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By H. R. Froning, R. O. Leach

In wertability alteration flooding, a chemical agent is rnoved through a reservoir by the flood water to increase oil recovery by decreasing the degree of wetting of the rock by the oil. Substantial amounts of the chemical may be lost during movement through the reservoir. The extent of the loss, and therefore the economics of the process, depends in some cases on factors which are difficult to reproduce in the laboratory. Therefore, a short-duration, low-cost field test method is needed to permit evaluation of chemical requirements under actual field conditions. This paper describes a small scale rest conducted at a single well for measuring chemical requirements, thereby giving a more reliable evaluation of this important factor in the applicability and economics of the process. In the rest a small wafer slug containing the chemical agent and a nonadsorbed tracer is displaced into the reservoir by a known volume of wafer. The well is then placed on producrion. Chemical loss per barrel of pore volume contacted is calculated from [he fractional recoveries of the agent tested and the nonadsorbed tracer. The method has been used to determine within the actual reservoirs the chemical requirements for both a sandstone and a dolomite reservoir. Several chemical agents are potentially available for wettability alteration flooding, although none is universally applicable. For some applications of the method, chemical costs per barrel of additional oil recovered can be substantially less than one dollar. INTRODUCTION Wettability alteration flooding provides a means of increasing oil recovery from reservoirs by decreasing the degree of wetting of the rock by the oil and increasing the displacement efficiency of the flood water. Earlier studies demonstrated a relationship between oil recovery during waterflooding and the degree of wetting of a rock surface by an oil. The application of wettability alteration flooding to the Harrisburg field of Nebraska provided a field test' of this recovery process. Subsequently, additional laboratory and field tests have developed additional procedures for evaluating wettability alteration flooding, and have indicated where the process may be applicable. Applicability of this process to specific reservoirs is determined by a progression of tests to determine sus- ceptibility of the reservoir to alteration of its wettability, to indicate the degree of recovery improvement and to estimate the amount of chemical required to process the reservoir. The economics of applying improved oil recovery processes depends not only upon the degree of improvement in oil recovery achievable by the process but also upon the process costs and the timing of the income and the investment. Emphasis in this paper is on the expenditure aspects of the process. The work reported in this paper indicates that the chemical investments required for wettability alteration flooding are substantial. For evaluating the economics of a potential flooding application it is imperative that a sound estimate of the chemical requirements be made for the reservoir. Generally, true reservoir conditions are not adequately simulated in laboratory chemical propagation tests. Because of wide well spacings, many years might be required to obtain chemical propagation data from conventional pilots or inter-well tests. Consequently, n short-duration, low-cost method is needed to determine chemical requirements in the field. The potential applicability of wettability alteration flooding is discussed, as well as the economics of wettability alteration with respect to the inherent and imposed restrictions on the timing of income and investments. DETERMINATION OF CHEMICAL REQUIREMENTS In the process of moving a chemical bank through reservoir rock, some of the chemical agent lags too far behind the flood front to be effective or is otherwise lost to the reservoir system. The extent to which these losses occur overshadows the reductions in chemical concentration due to diffusion and to mixing with the reservoir fluids. Experience indicates that almost without exception, chemicals which induce a wetting change undergo either sorption reactions or chemical reactions with mineral constituents of the pore surfaces. Other reactions may occur between the added chemical and the reservoir oil and water. Even in limiting consideration to reactions of the relatively inexpensive inorganic salts, bases and acids, the reactions may be exceedingly complex. Reservoir pore surfaces consist of more than silica in sandstone reservoirs, and more than calcite or dolomite in carbonate reservoirs. Many mineral species are present, each exhibiting specific tendencies to react with an injected chemical. The reactions which occur can consume enough of the agent to have an important effect on economics. These reactions can cause a change in pH of the chemical bank, or may remove some of the active chemical by precipitation, adsorption or reaction to form a new chemical which may or may not be effective in

