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By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

The objectives of this study were to propose a viable alternative method for recovery of precious metals such as gold (Au), silver (Ag) and palladium (Pd) from waste printed circuit boards (WPCBs) and to regenerate the spent lixiviant solution for reuse. The proposed method generally consists of several steps as follows: 1). iodine-iodide leaching for metals extraction; 2). separation and recovery of precious metals and metal impurities from a pregnant leach solution; 3). regeneration of the spent iodine-iodide solution/lixiviant. In this method, more than 99% of Au leaching was achieved in the iodine-iodide solution from the solid residue of WPCBs that was obtained via sequential processes including incineration at 800 ?C and high pressure oxidative leaching with a diluted sulfuric acid at 120 ?C, while the leaching of Ag and Pd was less than 1%, respectively. Besides Ca, Cu, Ni, Co and Zn as main metal impurities, leaching efficiency of other metals did not exceed 1%. The precious metals and base metals as metal impurities present in the pregnant leach solution were separated and recovered by precipitation using L-AA and NaOH solutions. About 99.8% Au, 81.7% Ag and 72.8% Pd were recovered from the pregnant solution at pH of 2 with the addition of 0.1 M L-AA as precipitating agent. The remained small amounts of precious metals and metal impurities were precipitated at pH 13 using 1 M NaOH. The spent lixiviant after sequential precipitation was regenerated in the presence of hydrogen peroxide, hydrochloric acid and potassium iodide. It was revealed that over 90% of gold could be extracted from the residue of WPCBs with the regenerated lixiviant solution.

Jan 1, 2018

By Hendrix JL, Nelson JH

Three ores (sulfidic, oxidized and carbonaceous) were analyzed to determine the effects of leaching time, ore depth, and ore mineralogy on cyanide species concentration. NaCN solutions were percolated through opaque columns filled with milled ore. Column design made liquid sample collection possible from various depths at specific times. The concentrations of weak acid dissociable(WAD) and total cyanide, Fe(CN)63 , Fe(CN)64 , SCN , and Cu(CN)43 were determined for each sample. Extended percolation time led to increases in WAD cyanide concentra- tions and decreased SCN and Cu(CN)43 concentrations regardless of ore depth. WAD cyanide concentration decreased while Fe(CN)64 concentra- tion increased with ore depth. Highest concentrations of Fe(CN)64- SCN and Cu(CN)43 were found in the sulfidic ore, with expected low WAD cyanide concentrations. Lowest concentrations of Fe(CN)64 , SCN 3 and Cu(CN)4 were found in the oxidized ore. Intermediate concentra

Jan 1, 1988

By Denghong Wang

Abstract- The Ashele Cu-Zn deposit is a recently discovered volcanogenic massive sulfide deposit in Xinjiang, China, hosted by Lower to Middle Devonian submarine bimodal volcanic rocks. The primary ores of this polygenetic deposit are represented by massive syn-depositional pyrite, chalcopyrite, and sphalerite, and were formed by submarine exhalation. Hydrothermal alteration consists of strong sericitization, chloritization, silicification, and carbonatization of the metavolcanic rocks beneath the massive orebodies. Depletion of Na2O is an obvious chemical change in the hydrothermal halo. Geological and geochemical evidence suggest that the Ashele Cu-Zn massive sulfide deposit was formed by submarine exhalation related to bimodal volcanic rocks, trapped in a rifting basin, then deformed by shearing, and thermally metamorphosed by the intrusion of dacitic porphyry. Sulfur and lead isotopic studies indicate that metals such as copper and zinc may have originated from spilites, but that volatile components, especially sulfur, were derived directly from submarine volcanic magmas.

Jan 1, 1999

By Rush Kramer

A bulk compositional chemical analysis often provides incomplete information to help the mineral processor when faced with the problem of removing troublesome contaminants in low concentrations. Michigan Tech has developed a unique approach for addressing this problem. A combination of Scanning Electron Microscopy (SEM). Energy Dispersive Spectroscopy (EDS). and image analysis was successfully used to characterize the species responsible for phosphorus contamination of less than .05 weight percent in iron ore. An automated routine acquired the chemical signature of each particle on a backscattered electron image. The few particles containing phosphorus were identified from the hundreds of particles examined. and the phosphate phases present were easily characterized.

Jan 1, 1991

By Evans E. C.

