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The Permian coal in the Muja Coal Measures of Collie Basin of Western Australia has a subdued lustre because of the fine laminations of lithotypes, and the dominance of dull and dull banded lithotypes with minor bright, bright banded and fusinous types. The maceral composition of the coal is variable, however the macerals of vitrinite and inertinite groups dominate and the exinite and mineral matter contents are low. The lithotypes have low concentrations of trace elements and the boron concentration is between 10 - 100 ppm recorded only from the dull lithotypes. On the basis of organic petrology, the inter-seam sediments, flora and the very low concentration of boron, the depositional environment postulated for the coal is braided, fluvial and fluvio-lacustrine with marked fluctuations in the water table. The low water table in the environment accounts for fusain and inertodetrinite in the coal.

Jan 1, 1996

By H. A. Fisch, A. J. Opinsky, J. L. Bartos

Fort?-six- two-grain bounduries were studied in doped tungsten 1amp wire that had been heated to 3450°K very vapidly. Back-reflection Laue photograms were taken of the grain boundary partners and solved, using a computer. The resulting distribution of large-grain orientations was analyzed. Rotational axes were calculatedfor each grain boundary pair. The axes of least rotation show an anisotropy of rolalional angle. WhILE the orientations of large grains in straight doped tungsten wire have been studied extensively, little has been done to characterize the boundary that separates them. Rosi.1 upon seeing the jagged interlocking boundary in doped tungsten wire. inferred that the grains should have a preferred orientation, and proved it. He interprets his data as indicative of a single ideal orientation—(531)— being parallel to the wire axis. Rieck2, 3 and Mannerkoski' have essentially confirmed this finding. Opinsky, Orehotsky, and Siegle argue that the data suggest that (211)—a plane-is parallel to the wire axis instead. This (211 ) contains the (531). and hence would appear to be a more general case.5 Ahlborn and wasserman6 report that their orientation data stretch from (110) through (531) to (311). This path is the locus of {211 Recently. Opinsky has suggested that the data can be interpreted as a series of ideal orientations that can be related by coincidence relationships to the (110) fiber texture. All these investigators have determined the orientations of the large grains by the back-reflection Laue technique, and they have all obtained similar results. Only Rieck5 as methodically looked at the large grains along a wire. He was apparently not concerned with the relationships of the large grains across their common boundary, but only with their individual orientations. This research was undertaken to fill this gap in the under standing of the mechanical properties of tungsten wire. Only the crystallographic aspects of the problem will be reported here. In addition, the large number of large-grain orientations, which was accumulated in this study. will also be analyzed. EXPERIMENTAL MATERIAL AND TECHNIQUES All of the data were obtained from four pieces of the same 7-mil-diam General Electric tungsten lamp wire. Twelve-inch lengths of the cleaned wire were heated in vacuum by the flick of a switch to 90 pct of the amperes necessary for fusion (a temperature of approximately 3450°K) and held for 1 min. On the basis of other data. it is estimated that the rise time is of the order of 0.5 sec. The four pieces of wire could have come from anywhere within about 18 ft of wire. Consecutive segments of each piece of wire were mounted in bakelite and polished metallographically The polishing procedure followed that described by woods. "nly boundaries between two grains that each occupied the entire cross section of the wire were photographed and X-rayed. The metallographic sample was mounted accurately with respect to the X-ray unit. Steps were taken to read the films as accurately as possible with the conventional Greninger net. The data were then entered into computer programs that solve the Laue film by precisely the same techniques that are used in the solution of the film by means of the stereographic projection. The use of the computer has probably shifted the main source of error from the stereographic plot to the reading of the film. On the basis of several experiments, it is thought that the error associated with the entire process, from mounting the sample through the computer solution, is of the order of about one-half degree. The output of the computer is the direction cosines of the fiducial direction (the wire axis) and the locations of the three cube axes. The former data were used to calculate the differences in orientation between the two grain boundary partners, and the latter were used in the calculation of the rotational axes that could bring the two grains

