Search Documents

By I. V. Kubrakova, O. A. Tyutyunnik, M. L. Getsina, A. M. Asavin

An analysis of noble metals (NM) in natural samples is most problematic. Determination of their traces in geochemical samples, in part, for the purpose of deposit evaluation, is a difficult analytical task. A number of international standard reference materials of rocks and ores, in which NM content is certified, is estimated at a half dozen. For example, in the International proficiency test for analytical geochemistry laboratories (GeoPT), which is held by the Department of Earth Sciences (The Open University, United Kingdom), the data for gold and platinum are observed very rarely, and the results obtained in different laboratories differ on 1-3 orders of magnitude. It is caused by low contents of NM in nature, by a variety of their complex and mineral species, as well as by a complicated matrix composition of platinum-containing objects. Among these objects are ferromanganese ores, enriched strongly with Fe, Mn, Ni, REEs - the elements hampering a precise determination of NM due to a complexity of instrumental inter-element correction. The absence of the reliable methods of NM determination in these ores drastically limits the possibility of deposit evaluation.

By M. R. Peterson, C. R. Ferguson, T. H. Jeffers

The ability of microorganisms such as yeast, bacteria, and various aquatic flora to sorb metals from dilute aqueous solutions is well documented. Although microorganisms have significant potential in decontaminating waste waters, techniques and equipment suitable for bioassisted decontamination are limited. The Bureau of Mines has investigated the use of microorganisms immobilized in porous polysulfone beads for extracting toxic and heavy metals from dilute waste streams. The minus 8- plus 12-mesh beads were fabricated from high-density poly- sulfone dissolved in dimethylformamide (DMF). Dried, thermally killed yeast, algae, duckweed, xanthan gum, and alginates were blended into the polysulfone-DMF, and spherical beads were formed by injecting the mixture into water. Microscopic analysis revealed microorganisms immobilized within the bead pores. The beads had excellent handling characteristics and were tested in stirred reactors, fixed bed columns, and fluidized bed columns for their ability to remove metal contaminants from several waste waters. The effluents resulting from these waste waters met or exceeded the National Drinking Water Standards for cadmium, copper, manganese, and zinc. Other heavy metal contaminants readily sorbed by the beads included arsenic and mercury. Elution of metal values from the beads was accomplished using dilute nitric acid or sodium carbonate.

Jan 1, 1989

By F. A. Camisani-Calzolari

South Africa has adopted its own code for public reporting of Mineral Resources and Mineral Reserves in 2000. The South African Code for Reporting of Mineral Resources and Mineral Reserves (SAMREC Code or Code) (SAIMM 2000) is presented here in its local and global context. The main aspects of the Code are listed and elaborated upon. The Code has been written with the participation of the major South African stakeholders in the field including Government institutions, the legal confraternity and the mining industry. The Code is modelled on, and is 90% compliant with, the Australasian Code for Reporting of Mineral Resources and Ore Reserves (JORC Code) (AusIMM 1999). The paper also elaborates on the duties and responsibilities of Competent Persons signing off resource and reserve reports and on the listing requirements of the Johannesburg Securities Exchange (JSE), formerly the Johannesburg Stock Exchange, which has officially adopted the Code. The listing requirements were updated in 2000 to incorporate the SAMREC Code and subsequently in 2002, effective 2003. The ongoing obligations of the JSE for the exploration and mining companies are being compiled and are expected to be effective from early 2004.