By Sangjian Zhang, Zhu Xiao, Lairong Xiao, Rushi Chen, Mei Fang, Zhou Li

The copper-graphite metal matrix composites were fabricated by two different production methods: directly sintering with copper and graphite (Cu-Gr composite), and in-situ sintering with cuprous copper and graphite (Cu2O-Gr composite). During the in-situ reaction sintering, a redox reaction occurs at the interface of the Cu2O particles and Gr particles, resulting in the improved physical and mechanical properties of Cu2O-Gr composites. Compared with Cu-Gr composite, Cu2O-Gr composite has a higher compression strength at any given graphite content due to the improved interface bonding and uniformly distributed fine graphite particles in the matrix. Increasing graphite content decreases the mechanical properties of the copper-graphite composites. The compression strength of Cu2O-Gr composite is 50-100 MPa higher than that of Cu-Gr composite. INTRODUCTION Copper-graphite composites have been widely used in industry due to their low density, relatively high strength and hardness, good thermal and electrical conductivity, arc ablation resistance and self- lubrication ability (Grandin & Wiklund, 2018; Han & Xu, 1999; Huang et al., 2017). Electric sliding contact friction pair in the high-speed railway system and motor brush in electric contact components have a very high demand on electrical conductivity and self-lubrication ability of materials. The electric devices need to bear both mechanical load and high electric current. Copper-graphite composites with good mechanical, electric and self-lubrication properties are the best candidates for application in multifunctional electric sliding contact frication components. The relative sliding speed of friction pair is developing towards 100 m/s or even faster, which can withstand the electric flow of more than 800 A, and it is often accompanied with vibration and impact (Guo & Ding, 2008). Conventional wear-resistant materials can no longer meet the current requirements and this promotes the development of copper- graphite composites with excellent comprehensive properties (Ding, Chen, Zhu, Zhang, & Zhou, 2009; Yasar, Canakci, & Arslan, 2007). There are many ways to fabricate copper-graphite composites, mainly including powder metallurgy method, liquid immersion infiltration method, rapid sintering method and electrodeposition method (Kalin & Poljanec, 2018; Kim, Lee, & Han, 2014; Liu et al., 2018; Wang et al., 2018). Each method has its own advantages and disadvantages, and the powder metallurgy method is the most commonly used one due to its simple process, high economic benefit, and industrial production applicability. The common steps of the powder metallurgy method are as follows (Samal, Parihar, & Chaira, 2013): firstly mixing the copper (copper alloy) powders and graphite with a certain ratio, following by die-forming, and then sintering at the high temperature with or without pressure. The advantage of copper-graphite composites is that the graphite distributed in the copper matrix uniformly and it can form a carbon diaphragm preventing the wear of the composite (Fu & He, 2010). However, the bonding strength of the interface between the copper matrix and the graphite is relative low as the combination between them is mechanical interlocking but not metallurgical bonding (Ma et al., 2008). It is meaningful to develop new fabrication technology of copper-graphite composites with better interface bonding, which could provide guidance for the design of copper-graphite composites with excellent comprehensive properties.

Jan 1, 2019

"Mine ventilation is in every underground mine a crucial process to ensure mine safety as well as acceptable working conditions. On the other hand is also a major cost factor depending on air requirement and air resistance. Due to the fact that the special layout of mines develop over time, ventilation systems change as well. This may result in complex systems which are suffering severe problems and low efficiency. With attention to the mine safety and costs, ventilation systems have to be controlled repeatedly and optimized continuously to fit changing conditions. The project “Improvement of ventilation systems in narrow vein mines” has been commenced with measuring and data collection in the Bogala Mine, Sri Lanka. This over 150 year’s old graphite mine consists of about 20 levels. The resulting ventilation system is highly complex and suffers problems like high temperatures and humidity as well as a mixing of fresh and used air on lower levels. To solve these problems and to optimize the system the complete ventilation system had been measured on-site first. The gained data have been used for simulations to develop and select an optimal and cost efficient solution. OBJECTIVE As an important process in mining ventilation is a major cost factor and can determine the economic feasibility of a mine. Due to the production mine layouts develop over time and mines increase in size and depth while the ventilation system becomes more complex and may suffer severe problems and inefficiency. Therefore mine ventilation systems have to be controlled and optimized regarding the general requirement of mine safety and health of the miners as well as the costs. Depending on the deposit type, depth, mining method, climate and as well corresponding laws and regulations the possible solutions are varying strongly. The work carried out paid special attention to the improvement of ventilation in narrow vein mines in tropical climate, in this case the graphite mine “Bogala” in Sri Lanka, South Asia."

