include rock mechanics and ground control solutions, incorporating health, safety and environmental issues.

Aug 1, 2013

By P. G. Clites

A laboratory furnace was developed by the Federal Bureau of Mines for use in studying the interrelationships among variables associated with skull melting and casting high-temperature metals. Although additional work is necessary to determine the extent to which the information obtained by using this furnace can be extrapolated to larger furnaces of the same type, many casting characteristics of metals and alloys can be determined on equipment of this size. This furnace is a laboratory-size, consumable-electrode, skull-casting furnace equipped with a water-cooled copper ladle. The ladle, which is a tilt-pour or over-the-lip type, has a volume of approximately 30 cubic inches and provides up to 20 cubic inches of molten metal for castings. Castings of various reactive and refractory metals, including zirconium, titanium, hafnium, columbium, molybdenum, tantalum, and tungsten, have been produced. In addition, castings of iron, chromium, and copper have been made. The simplicity and versatility of the apparatus would make it useful to metallurgical laboratories preparing cast specimens.

Jan 1, 1961

By J. P. Weiler

The increasing use of high-pressure die-cast magnesium alloys in the automobile industry requires a better understanding of the mechanical properties, the microstructure, and particularly, the relationship between these two. The goal of this study is to first understand the microstructural features which control the mechanical properties observed from an AM6OB magnesium alloy, and second, to be able to predict the local mechanical properties based on microstructural features encountered in different areas of the die-cast component. The two main tools used in this study are spherical indentation testing, used on local areas of the die-cast magnesium alloy AM6OB to detect changes in microstructure and mechanical properties, and X-ray tomography, used to non-destructively investigate the internal porosity in a sample. The results from these tests are then used to predict the local mechanical properties such as the yield stress, the strain-hardening characteristics, and the fracture properties of the AM6OB component.

Jan 1, 2006

By R. G. Johnston

Minerals have many uses in paint systems. These roles include use as primary and extender pigments, sheen control, film durability enhancement, and rheology control. These and other uses of minerals in paints, and the effects of mineral quality variations on coatings performance are discussed. As coatings performance requirements become more demanding, tighter consistency of important mineral properties, such as particle size distribution and purity, is becoming increasingly vital. Future directions of mineral use to meet projected environmental restrictions and performance demands on coatings, including the use of advanced minerals technologies, are examined.

Jan 1, 1993

By H. F. Zurbrigg

Introdduction The main line of ascent in the development of the nickel industry may be traced back through the International Nickel Company of Canada, Limited, to its earliest antecedents, the Canadian Copper Company and the Orford Copper Company. Mining geology is but one aspect of the overall development of this organization, and the stress it has placed on geology grew according to the need. In the early days, intensive geology was not required because ore supply was not one of the main problems of this or any of the pioneer companies. The difficulty then was to find economic methods for reducing the ores to nickel and copper, and markets for absorbing nickel in the face of a limited demand from consumers heavily prejudiced in favour of the New Caledonia product. "Very early in the history of the region it was patent to everyone that to share in the full benefits of the industry the same individuals or company must control the whole of the operation necessary to manufacture the finished product' (1, p. 45). These conditions were fulfilled for the International Nickel Company in 1902 when the Canadian Copper Company (incorporated 1886), with its ample ore supply, took the initiative to merge its interests with those of the Orford Copper (Refining) Company (incorporated 1887) to form the new company which, with reorganizational changes, emerged as the producer of the overwhelming bulk of the world's nickel. The Mond Nickel Company, Limited, entered the field in 1899 with a refining process, and over a period of years acquired ore through purchase of mining properties. This Company operated successfully and independently until 1929 when its assets were joined with those of the International Nickel Company in order to permit the most economic exploitation of the Frood-Stobie orebody in which both Companies were interested.

Jan 1, 1948

Risk management has taken on renewed vigor since the economic crisis of the late 2000s. The resources of governments, individuals, and corporations are being stretched to a point where only the most promising projects move forward. Risk management is a crucial part of the decision making process, yet it remains a broad term that includes disciplines from engineering to finance. A collaborative effort will be necessary to ensure that the most auspicious and appropriate projects are the ones moving forward. Risk management can be quantified to an extent by comparing the likelihood of an instance with the result of consequence of the instance occurring. In this manner it is possible to assign risk factors to instances and ultimately, begin to associate monetary value to the instance. Carbon sequestration is an emerging field that has a number of unique challenges. Risk management and mitigation must be an integral part of the overall picture. This begins with the planning and design phase, continues through implementation and production, site closure, and does not cease until termination of liability. The ability of carbon sequestration projects to successfully assess, mitigate, and recover from leaks will be a decisive characteristic of overall success. The costs of mitigation and failure will need to be analyzed on a test level, but will still need to be reliable enough to extrapolate to a commercial level operation. This paper will build a risk management profile based on case studies and field tests in Tennessee and Virginia. These tests are scheduled to commence in late 2013 and consist of small-scale injection tests in unconventional storage reservoirs with an emphasis on enhanced coalbed methane (ECBM) recovery and enhanced gas recovery. The ultimate goal will be to provide a clear and concise direction to move carbon sequestration from the test phase to commercial scale. While it is necessary from a risk management perspective to analyze all risk points, the scope of this paper will focus on pre-injection risk assessment for carbon dioxide (CO2) leakage potential. Despite the differences between the two tests, CBM compared to shale among other differences, a framework for analysis and mitigation can be developed pertaining to leakage risk. The probability of each type of failure will be assessed and analyzed, and plans to mitigate or reduce these risks will be reviewed.

