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We report the studies of Proton-Exchange Membrane Fuel Cells (PEM FC) and hydrogen storage materials at McMaster University for the last 14 years. From the initial investigation of ionic conduction mechanism to the revelation of the origin of non-Arrhenius temperature dependence, as well as the synthesis and characterization of high temperature polymer electrolytes, both experimental and theoretical works have been compiled for the fuel cell membranes. In addition to the discovery of suppressed ionic conduction in Electrode-Membrane Assembly (EMA) and novel hydrocarbon PEMs based on micro-emulsion, the first evidence of hydrogen adsorption saturation by carbon nano-tubes was also achieved, which has been the bottleneck for the application of PEM FC. Prior to our study, a number of controversial publications have claimed the hydrogen capacity of these materials to be between 0.1 to 10.0 wt.%, and none demonstrated a plateau of adsorption with pressure that is consistent with monolayer saturation. Others suggested that the tube bundle structure is opened under high pressure to enable higher adsorption on newly uncovered surfaces, but received no confirmation. Using our home made high-pressure instrument with in-situ electrical probes, we found that a plateau is nearly achieved at about 300 atm in the room temperature isotherm, and that nanotube bundles actually compress with pressure instead of splitting, using in-situ electrical measurements.

Jan 1, 2005

By Ali Kahriman, Abdulkadir Karadogan, Alper Celtikci, Ahmet Varol, Ertugrul Kaya, Turgay Ozat

This paper presents analysis of environmental effects induced by cautious blasting during the construction of the Istanbul Subway 4 Levent - Ayazaga Darulsafaka Metro Tunnel Project carried out by the contractor, located at Northern Istanbul in Turkey. Within the scope of the study, for the prediction of the peak particle velocity and to determine the slope of the attenuation curves together with the maximum charge per delay for the S6-7-8 shafts of this tunnel route, ground vibration components were measured carefully by using five vibration monitors during the construction of the tunnels which required blasting. The particle velocities and frequency values of all blast events are evaluated according to the United States Bureau of Mines (USBM) and German DIN 4150 Norms in order to predict, and compare the influence grades to the neighboring buildings, and structures. Also, data pairs of scaled distance and peak particle velocity obtained from 107 records belong to 51 shots were analyzed statistically. Empirical relationships with correlation at the 95 % confidence interval were established for these tunnel excavations and suggested for the test sites in order to estimate particle velocity of the ground vibrations. As a result of the studies, some practical charts are created in order to minimize the psychological effects of the shots, and simplify the authorities of shots’ job. And last but not least, make sure that the shots will be done in a controlled way.

Jan 1, 2011

By K. A. Foo

Minproc Resources Inc. is developing a tailings retreatment project in Bolivia at the Colquiri zinc-tin-silver mine, in the Bolivian Andes. Mining at Colquiri has been continuous since 1940 and COMIBOL, the Bolivian state mining company, has owned and operated the underground mine since 1964. There are 10 million tonnes of tailings at Colquiri containing 0.51% Sn, 4.21% Zn and 50 g/t Ag. Minproc plans to mine and concentrate the tailings at 1.15 million tonnes per year to produce feed for pyrometallurgical upgrading. The tailings are moderately complex, with cassiterite grain size ranging from 200 to 5 pm. The marmatite (ZnFeS) in the tailings is relatively easily recovered, with zinc recovery of 80% to a 40%-45% Zn concentrate. The major problem with the zinc metallurgy is that the marmatite is complexed with iron, which results in iron contents of 14%-17% Fe in concentrate. This makes the product very difficult to sell because of the low Zn:Fe ratio. Most zinc smelters require a Zn:Fe ratio of 6:1 or 7:1, whereas this concentrate has a 3:1 ratio. Concentrate sale terms are therefore unfavorable, and the high cost of transportation from Bolivia to the smelters is an additional burden.

Jan 1, 1992

By V. Svalbonas

When the Trelleborg Divisions of Boliden Allis and MPSI merged, a unique opportunity occurred for two independent mill fabricators to compare various design procedures and the research upon which they were based. This paper documents such a comparison in the structural design area. Several SAG mill analyses are compared using both Boliden Allis and MPSI methods. The differences and similarities are then utilized in a correlation of critical stress definitions and the acceptable design and inspection criteria.

Jan 1, 1992

By R. Walker

This paper deals with the selection and design of a belt conveyor handling steam coal between a mine and a barge loading terminal, and extending for some 5 ¼ miles over some of the most rugged terrain in the state of West Virginia, U.S.A. After a thorough analysis by consulting engineers and the owner's engineers, a single-flight cablebelt conveyor was chosen as representing the alternative of greatest reliability and lowest over-all cost. The value analysis and design features of the system are covered in this paper along with an updated report on the performance of the system since its start-up in the spring of 1969.

