Search Documents

By James M. Barker

No commodity agreements now exist for sulfur and a lack of reference to sulfur commodity agreements exists in the literature. Law (1975) made a passing reference to sulfur as one of a group of commodities where "there have been additional control efforts of various types." Clearly, sulfur was a candidate, at least conceptually in the past, for some form of commodity agreement and the following discussion centers on the world sulfur market of the early 1980's in this context. GENERAL THEORY OF COMMODITY AGREEMENTS The upsurge in demands for commodity agreements seen in the last decade or so stems largely from agitation by the less developed countries (LDC) for better economic treatment by more developed countries (MDC). Several economic factors, real or imagined, adversely affect the LDC's as follows (MacAvoy, 1977): 1) variable demand in MDC's causes wide fluctuations in commodity prices which hurt the economies of commodity producers, who are often LDC's although consumer economies may also benefit from more predictable prices; 2) a general decline of commodity prices relative to the price of manufactured goods which hurts commodity producers in their balance of trade while their stocks and overcapacity rise; 3) instability of LDC economies enhanced by the above factors lowers internal stability, inhibits foreign investment, and retards economic growth; and 4) a lack of self respect when dealing with developed countries o, following the OPEC lead, LDC producers want the stature related to cartel market power.

Jan 1, 1985

By James A. Wasson

This report summarizes the results and conclusions reached by various investigators who have attempted to determine the extent to which hydraulic fracturing will affect the secondary recovery of crude oil by waterflooding. It also discusses the most advantageous use of this well-stimulation method in waterflood projects. A thorough search of the literature was made, and pertinent information was abstracted from appropriate reports. A carefully designed and controlled program of formation fracturing is an effective aid in waterflooding because it increases water-injection and oil-production rates. Generally, fracturing has resulted in little or no reduction in ultimate oil recovery, but under certain circumstances recovery has been substantially increased.

Jan 1, 1963

By Serge V. Krasavin

The behavior of rocks subjected to dynamic loading conditions under explosion includes sufficient information about hydrodynamic variables such as pressure P, mass velocity U, internal energy E, specific volume V and density p as functions of time. Measurement of dynamic characteristics in compressed media with manganin wire sensors has become common in the past few years, but the experimental data for certain media, such as rock, do not provide an exhaustive description of rock's behavior in the near zone of an explosion, which is highly responsible for the transformation of energy of explosives.

Jan 1, 1992

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By Orr D. B

This is a case history of prospec- ting carried out by Comstaff Pty. Ltd. over the Pinnacles Area, part 4 of Exploration Licence 5/63, 9 km north of Rosebery in Western Tasmania. Evidence is presented to show that A 0 soil samp ling is a viable prospecting method for outlining polymetallic sulphide occur- rences in areas where leached organic/ glacial soils are common. Diamond drilling of low threshold anomalies has intersected base metal mineralisation.

Jan 1, 1977

By D. E. Traut

A fluidized countercurrent ion-exchange system was developed, operated, and evaluated by the U.S. Department of the Interior, Bureau of Mines. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows were continuous except for short periods when resin increments were withdrawn. The exchange of uranyl carbonate between a simulated in situ uranium leach liquor and a strong-base ion-exchange resin together with the subsequent elution with an ammonium chloride solution was studied. The effects of the number of sections, section height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. The kinetic and equilibrium relationships for the absorption and elution steps were also examined. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The column was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By M. Reza Saberi, T. Ted Miyake

Driven piles are a common tool in any engineer’s toolbox for supporting large structures over very soft ground, especially in high seismic risk zones. Challenges include achieving sufficient vertical and lateral load capacities within the constraints of pile spacing and geologic conditions. This was the case for a project in Orange County, California with a state-of-the-art, $180 million plant for biosolids processing, biogas management and energy recovery located in marshland next to an existing waste water treatment plant. The new construction for the Irvine Ranch Water District included a 70-foot (21 m) tall building and three closely spaced, 90-foot (27 m) high, 65-foot (20 m) diameter, egg-shaped steel digester tanks. The lower 35-feet (11 m) of the tanks were constructed below ground level. The site was underlain by up to 45 feet (14 m) of highly compressible peat and organic clays with standard penetration test (SPT) blows as low as 2 blows/ft (30 cm). Some of the peat layers had measured in-situ dry densities of less than 30 pcf (480 kg/m3) with moisture contents of over 250 percent. The soft clays and peat were underlain by a dense layer of sand and gravel at depth. Groundwater was very shallow. While nearby sites were designated by others as seismic site class “D”, this site was clearly class “F” (SF) which required site specific seismic hazard and time history analyses. Six recorded time histories were selected from the 1994 Northridge, 1989 Loma Prieta (California) and 1999 Chi Chi (Taiwan) earthquakes for the ground motion analysis considering the magnitude of the earthquake, distance to the source, characteristics of the earthquake source (i.e. type of fault displacement), peak ground acceleration, local site geology, station type (i.e. free-field or small structure stations), and spectral content that was similar to the period range of interest. Following ASCE’s Guideline Document 7-05, a site-specific horizontal acceleration response spectra (ARS) was developed for the maximum credible earthquake (MCE) associated with the site.

