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By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

By T. Urbancic, Eric von Lunen, G. Viegas, A. Baig

"The characterization of the failure process of induced fractures by hydraulic stimulation is fundamental to understanding the generation and evolution of the discrete fracture network within the reservoir. A more detailed analysis of the fracture mechanism can be a powerful tool for identifying fluid flow paths and proppant placement within the reservoir. For example, during the rupture process the energy release is partitioned into different physical processes for which the relative ratio is changed by the presence of fluids or rotations in the local stress field with relation to the frictional resistance in the fracture plane. Fractures occurring in the same host rock under the same stress conditions are expected to rupture similarly, independent of their size (self-similarity). Changes in the scaling relationships of fractures are indicative of a change in the failure process, host rock or in-situ stress. Correlation of failure process data with reservoir rock properties and the in-situ stress field will help identify regions within the reservoir with characteristic types of failures. Further correlation with hydrocarbon production data can be used to develop efficient treatment plans and production diagnostic tools.In this study we investigate the failure process of ~27,000 microseismic (M < -1) fractures induced during a hydraulic fracturing shale completion program in NE British Columbia, Canada by estimating static and dynamic source parameters, such as dynamic and static stress drop, radiated energy, seismic efficiency, moment tensor, fracture plane orientation, slip direction and rupture velocity. On average, the microseismic events have low radiated energy, low dynamic stress and low seismic efficiency, consistent with the obtained slow rupture velocities. Events fail in overshoot mode (slip weakening failure model), with fluids lubricating faults and decreasing friction resistance. Events occurring in deeper formations tend to have faster rupture velocities and are more efficient in radiating energy. Variations in rupture velocity tend to correlate with variation in depth, fault azimuth and elapsed time, reflecting a dominance of the local stress field over other factors.Further identification of spatial and temporal distribution of families of events with similar characteristic rupture behaviors, based on either rock formation, depth, source type, fracture plane orientation, stress drop, pad or proppant stage, may be used as a proxy for specific fracture network development and hydrocarbon production. This information may be used to determine reservoir properties, constrain reservoir geo-mechanical models with measured physical parameters, classify dynamic rupture processes for fracture models and improve fracture treatment designs. These will be the focus of future studies."

Jan 1, 2015

By Jack G. Croeni

The Bureau of Mines developed a method to extrude low-density tungsten powder billets into rods and sheet bar with high-energy-rate forming equipment. Billets were compacted and sintered in an atmosphere of hydrogen to obtain a density of approximately 60 percent. Extrusion was conducted at reduction ratios of 6.25 to 1 and 9 to 1 at 1,800° C to prod e high-density, sound material. Yield strengths obtained were higher than those of material produced by conventional powder-metallurgy techniques, but ductility was lower at high temperatures.

Jan 1, 1966

By Tamara Matveyeva, Tatiana Ivanova, Nadezhda Gromova

"The paper presents the results of study of the sorption and flotation properties of the reagents of plant origin - tannin and natural extracts of the oak bark and stems of plants, with a view to their application as a low-cost environmentally friendly modifiers of iron sulfide flotation for the recovery of minerals containing precious metals. The technique of preparation of plant extracts with a fixed content of extractable tannins has been developed.The mechanism of flotation reaction of tannin extracts has been identified as based on their adsorption on the surface of pyrrhotite and arsenopyrite to form strong complexes with iron (III) at concentrations below micelle concentration. It has been found that adsorption of plant extracts occurs without displacement of primarily adsorbed xanthate, and preliminary adsorption of xanthate did not preclude fixation of tannin on the mineral surface.It has been shown that plant extracts having hydrophilizing properties at low concentrations could be applied as selective depressants for pyrite, pyrrhotite and arsenopyrite in a weakly acidic, neutral or weakly alkaline medium. The use of plant modifiers could help to increase the quality of gold- and platinumcontaining concentrates and reduce the ecological impact on the environment."

Jan 1, 2014

By T. Kessler

As part of a respirable mine-dust research program at the U.S. Bureau of Mines, spark-source mass spectrometry has been used for the semiquantitative determination of trace elements (200 ppm weight or less) in raw coals. In addition, several minor and major elements have been determined using this technique. Sixty-four elements ranging in concentration from 0.01 to 41,000 ppm weight were determined in one anthracite, two mvb, four lvb, and six hvab raw coal samples. The samples represented 10 coal seams located in Pennsylvania, West Virginia, Virginia, Utah, and Colorado.