Aug 1, 2013

By Randall D. Peterson

Strip mining with draglines and other surface equipment has traditionally been the method of choice for mining shallow deposits. This is particularly true for soft deposits that require little or no blasting. High rates of productivity and low operating costs have set this standard. However, these methods can be improved. Strip mining methods are batch processes and difficult to accommodate in processing. Moreover, they are encumbered with overburden removal, reclamation expense, and human inefficiencies. This paper describes the invention of a novel shallow earth mining technique called the Softwall Mining Method. Softwall Mining is an adaptation of longwall mining for loose earth conditions. The method was specifically invented for recovering phosphatic clay ore from beds in North Central Florida, but is likely to be suitable for a number of other minerals as well. Potential deposits for which the method may be well suited include placers, disseminated deposits in soft host rocks, bauxite, soft coals and lignite deposits, and other deposits where overburden will subside readily and where the ore can be hydraulically broken and slurried. Unit operating cost advantages are expected over the current dragline systems used. The Softwall mining advantages are its high rates of productivity, control and automation of the mining process, reduction of dilution and waste, and elimination of the majority of stripping and reclamation.

Jan 1, 1998

By David J. Kinneberg, Barbara E. Mangion, Arnold M. Savolainen

Analytical laboratories require a qualitative or semi-qualitative method of determining major and minor constituents in "unknown" samples to select optimal analytical techniques. This is exceedingly important in precious metal assay laboratories where the precision and accuracy requirements are exacting (routinely within 0.02%, absolute basis). This paper describes the use of an x-ray fluorescence spectrometer with a specially designed software package to select optimal analytical procedures and specify relevant analytical parameters. A wavelength dispersive XRF spectrometer is capable of quick and accurate analyses of properly prepared samples without extensive standardization. When coupled with a specially designed software package, this preliminary assay system is applicable to a wide variety of sample types including gold and silver bullion, karat gold and karat PGM alloys, high silver and high copper metallic samples as well as particulate samples of ores and sweeps. The system relieves the assayer of tedious calculations for silver inquartation and proofing, minimizes human error and standardizes selections over time. Most importantly, the system allows for independent verification of final assay results.

Jan 1, 1999

By Charles W. Huggins

To determine the nahcolite and dawsonite content in oil shales, the Bureau of Mines compared X-ray diffraction, infrared spectroscopy, thermal methods, and a previously published method by Smith and Young based on the selective solubility of sodium compounds. The Smith and Young method and a new method based on the weight of carbon dioxide produced by thermal decomposition are recommended for determining nahcolite. X-ray diffraction and the Smith and Young method are recommended for determining dawsonite. X-ray diffraction, infrared spectroscopy, and differential thermal analysis were useful for identifying other minerals in the samples.

Jan 1, 1973

By Henning R. Norbom

Lime has been produced for many centuries. The simple pot kiln was one of the first devices used in this process. It was constructed of stone often on the side of a hill to reduce construction efforts and provide easy access to the top for feeding of limestone. It was fired from below with wood and coal. The pot kiln was very small and operated on the batch principle. The kiln being cooled between each batch, the fuel consumption was horrendous. The lime quality was poor with perhaps only one half of a batch being lime of suitable quality. Of the remaining half one part would be over burned and another part underburned. For centuries the lime burning technique was improved at a barely recognizable rate. One of the first major steps forward was the introduction of the continuous process vertical lime kiln. Although at first crudely constructed, the kiln had a refractory lining. It was charged with alternate layers of limestone and solid fuel usually in the form of coke. Continuous mode of operation, larger unit size and better heat distribution resulted in greatly improved fuel economy. However, quality of lime produced still left much to be desired. One problem was contamination by ashes from solid fuel.