Jan 1, 2018

By R. H. Grau, S. B. Robertson, J. Dolgos, T. P. Mucho

The National Institute for Occupational Safety and Health (NIOSH) has developed a computer program called the Air Quantity Estimator (AQE). The purpose of the program is to provide a starting point for estimating the air quantity needed to dilute diesel particulate matter (DPM) in an underground large opening mine, albeit taking into account various input assumptions. The AQE estimates the total air quantity needed to dilute DPM emissions that enter the main airstream of the mine to current statutory levels. It helps operators pinpoint vehicles that are high DPM contributors. In addition, it allows the user to make “what if” scenarios by varying the input parameters to achieve the most efficient and practical ventilation system. The AQE is a stand-alone software program that does not require any type of spreadsheet software. Engine data must be known or estimated with some accuracy and assumptions must be made in order to limit the variability of the program output. Program calculations and two case studies, for validation purposes, are included in this report. It should be noted that the program does not ensure adequate face ventilation and personal exposure compliance.

By U JSger

The Westerschelde tunnel will be the first permanent road link between the Dutch regions of South Beveland and South Flanders. Two tunnel tubes, each 6.6 km long, will be driven using the shield tunnelling method. The difficult ground conditions and a water pressure of up to 6.5 bar make great demands on the design. This paper describes the problems and their solutions.

Jan 1, 1999

Clinoptilolite as a Low-Cost Solution to Remove Heavy Metals from Water in Mining and Mineral Processing Industry

Sep 13, 2010

By Gerald A. Crawford

"1880s - Unmasking the Sudbury Basin Falconbridge Ltd. turned 60 in 1988 but its roots go back more than a century to the discovery and development of the mineral resources of the Sudbury Basin. Nickel was first identified in the area in 1856 but sustained exploration awaited the early 1880s and the advance of the CPR westward from Sudbury. Rock was laid bare in the right-of-way and by forest fires and logging. Reddish oxidized outcropping or ""gossan"" were exposed, heralding the presence of nickel as the shape of this astounding geological formation gradually began to emerge. Many great mines of the area were opened up in this period on the south rim of the Basin west of Sudbury. To the east the ore dips below overburden, however, and Falconbridge remained a mere dot on the map until the turn of the century when Thomas Edison detected a magnetic occurrence by dip needle."

Jan 1, 1999

By R. Grimard, M. Gamache, L. -P. Bigras, P. Cohen

This paper describes a real-time fleet management system for an undergroun mine. Dispatching, routing and scheduling are handled simultaneously, taking into account the mine status, operational constraints and vehicle location information. Each assignment decision takes into account the traffic on the road segments of the mine network, whether road segments are bi-directional or uni-directional, and ensures that each LHD (load-haul-dump) vehicle arrives at loading and dumping points with the correct orientation. Such a system can be used either as a simulation tool for strategic planning or as a real-time managing and optimizing system for operations. In the simulation mode, the system can accurately estimate the impact on productivity of decisions such as the development of waiting areas (bays, sidings), or the addition (elimination) of vehicles to the fleet in operation. When used for real-time dispatching, routing and scheduling of vehicles, the system can optimize production with respect to various assignment criteria such as cycle-time minimization or deviation from a target production plan.