Jan 1, 2015

By B Haase, R Saha

Conditional simulation (CS) has been extensively used in metal industry to assess uncertainty of geo metallurgical variables to build robust distributions around grade tonnages across different time horizons. Coal’s entry to nonlinear stochastic modelling is relatively new and this paper summarises the work done at BHP to enable its practical usage from production time frames to Life of Asset planning. CS in coal using Sequential Gaussian Simulation (SGS) is used to understand resource confidence around specific variables within pre-defined boundaries of spatially continuous domains for each coal seam. The variation between simulations for a given parameter reflects uncertainty. This paper demonstrates the use of CS to profile resource based upon agreed seam/parameter uncertainty thresholds which affect planning, forecasting, extraction and inform identification of key production risks and defining mitigation strategies. The end goal is to de-risk long-term plans by optimising infill data collection and improve stability in short-term planning through increased understanding of confidences locally rather than at global resource definition stages. The paper also briefly discusses the use of automated workflows and systems to minimise the time spent on the process to enable use in decision-making.

Mar 22, 2022

By Taghi Sherizadeh, Kutay E. Karadeniz, Dogukan Guner, Samuel Nowak

Underground mining environments bring occupational health and safety issues with some severe dangers such as mine disasters like explosions. During such events, miners might escape using main access openings, or find a safe haven like refuge alternatives (RAs) to wait and be rescued and evacuated to the surface. In this paper, RAs are explained with their early and current applications. A classification as permanent and portable is explained depending on the conditions and their abilities. This classification is followed by the utilization and survivability of RAs with the requirements and recommendations of the main mining countries. Based on the utilization and survivability constraints, basic human requirements, waiting for a rescue team, and the required physical specifications of RAs during the events are analyzed in detail for various countries with their regulations. Among these, the specification, resistance to the explosion, is discussed in particular, and the studies in the literature are examined in terms of structural deformation. The highest deformed zones, the beneficiation of reinforcing steel components such as stiffeners, and the simulation approaches are investigated through this review.

Sep 24, 2022

By Weiran Zuo, Narayan Krishnan, Frédéric von der Weid, Emmy Manlapig, Fengnian Shi, Klaas van der Wielen

Laboratory study has identified a new application of high voltage electrical pulse technology for pre-weakening ores. In recent years, the Julius Kruttschnitt Mineral Research Centre (JKMRC), Newcrest Mining and SELFRAG AG have conducted joint research in validation of pre-weakening of SAG mill feed through the pilot scale tests and comminution circuit simulations. Ten tons of SAG mill feed with a top particle size 150 mm were tested with two pilot scale SELFRAG machines installed in Switzerland. A simulation study using JKSimMet software was carried out to find where the high voltage pulses pre-weakening technique can be best applied in a gold-copper ore comminution circuit, based on the data of the pilot scale SELFRAG tests. A novel comminution circuit was designed, which incorporated SELFRAG to pre-condition part of SAG mill feed (9.5 to 150 mm) and to treat the circulating SAG mill pebbles. The high voltage pulse technology effectively reduced the amount of ‘critical size’ particles in the SAG mill and pre-weakened particle strength for grinding. Attributing to the nature of bi-modal size distribution and the significantly reduced F80, the simulations showed that the SAG mill had spare capacity to process part of hydrocyclone underflow from the secondary ball mill grinding circuit. The simulations indicated that the novel comminution circuit had the potential to remove two MP1000 pebble crushers and one 10 MW ball mill from the existing 2000 t/h grinding circuit. A 5 kWh/t energy reduction by adopting the novel comminution circuit in a gold-copper operation may be realized. This would result in substantial savings in operation costs.