Jan 1, 1973

By PETER ROBINSON, KEVIN BARBER, OLIVER WHATNALL

Investigation and uptake of filtered tailings continues to grow throughout the globe. This is driven by a wide range of site-specific considerations, which include such factors as tailings characteristics (e.g., amenability to filtration), production rates, climate, water availability, cost drivers, environmental requirements, and social factors. Despite the aforementioned technological growth, the currently available filtration technology is not able to meet the needs of many operations and projects that would otherwise adopt the technology. Experience with large-scale industrial filtration shows that vacuum belt filter systems meet the needs of many modern users, exceptions being the inability to effectively dewater tailings at altitude and/or with a fine particle size distribution: a potential fatal flaw. This paper presents a case study on the utilization of the patented Viper Filtration technology on gold tailings to overcome this challenge and shares the resultant full-scale plant design, highlighting the features designed to overcome cost and scalability deterrents. This technology is a novel mechanical process which complements the vacuum pressure in dewatering the filter cake as it travels along the belt filter. This project commenced with a pilot testing program, which successfully met the objective to rigorously test, measure and record any performance improvements achieved when engaging the Viper technology. Of the two tailings products tested, gross improvements of 4.2%w/w and 5.7%w/w were achieved when compared to the conventional vacuum belt filter operation. This pilot testing facilitated measurement of operating and design data, which forms the basis of the full-scale system design and resultant equipment supply of three vibration roller assemblies for retro-fitting on the existing vacuum belt filter.

Jan 25, 2021

By Athul Prabhakaran, Ramin Motamed, Ahmed Elgamal, Milad Jahed Orang, Reza Boushehri

Documented case histories from past earthquakes have exhibited the devastating effects of the liquefaction phenomenon on the performance of buildings that are often presented in the form of excessive settlement of shallow foundations. Example earthquakes include the 1964 Niigata earthquake in Japan, and more recently the 2010-2011 Canterbury Earthquake Sequence in New Zealand, and the 2011 Tohoku earthquake in Japan. All of the listed events comprised several examples of severe liquefaction-related damage to the buildings founded on shallow foundations. Although the liquefaction-induced building settlements have been experimentally studied extensively since 1964 using shake table tests and dynamic centrifuge experiments, studies focusing on cost-effective mitigation strategies are still limited. In this study, the performance of helical piles as a cost-effective countermeasure to minimize the damaging effects of liquefaction-induced ground settlements on buildings founded on shallow foundations is studied. Two large-scale shake table experiments were conducted at the University of California, San Diego (UCSD) to investigate the effectiveness of helical piles in liquefiable grounds. Results from these two experiments highlight a highly improved performance of a shallow foundation supported on helical piles. These largescale shaking table experiments demonstrate the efficiency of using helical piles as a cost-effective countermeasure to reduce the liquefaction-induced building settlement.

By Frederic Benard

THE Ontario Refining Company, Limited, wholly-owned subsidiary of The International Nickel Company of Canada, refines the entire blister copper output of the latter&apos;s Copper Cliff smelter. Prior to 1936, the blister was cast in 460-lb. cakes at the smelter, loaded on open cars, and transported by rail to the refinery, a distance of approximately 1 1/4 miles. Here the cakes were transferred to the plant narrow-gauge system, charged to furnaces, and re-melted. This procedure necessitated the operation of holding furnaces and casting machines at the smelter -extensive re-handling-and melting down of a cold charge at the refinery. Transfer of the copper in molten form direct from converters to anode furnaces promised a considerable reduction in costs, and this possibility was investigated. As a result, a portable holding furnace, or hot-metal car, was designed and constructed. It was placed in operation in July, 1936, to be followed a year later by three additional units of slightly modified design. Figure 1 shows the original car, and Figure 2 the lacer type. With four cars in service, operations were placed on an all &apos;hot-metal&apos; basis.

Jan 1, 1938

By Luis Fernandez-Deza, James Hawn, Dustin Mount, Jean-Marc Wehrli

The RiverRenew Tunnel System project in Alexandria, VA forms part of a CSO scheme aimed at reducing overflows of combined stormwater and sewage into the Potomac River during storm events. A major piece of the project is a 12-foot internal diameter tunnel of approximately 12,000 feet length lined with a single-pass precast concrete segmental liner and excavated by an Earth-Pressure Balanced Shield TBM. The tunnel lies between 120 to 140 feet below grade in the clays of the Upper Potomac Formation with occasional dips of more granular, saturated soils of the Terrace Formation and the Alluvium. The TBM is launched from a figure-8 configuration Pumping/Screening Shaft located within AlexRenew’s operational Water Resource Recovery Facility. This paper discusses the challenges encountered during the launch of the TBM in short mode within a highly congested site and from narrow deep shafts.

