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By R. Bryce, T. J. Doughty, K. Stoll

Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Ca6Al2(SO4)3(OH)12•26H2O Ettringite readily precipitates in high pH water and by doing so, removes sulfate from impacted waters. The SAVMIN process, piloted in South Africa, is one method to produce ettringite. In this process, aluminum hydroxide is the aluminum source. The Cost Effective Sulfate Removal (CESR) process is similar to SAVMIN, but uses a proprietary aluminum source instead of aluminum hydroxide. Outotec and Veolia also have their own versions of the process using their specialized process equipment. TWC patented a version of ettringite precipitation using metallic aluminum as the aluminum source for ettringite formation. The benefit of using aluminum metal is that no additional ions are added to the process. At high pH, the raw aluminum corrodes in water causing hydrogen gas generation as the water is chemically reduced. This reaction is shown below:

Jan 1, 2019

By Steven M. Puricelli

Sulfuric acid plants associated with smelters, have historically been an overworked and often neglected pollution control device. They could do little more than manage the wide fluctuations in gas flow and SO2 strength from the smelter. With the introduction of flash smelting, the picture began to change, but the fluctuating batch converters continued to dictate acid plant design. More recently, the commercial use of continuous converting processes utilizing high levels of oxygen enrichment has dramatically upgraded the SO2 strength and stabilized the gas flow to the acid plant. The SO2 gas now issues continuously and at concentrations that allow for compact and, cost effective acid plants. Relieved of the burden of excessive dilution air, the heats of reaction can also be recovered as medium pressure steam and used to drive a generator, making the acid plant a net producer of power and a valuable asset to balance sheets. This concept was put into practice at the Kennecott Utah Copper Corporation smelter modernization project, located in Salt Lake City, Utah. The new acid plant, which was commissioned in June of 1995, is a sophisticated, low environmental impact, energy producing plant, worthy of review. This paper examines the key features of this acid plant, such as controlling its tail gas, by catalysis alone, to an environmentally friendly, 100 ppm of SO2, while feeding the acid plant converter with an efficient 14% SO2. The acid plant is also a prudent steward of energy resources, recovering 220,000 lb/hr of 140 psig steam from process heat which is used to generate a substantial 20 MW of gross power. Also discussed will be some of the ongoing issues, such as handling of selenium and fluorine in the gas cleaning sections, as well as a review of some. of the problems that were identified and resolved. Today's modem acid plants, by necessity, are becoming a producer of quality, valuable products, making the acid plant an asset and not a liability. Plants like Kennecott are already gaining wider acceptance and are expected to be the vision of the future.

Jan 1, 1998

By R. Havens

During investigations of the occurrence of manganese in the western United States in the early 1940?s, examining engineers of the Bureau of Mines collected samples from seven claims and mines in southern Arizona. For convenience in reporting the results, the work on the properties is grouped in three districts. As the ores were too low grade to be acceptable to producers of ferromanganese, beneficiation studies were made to determine the amenability of the ores to concentration. The San Fernando group is about 10.5 miles south of Patagonia in the Harshaw mining district. G. T. Humphries and D. Alonso held an option on the property, which was owned by H. Bender. Two samples were taken; 1 was a picked sample and the other a representative sample of ore as exposed in the mine.

Jan 1, 1954

By Paul Culvenor, Brad Gyngell

Large language models (LLMs) have generated a lot of hype since ChatGPT was released in early 2023. In essence, they allow people to interact with computer systems through natural language and have the ability to generate highly complex text, images and videos (Patil and Gudivada, 2024). It is clear that this technology has significant potential, however most mining companies have not yet found practical applications for it within their operations. In this paper, we present a range of such applications along with the tactical considerations associated with developing and implementing them. We have identified use cases across a variety of operational and functional areas within the mining industry and evaluated them based on their potential business value and ease of implementation. Firstly, we provide an overview of how LLMs work and a review of how LLMs are being applied in other industries to provide best practice inspiration for mining. Next, we present a list of possible applications in mining and a critical assessment of each use case. This section also includes a technical deep dive into the different methodologies for developing the technologies as well as an analysis of barriers to adoption within mining organizations. Finally, we share a discussion of the potential path forward for LLMs in mining and the impact they could have on the industry. We analyze the potential differences between early adopters and laggards in the artificial intelligence (AI) space. This research draws on interviews and surveys with artificial intelligence experts as well as mining subject matter experts to connect cutting edge thought leadership with the specific problems faced by our industry.

