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By V Dolmage

In 1957 and 1958, ten topographically suitable damsites were investigated along the Peace river between Finlay Forks and Hudson Hope, B.C. Of these, three were eliminated after a reconnaissance survey indicated that the geology was unsuitable for the 650-ft.-high dam contemplated. ?After extensive drilling, five other sites were deemed unfeasible because of geological factors and, in 1959, the two remaining sites were designated as being suitable, one for the high dam and the other for a low dam downstream. The sites are located in the Peace River canyon, on the west and the south? side of Portage mountain, west of Hudson Hope. The site for the large dam, the Portage Mountain dam, has since been investigated by surface mapping, thousands of feet of diamond drilling, a seismic survey, laboratory rock tests and on-site grouting tests in order to establish the possible effect on the dam of all facets of the foundation rocks. Three diversion tunnels, 50 ft. in diameter and 2,200 feet in length, have been driven through massive sandstone and shale, and an intake cut, 500 ft. in length, 200 feet in width and 200 feet in depth, has also been excavated in rock.

Jan 1, 1963

By R. L. Marek

The number of persons fatally injured in the California petroleum industry in 1932 was 24, a decrease of 6, or 20 percent from the number killed in 1931. The decrease in the number of fatalities occurring in 1932 caused the fatality curve of the California petroleum industry to reach its lowest point in 10 years. Changing conditions in the oil industry - reduced personnel, decreased active field development, and curtailed production - have undoubtedly caused a part of this decrease, but continued accident-prevention efforts by the industry have also contributed to the reduction in the number of fatalities for 1932. The Bureau of Mines has analyzed and reported annually the fatalities in the California petroleum industry for a period of 10 years. Figure 1 shows the trend of fatal accidents during that period. Fatality statistics for 1932 show that the drilling and producing, pipe line and transportation, and refining and natural gasoline divisions of the industry had fewer accidents in 1932 than in 1931, sales and marketing being the only division that showed an increase over 1931. The number of fatalities by divisions for 1931 and 1932, percent of total, and percentages of increase and decrease are given in Table 1.

Jan 1, 1933

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By Fergusson E.

An account is given of the history and operation of the Straits Tin market and the Penang price. The procedure by which the official ruling tin price is determined is presented and the way in which bids are treated is outlined: the price declared in Penang is the result of a joint operation by the two Malaysian smelters and is arrived at by finding the highest price at which the whole of the day's offerings for sale can be sold, thus reflecting the marriage of the offerings of the individual mine producers with the demand for Straits Tin from the consuming countries of the world. A system of accurate weighing, sampling and assaying of concentrates delivered to the smelters' premises enables the various ore-buying agencies of the two smelters to notify their central offices promptly of the estimated tin content of the concentrates their customers wish to price that day, so that by 11.00 a.m. both smelters will have exchanged with each other figures giving the total quantity of metal they have for inclusion in the day's market, at the same time exchanging particulars of the bids they have received. Miners are encouraged to sell regularly for cash and an evenness is thus achieved which avoids large daily fluctuations in overall quantity.

Dec 30, 1971

By B. J. Jody

At Argonne National Laboratory, we have been developing a potentially economical process to recycle automobile shredder residue (ASR). We identified three potentially marketable materials that can be recovered from ASR and developed technologies to recover and upgrade these materials. We built and tested a field-demonstration plant for recycling polyurethane foam and produced about 2,000 lb (907 kg) of recycled foam. Several 300-lb (I36-kg) samples were sent for evaluation and were found to be of marketable quality. We are also preparing for a large-scale test in which about 200 tons (181 tonnes) of ASR-derived fines «0.25 in. [<0.62 cm]) will be used as a raw material in cement making. A major cement company has evaluated small samples of fines prepared in the laboratory and found that they meet its requirements as a substitute for iron ore or mill scale. We also produced about 50 lb (23 kg) of recycled acrylonitrile butadiene styrene (ABS) from obsolete automobiles and found that it has properties that could be readily upgraded to meet the specifications of the automotive industry. In this paper, we briefly discuss the process as a whole and summarize the results obtained from the field work on foam and fines recycling.