Jan 1, 1970

By Sheng Zhang

The compressive strength of coal in Yanlong mine area of China is less than 3 MPa. Basically, it is powdery. The roof and floor rocks are mudstone. Therefore this coal seam is a typical ?three soft? coal seam. Roof bolting cannot be used due to the very soft strata. When the conventional U-steel support was used, roadways deformation exceeded 30% of its original dimensions in some sections one half month after development. The required repair work was huge, seriously affecting the daily mine production. This paper describes how to support the soft coal roadways. The deformation characteristics of soft coal roadway were investigated. The conventional U-steel support is not subjected to uniform load, so the whole supporting structure must be strengthened. In addition, drilling holes in the coal seam can transfer high stress from near the ribs to the deeper parts of the surrounding strata, which is beneficial to the stability of the roadway. This new support method is to combine the strengthened U-steel support with pressure-relieving drill holes, providing an economic and efficient way to support the very soft coal roadways.

Jan 1, 2013

By D. G. Westlake

NUMEROUS hydride habit planes in zirconium, Zircaloy-2, and Zircaloy-4 have been observed by various researchers and have been compiled by Louthan and Angerman.1 While only partial agreement exists on the identification of these habit planes, there is a growing consensus that a tensile stress applied on a polycrystalline rod during slow cooling will cause the hydride platelets to lie perpendicular to the tensile axis. walters2 agrees with Louthan and Angerman who reason that "The particular plane on which precipitation will occur is the plane that will result in the maximum relief of stress by precipitation of the low-density hydride." The experiment described below was initiated to test this hypothesis on a single crystal of zirconium. A single-crystalline tensile specimen of zone-refined zirconium, designated number 13 in a previous study,3 had a square cross section with one pair of parallel faces only 4 deg from the basal plane of the hcp structure. The tensile axis was about 86 deg from the (0001) pole, 14 deg from the (1010) pole, and 16 deg from the (1150) pole. The specimen was charged to 50 ppm H by allowing reaction with the correct amount of hydrogen at 1073°K, homogenizing at this temperature for 2 hr, and cooling in the furnace. Two- surface analysis revealed that hydride platelets had precipitated parallel to the three {1010} prism planes. The specimen was heated to 673°K, in air, for 16 hr to bring the hydrogen back into solid solution, and furnace-cooled to 573°K.* It was then stressed in ten- sion at 1.2 kg per sq mm. (This produced a resolved shear stress of 0.6 kg per sq mm for glide on the prism plane with the highest Schmid factor. A higher stress would have produced significant strain at this temperature because the critical resolved shear stress for prism-plane glide in this crystal was only 1.0 kg per sq mm at ambient temperature.) The poles of the three prism planes were at angles of 14, 46, and 74 deg to the tensile axis so that an applied stress would exert normal stresses on the three planes in the approximate ratios 10:5:1, respectively. As soon as the stress was applied, the sample was furnace-cooled to room temperature. It was ground on wet Sic paper and chemically polished in 50 parts HNO3, 50 parts water, and 7 parts HF before examination. The result of the experiment was negative; i.e., the three (1010) planes were of equal importance as hydride habit planes.* It must be admitted that the ex- periment is not entirely comparable to those performed by walters,2 Louthan,5 and Louthan and Marshall6 on polycrystalline materials. They have found that some critical stress (below the macroscopic yield stress) is required for stress-orienting the hydrides. The applied stress in the present experiment was, by necessity, smaller by an order of magnitude than the critical stresses they report for the various materials. If the critical stress was related to the microstructure, one might postulate that it should be decreased by increasing the degree of perfection of the metal lattice and by increasing the grain size. But the experiment above suggests that, for the extreme case of a zone-refined single crystal of zirconium, the critical stress lies above that which one can apply without introducing gross plastic strain as another variable.