Jan 1, 2003

By Hae-Moon Choi, Sang-Don Lee, Hee Soon Shin, Choon Sunwo, Chang-Ha Ryu, Hyun-Koo Lee

Building tunnels means dealing with what rock is encountered. Relocation of the site of the underground structure is rarely possible. Tunneling engineers and miners have to cope with the quality of the rock mass as it is. Different tunneling philosophies and different rock classification methods have been developed in various countries. Most of the rock classification methods are based on the response of the rock mass to the excavation. Tunnel support requirements could be assessed analytically, supplemented by rock mass classification predictions, and verified by measurements during construction. Rock mass classifications on their own should only be used for preliminary, planning purposes and not for final tunnel support. Design of blast pattern in tunneling projects in Korea is also for the most part prepared according to the general rock classification methods such as RMR or Q. It, however, does not take into account the blast performance, and as a consequence, produce poor blasting results. In this paper, the methods of general rock classification and blast design for tunnel excavation in Korea are reviewed, and efforts to develop a new classification method, reflecting the blasting performance, are presented. Copyright ©

Jan 1, 2004

By J. J. Moore, B. Mishra, D. L. Olson

The production of radioactive and reactive metals, such as plutonium, uses various pyrometallurgical techniques that generate significant quantities of waste salts contaminated with hazardous, reactive or radioactive materials. Health concerns, environmental regulations and economic considerations require proper mitigation processes to recover the valuable components and for recycling or unrestricted release of these salts. The Oxygen Sparging Process converts soluble metal halides, such as chromium-, plutonium-, cerium chlorides, into insoluble oxides and/or oxychlorides which can be consolidated and separated for long-term storage or further processing. The matrix salt phase, viz. calcium and/or alkali chlorides, are clean after oxygen sparging and fit for recycling. This method has been described and its optimized parameters discussed to show that RCRA regulated elements, such as, chromium, lead, cadmium, etc. report to the consolidated phase making the salt recyclable. Salt Scrub Reduction Process for the recovery of radioactive and RCRA metals from the waste salts has been developed. The process uses a Ca-Ga intermetallic alloy which recovers over 98 percent of the reactive metals. The matrix salt phase in this process, viz. calcium or alkali metal chlorides, are clean after salt scrub reduction.

Jan 1, 1995

By A. M. Gaudin, W. D. Charles

IN flotation lime is used to depress pyrite. For this purpose it is preferred to caustic soda. The low cost of lime and the widespread availability largely account for this preference. However, there is some evidence' that pyrite is more readily depressed by calcium than by sodium ions at the same pH. To measure the difference in adsorption of calcium and sodium, which is thought to lie at the basis of the differences in depressing action, radionuclides of calcium and sodium have been used. The experimental work has included an evaluation of the effect of dissolved oxygen, of the concentration of calcium or sodium, of the concentration of hydrogen ion, and of the anions present. Preliminary work in the investigation entailed preparation of the pyrite, development of a technique for counting pyrite coated with Ca and Na, the radionuclides used, and development of an apparatus to study the adsorption of calcium and sodium on pyrite. The main experimental work included calcium adsorption and sodium adsorption studies detailed below. The following are the most salient observations made during these experiments. Oxygen in solution increases the adsorptive power of pyrite for calcium

Jan 1, 1954

By S. C. Sun

A study(1) on the sulfuric acid extraction of alumina from some Pennsylvania ferruginous clays indicated that the published electrolytic method(2)(3) seems to be more efficient than the known chemical methods (4-9) for removing iron from the leach liquor. The main disadvantages of the chemical methods are the consumption of excessive amounts of reagents and/or the precipitation of prohibitive amounts of aluminum. In the electrolytic method, iron is deposited on the mercury cathode, while aluminum is not and remains in solution. This method, however, had been handicapped by the lack of an effective and economical way to purify the contaminated mercury cathode.(7)(l0). Described herein is a scheme for cleaning the mercury cathode, and for recycling the clean mercury back into the electrolytic cell. Armed with such an apparatus, the effects of applied potential, temperature, and operation time on the electrolytic separation of iron from aluminum sulfate solutions were determined. For the sake of comparing results, a term, removability, was coined to represent the percentage of iron amalgamated per unit height of electrolyte (cm.), per unit surface area of cathode (cm.2), per unit of operation time (second).