Jan 1, 1996

By J. J. Kellar

Researchers have long speculated regarding the adsorption state of collectors on mineral surfaces. Only recently have analytical techniques become available which allow direct in-situ analysis of adsorbed layers. Fourier transform infrared spectroscopy coupled with internal reflection spectroscopy (FT-IRJIRS) with reactive internal reflection elements allows for unobtrusive investigation of the adsorbed layer (Harrick, 1979). This technique has been used both for the in-situ identification of adsorbed species and for the direct calculation of collector adsorption density in real time from infrared spectral data (Miller and Kellar, 1988). The reactive mineral IRE serves both to internally reflect the infrared light and to act as a substrate at which collector adsorption can be monitored. Shown in Figure 1 is a schematic of light being internally reflected in an IRE. As the light is totally reflected at the interface, an evanescent wave propagates a short distance (typically a few microns) away from the IRE, and sampling of the interfacial region occurs. Because of multiple internal reflections, great sensitivity can be obtained. Flotation systems for which this method has been demonstrated include CaF2/oleate, Al2O3/ dodecyl sulfate, CaCO3/oleate, ZnS/xanthate, and KCl/octylamine (Miller and Kellar, 1988; Kellar et al., 1989, 1990; Miller et al., 1990).

Jan 1, 1992

By D. Adiguzel

In this research, providing the sustainability of production quality was aimed for a quarry which is located in Istanbul western part of Turkey and producing concrete aggregates with different types of rock. First, research field was divided in 3 different areas in accordance with the geological differences and parameters that control their product quality, limit values of standards and effect levels were determined. Concrete aggregate conformity tests which are stated in international standards were applied on samples which were taken from these 3 different areas and physical, geometric and chemical properties of each rock type were revealed. The properties of the 3 different types of rock which were produced in the quary were determined and the binary blends were composed. Blending studies were conducted with linear programming technique. In the linear programming model, the cost of aggregate production was aimed to be minimal. The limit values that meet literature and national standards for usability of aggregates in concrete were defined as constraints in the linear programming model and evaluated with objective functions, thus the most suitable aggregate blends were composed. In conclusion, to provide the sustainability of product quality, the most appropriate product blends were composed for the research field and the usability of this model for those quarries were revealed.

Aug 1, 2013

Experimental determination of the response of an AG/SAG mill treating two components of significantly different impact resistance is challenging for two main reasons: firstly, small scale laboratory tests have yet to be confirmed as valid representations of the full scale milling environment, and secondly pilot plant testing requires 10-20 tonnes of ore per scenario which precludes the use of drill core, rendering the process very expensive. In order to mitigate these difficulties, modelling was considered as a potential way forward. However, as the JKSimMet AG/SAG model currently has no capacity to simulate the interaction of two ore types with differing impact resistance, density and/or feed size distributions, an alternative modelling approach was developed. This approach aims to essentially calibrate the AG/SAG process under a set of given conditions, for which survey data and the ore properties of the main components in the feed blend already exist. This paper describes a new conceptual model, which provides a simplified approach for investigating the multi-component behaviour of two ores of differing hardness/SG in a given AG/SAG milling environment, and which can potentially be used for scale-up from laboratory/pilot testwork and geometallurgical estimation of throughput.

