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By W. J. Feuerstein

Plastic deformation of the germanium adjacent to the re-growth material has been observed after alloying single crystal germanium with tin. Of several solder alloys investigated, plastic deformution was observed only in the germanium samples in contact with a tin-doped regrowth material. Dislocations were observed to move on a viewed (111) plane following thermal cycling of tin-doped regrowth material on germanium. OBSERVATION of germanium samples to which solder had been fused indicated that plastic deformation, as evidenced by slip arrays of dislocation etch pits, occurred during the fusion of the solder alloy, Figs. 1, 2. The samples had been prepared by placing the solder in contact with the germanium and heating the assembly to approximately 575"C, followed by cooling to room temperature. During this process, the solder first melts, and then as the temperature is further increased, dissolves a portion of the germanium with which it is in contact. During the cooling portion of the thermal cycle, the dissolved germanium is precipitated, and provided

Jan 1, 1961

By A. E. Wells

IN 1866, Thomas Graham1 called attention to the volume of gases, three times the volume of the sample, evolved from a meteoric iron heated in an evacuated porcelain tube. From that time to this the occurrence and significance of gases in metals have been the subject of investigation by many workers, among whom Sieverts,2 Iwasé3 and 0. W. Ellis4 stand preeminent. Sieverts and Iwasé concerned themselves with the solubility of a number of gases in metals in the liquid and solid states. They determined the absorption coefficients of these gases, and in all cases found a sharp change in solubility at the melting point of the metals. Ellis analyzed the gases evolved by solidifying copper and those occluded by the solidified metal. Lobley and Jepson5 endeavored to determine the effects of hydrogen, carbon monoxide and nitrogen on the porosity of copper that was allowed to solidify in the presence of each gas after 30 min. exposure to it in the

Jan 1, 1930

By W. L. Thayer, K. A. Jonasson, R. D. Coleman, J. D. Hazlett, C. E. Capes

"Loss of coal fines in reject slurries limits the yield of coal cleaning operations. Difficulties in handling fines also limit the extent of physical cleaning in treating coals with finely-disseminated impurities. Selective oil agglomeration allows even extreme fines to be processed and offers some novel approaches for coal cleaning and utilization.The oil agglomeration process for the recovery and beneficiation of fine and ultrafine coal has now been commercialized by the Chemical Engineering Section/Chemistry Division of the National Research Council (NRC). This paper describes these activities to apply oil agglomeration and related fine coal technologies on an industrial scale. Pilot plant and large scale results are described, as well as aspects of agglomerate utilization in both wet and dry form."

Jan 1, 1988

By E. Burgos Cruz

The behaviour of S, N and P during refining of Fe-18 wt%Cr-10 wt%Ni with calcium carbide was investigated. The effects of the initial contents of C and N in the metal phase, as well as the supply method of calcium carbide to the melt on the removal degrees of S and P were evaluated. Heats were carried out at 1873K, in MgO crucibles, using a laboratory induction furnace. It was observed that simultaneously with S and P, N and O have also participated in the reactions. It seems that, in fact, O governs the behaviour of the other elements dissolved in the melt and that N is had to the removal of P with calcium carbide. It was also noticed that high C content in the metal phase have not altered the dephosphorization and desuffirization degrees, but that the supply of calcium carbide done by injection led to a lower dephosphorization degree than the one obtained by dumping it.

Jan 1, 1995

By W. K. Collins, C. L. Dahlin, D. C. Dahlin, W. K. O’Connor, G. E. Rush

Direct mineral carbonation was investigated as a process to convert gaseous CO2, into a geologically stable final form. The process utilizes a slurry of water, with bicarbonate and salt additions, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine [Mg3Si2O5(OH)4]. Carbon dioxide is dissolved into this slurry, resulting in dissolution of the mineral and precipitation of magnesium carbonate (MgCO3). Optimum results were achieved using heat-pretreated serpentine feed material and a high partial pressure of CO2 (Pc02). Specific conditions include 155°C, PC02 = 185 atm and 15% solids. Under these conditions, a 78% conversion of the silicate to the carbonate was achieved in 30 minutes. Process mineralogy was utilized to investigate the appropriate feed characteristics, identify the process products and interpret the mineral dissolution and carbonate precipitation reaction paths. Key words: Mineral carbonation, Carbon dioxide sequestration, Carbonates