Jan 1, 1968

By M. J. Ferrante

The Bureau of Mines determined the enthalpies of Ni3S2 relative to 298.15 K to provide new thermodynamic data for advancement of mineral science and technology. Enthalpies were measured with a copper-block calorimeter from 298.15 to 1,197 K. A solid-solid transition was found at 834±1 K, with an isothermal heat absorption of 13.32 kcal/mol. The temperature of this solid-solid transition was accurately measured by differential scanning calorimetry. Because Ni3S2 does not melt congruently, the heat of fusion of 4.70 kcal/mol was obtained by extrapolation of enthalpy measurements from the solid and liquid phases to approximately 1,064 K. Tabulated values are given for the relative standard enthalpy, heat capacity, entropy, and Gibbs energy function between 298.15 and 1,800 K. Enthalpies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation. Similar calculations were made for the reaction of crystalline and liquid nickel with gaseous diatomic sulfur for Ni3S-2(c, l).

Jan 1, 1982

By D. O. Ehrenburg

DURING the earlier period of electrical prospecting, the search for orebodies was by far the most important application of this method of geophysical prospecting. In the past few years, however, increasing attention has been paid to the possibilities of this method in the investigation of subsurface structures. Not only have fault zones been located, but attempts have been made to determine the depth to certain strata and thus contouring on some bed which proves to be a good "electrical marker." Many workers have published the results of field tests showing how their particular interpretations have agreed with the actual field conditions, but very few have stated their method of interpretation. Weaver, Hummel and Stefanesco and Schlumberger1 have given a more theoretical discussion of the resistivity methods. Hummel and Stefanesco and Schlumberger have published mathematical solutions for the flow of electricity in a medium involving four layers. In this paper the authors present a solution for the flow of electricity in a medium of any number of horizontal strata. By means of this solution, curves showing the relationship between the apparent resistivity and the electrode spacing can be computed for ideal cases.

Jan 1, 1931

By Shiou-Chuan Sun

THE effects of oxidation on the flotation behavior of sulphide minerals have been extensively studied,1-3 but no similar study has been made of coals. Coals of bituminous and lower rank undergo atmospheric oxidation during mining and storage, and their degree of oxidizing increases with temperature4,5 and time of exposure.6 The problem of recovering fine oxidized coal from culm piles, rivers, and streams by froth flotation has become increasingly important to the coal industry as well as to those concerned with air and stream pollution. This paper describes the flotation behavior of oxidized and unoxidized coals and carbons in the presence of oily collectors and presents the reagents found effective in the flotation of oxidized coals and carbons. Except where otherwise stated, flotation tests were performed in a 50-g Denver flotation cell. Solid feed for each test was 30 g, and the pulp dilution was kept at 8.5. The -65 mesh coal sample was wetted by agitation with water in the flotation cell for 6 min, then conditioned with a predetermined amount of collector for 2 min, and finally floated with pine oil as frother for 3 min.

Jan 4, 1954

By Robert P. Vinson, Fred N. Kissell, Edward D. Thimons

Because of the high number of accidental methane gas ignitions in metal and nonmetal mines, the Bureau of Mines searched for a simple guideline that would allow mine personnel to evaluate the methane hazard in a given mine. Air samples were collected by the Bureau in 53 metal and nonmetal mines and analyzed for trace evidence of methane gas. Samples were collected in the returns and at the working faces. Those mines classified as gassy by the Mine Safety and Health Administration had a significantly higher average methane concentration than those classified as nongassy. Of the 9 gassy mines sampled, 7 had methane concentrations above 100 ppm, whereas only 1 of the 44 nongassy mines had a concentration above 100 ppm. The 100-ppm concentration may be used as a simple and convenient guideline for forecasting the methane hazard in a mine, whether or not the mine is classified as gassy. There was no consistent correlation between commodity mined and methane concentration, nor was there a correlation between mine depth and methane concentration. Neither of these factors can be considered a guideline for predicting methane hazards.