Feb 1, 2025

By D. W. McDonald

Coal mining and railway transportation are so closely en-twined and so dependent one upon the other that the failure of one would mean the total collapse of the other. With this indisputable fact in mind, there is no doubt that the operator of each is deeply interested in the other's success. Railway transportation began at the mouth of a coal mine. The first railway car was the English coal-wagon, a crude box on four wooden trowlets, running on wooden rails and holding 1,600 pounds. This was operated by gravity or horse-power in England to convey coal from the mines to the rivers. The first coal-cars used on Nova Scotia railways were of 4 tons capacity with side doors and "V" shaped centres. Then followed flat-bottom, 4-ton cars that operated on tipples, the car bei.ng held in tipple by a chain passing over the top and fastened on either side. Next came the 6-ton car with drop-bottoms, then the 10, 15, 30-ton cars, and now the modern 50 and 100-ton steel cars, equipped with automatic couplers, brakes, and rachet dumping device. Contrast the first coal-car with a modern luxurious pull-man or a I 00-ton coal and ore car, and you have a record of progress in railway transportation. The development of the steam locomotive was no doubt the greatest factor in this progress, but let us not forget that the foundation of all industrial development was and is coal. and that development in mining and railway transportation should keep abreast.

Jan 1, 1924

By A. Haghighat

The Missouri University of Science and Technology?s (Missouri S&T) Experimental Mine is a teaching and research facility which has been excavated in limestone by mining engineering students over almost 100 years. The mine is currently being extended to a second level. Available fans for ventilation are two surface fans of 24 kW and two underground booster fans of 12 kW. The design of a ventilation network in conjunction with multi surface fans and booster fans entails a complex procedure. Ventsim Visual software modeling has been used for network analysis to determine the optimum surface and booster fans locations, blade settings, and speeds. Both natural and mechanical induced ventilation pressures have been taken into account. Three working faces on each level have been designated as target points that minimum air quantities are required. The model has been calibrated against a pressure and quantity survey. Design of ductwork, door/stopping positions and different fans characteristics have been examined. The optimum flow rate at identified working faces, efficiency and minimum energy losses and annual network power cost determine the best scenario. The optimum design has been determined for the ventilation network for the next 100 years. The optimum flow rate across working faces is the key criterion selected.

Feb 23, 2014

By Carla Lupi

Zinc electrowinning from sulfate solutions is the traditional industrial method to produce SHG zinc. Over the past few years several efforts have been done to improve process efficiency in order to reach high productivity with low energy requirement. The latter aim can be pursued both by means of a hard purification of the electrolyte and reducing the anodic voltage. This work is a comparative study of the results obtained in several previous researches on zinc electrowinning from both sulfate and chloride solutions. Zinc electrowinning tests on industrial sulfate solution have been carried out by using Pb alloy anodes and by adding organic depolarizers such as ethanol, acetic acid or ethylene glycol. Experiments on chloride solutions, obtained by purification of zinc exhausted electrolyte, have been performed by using DSA anodes and by testing the effect of additives such as TEACI and TBAC\. Comparing the best results obtained with the two methods it can be highlighted that a high quality zinc is electrowon in both cases with comparable energy requirements.

Jan 1, 2000

In spite of the efforts done in the past to implement in Codelco best practice guidelines and standards on several important sampling, assaying and variability issues, many people, particularly top managers and operators, are still not aware of the relevance of the use of the principles and practice of geostatistics, sampling theory, analytical chemistry and the understanding of processes variability from rock to cathodes. As a result, an important challenge for the sampling community is to find out the causes of this lack of awareness and to develop communication skills to influence the organisation, particularly the top management level. This situation is not affecting only Codelco; it is a common characteristic of the copper mining industry. The main cause is cultural. Judeo-Christian and occidental sciences are deterministic. This implies a disregard of process variation and the assumption that homogeneity is omnipresent. Another important aspect of the cultural challenge is education. Education is the most efficient way to transfer a system of ideas, traditions and practices. To implement proper courses of sampling theory and geostatistics and support to multidisciplinary education at universities, mining companies will improve teamwork between geologists, mining engineers, metallurgists and chemists. The improvements will imply a more sustainable and efficient mining business.

Mar 1, 2010

By Glenn E. Johnson

The Bureau of Mines investigated the production of hydrogen cyanide by reacting powdered coal (minus 300 mesh) with ammonia at 1,250° C in a bench-scale study. Both metallic and ceramic reactors were used. Yields up to 0.7 cu ft of hydrogen cyanide per cubic foot of ammonia consumed r- obtained. The resulting ammonia conversion of about 75 volume-percent approximates conversion obtained commercially in processes utilizing natural gas and platinum catalysts. The coals that had higher volatile-matter contents gave the best yields of hydrogen cyanide. Allowing the coal to adsorb ammonia before reaction resulted in increased yields of hydrogen cyanide. Cost studies for a plant with a 40-million-pound-per-year capacity indi-cate that hydrogen cyanide can be profitably coproduced with carbon black, from coal and ammonia, at the current market price of hydrogen cyanide (11.5 cents/lb). These figures are based on heating the reactor electrically. If a cheaper heating method were devised the economics of the process would be more favorable.