Jan 1, 2003

By Doris M. Hyde

Mineral output and trade in the Central American countries were directly or indirectly affected by the sometimes violent civil unrest and recessionary economic developments that have pervaded the region for several years. Central American countries found their foreign exchange export earnings and traditional market areas shrinking while essential import costs were rising. Restricted spending measures were adopted by governments and private industries. Domestic investment funds for mineral development and exploration projects were among the first casualties of these austere budgetary measures, especially since weak demand and depressed mineral prices diminished the probability of a favorable cost-benefit ratio. The lack of physical security and political stability also discouraged private foreign investment. The United States Congress enacted the Caribbean Basin Economic Recovery Act of 1983 (19 U.S.C. 2702), more popularly known as the Caribbean Basin Initiative (CBI). This legislation was designed to stimulate economic recovery and promote economic development by increasing private investment and trade in the Caribbean Basin countries. The act provided for the elimination of U.S. duties on most trade items imported directly from eligible Caribbean countries, provided at least 35% of the product value originated in the region. The financial assistance components of the CBI were to be supportive of the basin's private sector as well as assist general economic stabilization programs.

Jan 1, 1985

By Patrick M. Hurley

The relationships between mineral deposits and various plate margin mechanisms are examined under the constraints of radiogenic isotopes and other geochemical indicators. It seems like1 y that: (1) deposits of the spreading ridge association are fairly ubiquitious through most of geologic history and can be recognized by the lithologic assemblage and primitive lead isotope ratios; (2) most metals in the island arc association are not derived entirely from a subducting oceanic plate, and have a partly continental affinity; (3) subduction beneath a continental plate generates ores which are derived either from the downgoing plate or from the lower crust; (4) the heating of a continental plate by thickening or by mantle plumes may develop a metallogenic province involving extraction of metals from the curst; (5) rifts and grabens developing thick sections of marine sediments with evaporites may be the locus of base metal mineralization by movement of reducing brine solutions resulting from diagenesis and bacterial reduction of sulfates

Jan 1, 1978

Detect fires in or near mine shafts, isolate smoke filled areas, and remotely extinguish fire. Approach A system (of sensors, automatic alarms, an aboveground control console, remotely operated ventilation doors, and sprinklers) has been built from off the-shelf components, and fire, tested in two mines. How It Works The system uses three different kinds of sensors that can detect the heat or smoke of a fire and automatically actuate alarms. When the alarm sounds in the control center on the surface, water sprays in the mine shaft and shaft station areas can be remotely turned on to deluge both the inside and the outside of the mine shaft's wooden support structure. To protect miners from toxic fumes, smoke control doors can be closed or opened, either remotely from the control center or directly by miners using the manual or electrical actuators at the door locations. Man doors built into each ventilation door allow persons to pass without opening the main door.

Jan 1, 1977

By R. C. Dalzell, A. E. Wells

In 1866, Thomas Graham1 called attention to the volume of gases, three times the volume of the sample, evolved from a meteoric iron heated in an evacuated porcelain tube. From that time to this the occurrence and significance of gases in metals have been the subject of investigation by many workers, among whom Sieverts,2 Iwasé3 and 0. W. Ellis4 stand preeminent. Sieverts and Iwasé concerned themselves with the solubility of a number of gases in metals in the liquid and solid states. They determined the absorption coefficients of these gases, and in all cases found a sharp change in solubility at the melting point of the metals. Ellis analyzed the gases evolved by solidifying copper and those occluded by the solidified metal. Lobley and Jepson5 endeavored to determine the effects of hydrogen, carbon monoxide and nitrogen on the porosity of copper that was allowed to solidify in the presence of each gas after 30 min. exposure to it in the

Jan 1, 1930

By Ann G. Kim

The Bureau of Mines investigated factors that influence the formation of methane and other hydrocarbon gases in coal, which is an integral part of the coalification process. Coalification begins with a biogenetic stage in which plant debris decomposes and peat is formed; methane and CO2 are the predominant gases produced during this stage. During the diagenetic stage of coalification hydrogen and the hydrocarbon gases methane, ethane, ethylene, propane, propylene, butene, iso-and normal butane, and pentane are formed by dissociation of the organic material. Methane may also be produced by a secondary reaction of hydrogen with unsaturates or by the reduction of CO2. The gas contained in coalbeds is a mixture of methane, C2 through C5 alkanes, CO2, O2, N2, H2, and He; its heating value is equivalent to that of natural gas. The gas content of coal depends on many variables, but an empirical relationship between adsorptive capacity, rank, and depth has been observed.

Jan 1, 1978

Nickel laterite approximately 40% of the remainder caning deposits. ores are the source of the world's nickel with from sulphide ore Although laterite ores are near the surface and cheap to mine they require significantly more energy to treat than sulphide ores. The escalation of oil prices comiencing in 1973 meant that nickel laterite refineries using oil as an energy source were placed at distinct disadvantage relative to sulphide refineries or those with coal derived energy. The Queensland Nickel refinery commenced a construction programme; in 1980 to allow ore drying and power generation to be converted from oil to coal. Since late 1981 ore drying has been undertaken using heated air from two moving grate spreader grate stokers. The changeover from oil to coal drying proceeded without process disruptions. This paper discusses the plant changes required to allow the receipt of coal and the operating performance obtained from the coal fired air heaters.