Jan 1, 1967

By J. T. Norton, N. J. Grant, A. M. Gervais

An investigation of the creep deformation of coarse-grained high-purity aluminum at temperatures approaching the melting point permitted the formulation of a theory of subgrain formation. Subgrain boundaries were found to be formed by two different processes: kinking and polygonization. Polygonization is considered as the main factor in subgrain formation. SINCE "slipless flow" was first discussed in detail by Hanson and Wheeler,' many studies have been undertaken to determine how metals deform at high temperatures. Several types of observations have been reported. Jenkins and Mellor,² working on the creep of mild steels and various grades of commercial irons, found metallographic evidence of a kind of substructure within the grains after deformation at high temperatures. Homes" observed after creep deformation of steel at high temperatures that the original X-ray spots were sharply divided into several small ones. The same phenomenon was reported by Hirst4 from his studies on lead and later by Crussard5 from his work on aluminum. The works of these investigators demonstrated beyond any doubt that the splitting of the X-ray spots was due to the fact that the grains underwent a division into subgrains during deformation at high temperatures. Since then, numerous experiments have been undertaken on aluminum in order to determine the mechanism of formation of subgrains. Research workers can be divided, for the purpose of discussion, into two different groups as regards thinking on subgrain formation. On one hand, based on the work on polygonization by Cahn,6 Guinier and Lacombe,7 Greenough and Smith," Crussard,10,11 and Servi, Norton, and Grant," it was concluded that subgrain formation was a consequence of the simultaneous effects, first, of inhomogeneous deformation which produced bending of the lattice, and second, polygonization. On the other hand, Wood and coworkers13-16 based their work on the results of an earlier report" which dealt with crystallite size and a fragmentation theory. It is interesting to note that while Greenough and Smith8 and Wood et al. performed similar experiments, their conclusions were quite different. Wood et al. did not recognize polygonization as a fundamental mechanism and said that aluminum, at the beginning of the deformation, fragmented immedi- ately into subgrains in order to permit deformation of the metal, the number of these subgrains being a function of strain rate and temperature. They concluded that deformation of grains occurred by flow along the subgrain boundaries. In view of the contradictory conclusions, it would appear that the data were not explicit enough to provide an unambiguous conclusion. It appears that the techniques by which most of the results were obtained, namely, X-ray work, were not enough by themselves to solve the problem. Another approach was needed. In the present research, therefore, an extensive metallographic study was planned to supplement the X-ray work. The importance of revealing the subgrain boundaries metallographically was realized, and this will explain the extensive development and use of etching techniques. In order that subgrains would be considerably larger and therefore more readily visible under a microscope, the creep experiments were performed at very high temperatures approaching the melting point of aluminum. Development of Experimental Technique Creep tests were run at constant load on high purity (99.995 pct) aluminum specimens having a very coarse grain size. None of the specimens was run to fracture. The specimens were originally round (diameter, 0.187 in.; gage length, 1 in.) and had parallel flats milled in the gage section to permit

Jan 1, 1954

By Wei-Kao Lu

A general rate equation is derived for gas -solid reactions in metallurgical processes by considering the contributions of chemical reaction at inter-phase boundaries and diffusion through the solid product layer simultaneously. This equation takes care of the whole range continuously from purely diffusion control to purely chemical reaction control. The parabolic law,' McKewan's equationa derived with the assumption of interface area control and the equation derived by Kawasaki et al. with the assumption of purely diffusion control are found as the limiting cases of the corresponding forms of the general rate equation. Many metallurgical processes involving gas-solid reactions have been extensively studied. The common examples of these processes include the reduction of oxides to metallic products, the roasting of sulfides to oxides or chlorides and the oxidation of metals. Gas-solid reactions consist of at least two kinds of steps; one involves the transport of reactant and product to and from the reaction zone and the other is the chemical reaction taking place at the interphase boundaries. In the limiting cases one or the other of the above mentioned steps will be much slower than the other and is then rate controlling. For example, the oxidation of metals is diffusion controlled and obeys the parabolic law.' On the other hand, if the diffusion rate is much larger than the chemical reaction rate then it will be controlled by the chemical reaction rate. This latter case occurs for the reduction of iron oxides studied by McKewan. If the rate of diffusion and of the chemical reaction have the same order of magnitude, a more detailed analysis is necessary. Thus at the beginning of the reaction when the solid and gaseous reactants are in direct contact, the reaction should be chemical reaction rate controlled as no diffusion process is involved. At the other extreme as the reaction zone moves further into the solid, the diffusion distance becomes greater and the diffusion rate continuously decreases. Eventually, therefore, for a sufficiently large sample the rate must become diffusion controlled. As the transition from one controlling step to the other must be continuous, we cannot describe this transition period by either of the two limiting cases. In this paper the author attempts to derive a general rate equation for gas-solid reaction systems. This is effected by considering the rates of diffusion and chemical reaction simultaneously from the state of pure diffusion control to pure chemical reaction control. I) DERIVATION The system under consideration is made of at least three phases, namely the gaseous one, the solid reactant, and the solid product as shown in Fig. 1. The notations are listed at the end of the paper. The mass transfer process involves the diffusion of reactants and products across the solid product layer. It is reasonable to consider that no chemical reaction will take place in the solid product layer with respect to both gaseous reactant and product. For the characteristics of local equilibrium of the system, the diffusion process is really in a quasi-steady-state. It will be proved in the following paragraphs. Then we can invoke the law of conservation of mass valid for all chemical species passing through the layer. The solid reactant sphere has an initial radius, ro, after a fraction of completeness of the reaction, the unreacted core has a radius ri, where r, is in the solid product region. Let Cg be the activity of gaseous reactant in the