Jan 1, 1967

The content of the book covers: (1) The theory of the Eötvös torsion balance; derivation of the working formulas; description of the instrument; method of observation; relation of the magnitudes observed to the lines of force and the level surfaces of gravity; corrections or normal effects, near and distance terrane; subterranean effects; effects due to certain mathematical bodies. (2) Notes on the practical employment of the Eötvös torsion balance; initial testing of the instrument and of accessories; hints on planning the survey; work at the station site; office computation and plotting of results; the interpretation of the results: (3) A description of the instrument and instructions for its manipulation. This book was the best discussion in English on the theory and use of the Eötvös torsion balance and is surpassed only by a later paper by the same authors that covers much of the same ground. The book is suitable for a textbook for beginners, and advanced students will find it of use. It should be available as a reference book in all geological libraries and in all torsion balance department offices.

Jan 1, 1929

By L. Wade, R. Wang, M. A. Horton

Laboratory methods to find the mechanical properties of rock are inherently biased towards stronger strata, which best survive the sample preparation process. Geophysical techniques are not subject to such bias and may be used to predict mechanical properties rapidly and cheaply. Samples (151) were obtained from a borehole that had been comprehensively geophysically logged. The mechanical properties of the samples were established in the laboratory and correlated with the geophysical responses of the strata from which they came. The results indicate that, for homogeneous strata at least, it is possible to predict the unconfined compressive strength reasonably well from sonic travel time measurements made in the field. Predictions of static Young's modulus may also be made from this data source, but with a lesser degree of confidence. A multivariate regression equation is presented which relates down-hole sonic travel time to unconfined compressive strength, depth and the frequency of fractures in the rock mass. This equation may offer potential for the prediction of the mechanical rock properties of fractured and layered strata.

Jan 4, 1993

By K. Raht

LEAD poisoning is perhaps the oldest and, until recent years, the most misunderstood of all industrial diseases. Hippocrates appears to have recognized a relationship in the colic experienced by a patient who worked with metals, and the ancient literature is filled with references to the colics and 'dry bellyaches'. The colic and other sequalæ following drinking of lead-bearing waters and, particularly, wines has excited possibly more comment in the older medical literature than any other ætological factor. It was not until1656, when Stockhusen definitely connected the colic of the workmen with the fumes given off in the process, that the true danger to those working with lead was recognized. Unfortunately, something over 200 years elapsed before industry took any note of Stockhusen's discovery; it remained for Legge and Goodly and investigators of the early 1900's to forcibly educate their profession and industry to the manner in which lead gained entrance to the body. The work of Legge and Goodly was published in 1912 and the clearness with which these investigators presented the scientific data which they had accumulated will mark this volume as perhaps the first and most important contribution to our modern knowledge of the subject. It also ushered in a period when, in the short space of thirty years, lead poisoning has been reduced from one of the most baffiing and widespread o industrial diseases to one which can be anticipated and controlled. The next great contribution came in 1926 with the publication of the work of the Harvard group. Here, for the first time, was the physiological behaviour of lead laid bare, and it is to the discoveries of these authors that we owe our modern treatment of lead poisoning.

Jan 1, 1941

By P Stoker

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Mining and exploration properties have a unique set of technical risks. Privately-owned companies considering investing in the resources sector can optimise their investment decisions by adopting a systematic technical assessment of acquisition assets, similar to the approach commonly adopted by public financial institutions and publicly-listed companies.Technical due diligence provides a process to identify key geological, mining, geotechnical, metallurgical, environmental and social risks and opportunities and determine the most likely business case and valuation of assets. Technical due diligence is commonly carried out in parallel with legal, commercial and financial due diligence, often involving the acquirer, to maximise the understanding of the investment.There are significant advantages in investors conducting a comprehensive technical due diligence, which typically involves site visits and project assessment to international standards by an independent, multidisciplinary team of experts. The outcomes provide the opportunity for the investor to make early, informed decisions and to understand and manage risks.Technical due diligence may be carried out at several stages: when considering and weighing up a number of investment options, prior to and during a transaction or immediately post-transaction. In the first stage, the outcomes will inform the choice of investment and, more particularly, whether there are any fundamental flaws in the projects being considered. In the second stage, due diligence outcomes can inform the level of investment and approach to risk management and planning. In the third stage, risks and opportunities can be investigated in more detail, allowing the investor to consider the best options to reduce risk and maximise the benefit of the investment.This paper presents a summary of the technical due diligence assessment process, its benefits to investors, common risks in mining and exploration projects known to cause mining asset write-downs and principal technical due diligence approaches.CITATION:Keogh, A, Stoker, P and Thomas, M, 2015. Benefits of due diligence in private equity mining investments – maximising value and unearthing common risks , in Proceedings PACRIM 2015 Congress, pp 115–126 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Sergio Romo, Gerardo Fuentes, Adriana Garcés