Jan 1, 1987

By Tamura S, Maekawa M, Nagai C, Deguchi M

Heavy fuel oil has been injected into blast furnaces in order to reduce the coke rate, to improve productivity and to control the furnace heat condition. However, in the first oil crisis at the end of 1973, it became necessary to develop an injection technique of new fuels into blast furnaces to reduce oil consumption. In Kobe Steel, Ltd., it was thought that the injection of a coal-oil mixture (COM) into blast furnaces could be developed in a shorter time than pulverised coal injection. The development of this technique was under- taken in 1974, and COM was injected through two tuyeres of the No.3 blast furnace at the Kobe works in 1977 and 1978. In addition, in order to study the combust- ibility of COM and the phenomena in the tuyere zone, the development of a gas sampling method was under- taken in 1975. In this paper, the results of the injection tests and gas sampling tests are reported.

Jan 1, 1981

By Eugene Stebinger

PAGE Introduction.............. 890 Position oF Montana in the Western Coal Province*..... 890 Montana's Total Coal Tonnage.........891 THe Coal-BearINg Formations,........891 General Statement............. 891 Kootenai Formation............ 895 Eagle Sandstone............896 Judith River Formation............ 896 Homethief or Lennep Sandstone.........897 Lance Formation..........• 897 Fort Union Formation............ 898 Tertiary Lake Beds............. 899 Distribution of the Coal Fields.......... 899 Classification of Montana Coals.........900 General Statement............. 900 Comparison of Chemical Analyses and Heating Values..901 DESCriPTions of the CoaL Fields.......... 905 • Fields Containing Bituminous and Higher Grade Coals..905 Bridger Field............. 905 Stillwater Field............ 906 Electric Field............ 907 Trail Creek Field...........908 Gallatin Field............909 Lombard Field...........910 Great Falls Field............ 910 Lewistown Field............ 911 Valier Field............. 912 Blackfoot Field............ 913 Fields Containing Sub-bituminous Coal.. 913 Bull Mountain Field..........913 Red Lodge Field............ 914 Missoula and Drummond Fields......... 916 Milk River Field............ 916 The Eastern Plains Region of Lignite and Sub-bituminous Coal.... 917

Jan 1, 1914

By Ann G. Kim

Hydrocarbon gases, primarily methane but also the Ca through Cs paraffins, the Ca and C3 olefins and possibly the C4 and Cs olefins, are byproducts of coal formation. Although it is generally believed that coal formation occurred at temperatures below 200° C, most experimental work on gas formation from coal has been performed at temperatures between 200° and 1,000°C. The objective of this Bureau of Mines experiment was to determine if observable changes in the gases from coal could be produced at temperatures below 200° C in relatively short periods of time. The experiment involved heating coal samples from six coalbeds at constant temperatures and analyzing evolved gases. The composition of the gases at three temperatures was compared. At 35° C, over 99 pet of the gas is methane; at 125° and 150°, methane constitutes approximately half of the hydrocarbon gas. Isobutane and pentane are the predominant higher hydrocarbons at temperatures between 100° and 150° C.

Jan 1, 1974

By Qi Shifu, Guo Tao, Liu Haoquan, Yao Chaogui, Zheng Li

Abstract: To excavate oil-gas pipeline ditches in a rocky region or area the explosive method is needed. When a parallel ditch is to be dug by blasting near or in the vicinity of an existing pipeline, a safe criterion must be determined to ensure safety for the latter. In this investigation, with the construction of the second phase of the West-East Gas Pipeline Project, we carried out real blasting tests and numerical simulations to explore the safety criteria for the existing pipeline. Through this investigation, we obtained the safe strain elasticity threshold es2000µe, blast vibration velocity calculation formula, and the maximum vibration velocity Vmax=14cm/s(5.51in./s) for the pipe under blast shock loading, and worked out how to determine the charge size in the follow-up blasting excavation. These results can be used to determine the maximum explosive weight per delay and decide delays for the initiation circuit network in blasting a parallel pipeline ditch, and to make safety assessments for the existing pipeline in service. Having successfully been applied in the second and third phases of the West-East Gas Pipeline Project, China-Russia Oil Pipeline Project and China-Myanmar Gas Pipeline Project, these findings are very significant for other similar pipeline construction.