Jan 1, 1963

By A. H. Farazi, C. Quamruzzaman

The freezing and subsequent solidifying of unstable, weak (sands, silts and clays) and/or wet soil to form a desired-shape frozen barrier around a construction area are possibly the main features of the freezing method for shaft sinking. The barrier, along with strengthening the soil, provides a dry environment to ensure sustainable subsurface construction work before placing a permanent lining. The freezing method requires the installation of freezing pipes in boreholes around the construction area and the circulation of chilled salt water through these pipes and has long been a proven technique for dry shaft sinking through unstable and water-bearing seam around the world. As removing heat from the ground is the main feature of the method, an efficient thermal design of the freezing process is mandatory to ensure success of the shaft sinking operation. This applies to both the sustainability and economy of the intended structure. The design presented in this paper is aimed at figuring out the heat-removing ability and operating time of the refrigerative equipment using some simple formulae. The authors adopted a theoretical approach to determine the quantity of heat to be removed from the ground. The amount of energy for the equipment was found to be greater than that for freezing, which proved the validity of the design. The active freezing period was calculated to be 121 days. The authors followed the structural design of the freezing process they proposed in their previous work (Farazi and Quamruzzaman, 2013). Though the first coal seam in the coalfield was encountered at a depth of approximately 352 m in the subsurface, the target depth for cooling and freezing was decided to be 162 m. The formation demands extra care to nullify its risk of the temporary structure collapsing and water rushing in (Farazi et al., 2012). Discussion on the determination of refrigerative equipment parameters was excluded from the scope of this work.

Jan 1, 2014

The flotation behavior of kaolinite and diaspore using N, N-diethyl dodecyl amine (DEN12) and N, N-dimethyl dodecyl amine (DRN12) as collector have been investigated through flotation experiments. The mechanism of adsorption of two tertiary amine collectors on surface of kaolinite and diaspore were investigated by FTIR spectral, Zeta potentials measurements and calculation of molecular orbital energy. It has been found that DEN12 and DRN12 have stronger collecting power to kaolinite and weaker collecting abilityto diaspore than DDA. Kaolinite and diaspore in bauxite ores can be separated by using DEN12 and DRN12 as collectors at pulp pH below 8 and 6, respectively. The results of zeta potentials and calculation of molecular orbital energy indicated that the adsorption strength on kaolinite surface is in the order DEN12>DRN12>DDA and the adsorption strength on diaspore surface is in the order DDA>DEN12>DRN12. FTIR spectral analysis and Zeta potentials approve that the action between kaolinite and tertiary amine collector is strong electrostatic adsorption and that of diaspore is weak electrostatic adsorption in the range of pH 5~6.

Jan 1, 2014

By Thomas E. Ban

The continuous sintering process was invented more than 60 years ago by two metallurgists, Arthur S. Dwight and Richard L. Lloyd, who saw a need for automation in mineral processing. Their specific objective was to beneficiate copper ore by desulfurizing and agglomerating it for copper blast furnace smelting at the Cananea plant in Mexico1. Since their early development the process expanded widely in scope, size, and application. The current worldwide sintering applications exceed 250 million tons per year for agglomerating ores of lead, manganese, zinc, and iron. Sintering is also widely used for production of sintered lightweight aggregate from clays, shales, and fly ash. The continuous sintering process took on wide expansion during the 1960's in foreign countries. Plants for production of approximately 135 million tons per year were built in these countries for sintering iron ore fines as shipped from new iron ore projects of Canada, Liberia, India, Brazil, and Australia. This expansion represented construction of approximately 80 new sintering plants, some as large as 15 thousand tons per day production on a single large sintering machine. Sized self-fluxing or highly fluxed sinter has become recognized as a premium blast furnace charge and has enabled blast furnaces of Japan and Europe to produce upwards of 10,000 tons of metal per day with coke rates less than 1,000 pounds per ton of metal. This coke requirement is practically 50 percent of the ordinary rates achieved during the early 1950's when the peak blast furnace production was less than 113 of the current records.