At first sight, the extinction of a mine fire by the action of some such gas as carbon dioxide would appear to be quite a simple and practicable operation. From a consideration of the theoretical aspects only of the question, it becomes evident that the matter is not so simple as it appears to be at first sight. The fire at the Senghenydd Colliery occurred as the result of the disastrous explosion of October 14th, 1913. This explosion was confined to the west side of the colliery; and as a result the timbers in the main intake on this side were set on fire; but these were soon buried beneath falls, and the tire continued under them. Attempts were made to extinguish it with water, with the aid of chemical extinguishers, and by digging it out; hut these had to he abandoned, and ultimately the fire-zone was sealed off by “ bashings” (stoppings). By December, progress in the decrease of combustion was so slow that it was decided to try the effect of inert gas. The installation, control and operation of the carbon dioxide plant and associated water-gauge are described in detail and conclusions drawn for the extinguishing of mine fires by CO2

Dec 1, 1916

By Robb. V. M., F. Walraven, L. J. Robb

"Abstract -The old Albert Silver Mine is a polymetallic deposit comprising concentrations of Cu­ Pb-Zn-Ag-U-F within a set of sub-parallel quartz-hematite veins which occur within the fine-grained apical phase of the 2050 Ma old A-type Bushveld granites. Mineralization occurs as an early pyrite­ chalcopyrite-arsenopyrite-galena-sphalerite-(argentiferous) tetrahedrite paragenesis followed by a later, more oxidized assemblage comprising chlorite-hematite-fluorite-pitchblende. Accumulation of metals appears to have taken place at the interface between a coarse-grained porphyritic granite and an overlying fine-grained phase: veins occur in the latter and represent leakage of magmatic fluids from the differentiated, water-saturated, subjacent granite.Mineralization processes in the Bushveld granites are believed to be related to long-lived circulation of dominantly magmatic fluids stimulated by the high heat productive capacity of the host rocks. Endo- and exogranitic tin-tungsten and base metal mineralization formed during an evolving hydrothermal system that lasted for several hundred million years, forming innumerable small- to medium­ scale polymetallic deposits. At the Albert Silver Mine, unroofing of the cover sequences at circa 1600 Mato 1700 Ma resulted in the incursion of lower-temperature, high-f02 meteoric fluids which remobilized the earlier sulfides and introduced the paragenetically late U-F mineralization ."

Jan 1, 1994

By Robin P. Gardner

The mechanistic or phenomenological approach to ball milling involving the, concepts of particulate selection and breakage functions with particle population balance models has been well established over the past decade (c.f., the review articles by Austin (1) Herbst and Mika, (2) and Snow (3)). Initial efforts to apply this approach concentrated on batch milling, but since most milling in industrial practice is continuous, much recent research has been directed to extending this approach to continuous milling. The primary difference between batch and continuous milling processes is the relative importance of material mixing and transport in the mill in the latter case. Much analytical (4-8) and some experimental (9-15) work on the effect of mill mixing and transport on milling has been recently reported. Much of the analytical work has naturally centered around extension of the well-developed concepts that have been applied to chemical reactors, (16-18) Fortunately, it has been found(1) that most milling processes are analogous to first-order chemical reactions so that the combined effects of material transport and reaction (breakage) can be handled by the relatively simple segregated flow concepts. (8)

Jan 1, 1973

By David H. Sanders, Ramin Motamed, Fahim M. Bhuiyan, Raj V. Siddharthan

Large-diameter drilled shafts (DS) are a critical part of a seismic-resistant system, and therefore it is important to be able to accurately model lateral resistance. To undertake the lateral load analysis of largediameter DS, a finite-difference p-y analysis program, NVShaft, is being developed at the University of Nevada Reno. Validation of the new program involved numerous p-y analyses using commercially available programs. Subsequent comparisons suggested the program's ability to yield reasonable predictions for typical diameter DS. Based on the I-15/US 95 load test program carried out in Las Vegas, NV, this study presents the evaluation of NVShaft in Nevada’s subsurface condition. Lateral load analyses of a 2 ft and an 8 ft diameter DS were attempted using NVShaft. The location of the applied lateral loads and the presence of cemented soil-layers were incorporated in the modeling. A good agreement between NVShaft prediction and the measured response was found for the 2 ft diameter DS. For the 8 ft diameter DS, a stiffer response was predicted. The inspections of the moment-curvature characteristics at different load levels suggested cracked response of the concrete due to prior axial load testing may be one of the reasons behind the deviation.