Jan 1, 2014

By Donghai Li, Cheng Pan, Pan Chen, Xuewei Lv, Mei Liu

"Chromite concentrate after beneficiation can not be directly used in the electric furnace. Therefore sintering is one of the effective way to agglomeration, by which the chromite concentrate can be utilized and the power cost of ferrochrome smelting can be reduced. The properties of raw materials and the sintering process of chromite concentrate were studied in this work. The results showed that chromite concentrate used can hardly granulated alone, while chlorite addition can improve the effect of granulation. Moisture plays an important role in sintering process. The granulation effect is optimal when the amount of water addition is 12%. Strength and abrasion index are the evaluation indexes of sinter quality. It was found that the strength of sinter increased with coke dosage increasing to 12%, and then decreased when it continuously increased. Opposite regularities were found for the abrasion index of the sinter.1 IntroductionChromium is a very important metal element which is mostly used in the production of stainless steel. In the earth, it is always formed compound with iron as ferrochromium spinel (FeO.Cr203), and its mineralogical name is chromite.[1] Currently, the global production of chrome ore is about 20 million tonnage every year , in which fine ore (less than 8 mm) accounted for about 80% [2] Although the price of the fine ore is cheaper than the lump one, too much fines will lead to the poor permeability and causes increased electricity consumption while producing ferrochrome. Therefore, the agglomeration process of chrome ore is one of the effective measures to increase the usage ratio of fine ore."

Jan 1, 2013

By Z X. Zhang

If the iron ore loss is 15% in the process of mining, the total iron ore loss in the world will be about 461 million tons, this is equal to the total production of 230 iron ore mines each of which produces 2 million-tons of iron ore per year. Based on a series of blast tests in the Malmberget mine, this paper shows that ore recovery can be markedly increased by improving blasting technology such as choosing a correct primer position and making use of shock wave collision. The paper further suggests that a high ore recovery can not only reduce natural resource loss and mining cost but also prolong the life of a mine. In addition, the paper shows an example of reducing blast-caused rock damage in the roofs and walls of underground drifts (tunnels) by using new blasting methods in the Malmberget mine. Finally, the paper shows how the Malmberget mine has successfully reduced the ground vibrations, without adversely affecting fragmentation and ore recovery in sublevel caving mining.

Jan 1, 2014

By Nick Barton

The ability to estimate that support is unnecessary for various dimensions of opening in certain rock mass environments is of particular relevance in the mining industry, where most excavations are not expected to remain open indefinitely. As Hoek1 observes: "the basic aim of any underground excavation design should be to utilize the rock itself as the principal structural material, creating as little disturbance as possible during the excavation process and adding as little as possible in the way of concrete or steel support". Approximately two hundred case records have been analysed for the purpose of determining the amount of permanent support normally used when a given span is excavated in known rock mass conditions Some thirty cases concerned unsupported openings. Excavations that can stand unsupported appear to have certain common characteristics as regards rock mass quality. However, the mechanical properties of the rock mass are not the only factors controlling the choice of design. The dimension of the opening (span or height) and the type of excavation are two important variables.

Jan 1, 1975

By M McDonald

KiwiRail has a goal of significantly improving passenger rail services to west Auckland, as part of its DART (Developing Auckland’s Rail Transport) suite of projects. The New Lynn Rail Trench (NLRT) project was a significant component of this work. The NLRT project facilitates essential doubletracking of the Western Auckland line, and provides a new commuter transportation hub within a busy town centre.The 1.5 km stretch of track through the New Lynn town centre has bisected the township for over 80 years. Double-tracking the line provided the opportunity to grade-separate road and rail, which would help to re-connect both sides of the township and enhance public amenity and safety.KiwiRail employed an Early Contractor Involvement (ECI) procurement model engaging a consortium comprising Fletcher Construction, Beca Infrastructure and Synergine to develop a Design and Construct solution.With weak soil conditions and high groundwater levels, a diaphragm wall construction method to form the trench walls was selected as the best solution. Further challenges to construction included working within a narrow rail corridor constrained by buildings along much of the boundary, and a requirement to keep the existing line open for rail services. Detailed construction planning was required to ensure rail and construction safety in a constrained space whilst building the trench walls, propping these walls during excavation, and constructing the base slab in the most efficient way possible.This paper will detail the geotechnical conditions and the additional constraints that made this rail trench a challenging structure to design. It will also describe the fi nal design and construction methodologies that were employed, that allowed very successful completion of the project.Additionally, this paper will review the design and construction lessons applicable to the current Victoria Park Tunnel project, and indeed for all future cut and cover tunnel projects in the Auckland isthmus.