Jan 1, 1975

By Barry L. Warner

This program involves testing to determine whether a fire hazard exists when the exposed wood surface area of timber in a mine passageway equals 40 percent of the surrounding strata surface, excluding the sill. Twelve full scale fire tests were conducted in a simulated mine passageways, using kerosene pan fires as the ignition source. The tests included three timber sizes, plus one test with roof lagging, two wood types, plus one test with treated timbers, and two ventilation air velocities. The results show air velocity to be an important factor in the occurrence of flame propagation, and that the 40 percent surface area ratio of wood to surrounding strata appears to b0. a valid criteria for fire safety at 150 fpm, but not at 350 fpm.

Jan 1, 1975

By J. Seiter, S. Cox, E. Kim

Mining has always been among the most hazardous of occupations, and with the increasing demand for coal and minerals, safety in mines assumes even greater importance. Worldwide, underground miners are being exposed to noise and respirable dust hazards associated with roof bolt drilling. These hazards are now being understood to cause irreparable damage to the health of miners. The objective of this research was to discover if a polycrystalline diamond compact (PDC) drill bit generates less respirable dust and hazardous noise than a competing tungsten carbide (WC) bit in dry vacuum drilling. In order to control the drill parameters the drilling tests were conducted in a laboratory setting. The results were obtained by determining the quantities of dust and noise generated using each drill bit and analyzing those levels, using monitoring devices and software to collect the data. This paper includes information on the experimental setup, equipment used, drilling parameters, and data collected. Our results indicate that PDC bits produce significantly less noise and dust than WC bits. Our findings can contribute to improving the working conditions of rock bolter operators by reducing noise and dust generation.

Jan 1, 2014

By Orica Peru, Pedro Lozada

Proper management of exclusion zones in blasting operations is essential to ensure safety without compromising operational efficiency. In Peru, mining regulations establish minimum exclusion distances specifically for personnel (500-meter radius / 1,640 feet), but do not define clear technical criteria for equipment. As a result, conservative distances such as 200 meters (656 feet) are often applied, negatively impacting productivity. This study proposes a technical-scientific methodology to reduce equipment exclusion zones, based on the use of advanced technologies such as drones, high-resolution cameras, and specialized software tools. The solutions used allow video recordings of blasts to be transformed into dynamic data through artificial intelligence and computer vision, as well as execute probabilistic simulations of the flyrock phenomenon using Monte Carlo algorithms and physical models calibrated to real operating conditions. Technological integration enabled the simulation of real operational scenarios, considering variations in critical blasting parameters that directly affect flyrock generation, such as drill diameter, explosive density, linear charge, and stemming height. Additionally, the Terrock methodology was incorporated, allowing the behavior of the rock mass to be included as a variable in risk assessment, improving analysis accuracy under different rock hardness conditions. The methodology was applied in four phases: diagnosis of the current design (15 blasts), modeling, validation of the calibrated model (6 blasts), and subsequent operational implementation. As a result, it was determined that the exclusion radius can be safely reduced from 656 to 492 feet (200 to 150 meters), maintaining as the main restriction the use of stemming lengths greater than 5.0 m. This optimization has the potential to generate tangible benefits, with estimated monthly savings exceeding USD 50,000, associated with reduced evacuation times, lower fuel consumption, less equipment wear, and increased productivity in drilling and hauling activities. The comprehensive approach presented here highlights the transformative potential of digital technologies applied to blast management, contributing to safer and more efficient mining operations.