By Anderson DR, Tassell G

A major environmental impact study carried out in the sand dunes of eastern Cape York used image analysis of remotely sensed data to both select sites for ground investigation and categorise the different ecological units present. The approach adopted was particularly suited to the type of environment in question and allowed a high degree of quantification, at a high level of confidence, at costs several orders of magnitude less than conventional Methods.

Jan 1, 1987

By R. A. Pallanch

Probably one of the most perplexing problems with which a mill operator contends is the proper evaluation of his mill results. True, he accurately determines his recoveries of metals and grades of products monthly, weekly, and often daily. These figures do not of themselves directly translate to mill economics. When one figure is unusually good there may be an offsetting circumstance. The advantage of high lead or zinc concentrate grade may be offset by poorer recovery; high lead recovery may be offset by poorer zinc recovery, or vice versa; and so on. Besides, grades or recoveries may not of themselves mean more than a reflection of the grade and character of the ore during the period under study. What the operator sorely needs is some one measuring stick that tells him when he has achieved his greatest return, regardless of grades or recoveries—for if he knows his methods and practices are yielding the optimum return he need no longer concern himself with the assays of products and tailings, or the corresponding distribution of metal values. At first blush it would appear that the obvious answer to this is the actual money return to the mill. Paradoxical as it may seem, however, money return does not make a dependable yardstick any more than do grades and recoveries, as ore condi- tions would vary enough to bring about greater money return during periods when the actual metallurgical work is not as good. The mill operator, of course, should always aim for the greatest return on the ore, once it is in the mill bins, with proper attention always to mill treatment cost. The need of a proper yardstick becomes more imperative with the increasing complexity of the problem. In the case of a simple, single-product operation on a fairly uniform ore, in which only one metal is of significant importance, the need is not great, as grade and recovery pretty well tell their own story. At the other extreme is the operation that makes three or four separate marketable products from a complex mixture of heterogeneous ores that vary tremendously in individual metal contents and ratios, degree of oxidation, and other characteristics, and in which gold, silver, copper, lead and zinc are all significant values. Economic Recovery The first attempt at obtaining a proper single yardstick for a fairly complex ore with which I am familiar is the use of the ''Economic Recovery" term at the lead-zinc flotation mill of the Sunnyside Mining and Milling Co., Eureka, Colorado. This method had been applied there early in Sunnyside flotation-mill history (not later than 1920) and credit for the innovation I believe belongs to Messrs. Kuryla and Marquand. The term "Economic Re-

Jan 1, 1949

By Werner A. Dürrfeld

The Bullflex® System was introduced as a substitute for timber and debris lagging in mines and to create an in-situ early-stage interlocking effect between steel supports and the rock wall. As deplacement and/or disintegration of strata and of rock beds is to be avoided under all circumstances - following the ideas of NATM-steel support can only be loaded to the maximum when point load is avoided and ideal bedding of the rock is maintained.

Jan 1, 1981

By J. Van Oirbeek

The ash-fusion gas producer, blown with air preheated to a high temperature, was perfected by the Société des Houilléres de Saint-Etienne during the years 1920 to 1925, for the treatment of a mixture of ashy fuel and limestone. The temperature, about 1800° C., obtained by using hot air in running the producer, ensures the fusion of all the slag and the transformation into carbon monoxide of every particle of carbon contained in the materials treated.

Jan 1, 1937

By Lawrence D. Ramspott

A test of retrievable geologic storage of spent fuel assemblies from an operating commercial nuclear reactor is underway at the Nevada Test Site (NTS) of the U.S. Department of Energy his generic test is located 420 m below the surface in the Climax granitic stock. Eleven canisters of spent fuel approximately 2.5 years out of reactor core (about 1.6 kW/canister thermal output) were emplaced in a storage drift along with 6 electrical simulator canisters. Two adjacent drifts contain electrical heaters, which are operated to simulate within the test array the thermal field of a large repository. Fuel was loaded during April-May 1980 and initial results of the test will be presented.