Jan 1, 1971

By M. S. Badollet, W. C. Streib

"AbstractA commercial method .has been developed for controlling the texture of chrysotile asbestos fibers so that they may possess properties comparable with natural sem1-harsh fibers for use in wet •processes.The physical properties of the soft, silky and slimy fibers are partially altered by a flash-heating process which removes a portion of the molecular water.The heat-treated fibers show an improvement in filterability, an increase in bulk, absorption, and surface area and better electrical properties, such as volume resistivity.IntroductionCHRYSOTILE ASBESTOS fibers are found in nature having varying degrees of texture, referred to as soft, semi-harsh, and harsh. Fibers of each type of texture have inherent characteristics which directly affect their usefulness to industry. Visual differences are apparent under a microscope where it is seen that the soft-textured fibers have a silky, serpentine or wavy appearance, whereas the harsh-textured fibers are coarser and spicular. Semi-harsh fibers, of course, have properties intermediate between these extremes.Fankuchen and Schneider ( l) have shown by the use of low-angle X-ray scattering that the diameter of the harsh type of chrysotile fiber is somewhat greater than tha of the soft variety. Surface area measurements on various chrysotiles of different textures tend to confirm their findings. By nitrogen adsorption methods, it was found that the surface areas of soft types of chrysotile asbestos are approximately 23M2 / g whereas for the harsh types they are as low as 11M2/g."

Jan 1, 1955

By R. Riding

Degussa Corporation's peroxide-assisted leaching (PAL) process was evaluated in the batch concentrate leach circuit at Hecla Mining Company's Republic Unit. The product leached in this batch circuit is a high grade gold-silver sulfide (predominately pyrite) flotation concentrate. The primary objectives of the test program were to determine the effects of dilute hydrogen peroxide addition on leaching kinetics, sodium cyanide consumption and precious metals recovery. The results of the testing demonstrated that using dilute hydrogen peroxide produced the following benefits: - 1. Batch leach time requirements decreased by 80%. - 2. Sodium cyanide consumption in concentrate leach reduced by 55%, which translated to an overall plant reduction of 20%. - 3. In the concentrate leach process, gold recovery was increased by 1 to 2%. Because of the excellent metallurgical results achieved with the use of dilute hydrogen peroxide, as well as an economic incentive, PAL has become standard practice in the concentrate leach circuit operation. A complete description of the Republic PAL plant evaluation and performance is provided in this paper. In addition, process chemistry considerations in regard to the role of hydrogen peroxide are discussed.

Jan 1, 1992

By P. W. Billwiller

Abstract The Britannia Mining and Smelting Company, Limited, have replaced diamond drills with percussion drills and tungsten: carbide bits for most of their blast hole drilling operations and have thereby reduced ore breaking costs. Two-inch Carset bits .are used, with one-inch hexagonal Atlas Chippewa alloy steel in 3-foot .and 6-foot lengths. Locally made couplings of Atlas SPS 245 alloy steel connect the rods. The machines used are 31½-inch automatic leyners with lugged or anvil block chucks. For drilling holes below the horizontal, the lugged machines with special adapter rods made from 114- inch solid round Atlas SPS 245 are required. These rods are lugged at one end and a water hole is drilled for six inches into the other end. Over this rod is placed a water swivel which permits the water or air to be sent directly into the steel. A decreased cost per foot, increased footage per shift, and the use of standard equipment and crews are some of the main advantages of tungsten carbide drilling over diamond drilling. Introduction Long-hole drilling with percussion drills and sectional steel was introduced in several American mines some twenty-five years ago. It did not prove very successful, however, because the rapid gauge loss in steel bits necessitated the use of very large starter bits. This in turn rapidly fatigued the straight carbon-steel then in use, made it difficult to maintain the couplings, and resulted in a slow drilling rate. The introduction of the tungsten carbide insert bit and alloy drill still has changed this picture and opened real possibilities for the application of percussion drills to blast-hole drilling. If this type of bit had been perfected ten years ago, much of the research work and experimenting done to apply diamond drills to ore breaking would have gone toward developing the application of the tungsten carbide bit to this problem.

Jan 1, 1950

By D La Rosa, G Power, K Riihioja

In underground mining, the often unpredictable variability in ground conditions may lead to the application of suboptimal drilling and blasting patterns, resulting in poor performance. Experience and pertinent information to develop and implement improved drilling and blasting strategies can be easily lost due to the lack of means to help engineers store, access and manage this information. The Julius Kruttschnitt Mineral Research Centre (JKMRC) through a series of industry funded applied research projects has been developing a system that can facilitate the drill and blast design, analysis, auditing, documentation and data management processes. The system is a hybrid between an information management software module called BMS (Blast Management System) and two design and analysis modules, 2DRing for underground production blasting activities and 2DFace for development blasting activities. A concise description of the software tools and its applications are given in this paper, supported by two case studies. Opportunities to further develop the software are also highlighted, they include options to integrate these tools to existing drilling and blasting automation systems and portable computing technology to facilitate the design, implementation and continuous improvement processes.