Jan 1, 2004

By Eric Barnard, Andreas Nashitati, John Tero, Guy Deschênes, Setta Mbalamba, John Rajala

The Otjikoto Mine, owned at 90% by B2Gold Corporation, is located 300 km north of Namibia’s capital city of Windhoek. The reserves from the open pit mine, estimated at 25.9 million tons with an average grade of 1.28 g/t Au, contain gangue minerals, pyrite and pyrrhotite, and have an estimated 10 year mine life. The feasibility study included an optimisation of gold leaching using CSTR for the original design. The results of the test work were used to establish the design criteria. Gravity tails from three composites (drill cores), representing the major ore types, were used. The XR3 sample (gravity tails) contained 0.32 g/t Au, while the XR2 and XR1 gravity tails samples (used for variability) contained, respectively, 0.30 g/t Au, and 0.47 g/t Au. The optimum leaching conditions were: a pre-treatment of 7 h at pH 10.5 with 100 g/t lead nitrate, DO > 5 ppm followed by cyanidation at 300 ppm NaCN, pH 10.0, DO > 5 ppm for 48 h. The gold extraction was 91.5% (97.2% overall extraction gravity/leach) and the cyanide addition was 0.57 kg/t NaCN. Increasing the DO to 16 ppm did not show any economic benefits. No pre-treatment or a 4-h pre-treatment reduced the gold leaching kinetics. The XR2 and XR1 gravity tails samples had gold extractions of 92.9% and 92.3%, respectively. At the plant scale, an 11 h pre-treatment is used followed by 42 h cyanidation with 250 ppm NaCN and an average DO of 8 ppm and 230 g/t lead nitrate in 2016. The cyanide addition was 0.49 kg/t NaCN. The commercial operation started on February 28th, 2015. The overall gold recovery and production were 98.4% and 145,696 ounces for 2015 and 98.1% and 166,286 ounces for 2016. It was found that retention times, gold content of leach residues and cyanide addition are comparable for the lab and the plant. Details of the Otjikoto process flowsheet are discussed in this paper along with the results of the lab leach optimisation test program and the plant leach circuit performance and improvements.

Jan 1, 2017

By J Williamson, M Griessmann

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Watershed tungsten deposit is located in the Hodgkinson Province of north Queensland, Australia. The deposit is hosted by Siluro-Devonian flysch-type meta-sediments of the Hodgkinson Formation, which were subjected to four major deformation events. Mineralisation has occurred syn- to post-D4 and is related to the intrusion of S-type granitoids of the Permian Whypalla Supersuite.Watershed is located within a regional NW–SE-striking melange zone composed of brecciated and intermixed arenites and shales. The major NW–SE-striking Tullah fault zone is situated in close proximity to the east of the deposit.The Watershed deposit occurs within a tightly folded upright anticline with NW-plunging fold axis. The anticline contains a major package of coarse-grained to conglomeratic arenite, which harbours the Watershed mineralisation. Several alteration styles occur within the arenites, of which Fe-poor calc-silicate alteration dominated by clinozoisite/epidote is the most significant. Less widespread but locally important alteration styles comprise garnet-dominated calc-silicate alteration, albitisation and sericitisation. The arenites are enveloped by unmineralised carbonaceous shales and shale breccias.Tungsten mineralisation occurs solely as molybdenum-poor scheelite and can be found as three styles: disseminated mineralisation in calc-silicate altered arenites, vein-style mineralisation with quartz-albite-scheelite veins and minor but high-grade mineralisation in albitised felsic dykes.Contact metamorphic rocks and geophysical data indicate the proximity of an underlying granitic body. It is believed that this granitic body was the main driver of the hydrothermal system generating the Watershed deposit. An early mineralisation stage caused the selective calc-silicate alteration of the arenites, while a second stage caused the vein-style high-grade mineralisation. The folded shales enveloping the arenites worked as an effective barrier that kept the mineralising fluids in a confined rock volume.The scheelite mineralisation at Watershed is open to depth, with a granite-hosted porphyry or greisen-style mineralisation anticipated below the current resource.CITATION:Griessmann, M and Williamson, J, 2015. The calc-silicate-hosted Watershed tungsten deposit, far north Queensland, Australia , in Proceedings PACRIM 2015 Congress, pp 545–550 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By J. H. East