Jan 1, 1981

By S. Mellgren, W. Opie

AN equilibrium state of importance in the process of electrolytically depositing titanium from fused chloride electrolytes is that which exists between titanium metal, titanium dichloride, and titanium trichloride. This can be expressed by the reaction titanium concentration of the solution, temperature, and the proportion of strontium chloride and sodium chloride in the solution. Procedure The general procedure used consisted of the following steps: 1) Development of an analytical method for determining Ti+2 and total titanium. 2) Preparation of batches of fused salt solutions containing various amounts of total titanium, Ti+2 and Ti+3 3) Blending of the prepared batches and excess titanium metal in Vycor tubes and allowing the solutions to come to equilibrium. By blending, solutions with different total titanium content could be prepared and equilibrium could be approached from the high Ti+2 and low Ti+2 sides. 4) Studying the effect of titanium concentration, temperature, and the mole ratio of the solvent chlorides, SrC1, and NaC1, upon the equilibrium.

Jan 1, 1958

By D. Krammer, E. S. Machlin

The effect of a brior high-temperature creep strain on the low-temperature ductility of commercially pure nickel has been evaluated. The low-temperature (-196°C) ductility decreases linearly with an increase in prior high-temperature (920°C) creep strain. The effect is experimentally correlated to the formation of inter crystalline cracks and voids during the prior high-temperature creep strain. The magnitude of the effect is also believed to be a function of the notch sensitivity of the material. SEVERAL mechanisms have been presented to explain the process of inter crystalline cracking in metals undergoing high-temperature creep. zenerl has suggested that grain boundary relaxation of shear stresses could build up high stresses at ob- stacles to grain boundary shear and thereby nucleate a crack. Chang and rant' have experimentally demonstrated that cracks do form at obstacles to grain boundary shear such as lines where three grains meet. The role of vacancies in the mechanism of high-temperature inter crystalline cracking has been explored by Machlt with the conclusion that the nu-cleation of voids by vacancy condensation is almost

Jan 1, 1960

By A. M. Galperin

Back analysis is a very important procedure for proper understanding of physical processes. Back analysis can be used to establish the role of different factors, define parameters to be calculated and formulate the behavior of natural or physical processes based on field experimental results. It is evident that, in order to obtain the necessary data for back analysis, field observations are required. For the Michailovsky region (Kursk Magnetic Anomaly, KMA) the long-term strength characteristics of the clay covering the quarry slopes were established with the help of back landslide calculations. The obtained data allowed quantification of the shearing resistance parameters at the presence or absence of intermittent dips of discharge in the pit bank massif structures. Based on the results of investigation for material composition, strength and deformation of finely dispersed (clay-chalk) deposits in the Kursk Magnetic Anomaly including measuring of the settlements of filled structures, complex probing and laboratory determination of water-physical and mechanical properties of "man-made" soils, engineering-geological zoning of filled structures was carried out.

Jan 1, 2005

By J. D. Noll

Elemental carbon (EC) is used as a surrogate for regulating the exposure to diesel particulate matter (DPM) of underground metal/non-metal miners. EC was chosen as a surrogate because EC is selective to DPM and is a major component of DPM. Using EC as a surrogate also gives one the advantages of no sampling artifacts and being able to sample at all locations in the mine. Currently, EC represents DPM well in underground mines. Some control technologies have been shown to possibly alter the relationship between DPM and EC and characteristics of DPM. Therefore, future work will investigate the relationship between DPM and EC as new control technologies are implemented.

Jan 1, 2002

By M J. Thurley, M Wimmer

To assess the present-day functionality of large-scale sublevel caving at LKAB Kiruna a comprehensive measurement program was undertaken involving blast function, fragmentation and gravity flow. As part of this assessment, a fragmentation measurement trial was performed based on 3D imaging of the drawpoint and corresponding bucket load of the underground load-haul-dump (LHD) excavator. 3D image data from stereo photogrammetry was collected and an automated image analysis strategy developed. A number of data sets were collected for each of the drawpoint and LHD bucket, along with sieving results for four of the LHD bucket loads (totally about 70 t). Two of the sieving results were used to inform the automated image analysis strategy, and two were held back as a comparison. Large variations in the visible particles are apparent when comparing corresponding drawpoints and LHD buckets highlighting the impact of sampling location and the need to measure large quantities of data in order to avoid bias from small samples. The results show that 3D imaging and analysis can produce fully automated measurement and analysis of the visible particle size distribution. Although this is not the same as the sieve-size distribution it provides useful estimation of both the larger size classes and a bulk estimate of fine material below approximately 60 mm. The 3D stereo photogrammetry measurement system used produced very high 3D point density but this was achieved using a custom up-sampling technique which significantly smoothed the data, removing small particles, smoothing edges, and this negatively affected the particle delineation algorithms.CITATION:Thurley, M J, Wimmer, M and Nordqvist, A, 2015. Blast fragmentation measurement based on three-dimensional imaging in sublevel caving drawpoints and underground excavator buckets at LKAB Kiruna, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 763–774 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By N. M. Komkov