Jan 1, 2001

By K. Howard Poulsen

Shear zones are tabular tructures which tend to occur either discordantly within, or concordantly along the margins of, competent rock masse uch as plutons, sill or flows. They contain deformed equivalents of their host rock and are common sites for gold mineralization localized in tructure oriented y tematically relative to the shear zones and internal linear fabric. Apan from genetic implications, hear zone analysis proves useful in exploration for this type of deposit because the zones are generally wider and more continuous than associated mineralization and because there is an element of predictability to mineralization geometry (i.e. vein orientation. plunge).

Jan 1, 1986

By Jean Philippe Santos Gherardi de Alencar

O fenômeno de colagem é a formação de aglomerados de pelotas, denominados clusters, devido à sinterização do ferro gerado durante o processo de redução. O resultado disto é a elevação da perda de carga nos reatores de redução direta. Tal fenômeno vem sendo estudado por vários pesquisadores, pois as práticas operacionais dos reatores têm priorizado o uso de temperaturas de bustle gas (BG) cada vez maiores, o que potencializa o aparecimento dos clusters. Uma alternativa para controlar a colagem é por meio de utilização de agentes de coating (AC’s). Em relação às matérias primas utilizadas como AC´s, as questões que surgem agora são as seguintes: Como se comportam os AC’s em temperaturas muito elevadas de BG? Qual seria a maior temperatura possível de BG? A fim de começar a entender a melhor maneira de responder a estas questões foram realizados alguns testes de caráter exploratório e não convencionais para avaliar o comportamento de alguns materiais de coating a elevadas temperaturas de redução. Os resultados destes testes mostraram a possibilidade dos AC’s funcionarem a temperaturas maiores que a de inicio do amolecimento da carga e que, nestas temperaturas, a sua granulometria pode ser parâmetro determinante para seu desempenho. O aprimoramento dos ensaios de simulação do processo de redução em reatores de redução direta é fundamental para responder as questões que se apresentam em relação ao tema.

Aug 2, 2018

By R. D. White

"The Cumberland Basin of Nova Scotia has long been considered a structural basin by virtue of the elliptical outcrop and inward dip pattern of the Pennsylvanian outcrops. Recent published and unpublished data indicate that subsidence began in the late Devonian, perhaps resulting from a graben or rift. The Mississippian sediments which filled the growing depression were continental, lacustrine and marine with evaporites. The cessation of the riftforming processes is recorded by the alluvial swamp-type sediments of the Pennsylvanian which filled the depression. In excess of 25,000 feet of Carboniferous rocks are believed to be present in the deepest part of the Basin. Starting with the rift hypothesis, we can speculate on the kinds of sediments, their location and the structural features present beneath the Pennsylvanian surface. Using surface exposures and a limited amount of subsurface data, we theorize that (1) the Mississippian evaporites acted as glide zones which effectively divided the Basin into two horizontal structural layers. The rocks above the evaporites, responding to Appalachian stresses, formed the long diapiric folds with cores of overthickened evaporites. Below the evaporites the structures are related to movements of the rift floor, compaction closures and structures formed by differential horizontal movements of the rift walls. (2) The rift, in its deeper parts, will have more and a greater variety of marine rocks than the outcrops indicate. Should the rift hypothesis be correct, the possibility of finding hydrocarbons is enhanced."

Jan 1, 1972

By G. Gerbeth, Y. Gelfgat, A. Cramer, A. Bojarevics

The production of highly porous metallic substrates requires an effective and well controlled production of metallic fibres with diameters in the range of 50 to 200 microns. The melt extraction, where a quickly rotating wheel extracts fibres directly out of the inductively heated melt, is a promising technology for that purpose. The main limitations of this process are due to turbulence within the melt and a wavy motion on the surface. Both effects give rise to strong and time dependent deformation of the melt surface which, in turn, causes non-stationary conditions of the contact zone between the extraction wheel and the melt. In the patent literature many examples can be found which try to overcome these problems by submersing mechanical parts directly into, or placing them at least in close vicinity to the melt, aiming at a stabilisation of that contact region. Even made of heat resistant ceramics they suffer from corrosion or cracks and do not work reliable at all. The present work describes a non invasive control mechanism by means of a magnetic field. Model experiments were carried out to study the calm down of the turbulent surface of a inductively stirred melt. The stabilisation of the melt surface has been demonstrated in practise by the installation of a solenoid at a working extraction facility under rough industrial conditions like a powerful induction heating and vacuum.