Mar 8, 2011

By O Omidi, P D. Katsabanis

The effect of delay time on fragmentation has been discussed for a long period but rarely in a satisfactory and unbiased way. Despite the efforts of many researchers, delay selection for fragmentation improvement or optimisation remains a controversial issue. Large-scale tests have been plagued with scarcity and scatter of observations, while small-scale tests have been associated with boundary effects and energy losses. Theoretical work is often used to produce explanations for available measurements or tries to simplify wave propagation and wave interaction to guide observation and practical work. The present work analyses results obtained from a relatively large number of small-scale experiments in blocks made of grout, and re-analyses results of previous experiments, to conclude on the effect of delay on fragmentation. It is shown that the main contribution of the delay is found in the fragmentation of the larger fragments of the blast, while the small fractions show almost no effect. Samples, where copper liners were used to inhibit penetration of detonation products in the rock mass, showed effect of delay only when short times were used and steady but poor fragmentation when long delays were used. Based on small-scale experiments, it appears that the fragmentation is optimised when a hole fires prior to the radial cracks, produced by the previous hole, reach the free face of the blast. Gas penetration may result in the development of few more fractures that affect the fragmentation of the largest particles of the blast.CITATION:Katsabanis, P D and Omidi, O, 2015. The effect of delay time on fragmentation distribution through small- and medium-scale testing and analysis, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 715–720 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By B. Holaday, H. McLaughlin

Orano Canada Inc. (Orano) operates the McClean Lake mill, located in the Athabasca Basin region of northern Saskatchewan. It processes high concentration uranium ore, delivered in slurry form from the Cameco Corporation operated Cigar Lake mine. After the ore slurry is leached at the McClean Lake mill, the leach residue solids are washed in a process known as counter-current decantation (CCD). This process uses six thickeners to facilitate counter-current washing of solids with diluted acid, flocculation and settling, as well as pumping the washed leach residue to the tailings neutralization circuit (TN), and the uranium laden aqueous to the solvent extraction circuit (SX). Challenges in settling the slurry in CCD started in early 2017. This is largely due to the variation in fines content of the slurry (D80≤75μm), and clay content. There are several changes that have allowed the mill to adapt to the evolving challenges of settling leached Cigar Lake leach residue. Flocculant selection and mixing, temperature effects, bed level management philosophy, and centre-well feed density are key parameters that have been explored as part of adapting to changes in Cigar Lake ore quality.

Jan 1, 2020

"Status of the Mineral Industries" provides a written and graphic view of the Nation's mineral position and its mineral industries. The report, issued annually by the Bureau of Mines, U.S. Department of the Interior, describes recent activities in mineral production, consumption, imports, exports, and uses of significant minerals and mineral raw materials. Charts profile trends for the past 28 years in supplies and uses of iron, steel, major nonferrous metals, primary nonmetallic construction raw materials, fertilizers, and plastics. Also included are current and historical financial data on the mineral industries, such as debt-equity ratios, asset-to-liability ratios, and plant and equipment expenditures.

Jan 1, 1979

By Hidekatsu Takeuchi, Masaru Sakakibara, Shigeo Tanabe, Kenji Harada, Akihiko Suzuki, Shoji Morihana