The main operation of obtaining zinc from sulfide raw materials by hydrometallurgical technologies is the oxidation roasting of zinc concentrates in fluidized bed furnaces. The technical-economic parameters are determined by the parameters of the roasting process, which depend on the composition of the initial raw materials, the temperature of the bed and on other factors. The predetermined roasting temperature is maintained due to the change of specific efficiency as well as to the quantity of the heat removed from the bed. The efficiency of caissons depends at a high degree on the composition and the thickness of the accretion formed on the surface of the caissons. Forecasting the roasting results is impossible unless we know the mechanism of the accretion formation. The aim of the present paper is the thermodynamic analyses of the behavior of the charge compositions under roasting and the determination of the potential mechanism of the accretion formation. The thermodynamic analyses show that under conditions of the oxidation roasting the thermodynamic probability of the formation of zinc sulfate is higher than the probability of the oxide formation until a temperature of873 OK is reached. The thermodynamic probability of the formation of the lead sulfate is higher than the probability of oxide formation in the entire temperature range of roasting. The probability of formation of ferrites and silicates of zinc decreases only insignificantly the sulfate stability. The results of the investigation of the accretions composItion formed under roasting of concentrates with particle sizes less than 0.02 J..lm (60%), containing 65% of sphalerite (ZnS), 12% of pyrite and chalcopyrite (FeS2 and CufeSz) each, 3% of galenite (PbS), 7% of silica and other non-ore minerals, have shown that the composition of accretion varies depending on the depth of the accretion layer. The accretions on the caissons and the thermo-siphons consist mostly of zinc sulfate (more than 50%). The accretions of forehamber consist mostly of zinc oxide. They also contain ferrites and silicates. The formation of the sulfate zinc accretion in the cold parts of the fluidized bed furnace (the caissons and thermo-siphons) may be explained by a lower temperature on the surface and probably by a catalytic influence of the present oxides in the formation of S02 and sulfates. The nature of the structure of the accretion in the hotter parts of the furnace may supposedly be explained by the formation of elemental vaporous zinc during roasting.

Jan 1, 2003

By J. Edberg

"This article details the use of an alternative testing method to the 2004 "Post-Tensioning Institute (PTI) Recommendations for Prestressed Rock and Soil Anchors" manual’s recommendations for temporary and permanent rock anchors for applications in shafts and tunnels. This method was developed and used for the Black River Tunnel (BRT) project in Lorain, OH as a means to reduce testing time of rock bolts during shaft construction while maintaining a similar level of quality control and assurance. The following sections will detail the project background, subsurface characteristics, shaft construction, the 2004 PTI testing method and associated difficulties, the alternative testing method and conclusions reached.Project backgroundThe city of Lorain is located in north central Ohio on the south shore of Lake Erie, approximately 40 km (25 miles) west of Cleveland and 119 km (74 miles) east of Toledo. The city chose to build a large-diameter storage tunnel and pump station to meet its requirements to reduce sanitary sewer overflows to the nearby Black River. NTH Consultants Ltd. (NTH) was retained by the city’s prime consultant, Malcolm Pirnie Inc. (now the water division of Arcadis), to perform a geotechnical investigation, develop design and construction bid documents for the tunnel and shaft liner systems and ultimately provide oversight assistance during the construction phase of the project.The BRT is an approximately 1,700-m (5,560-ft) long, 7-m (23-ft) diameter rock tunnel to be lined with a 5.8-m (19-ft) inside diameter secondary concrete lining (Fig. 1). The tunnel is designed to accept flow at a new drop shaft (Shaft 3) located on the west side of the Black River, across from the city of Lorain Black River waste water treatment plant (BRWWTP). The tunnel will be dewatered at the south end by a large diameter pump station (Shaft 1) located in the existing Lorain Port Authority Public Boat Launch. Flow from the new pump station will be discharged into an existing shallow interceptor sewer and directed back to the BRWWTP."

Jan 1, 2014