Jan 26, 2026

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

Roof falls in coal mines typically occur in or around intersections and this has not changed in the last two decades. This research develops an improved scientific understanding of stress distribution and associated failure behavior around 4-way and 3-way coal mine intersections. Three-dimensional numerical analyses were performed to determine factors that influence intersection stability. The analyses used Hoek-Brown failure criterion. Failure zones around 3-way and 4-way intersections were developed. Intersection span and horizontal stress have a major influence on intersection stability. For the 4-way intersection, pillar corners across the intersection fail first and lead to progressive failure of immediate roof and floor layers. The mechanism of failure is similar for the 3-way entry but the shape and extension of failed zones differ. Coal ribs mostly fail due to tensile stress, while roof and floor strata fail due to shear stresses. Rib corners fail due to a combination of shear and tensile stresses. In addition to stress distribution; safety factor contours analysis was performed to assess stability of intersections.

Feb 27, 2013

An investigation into the stability of large open stopes at Premier diamond mine, Culinan, South Africa, is described. The open stopes are located in a weak kimberlite orebody, directly underneath a 75 m-thick sill of gabbro. Two and three-dimensional stress analyses were carried out in a back-analysis of the stresses and failure around the first open stope created under the sill. The results were used in the prediction of the future stability of the planned open stopes, intervening pillars, and sill.

Jan 1, 1987

By F. H. Newell

In 1888 the United States Geological Survey began a systematic examination of the water-resources of the West, comparable in character and scope to the study of the deposits of ores or coal. As experience was acquired, the surveys were extended to the East, until now they embrace representative localities in all parts of the United States. The object to be attained is to note and record the distribution of water-supply, and to learn, as far as practicable, the laws governing its fluctuations.

Jan 1, 1901

By W. F. Boericke

The character of the Wisconsin orebodies must be clearly understood to appreciate the difficulties encountered in sampling and estimating them. Unlike the western vein deposits, they do not lie between regular walls, but form large, often highly irregular bodies, on a single floor in the so-called Galena limestone. The bottom of the ore is nearly always on the clay bed (a flat generally well-defined clay seam a few inches thick) which marks the junction of the base of the Galena lime and the top of the next formation, the Trenton lime. Above the clay bed, the orebodies make the unique pitch and flat formation described by Chamberlin.' Theoretically, we should find two pitches, one on either side of the top crevice, diverging as they go down, with the final flats a considerable distance apart on the clay bed. The area between, known locally as core ground, should thus constitute a single defined orebody, with the richer portions near the pitches and the leaner portion in the center of the core. Practically, we find few examples of this perfect orebody. Almost invariably one pitch is better defined than the other, and often the opposite pitch is marked only by a faint line of fracture showing stronger mineralization than the wall rock, or it may be totally lacking. But with an orebody of any size or richness, at least one strong pitch usually tends to follow an east-west trend, or a quartering course. Late mining developments in the rich New Diggings field indicate that these pitches often assume a horseshoe or crescent shape, the richer ore being in the heart of the crescent and the pitches showing less mineralization as they extend outwards. In the northern end of the field, on the contrary, the pitches maintain generally a consistent direction, and have been mined for thousands of feet from the shaft. The length of the orebody may be several thousand feet, the height varying from 10 to 60 ft. and the width from 60 to 250 ft. In fact, on the core side, there is no definite end to the ore. The mineralization simply gets thinner and thinner, and the limit of working depends on the cost sheet and the profit from the recovery.

Jan 1, 1923

By W. F. Boericke

The character of the Wisconsin orebodies must be clearly understood to appreciate the difficulties encountered in sampling and estimating them. Unlike the western vein deposits, they do not lie between regular walls, but form large, often highly irregular bodies, on a single floor in the so-called Galena limestone. The bottom of the ore is nearly always on the clay bed (a flat generally well-defined clay seam a few inches thick) which marks the junction of the base of the Galena lime and the top of the next formation, the Trenton lime. Above the clay bed, the orebodies make the unique pitch and flat formation described by Chamberlin.' Theoretically, we should find two pitches, one on either side of the top crevice, diverging as they go down, with the final flats a considerable distance apart on the clay bed. The area between, known locally as core ground, should thus constitute a single defined orebody, with the richer portions near the pitches and the leaner portion in the center of the core. Practically, we find few examples of this perfect orebody. Almost invariably one pitch is better defined than the other, and often the opposite pitch is marked only by a faint line of fracture showing stronger mineralization than the wall rock, or it may be totally lacking. But with an orebody of any size or richness, at least one strong pitch usually tends to follow an east-west trend, or a quartering course. Late mining developments in the rich New Diggings field indicate that these pitches often assume a horseshoe or crescent shape, the richer ore being in the heart of the crescent and the pitches showing less mineralization as they extend outwards. In the northern end of the field, on the contrary, the pitches maintain generally a consistent direction, and have been mined for thousands of feet from the shaft. The length of the orebody may be several thousand feet, the height varying from 10 to 60 ft. and the width from 60 to 250 ft. In fact, on the core side, there is no definite end to the ore. The mineralization simply gets thinner and thinner, and the limit of working depends on the cost sheet and the profit from the recovery.