Jan 1, 1979

By Thomas B. Dellinger

Since 1950, rotary-drilled, large-diameter holes, "big holes", with depths to over 300 ft and diameters of over 30 in., have become numerous and widespread. 50 such holes have been drilled for access shafts to LPG mined caverns. Over 70 holes have been drilled for various other commercial activities. Over 150 holes have been drilled by the AEC for atomic testing purposes. These holes have ranged up to 300-in. diam with 1600-ft depths, 120- in. diam with 570-ft depths, and 72-in. diam with 4800-ft depths. Equipment is now available to drill a wide range of big holes for varied requirements. At least a dozen drilling contractors are participating or have participated in the drilling of big holes. The accompanying tables show pertinent historical, technical and economic data on over 250 holes. The purpose of this paper is to present a review of the big hole drilling equipment available, a compilation of the available data on large-diameter holes, to show the experience obtained to date and to show that big hole drilling is feasible and available to the industry.

Jan 12, 1965

By McDonald E, Clifford PJ

A mine planning system comprises all elements necessary to carry out the full range of mine planning activities from exploration to operations control. The application of computers as part of a mine planning system has great potential for increasing the efficiency and quality of mine planning and reducing its cost. The introduction of computers to mine planning in open cut coal mines has been hindered by the cost of processing the large databases associated with large coal deposits and the inherent inconvenience of performing an interactive process on a time-shared computer. A dedicated computer is ideally suited for the purpose but reasonably priced micro/ mini-computers until recently have not had the capacity to store the volume of data or the processing capability required. Recent hardware developments have cleared the way for the development of truly interactive mine planning software, covering the complete range of activities associated with open cut coal mine planning, incorporating them into a single system using a common database. The MINEMAP System is a hardware and software package tailored specifically for mine planning of open cut coal mines and is an example of such a system.

Jan 1, 1983

By Young C. Kim

Determination of the minimum sampling requirements of the run-of-mine (ROM) coal is very important for the purpose of meeting contract specifications. It is also important for the purpose of meeting emission regulations at a coal-burning power plant, such as the one located at Homer City, Pa. The classical statistical sampling theory can be applied to this problem, if ROM coal samples are known to be spatially (or serially) uncorrelated. On the other hand, the estimation variance concept from the Matherson's geostatistics must be used, if the samples are spatially correlated. Conditional simulation technique combined with simulation of the existing mining method is used to determine under which circumstances ROM coal samples do not preserve the spatial correlation. Only after establishing the degree of correlation that exists among ROM samples, an optimal sampling scheme can be devised using either the classical statistics Or the geostatistics. The minimum required sample volume can then be calculated using the well-known Gy's formula. This paper describes the results of the above investigation using the Helen coal mine data of the Homer City Owners. Empirical guidelines for determining the degree of correlation are also provided for coal mine operators.

Jan 1, 1986

By James L. Sweeney

The Project Independence Evaluation System (PIES) is a complex evaluation, forecasting, and analysis system which represents the U.S. energy production, conversion, transportation and consumption activities. The system includes various models: An econometrically estimated energy demand model, used to evaluate the final demand functions for energy commodities ; A collection of supply models, used to evaluate the cost curves or supply curves for domestic crude oil, natural gas, coal ; An integrating model used to describe energy conversion and transportation activities and to calculate prices which equate energy supply and demand in each market. PIES has been used to generate conditional forecasts of the 1980, 1985, and 1990 states of the energy system--forecasts conditional upon the world oil prices, the energy policy environment, and other uncertainties. Scenarios have been structured to separately examine conservation initiatives, domestic energy supply enhancements, an extensive electrification strategy, and oil and natural gas well -head price regulation. This paper presents the basic model, discusses its use for examining policy options, and describes several forecast results. The paper draws heavily upon work completed for the 1976 National Energy Outlook, published by the Federal Energy Administration.