Refractory ores with gold entrapped in a sulfide matrix, must be processed in a first stage with chemical or physical treatment in order to liberate the gold for a subsequent step with cyanide. The goal of this research was to compare the refractory behavior of a gold concentrate treated using two pretreatment methods: pressure oxidation and fine grinding. Gold concentrate from Viacha Mining in Bolivia, assaying 50.11 gpt, with a P80 of 131 ?m was used. The concentrate contains arsenopyrite and pyrite as main sulphides in the matrix. A preliminary test with cyanide resulted only 13.5% of gold extraction with 4 hours of stirred leaching. Using an autoclave oxidation with sulphuric acid and 12 bar oxygen pressure at 220°C pretreatment, the cyanide gold extraction increased to 69.0% in 4 hours. When material was ground in a pulverizer, producing a P80 of 20 ?m and the product directly cyanided, stirred leaching gave a gold extraction of 65% in 4 hours. For both techniques, the effect of temperature, sulfur produced in autoclave oxidation, optimization of the cyanide and the nature of residues were also studied.

Jan 1, 2014

By Auhin Kumar Maparu

Metal oxide nano-particles are used as additives in various industrial applications such as pigments in paints, additives in adhesives, plastics, cosmetics, functional coatings, personal care and health care products, for antibacterial applications and more recently in heat transfer applications. In most of these applications, usually dry nano-particle powders are added to the formulations. However, often it becomes difficult to achieve a uniform and stable dispersion of nano-particles in the given formulation. Thus, a scalable and commercially viable process for in-situ production of stable nano-particles suspensions in the desired medium will certainly be more beneficial. Ultra-fine grinding in high energy mills (planetary mill, stirred media mill) has been used to produce fine particles (sub-micron size). However, in order to obtain nano-particles (particle size <100 nm), the choice of appropriate dispersant and solvent is crucial, since freshly generated nano-particles tend to agglomerate due to their high surface reactivity. We have employed molecular modeling (MM) based selection methodology to arrive at the most suitable solvent?dispersant combination for preparation of the given metal oxide nano-particles. Molecular modeling techniques are employed to compute the interaction energy of a given dispersant with surface of the metal oxide particles in the presence of the dispersion medium. The interaction energy helps identify a dispersant that has strong affinity for the metal oxide surfaces allowing for strong dispersant adsorption and hence a more stable dispersion. For example, in case of aqueous nano-titania suspensions, poly-carboxylic acids like citric acid provide better dispersion than mono-carboxylic acids like lauric acid, mysristic acid, and oleic acid. While in non-aqueous medium like ethanol, p-hydroxybenzoic acid and glycerol trioleate perform better. The suspension is produced in-situ by ultra-fine grinding of the metal oxide powder in the presence of the selected dispersant and dispersion medium in a planetary ball mill. By careful selection of various process parameters such as percent loading of powder, jar filling, grinding media to powder ratio, time and amount of dispersant addition, both aqueous and non-aqueous suspensions of metal oxide nano-particles with average particle size less than 100 nm are produced. The aqueous suspensions of alumina and titania produced in presence of citric acid dispersant exhibit median particle size of 83 and 62 nm, respectively. These suspensions have been found to be stable for nearly 3 years. The nano-particles thus produced are used in the preparation of nano-fluids?advance heat transfer liquids, which show enhanced heat transfer capabilities and unaltered stability and performance even after several heating-cooling cycles. The nano-particles are also utilized for making efficient photo catalysts, which are found to be highly effective under sunlight. Keywords: stability, nano-fluid, milling, grinding, thermal conductivity, nanocoolant, photocatalyst