"INTRODUCTION .Very little information regarding coal mining in Spain has been published in the American technical press, and few people realize the extent of this industry or the conditions under which coal is mined. The information in this publication was collected in 1945 and consists of personal observations in Spain, statistics, and other data of a, general nature obtained from official sources.Spain produces bituminous coal, lignite and anthracite, but the total tonnage mined is less than the national requirements. Before the war, an appreciable tonnages coal was imported from Great Britain under the Anglo-Spanish treaty, which rebated import duties and effectually prevented competition from any other foreign source. The war stopped the major part of the important of British coal and caused rapid expansion of the domestic sources, but this was not sufficient to supply the industrial demand. Coal that formerly was not acceptable to industry because of quality is now mined and marketed. The Government, allocates the better-grade bituininous coal to the various industries in accordance with the national importance of the work in which they are engaged; for example, the railroads are allotted 100 percent of their requirements, but cement companies can obtain only 25 percent.The Government offered to inducements to increase the production of coal of any class, but the larger part of the increased tonnage obtained was in inferior grades; as a result, the lignite production was taxed, while a bonus was paid for bituminous-coal production in excess of the 1942 tonnage.The anthracite and bituminous-coal areas were severely damaged during the Civil War and many experienced miners migrated to the lignite mines in eastern Spain. This has resulted in an acute shortage, particularly the Province of Oviedo where the most important bituminous-coal deposits are located."

Jan 1, 1947

By Jan M. Peter

Many massive sulfide deposits and districts around the World contain rocks that are variously referred to as ?exhalites?, banded iron formation (IF), ?Algoma-type? IF, ferruginous chert, jasper, jasperoid, cherty tuff, tuffite, tuffaceous exhalite, chloritic IF or sulfide IF. With few exceptions, such rocks are thought to be (in part) fossil hydrothermal sediments deposited from hydrothermal fluids vented into a submarine rift environment. Such hydrothermal sediments are associated with a wide variety of ancient base-metal sulfide deposits (e.g., Cyprus-, Besshi-, Kuroko-, and Broken-Hill-type deposits), and hydrothermal sediments are commonly associated with some of the largest base metal sulfide deposits in the world. Analogs of ancient hydrothermal sediments can be found around many modern seafloor hydrothermal deposits which themselves precipitate from high-temperature (350°-400°C) hydrothermal fluids. Hydrothermal fluids are quenched on contact with ambient seawater, and most of the metals are immediately precipitated to form the mound and chimney deposits. However, for kinetic and solubility reasons, not all metals and other species are immediately precipitated at the vent site. Fine particles (up to several hundred microns in diameter) of sulfides, sulfates, carbonates, oxides, silica, Fe-oxyhydroxides, clays, and other phases are precipitated from the hydrothermal fluids in the water column above the deposits. These particles or "particulates" are carried upward for several hundred meters in a buoyant hydrothermal plume (which is typically several hundred meters thick) until it reaches a neutral density, and disperses laterally from the vent site. Modelling of plume dynamics has shown that the majority of particulates are deposited by gravitational settling a few hundred meters from the vent site, and Å99% of particulates are deposited within 3 kilometers. However, signals from modern plumes have been detected even hundreds of kilometers from their source. Factors which can affect the morphology of the plume (and the resultant fallout pattern) include: particulate size, shape and density, bottom topography, and the direction and velocity of bottom currents.

Jan 1, 1998

By P. J. Williams, A. R. Foster

Petrographic studies, assay records, and laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) analyses of major sulfides suggest nearly all of the gold at the Ernest Henry Cu-Au deposit occurs in the form of native gold or electrum (95-65 wt.% Au); sylvanite and dissolved gold in cobaltite, chalcopyrite, and pyrite make only minor contributions. LA-ICP-MS analyses of the gold contents of chalcopyrite gave from 8 to 139 ppb (mean = 56 ppb), more than an order of magnitude lower than those experimentally determined in chalcopyrite in equilibrium with native gold at the estimated mineralization temperatures (350°-450°C). Gold content is more variable in pyrite (1-400 ppb, mean = 77 ppb) and highest in narrow growth zones of a subordinate type of complexly zoned pyrite wherein it is associated with elevated As, Ag, Sn, Sb, Te, and Bi. Deposition of gold-electrum was closely associated with, but preceded some of the chalcopyrite deposition, as indicated by microtextures and lower bulk Au:Cu ratios in late-stage chalcopyrite-rich veins. Gold grains have maximum dimensions from <1 to 50 micrometers, and are heterogeneously distributed with most occurring in microscale clusters. Fifty-five out of 76 grains recorded in polished sections are in contact with both chalcopyrite and pyrite, and many of the rest are in sites where such a relationship could exist in the third dimension. The dominant textural sites are intergrowths with chalcopyrite in microveinlets cutting pyrite, and on faces of pyrite grains in contact with chalcopyrite. Scanning electron microscopy, electron microprobe analysis, and proton induced X-ray emission studies show that pyrite associated with gold includes complexly zoned, weakly zoned, arsenian, and arsenic-poor types. The textures are compatible with the possibility that most gold was deposited electrochemically as native metal on pyrite surfaces. The textural distribution of gold has important metallurgical implications given that the ore processing circuits at Ernest Henry and most other sulfide copper mines are designed to exclude pyrite (and arsenic) from concentrates.