Jan 1, 1977

By D. A. Vetter

A novel mathematical model is presented which describes the behaviour of beds of particles, of uniform size and shape but different densities, during autogenous separations. The approach used in the formulation of the dispersion model is a phenomenological one based on a statistical view, which leads to a diffusion-like representation of the autogenous-separation process. Although the model currently considers only density-related phenomena, it accounts quantitatively not only for the density-segregation aspects of the process but for the interactions between the particles. Quantitative predictions of the dispersion model are compared with the results obtained in tests using a specially constructed experimental batch jig, and it is shown that the model provides an adequate quantitative description of the process for particles of uniform size and shape. It is pointed out that, for the description of more complicated autogenous separations, a more rigorous formulation of the particle drag and density-segregation terms will have to be incorporated into the dispersion model. Nonetheless it is concluded that the model as presented in this paper provides not only a novel insight into the mechanisms of autogenous separations but a means by which to analyse similar systems.

Jan 1, 1987

Virtual reality (VR) simulators represent a powerful tool for training humans to perform tasks which are otherwise expensive or dangerous to duplicate in the real world. The idea is not new. Flight simulators have been used for decades to train pilots for both commercial and military aviation. These systems have advanced to a point that they are integral to both the design and the operation of modern aircraft (Adams, Klowden and Hannaford, 2001; Mastaglio and Callahan, 1995). This technology has been successfully extended and utilised in the mining industry in a range of successful applications (Bise, 1997; Denby and Schofield, 1999a; Schofield, 2005; Henning et al, 2002; Kaiser, Vasak and Suorineni, 2005). There are a number of lessons that can be learned from other industries that have successfully utilised virtual technology for a number of years. Specific rules of thumb regarding the specification, development, application and operation of these simulators can be garnered from other industrial training systems and examined in a minerals industry context (Tromp and Schofield, 2004; Schofield, 2006). This paper intends to discuss some of these generic rules in the context of a number of recently developed virtual reality mining applications.

Jan 1, 2008

By Connie S. Musulin

The Bureau of Mines conducted an experiment at Exxon Mineral Co.'s Buffalo Shaft Operation to determine the time required for radon concentrations to return to a base average after fan shutdowns. Shutdown times ranging from 5 min to 16 hr were evaluated. An equation was derived to calculate a ratio that determines the time required for the radon concentration to return to the average level that existed in the mine prior to shutdown. For fan shutdowns of 15 min or more, underground personnel should be evacuated to areas with natural downcast ventilation. For shutdowns of less than 1 hr, personnel should not return to the working area until the elapsed time is four times the shutdown, or until the working area is resampled and found safe. If the mine is not in production during weekends, the downcast fans can be turned off .from midnight Friday until 4 p.m. Sunday, and the radon daughter concentration should be below 1 WL throughout the mine by the start of the shift Monday. This fan shutdown would conserve energy and save the mining company an estimated $21,000 each year.

Jan 1, 1982

By R. V. Ramani, R. Bhaskar

Control of respirable dust in mines has been given paramount importance due to the health and safety implications associated with fine dust. Understanding the temporal and spatial behavior of dust has been recognized as essential for increasing the efficiencies of existing control techniques and for developing new control strategies. Mining-related studies in this area are, in general, limited. They are also mostly experimental. Some mathematical and computer analyses have been at-tempted. In this paper, first, a review of the mathematical studies performed in the last three decades in this area is presented. Second, a mathematical model for analyzing dust flow in mines is proposed. The model takes into account a number of factors affecting dust transport. It in¬corporates varying dust generation source strengths and dispersion, deposition, and coagulation of dust in mine airways. Finally, application areas for the model are discussed. A computer program based on the mathematical model has been developed. The program will output the dust concentration in the mine atmosphere as a function of time and distance from the source. The amount of dust deposited on the sides, roof, and floor of the airway is also determined.

Jan 1, 1987

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014