Sep 1, 2012

By A. Bascetin

Materials produced in quarries have been used for different intentions such as concrete and cement raw material, asphalt and embankment aggregates, railway ballast. Especially in cement manufacturing, the chemical composition and the uniformity of the raw materials play a strategic role in the economy and quality of the cement process. Therefore, it is necessary to achieve uniformity and desired chemical composition and maintain these at all production stages according to the type of cement produced. To achieve this goal the production planning and pit design play an essential role. This paper briefly outlines the production optimization of cement raw materials in a quarry in Istanbul western part of Turkey. For the purpose it was used the 3D ore body modeling and the geostatistical techniques. The variation of chemical components (%CaO, %Al2O3, %Fe2O3 etc.) and quality control parametres (LSF, SR, AR and etc.) obtained from the quarry were determined. Then the values of unknown chemical components and quality control parameters in the ore body were estimated using Kriging which is one of the geostatistical interpolation methods. The open pit design was also created by specifying wall slopes and taking into consideration of the grade distributions of the benches. The most important revolution in the paper is investigating the effects of the block dimensions in block modelling which is important for reserve estimation. The other important point in the study is using the different range values in variogram analysis for determination optimal reserve estimation. n this study, the effects of two parametres on reserve and waste amount estimation were determined according to CaO% distribution. The study was pointed out that the changing of the two parameters are very important for the optimal mine planning and environmental considerations.

Jan 1, 2010

By S a m u e l D e a n

The author's written response to previous discussion was presented at the North of England Institute of Mining and Mechanical Engineers general meeting held in Newcastle-upon-Tyne, 8 April 1916, followed by further comments by Hare S. in support of his view that the conditions in English mines were the reason for less satisfactory results being obtained with heading machines and brief comments by Greener T.Y., President

Dec 1, 1916

By "Andreas Steinwandter

The demand for increasing energy efficiency and CO2 reduction is one of the global megatrends of our time. Although the steel industry suffers from a volatile economic environment, the steel plants are interested to find opportunities for sustainable cost reduction and put efforts into healthy solutions for the environmental. Integrated steel plants are trying to cut electrical power and energy costs as these are among the biggest cost factors that can be influenced and taking all the advantages they can. For the integrated iron and steel making route the interaction of waste energy utilization along with process energy demand, natural and metallurgical gases, steam and heating systems as well as power generation has to be considered. Potential energy sources, such as sinter plant, basic oxygen furnace (BOF) cooling stack or reheating furnaces are considered in order to elaborate an integrated energy concept. Especially electric power generation is an attractive option for steel plant operators since it can easily be connected to the existing power grid of the steel plant. When direct local use of waste heat is limited, the best option is to convert it to mechanical/electrical power with a Rankine Cycle. A stand-alone system, compact design with minimum operational costs in order to fit into the existing steel plant layout, are the main requirements of such units. The objective of this paper is to demonstrate economic feasible opportunities for energy recovery for sinter cooler and basic oxygen furnace with focus on electric power generation via ORC modules taking at the same time advantages of CO2 reduction by utilizing waste heat from the process. Furthermore typical arrangements and layouts of such solutions as well as basic economic calculations will be presented in the paper.

Oct 30, 2017

By A. Melkumyan, M. Balamurali, J. Zigman

Understanding the contribution of geophysical variables is vital for identifying ore indicator regions. Both magnetometry and gamma-rays are used to identify the geophysical signatures of the rocks. Density is another key variable for tonnage estimation in mining, and needs to be re-estimated in areas of change when a boundary update has been conducted. Modelling these geophysical variables in 3D will enable investigation of the properties of the rocks and improve our understanding of the ore. The Gaussian Process (GP) was previously used to generate 3D spatial models for grade estimation using geochemical assays. This study investigates the influence of the following two factors on the GP-based autonomously generated 3D geophysical models: the resolution of the input data, and the number of nearest samples used in the training process. A case study conducted on a typical Hammersley Ranges iron ore deposit using geophysical logs, including density, collected from the exploration holes, is examined in this paper.

Sep 1, 2021

By John Convey

"IRON ORE was first smelted in Canada about the year 1736 at Les Forges, Quebec -a most appropriate name for such a historic locale. During these early years of the 18th, 19th, and first quarter of this century, about six million tons of ore were mined and employed in the manufacture of items ranging all the way from kettles, stoves, and cannon for the early settlers to weapons of war for the allied armies of World War I.But this symposium on iron ore is not concerned with this early period. Instead, it is concerned with the iron ore industry of today -an industry which will soon be-come one of the two most valuable mineral industries in Canada.The subject in its broad geographic and economic aspects will be introduced by Mr. Buck; Dr. Harrison will describe the geology and origin of the principal iron ore deposits; Dr. Downes will go into beneficiation as it applies to iron ores; and Mr. Gertsman will discuss primary processing. The symposium will not deal with the steel end of the industry, because that phase itself could well form the subject of a symposium."

Jan 1, 1955