Jan 1, 2007

By G. M. Cresswell

The 2 360 t/h two module Phola coal preparation plant represents anew era of large plant in the Witbank coalfield designed to extend its life to 2020 and beyond. The plant uses the optimum processing model for Witbank coals, receiving a feed coal size of -50 mm, wet screening it into coarse and small coal fractions 50 x12 and 12 x0.63 mm before processing them in parallel through two primary DM cyclone sections, in order to make a 27.5 MJ/kg export floats product. The sinks are processed through a common high density DM cyclone section to produce a 21.5?23 MJ/kg thermal coal middlings product. The plant design incorporates the largest size DMS equipment used to date in South African coal preparation plants, i.e. 1 150 mm large diameter pump fed DM cyclones and 4.2 m width banana screens. The fine coal is conventionally processed by spirals, whereas the raw coal slimes are filtered using automated plate and frame filter presses and added to either the middlings or discards depending on its quality. The paper describes the database, innovative design concepts, construction, and commissioning.

Jan 1, 2010

Grinding and Flowing Investigation on Dry Stirred Ball Milling in Order to Determine the Influence of Grinding Aids Huge difficulties of the great ultra fine ground material production in dry stirred ball mill are the cohesion and agglomeration of the particles. During grinding the material stick on the grinding wall and the grinding media furthermore the grinds start cohere, making aggregation and agglomeration to appear. Due to these effects the particle size will not decrease after a certain value during grinding and the energy demand increases significantly. According to experience on fine grinding in ball mill, it is well known that these effects can be reduced with the use of grinding aids. The influence of grinding aids has three different effects: due to the adsorption strength reduction (Rebinder effect) the grinding resistance of the material decreases; the surface energy diminishes and the agglomeration liability decreases; and the flow properties of material improve. The aim of this study is to investigate the flow properties of fine grinds and the effect of grinding aids on flow properties in case of dry stirred ball milling. In addition, the influence of grinding aids was investigated based on the particle size distribution and specific surface area of grinds and the specific energy demand of grinding. The examinations were carried out with three different model materials (limestone, clinker, quartz) using the usually applied grinding aid. The flow properties were measured by the Jenike shear cell; the particle size distribution and specific surface area were measured by laser particle size analyser (Fritsch Analysette 22), grinding energy demand was measured with microcomputer controlled digital energy meter. It can be said that under certain measuring circumstances the influence of grinding aid on flow properties can be demonstrated by Jenike shear cell, so the grinding result is in correlation with the flow properties of grind.

Sep 13, 2010

By H. Conrad

The strain hardening associated with the creep of magnesium single crystals at room temperatu.Je was investigated by shear tests in which the direction of stressing was reversed a number of times after creep in a <100> direction. The strain hardening was strongly anisotropic; the largest amount occurring in the direction of flow and the least 180 deg to this. The time law for creep changed from a parabolic type to logarithmic for the first and subsequent reversals of stress. For a given stress the creep strain decreased significantly for the first and second reversals and then only slightly for subsequent reversals. The logarithmic creep constant a changed in a similar manner. A linear relationship was observed between the creep strain for a given reversal and the stress. The slope for the third reversal yielded a strain hardening coefficient 12 to 16 times greater than that observed for unidirectional flow. Al-though no recovery was observed upon resting at room temperature, the hardening resulting from stress reversals could be completely removed by heating to 450" C. PREVIOUS work1.&apos; indicated that the creep rate of magnesium single crystals tested in the temperature range of 78" to 364°K decreased with time. This was attributed to an increase in internal stress resulting from an accumulation of dislocations at internal obstacles. The object of the present investigation was to further evaluate the nature of this hardening by conducting tests in which the direction of stressing is changed after previous creep in shear in a given slip direction. Previous to 1950 three investigations indicated that a Bauschinger effect3 occurred for single crystals as well as polycrystals brass in tension compression,

Jan 1, 1960