"Deep mixing (DM) method, one of the most commonly used solidification methods, is based on the principle of solidifying soft ground. It can be classified into two categories such as Cement Deep Mixing (CDM) method and Dry Jet Mixing (DJM) method which apply hardening agent in slurry condition and in powdery condition respectively. In recent years, DM methods have undergone changes that have evolved them from the traditional method to meet the needs of the diversifying market. Among them, the Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method is a DM method which mixes a cement-type hardening agent in slurry condition mechanically with soils in situ and incorporates the innovative technique, “atomized ejection” that has been developed to allow faster installation of larger diameter columns without sacrificing quality compared with conventional methods. At this technique, the atomized hardening agent is discharged together with compressed air through a device incorporated into the mixing blade. It also has advantages of performing the works with low-displacement of the surrounding soils in consideration of environmental friendliness and with higher penetration capability against hard ground.This paper presents the technological outline of the above-mentioned CI-CMC method, focusing on the atomized-ejection technique, followed by some construction examples, applied to the self-earth-retaining wall, to the hard ground and the area adjacent to the existing structures.INTRODUCTIONAccording to the accumulation of its case histories, Deep Mixing method has been receiving the demands of its application to more challenging conditions, such as harder ground condition, and requirement of lower displacement of the surrounding ground during its operation. In addition, to match its price against the other cheaper methods and widely receive its benefit of higher quality, the cost reduction of Deep Mixing is also one of the major challenges. For the cost reduction, higher productivity and lower consumption of the material to obtain the equivalent strength and homogeneity with the conventional method are required.The Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method has been developed to meet these demands. CI-CMC incorporates the mist ejection that has been developed to achieve faster installation of larger diameter columns without sacrificing quality compared with the existing methods. Normally, we obtain cement columns of about 1.0 m in diameter by using Deep Mixing method. To increase the productivity, it is not preferable to drastically increase the penetration and withdrawal speed of the mixing blades because of the hardness of the ground and restriction by minimum number of passage of rotating blades per a certain height of the soil cement. Instead, the expansion of diameter of the columns will simply increase the productivity. The development of the new mist ejection system, as shown in Photo 1, has enabled the diameter of soil cement columns to 2.0 m on single axis while 1.6 m on double axes. Mist ejection means that the hardening agent slurry is sprayed into the ground in mist form together with compressed air thereby achieving homogeneous mixing and reducing the resistance on rotating blades."

Jan 1, 2015

By P Clark

This paper discusses the challenges, solutions and lessons learnt as tunnelling work continues on the Melbourne Main Sewer Replacement (MMSR) project.The MMSR project is a $220 million dollar project for the Melbourne Water Corporation. It involves the construction of approximately 4.2 km of new sewer from the southern fringe of the CBD through the inner metropolitan suburbs of Port Melbourne and South Melbourne.Of the 4.2 km of sewer currently in construction approximately 2.2 km will be constructed using a 2.95 m diameter Lovat EPB tunnel boring machine (TBM) with approximately 1.9 km of small diameter (300 to 600 mm) reticulation sewers constructed using trenchless techniques.These sewers are being constructed in a dense urban environment, which means that the tunnels and shafts are often in close proximity to buildings and structures. The underground constructionof the sewer is further complicated by the variable geology of the ancient Yarra River delta which includes weathered basalts, the infamous Coode island silt formation and fine loose sands.Some of the key challenges and lessons learnt so far during construction include:· steering and alignment control of the TBM through very soft silt with little residual strength,· development and refinement of a monitoring and alarm system for leaving the machine dormant on a day works only project,· control and measurement of tunnel lining defl ection during ring build and grouting,· prediction and monitoring of surface settlements during tunnel excavation,· improved understanding of the geology and hydrogeology at this previously unchartered area of Melbourne,· consolidation settlement due to dewatering at shafts required careful construction controls, and· ground support and excavation in close proximity to the existing 110 year old sewer which requiredvery detailed risk control measures.

Mar 8, 2011

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By William B. Plank

IN this paper are presented the results of a complete statistical survey of the enrolment, courses and degrees, and the employment situation of recent graduates in all of the 46 institutions in the United States, including Alaska, and four of the six schools in Canada that grant degrees in mineral technology. The data were collected by the writer by means of a questionnaire in December, 1933, to which all the institutions, except one, replied. Included also are data of a similar study made by the writer in May, 1933, for the S. P. E. E. summer session of mining and metallurgical teachers at the University of Wisconsin and published in the Journal of Engineering Education for December. 1933. Some of the data of a paper of the writer's entitled, "The Trend of Mineral Engineering Student Enrolment in the United States," read at the A. I. M. E. meeting on Feb. 16. 1931, are given for comparison. Acknowledgment is made to all the administrative officers of the institutions who took the time from their busy lives to supply the in- formation asked for. Their fine cooperation has alone made possible these two surveys with a completeness of detail never before attempted