Jun 13, 2023

By Lucia Vieira

Kelvin probe force microscopy (KPFM) can be used to monitor electrostatic charges on the surfaces of materials. In this paper, we describe the use of KPFM to evaluate the electrostatic effect induced by silver nanoparticles incorporated as clusters in diamond-like carbon (DLC) films, before and after scratching. The results are compared to those obtained for DLC films without silver nanoparticles. Raman spectroscopy was used to identify the DLC signature, and energy dispersive X-ray spectroscopy (EDX) was used to confirm the presence of silver in the film. The morphology of the DLC film containing silver was investigated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The findings suggest that the incorporation of silver nanoparticles in amorphous materials could offer new options for electrostatic energy storage on the surfaces of these materials.

Jul 31, 2018

By E. E. Maurer

Kerr-McGee has operated the Ambrosia Lake uranium mill since startup in 1958. Tonnage milled per day has varied from 3500-7000 tons. The mill capacity is currently rated at 7000 tons per day. The process consists of two parallel circuits following crushing and sampling, \\lhich include open circuit rod mill grinding, sulfuric acid leach, cyclone classification, and counter-current washing circuits of sand classifiers and slime thickeners. Pregnant solution is clarified and polished by precoat pressure leaf filters prior to amine solvent extraction. Yellowcake is precipitated from the pregnant strip solution with ammonia, filtered and dried.

Jan 1, 1972

By Yuting Xue, Todd Minoski, Daniel Su, Mark Van Dyke, Mark Mazzella, Steve Hicks, Zoheir Khademian, Nicole Evanek

Design of chain pillars in a longwall mine setting is one of the main engineering controls on the global and local stability of the mine. Challenges with roof instabilities, floor heaves, and pillar failures can be alleviated, to some extent, by careful design of gateroad configurations and chain pillars. This work investigates three different alternative designs in a three-entry-system gateroad configuration with an inter-panel barrier in a longwall mine in Virginia. Starting with the current design, which has faced challenges such as excessive floor heave, a geomechanical model developed in 3DEC software is validated by monitoring in-situ pillar stress in the yield, abutment, and barrier pillars in the mine. Next, three different chain pillar designs are evaluated in the model with a focus on roof sagging, floor heave, and pillar average stress. Results show the relationships among the alternative designs and instabilities associated with roof, pillar, and floor in the study mine, providing insights for optimizing longwall mining designs in deep-cover settings.

Feb 1, 2025

By C. Mattich, A. L. Beyzavi

The Waelz Plant at Taiwan Steel Union Co. Ltd. (TSU) was erected within nine months from September 1, 1998 to May 15, 1999. The nominal capacity of the plant is 50,000 tonnes per year of electric are furnace dust (EAFD). The plant, consisting of material handling, a waelz kiln, a waste gas cleaning system, waelz oxide leaching and waste water treatment, was commissioned within three months from July 1, 1999 until October 12, 1999. The specific problem of the plant is the high chlorine content in the EAFD pellets which is up to 6 %. Lurgi Metallurgie GmbH, Frankfurt, Germany was responsible for the engineering erection and commissioning of the plant.

Jan 1, 2000

By Zachary E. Wedding, Zach Agioutantis

Excavation of underground openings results in the redistribution of the in situ stress into the rock adjacent to the opening. Stress redistribution depends on opening geometry, pillar geometry, material properties, possible confinement, and constitutive models describing the behavior of adjacent rock. This paper presents typical pillar stress distributions for elastic and yielding pillars as a function of opening geometry, material properties, and material constitutive models and highlights the differences between them. Stress distributions are compared with empirical strength profiles that have been developed for coal pillars as well as actual pillar geometries documented for stone pillars.

Jul 1, 2023

By P. R. Khangaonkar

The industry of tin ore mining, beneficiation and smelting gives rise to a number of waste products like the beneficiation plant wastes (called amang), tin smelting slags, refinery dross etc. Some of the wastes deserve treatment to obtain economically useful products or to recover the metal values. The paper describes studies conducted on two materials, viz., struverite-middling (struverite-magnetic tin), which is an intermediate product of beneficiation circuits of tin tailings, and tin-smelting slags. The struverite middling was studied for treatment by chlorination using carbon tetrachloride, so as to yield vapour products separable by convenient condensation. The treatment was also found to lead to a tin-rich product amenable for treatment by known hydrometallurgical routes. The tin smelting slag was studied by alkali-leaching so as to avoid any dissolution of iron and it was possible to obtain an iron-free product solution suitable for high purity tin recovery.