Jan 1, 2014

By W. S. Ayres

The construction of a new breaker at the Cranberry Colliery, Hazleton, Pa., was forced upon the operators, A. Pnrdee & Co., by a fire which destroyed the entire plant early in January, 1896. The loss included, in addition to the breaker, three boilerhouses and three engine-houses. The boilers were not injured, but the steam-pipes and connections were all broken and warped by the fire. The boilers were probably saved from injury by the presence of mind of the fireman., who started all his feed-pumps and filled the boilers with water. The hoisting-engines were more or less warped and cracked, but by patching and replacing the injured and broken parts, they were made to do satisfactory service in the new plant. It may be worthy of mention that the wrought-iron shaft of one of the hoisting-drums, 12 inches in diameter by 17 feet long, was so heated in the fire that the weight of the drum caused it

Jan 1, 1899

By G. Sachs

THE iron-rich iron-nickel alloys have at-tracted considerable academic interest in recent years. The carbon-free alloys are of minor practical importance, but they are Atomic per cent nickel FIG. I. FIG. 2. FIG, I.-HONDA'S AND MERICA's IRON-NICKEL DIAGRAM, FIG. 2.-MARSH'S IRON-NICKEL CONSTITU-TIONAL DIAGRAM. the base of many alloys with various out-standing properties. The iron-nickel alloys, therefore, have been investigated exten-sively regarding both their structures and their properties. The researches on these alloys up to 1938 have been collected and critically reviewed by J. S. Marsh,1 and will be discussed in some detail in the sec-tions of this paper dealing with specific subjects. These numerous investigations have not succeeded in establishing the equilibrium conditions in this system. Alloys containing more than a certain amount of nickel (8 to10 per cent Ni) undergo the allotropic transformation extremely sluggishly, both on heating and cooling, showing a large hysteresis,2 which is not dependent upon

Jan 1, 1940

By Basak Anameric

Pig iron nugget process was developed by Kobe Steel as an environmentally friendlier, economical alternative to traditional blast furnace process. The process aimed to produce highly metallized, slag free pig iron nuggets throughout a single stage heat treatment, utilizing coal as a reducing ? carburizing agent. The objective of this work was to determine whether the pig iron nuggets produced at the laboratory conditions had comparable physical and chemical properties with the blast furnace pig iron. The physical and chemical properties of the pig iron nuggets were determined utilizing x-ray fluorescence spectroscopy, x-ray diffraction, optical microscopy, scanning electron microscopy, energy dispersive spectroscopy and apparent density measurements. The pig iron nuggets had similar chemical composition and apparent density values (6.7 ? 7 g/cm3) with blast furnace pig iron and they had microstructures similar to low carbon white cast iron. These properties make them a competitive alternative to blast furnace pig iron.

Jan 1, 2006

By Dean McDonald

The Committee Bay Greenstone Belt extends over 300km and is one of the largest unexplored greenstone belts in North America with excellent gold and diamond potential. Committee Bay Resources Limited holds over 550,000 acres of land with prospective geology in the Committee Bay area southwest of Melville Peninsula, Nunavut. Committee Bay is a typical Archean greenstone belt comparable to the Yellowknife, Red Lake, Kirkland Lake and other prolific gold belts. Drilling during 2003 at Committee Bay resulted in: 1) the discovery of high-grade gold-bearing quartz veins with silicification and sulphidation at Three Bluffs, and 2) the continuation of high-grade gold mineralization in the hinge area of the iron formation at Inuk. Gold mineralization at Three Bluffs is identified in iron formation and adjacent sediments and has been traced by drilling for over 700m. The Three Bluffs iron formation is open to depth and along strike where is has been traced on surface for over 6km. In January 2004 Committee Bay and joint venture partner Gold Field?s announced a $7.1 million exploration program for the Committee Bay project in 2004. A total of 8,000m in exploration drilling has been approved for the expansion of the Three Bluffs to the resource stage and drilling of at least five new target areas. Additional mapping, sampling and geophysics will be used to identify new gold targets along the very prospective Committee Bay belt.

May 1, 2004

By J. Spotts McDowell

INTRODUCTION The magnitude of the thermal expansion of silica brick, and its inability to withstand rapid temperature changes, present problems of considerable importance in the manufacture of siliceous refractories. In the study represented by the experimental data herein described, these problems are considered from the point of view afforded by the results of recent investigators: Fenner and his associates of the "Geophysical Laboratory, Washington, D. C., who have established the stability relations of the silica minerals, and Endell and co-workers in Berlin, who have studied the changes brought about in the constitution of siliceous refractory materials upon the application of heat. In the process of manufacture, the quartzite from which the brick is made changes in part into cristobalite and tridymite. The attempt is herein made to determine by microscopic methods the degree of transformation in various specimens of test bricks manufactured at slightly varying temperatures of burning, with varying coarseness of grain, and to determine the effect of repeated burning. The effect of variations

Jan 10, 1916