Jan 1, 1934

By M Zengerer

The Basil Cu/Co deposit comprises a 26.5 Mt Inferred Resource of copper and cobalt, grading 0.57?per cent Cu and 0.05 per cent Co. It lies in the Harts Range, Central Australia, within the Riddock Amphibolite of the Irindina Province. Analysis of drilling within the mineralised zone of the deposit determined a spatial association between pyrrhotite with high magnetic susceptibility and chalcopyrite, following a strong magnetic trend as determined from airborne geophysics. A study was commissioned to examine if geophysical inversion could predict the distribution of sulfide mineralisation based on pyrrhotite from drill hole intersections, as well as predicting further mineralisation at depth or in the vicinity of the deposit. Petrophysical and geostatistical analysis of drilling susceptibility and mineralisation provided a basis of property distribution inside the model. This was followed by 3D geological modelling of mineralisation based on domain kriging of drill hole susceptibility sensitivity testing of signal to source depth, and distribution was performed using 3D forward modelling. Stochastic inversion generated alternative 3D geological models, which were tested for behaviour and adherence to observed drilling data and geostatistical limitations using GeoModeller software. Predicted mineralisation distribution was compared with conventional geostatistical modelling and found to be in agreement in planar behaviour but exhibiting possibly isoclinally folded trends, with reliability increasing closer to the surface. Predictions of mineralisation at greater depth and beneath weaker anomalies were more diffuse due to small model cell size having limited influence on the signal at depth.The Blackbush uranium deposit comprises a 64.5 Mt Inferred Resource, grading 230 ppm U in the Pirie Basin south of Whyalla, South Australia. It directly overlies the radiogenic Samphire Granite and is considered a tertiary unconformity deposit. Sensitivity modelling was performed using high-resolution ground gravity to see if a deposit signature could be detected using gravity. This required 3D implicit modelling of the geology and mineralisation from drill hole data and characterisation of an associated physical property model using domain kriging in GeoModeller. Density models relied on exploiting an observed relationship between logged density and measured uranium oxide percentage. The residual gravity response of the background geology model identified the location of the uranium deposit. Stochastic inversion of the litho/property 3D model has refined the known distribution of uranium from drilling and provided structural insights into the deposit.These projects have become excellent case studies for exploiting the relationship between mineralisation and potential fields and for testing the applicability of using domain kriging of properties determined from drilling to build robust 3D geological models for stochastic geophysical inversion, leading to robust methods for exploration targeting and mineral deposit prediction.CITATION:Zengerer, M, 2014. Use of geostatistically-constrained potential field inversion and downhole drilling to predict distribution of sulfide and uranium mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Robert Hamilton

Aur Resources is Canada's leading copper mining company with producing mines and development projects in North, Central, and South America. Copper production from Louvicourt Mine in Quebec, Quebrada Blanca, and Andacollo Mines in Chile had a record of 245 million pounds in 2001. Located 600 km North of Montreal, Louvicourt Mine is a joint venture between Aur Resources (30%), Teck Cominco (45%), and Novicourt (45%). Aur Resources is the mine operator with 280 employees working to produce a copper and zinc concentrate. In operation since 1994, the mine has produced a total of 12,606,000 metric tonnes of ore grading 3.6 % Cu, 1.5 % Zn, 26gr./m.t Ag, 0.9gr.m.t Au. This highly mechanized mine reached full production in August 1995 at 4,000 tpd. From 1996 to 2001, the average mine production rate was more than 4,300 tpd. The Louvicourt Mine continued its record of solid performance in 2002 and is expected to continue to do so for the balance of its 2.5 years mine life.

May 1, 2003

By William E. Torres

The Southern Peru Limited smelter, in Ilo, operates two reverberatory furnaces, seven Peirce-Smith converters, one Teniente Converter, two casting wheels and a single contact acid plant. The Teniente Converter was commissioned in August 1995 and was designed to smelt 744 dry metric tons (820 dry short tons) of concentrate per day. The process off-gas is collected in a water-cooled hood, cooled in a spray chamber, and cleaned in a Joy electrostatic precipitator for further treatment in the Acid Plant. This paper presents the current Teniente Converter operating practices and control philosophy. Relevant improvements and modifications to achieve a 379 day campaign without tuyere replacement and a daily average smelting rate of 862 dry metric tons (940 dry short tons) of concentrate are discussed.

Jan 1, 1998