Jan 1, 1996

By K. J. Shelswell

This work describes the design, analysis, and comparison of discrete simulation and static spreadsheet models developed to compare the oreflow efficiency of two conveyor-based material handling systems; one approach with a conveyor stream in series and one with parallel conveyor streams. Analysis and comparison indicated that daily rates were significantly affected by random conveyor failures in both designs. The compound effect of random failures limited the effectiveness of long belt assemblies in series, while the parallel conveyor stream design partially alleviated this constraint. The static spreadsheet model predicted a lower average daily oreflow rate for the series conveyor stream design and a higher average daily oreflow rate for the design with parallel conveyor streams when compared to the discrete simulation results. These discrepancies were the product of model sensitivity to operational factors incorporated in the system and provided the opportunity to further use the discrete simulation models for trade-off comparisons and sensitivity breakdowns of mine operating practices and material handling system efficiencies in both the series and parallel belt stream designs

Feb 23, 2014

By Robert P. Harrison, Marie-Christine Patoinel, Kristian E. Waters

This paper describes a collaboration between McGill University and Hatch Ltd. to expose undergraduate students to real-world industrial projects. As part of the final-year design course, the students receive a detailed lecture on Scale-Up of New Technologies&apos;, including seven case studies drawn from over fifty years of full-scale industrial projects. The students are taught the basic concepts of scale-up, including the limits of pure theory and the need for empiricism. Insights from real scale-up failures and successes are fictionalized as Projects A, B, C, etc. The students are then asked to identify the guiding principles that can be distilled from these case studies.

Jan 1, 2011

By Eugene Guccione

Australia could eventually become a major world supplier of uranium oxide-but how quickly that happens depends on the outcome of a highly complex and emotional battle among different special interests.

Jan 1, 1977

By Hongxu Li, Zhaobo Liu, Zihan Zhao

A completely new process of selectively recovering Sc3+ without impurity of Fe3+ from Bayer red mud was developed. Prior to water leaching process, red mud needs to be digested and sulfated at a low temperature and subsequently roasted at a higher temperature for a period of time. During the roasting process, the products such as SO2, SO3 and H2SO4 molecules of thermal decomposition of sulfites including NaFe(SO4)2 and NaAl(SO4)2 could be recycled and reused as the raw materials of sulphuric acid. The leaching results indicate that roasting temperature and roasting time are the main constraint on selective leaching performance of scandium. As the sulfated red mud sample is roasted at 750 degrees C for 40 min and subjected to water leaching at 50 degrees C for 30 min, 53.0 wt% Sc3+, <1.0 wt% Fe3+, <0.3 wt% Si4+ and ~8.9 wt% Al3+ could be leaching out. Of note, the solid-liquid separation process is quite easy to be carried out.

Mar 1, 2017

By K. T. Brashear, N. Ripepi

"Over recent years, specifically following the MINER Act of 2006, an increasing number of manufacturers of underground mine seals in the United States have begun using a form of pumpable cement or shotcrete to create barriers separating the working and abandoned sections of underground coal mines. This seal material, while generally considered to be homogenous and solid, contains a network of microcracks, voids, and delaminations. Generally, it has been assumed that methane (CF4) leakage around these seals is a result of movement around the boundary interface between the seal and surrounding strata. Using a perfluorinated tracer compound, perfluoromethyl-cyclohexane (PMCH), the movement of gases can be monitored through seal material to observe how gases move though the material, both intact and with faulting in the material. This paper documents two large experiments where the movement of PMCH was monitored in the field, along with modeling confirmation using 3D visualization software. INTRODUCTION According to a report in 2007, there were over 14,000 active mine seals in underground U.S. coal mines alone (Zipf, Sapko, & Brune, 2007). These seals are used for both ventilation and safety purposes, to direct the flow of air away from the abandoned area of the mine and to help eliminate the propagation of explosions that can occur on the outby side of the mine seal. The atmosphere on the outby side of these seals typical consists of low levels of methane that have the potential of producing leakage along the face of the seal on the inby side. Methane leakage around mine seals has historically been attributed to the permeability between the seal and mine interface (McPherson, 1993). According to the United States Bureau of Labor Statistics (BLS) between 2003 and 2012 an average of 17 deaths occurred annually in underground bituminous coals mines. The only time during the ten-year period where the fatalities were higher than the average was in 2006 and 2010, years which had three major explosions occurring in underground coal mines in West Virginia and Kentucky. Two of the explosions were propagated through the mine by seal failure or methane leakage around newly poured seals (Light, et al., 2007) (Gates, et al., 2006). These recent events, and new regulations regarding seal strength (MINER Act), have created a need to monitor the condition of underground mine seals. BACKGROUND Measuring the permeability of solid materials, such as concrete or seal materials, can be a valuable tool in the field of non-destructible testing (NDT). By using an inert gas, such as nitrogen, injecting the gas into a solid structure, and measuring the resultant flow rate and pressure differential, this can provide valuable information about the structure. Studies have shown permeability can be affected by the stresses applied to the structure, as well as temperature and moisture (Choinska, Khelidj, Chatzigeorgious, & Pijaudier-Cabot, 2007) (Abbas, Carcasses, & Olliver, 1999)."

Jan 1, 2015