Jan 1, 1978

By V. A. Chanturiya

The results of development of new collecting reagents selectively interacting with the metals of platinum group (MPG) are presented. A new approach to the concentration of the platinum minerals from the fine grade platinum containing products with the use of cloud point polymers for the first time proposed for this purpose is discussed. An original method for the investigation of complexing reagents with the platinum under flotation conditions developed by authors is described. The influence of the complexing reagents on the xanthate adsorption and on the electrochemical properties of the platinum arsenide surface (sperrylite) as well with the interaction mechanism between the reagent and metallic platinum were investigated by means of the modern physical and physicochemical methods of the solid and fluid phase studies. The results of tests of some complexing reagents with the rich copper-nickel ore in the cycle of nickel-pyrrhotite flotation are given. The data obtained makes it possible to mark the complexing reagent containing phosphine group as the most effective additional collector for MPG. Cloud point polymers containing thioamide, aminosulphide, and phosphine functional groups were examined. It is shown that all the reagents tested increase the platinum and palladium extraction to the nickel-pyrrhotite concentrate without quality loss. Platinum containing particles flocculate selectively.

Jan 1, 2014

By C. F. Starr

This paper deals with the various types of cable in use in mines, with special attention paid to their construction. There will be a few comments regarding the different insulants, jacketing materials and armouring used, depending on their application. Governing standards and the differences therein will also be discussed.

Jan 1, 1969

By Michael D. Justason

"In January 2009, long-time competitors, Anchor Shoring & Caissons Ltd. of Toronto and Bermingham Foundation Solutions of Hamilton, joined forces to tackle one of the Greater Toronto area’s largest deep foundation projects: the West Toronto Diamond Rail Grade Separation. The two companies formed the “West Diamond JV” and succeeded in winning the contract from the Canadian National Railways. This deep foundations work was the first and most significant part of the $300-million-plus rail grade separation project. A big part of the job turned out to be dealing with local government regulations and citizens’ concerns with noise and vibration.The project is approximately 10 km (6 mi) northwest of downtown Toronto in an area of mixed-zoning including light industrial, commercial and residential buildings. The area is commonly called the “The Junction,” because of the heavy rail- traffic. The “West Toronto Diamond” refers more specifically to the railway junction where the North-South tracks of Canadian National (CN) Railway meet at a level crossing with the East-West tracks of the Canadian Pacific (CP) Railway. The goal for this part of the project was to convert the West Toronto Diamond into a grade-separated junction by depressing the CN lines under the CP lines, thus allowing commuter rail carrier, called GO Transit, intercity carrier VIA Rail, and CN freight trains to pass through the new underpass.Dawn Tattle, president of Anchor Shoring & Caissons says, “not only is the site in a densely populated area adjacent to homes and businesses, the crews worked adjacent to active rail lines with numerous trains passing daily. During the 7-hour working day, approximately 60 trains passed through the site in very close proximity to working crews.” Safety was paramount. While trains were passing through the site, it was a railroad requirement that all equipment and men stop working. In addition, at those times, all personnel were required to stay 6 m (20 ft) from the tracks and were required to face the tracks. For the faster commuter trains, this work interruption could last as little as 2-3 minutes, while interruptions caused by the slower freight trains could last as long as 25 minutes. The most disruption to the site occurred during the morning commute between 7 to 9 a.m., so work did not really get underway until after that time. Once work finally commenced the race was on to finish as much as possible before the afternoon commute – hence the shortened work day. The amount of disruption caused by the trains was a big unknown faced by the JV going into the project, but crews adapted quickly to the very unusual work environment"

Jan 1, 2012

By J. Noll, C. DeGennaro, C. Zhou, J. Srednicki

"The personal dust monitor (PDM) (model PDM3700), as well as other electronic devices, can cause electromagnetic interference (EMI) which can disrupt the operation of some proximity detection systems (PDSs). A 15 cm (6 inch) minimum separation distance between the miner-wearable component (MWC) of the PDS and the electronic device usually avoids these disruptions, but due to the amount of equipment on a miner’s belt and the method of wearing the PDM in some situations, this distance can be difficult to always reliably maintain. Another method of reducing EMI effects is utilizing magnetic field shielding. The shielding capability of several different materials was investigated by surrounding the PDM with the material and quantifying the EMI. A copper mesh pouch reduced the EMI from a PDM3700, allowing a minimum separation distance of 10 cm (4 inches) instead of 15 cm (6 inches) as shown in a previous study for an unshielded PDM. A MU-metal box had a better shielding effectiveness, as it further reduced the minimum separation distance to less than 7 cm (2.8 inches). Shielding reduced the EMI of the PDM with MU-metal providing better results than the copper mesh. These materials may be beneficial for shielding individual components of the PDM or for constructing a shielded pouch. However, before the advantages of a shielded pouch can be determined, the effects of just the shielding material (metal) on the PDS needs to be quantified. INTRODUCTION According to statistics from the Mine Safety and Health Administration (MSHA), 43 miners have been fatally struck or pinned by a continuous mining machine (CMM) since 1984. In an effort to prevent future striking and pinning fatalities from occurring, proximity detection systems (PDSs) have been developed and are required on all operating CMMs in underground coal mines, with the exception of full-face CMMs, by 2018 (MSHA, 2015)."

Jan 1, 2018