Jan 1, 1999

By Ronald D. Hill

The occurrence of acid mine Drainage (AMD) with coal mining has been well documented. (1) Less documentation is available of its association with other types of mining, e.g., copper, gold, zinc, and sulfur. Yet there are many locations in the western states where acid mine drainage is as great a pollution problem as in Appalachia and in some cases, because of the high copper, zinc, and arsenic concentrations, they present an even more difficult problem. Until a few years ago, it was generally believed that the neutralization of acid mine drainage was uneconomical thus, AMD was allowed to discharge freely into our streams. However, the demand for good water finally dictated that the mining industry be included under pollution laws. In 1964 the Commonwealth of Pennsylvania passed a law requiring that all active mine discharges meet a discharge standard of pH 6-9, iron less than 7 mg/1, and the water must have a net alkalinity. Several other states now require active mines to treat AMD. In all but a few cases, lime neutralization, often in conjunction with aeration, has been the treatment method used. The high cost of lime as compared to limestone and the poor quality sludge, (slow settling, large volumes, and low solids content) has stimulated work in the utilization of limestone. This paper reports on the current state-of-the-art of limestone treatment of AMD.

Jan 1, 1970

By H. Sevim

The utilization of high sulfur Illinois coal by utility plants has been decreasing since the enactment of 1990 Clean Coal Air Act Amendment. Illinois coal producers can make their coal saleable by offering the choice of taking the combustion by-products from the utility plants and placing them in the abandoned sections of their mines. To be competitive, however, coal producers need to select an environmentally acceptable transportation-handling-placement system through which the cost-per-ton of by-product disposed can be minimized. In this paper, a few such systems are presented. The favorable operating range of each system is determined in terms of distance and tonnage. A case study is given whereby cost analysis is conducted for an underground coal mine receiving by-products from two Illinois utility plants.

Jan 1, 1997

By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By Zhou Junwu, Han Long, Song Zhenguo, Sun Chuanyao

The deposit genesis, the ore property, and the mineral characteristics, which has a close relationship with the beneficiablity, could be regarded as the “Genetic Properties”, actually are the determining factors for beneficiation process development. However, in conventional concentrator’s process development and engineering, there have been lack of systematic research and test on those genetic properties, also lack of well-established collecting, statistics and analysis system for those huge amount of data such as the historical mineral processing technique research, process mineralogy study, practical operating and engineering data. Obviously it is far less than enough for profound integration combining modern IT together with traditional mineral processing technology, as a result there are a number of disadvantages in mineral processing R&D and engineering, such as long term, high cost, low efficiency as well as repetitive testwork not making full advantage of previous experiences. Aiming to make utmost of those Genetic Properties and overcome above disadvantages in mineral processing R&D and engineering, the concept of “Genetic Mineral Processing Engineering (GMPE)” is put forwarded, and the strategical study has been conducted on this regard, with the main focus on following aspects: a) Testing and extraction of the “Genetic Properties”; b) Establishment of data base and data warehouse of GMPE; c) Intelligent decision making system for beneficiation process; d) Verification testwork; e) Virtual concentrator. The technical route proposed is to firstly conduct research and test on those Genetic Properties mentioned above, based on that the specific data base will be set up and applied for intelligent process recommendation and simulation with a few verification testwork conducted in the meantime, finally achieve a fast, high efficiency and precise determination of technology and process for ore beneficiation. The systematic study on the three-in-one GMPE would make an innovative breakthrough in conventional mineral process testwork research and engineering methodology, and provide technical support for the concentrator’s design and upgrading.

Jan 1, 2018

By Mansoor Barati

The present paper is based on a term project for final year undergraduate students, requiring them to evaluate a process for producing silicon from rice husk. The traditional method for production of silicon involves carbothermal reduction of quartz in electric arc furnaces at temperatures exceeding 2000 °C. The technology consumes a considerable amount of electrical energy as well as fossil fuels, resulting in significant CO2 emissions. A flowsheet for production of silicon metal from rice husk is laid out in this paper. The technology will consist of combustors, which will generate steam using the rice husk biomass, power generator, and electric furnace for reduction of the rice husk. Materials and energy balance calculations presented here indicate that such process can be operated independent of external electricity.

Jan 1, 2014

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By J. R. Fisher

"Uranium may be leached to some extent in situ from the Blind River conglomerate uranium ores by using the products of bacterial activity from the bacterium Thio-bacillus ferrooxidans his paper describes some of the laboratory techniques used to investigate the characteristics of the bacteria, and to utilize their properties in uranium leaching. The application of some of the laboratory results underground at the Milliken mine of Rio Algom Mines Limited are de-scribed, along with the method of uranium recovery from the mine waters."

Jan 1, 1966