Jan 1, 1923

By Takayoshi Otsuka, Taher Elsamni, Ashraf Bou-Krisha, Takaya Takimoto

"INTRODUCTION Tunnel is a closed space structure and it is necessary to ensure the sufficient time and route for safe evacuation for the tunnel users in case of a tunnel fire. In order to do so, damages and collapse of the tunnel linings and the secondary disasters can be avoided. Furthermore, the road tunnel is one of important infrastructural facilities and stopping its function for a long time for a tunnel fire could cause a great economic loss. Therefore, the tunnel structure shall be the one which can be repaired as soon as possible, and the fire protection methods need to be selected among those which enable the service to start as early as possible. The necessity of the fire protection works is evaluated for the tunnel structure with the consideration of the expensive tunnel construction cost and the economic effects of the tunnel service. Naturally, the fire protection works, which can protect the tunnel linings from the tunnel fire with small repairs, are inevitable. Design engineers of the fire protection works estimate the scale of fire from the degree of damages on the linings and its repair cost, the effect of fire extinguishers placed inside of the tunnel, the secondary disasters in accordance with the tunnel lining damages if any, and the ratio of fire protection cost calculated from tunnel operation cost. Based on this information, the engineers design the fire protection works according to the permissible limits Among the design cases of the tunnel fire protection in Japan, as shown in Table 1, there is no cases that used the fire temperature-time curve to design the fire protection works for large fire caused by vehicles catching fire. However, the most of cases used 30-60 minutes for fire duration based on the entry prohibition of dangerous goods carrying vehicles or the effect of early fire fighting. This paper will study the variation between different methods used for fire protection in road tunnel in Japan to evaluate them and try to found some recommendations. Especial l care will be attention to Polypropylenes (PP) which is starting to be applied lately."

Jan 1, 2016

By Norman Hedley, George Barsky, S. J. Sawinson

The cyanidation of precious-metal ores is a complex chemical process. Numerous reactions occur, some of which cause an undesired consumption of alkali and of cyanide. A knowledge of these reactions, their products, and the factors that influence the rates at which they proceed should be of value in working out the most economical conditions for cyanidation; but at present, much of this knowledge is lacking. This paper is confined to a study of some of the fundamentals of cyanidation. At the start of such an investigation it is necessary to simplify the problem under consideration by eliminating as many variables as possible. The results are then, of course, not immediately applicable to practice, but it is hoped in further work to round out the information and thereby make it of more practical value. For convenience in presentation, the paper has been divided into two parts, one devoted to a study of the reaction between cyanide and gold or silver, the other to a consideration of the factors that determine the rate of dissolution. I. REACTIONS INVOLVED IN DISSOLUTION OF GOLD AND SILVER IN DILUTE CYANIDE SOLUTIONS Ever since the cyanide process for gold and silver extraction was introduced there has been discussion of the equation representing the reactions involved. In undertaking a detailed study of these factors, it was felt that the most logical first step was to determine, if possible, what reactions could theoretically take place when gold and sill-er are dissolved by dilute cyanide solutions. It is possible to determine whether or not a given reaction will theoretically take place by calculating the free energy of the reaction. This free-energy value for any given reaction is the algebraic sum of the free energies of formation of each of the reactants and products, and, if these values are known, the calculation is simple. (A chemical change always involves an energy change and the amount of energy change involved is the factor determining whether a given reaction will take place or how far it will go. In chemistry we consider what is known as the "free energy"; that is, the maximum amount of energy that can be utilized as

Jan 1, 1935