Jan 1, 2012

By J. P. Bennett

The Bureau of Mines investigated the dimensional changes of ceramic materials exposed to acid environments to evaluate construction materials for emerging technology in chemical and metallurgical processes. Six commercial ceramic materials (two red shale, two fireclay, one silica, and one silicon carbide (SiC» were exposed to H20, 20 and 30 wt pct HCl, 40 and 60 wt pct HN03, and 10 and 50 wt pct H2S04 at temperatures from 50° to 90° C for 300 days. Linear expansions ranged from a low of -0.02 pct for the silica to a high of 0.45 pct for the red shale. A general ranking of the volume expansion of the materials tested, (from high to low), is as follows: high-porosity red shale A and fireclay B » low-porosity red shale B and fireclay A > silicon carbide and silica. A general ranking (largest to smallest) of the effect of exposure environments is HCl > H2S04, HN03 > H20. An autoclave test method was evaluated. Data obtained from 8-to 24-h exposures were compared with data obtained from the 300-day exposures. The relative expansion trends were similar, indicating that this method could be used as an accelerated test.

Jan 1, 1988

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

In order to realize the resource utilization of spent hydrodesulfurization catalyst, a solvent extraction-oxalic acid precipitation process is studied in this paper for efficiently recovering vanadium, nickel, and aluminum from the acid leaching solution of spent hydrodesulfurization catalyst. The process conditions for extracting vanadium with Cyanex 272 and precipitating nickel using oxalic acid as a precipitation agent were explored in detail. The results show that vanadium (IV) in the sulfuric acid medium containing nickel and aluminum was efficiently and selectively extracted by Cyanex 272. After three-stage countercurrent extraction, the extraction efficiency of vanadium was 99.76%, and the co-extraction efficiencies of nickel and aluminum were only 2.47% and 1.87%, respectively. Thermodynamic calculation shows that the extraction of vanadium (IV) from the sulfuric acid medium with Cyanex 272 is an endothermic reaction. The innovative method of oxalic acid precipitation was used to recover nickel from the raffinate, achieving selective extraction of nickel from the solution containing a high concentration of aluminum. The precipitation efficiency of nickel was 98.58%, while that of aluminum was only 0.75% under optimal conditions. The proposed flowsheet for the separation of vanadium, nickel, and aluminum from acid leaching solution may provide a new idea for the comprehensive recovery of valuable metals from spent hydrodesulfurization catalyst.

Nov 30, 2022

By J. L. Eakin

Systematic flooding was introduced into Nowata County, Okla., in May 1931. The results of this means of stimulating the nearly depleted Bartlesville reservoir in the county has been the subject of four Bureau of Mines Reports of Investigations.2-5/ This report presents a discussion of four full-scale water-flooding projects in the Delaware-Childers field and 1 pilot project in the Curl Creek field (fig. 1). All five plants have been in operation for only a few months. Although substantial increases in the rates of oil production have been obtained 1 by the injection of water, the projects are of particular interest at this time because of the novel methods of operation and new equipment that are being employed. One project utilizes a portable "package" plant designed for a pilot operation. All of the controls for this project are centrally located. The design makes it possible to remove the test plant to another location if the project is unsuccessful or if the unit is to be replaced by a larger plant. This project also utilizes diatomaceous-earth filters successfully for the first time and makes use of plastic pipe. Another novel feature of the operation is the aeration of Arbuckle limestone water through an airlift in the supply well.

Jan 1, 1955

Silver has the highest electrical conductivity of all metals and consequently this property is an attractive feature which makes it a leading candidate for use in electronic devices. The research conducted was focused primarily on the development of a process for obtaining a deposited silver-coating onto alumina, for applications related to electrical-conducting devices and, ancillarily, catalysts. Alumina balls and plane substrates were utilized for the investigation. The coating process employed an aqueous arnmoniacal silver-nitrate electrolytes with a formaldehyde solution as the reductant. Modifying additives - an activator which would be expected to promote good deposition-characteristics onto the (dielectric) substrate and an inhibitor which would obviate homogeneous reduction (precipitation) of silver was observed when the activator-containing silver-electrolyte reductant constituents were combined. However, the silver-electrolyte/reductant system with inhibitor could be employed (at 80°C) to achieve a viable (subject to future research optimization) coating on alumina. The influence of the processing temperature on the deposition process was delineated during the course of the research. The morphology of the deposited-silver on the alumina balls was assessed by SEM imaging. A tape-peel test was employed, with the plane substrates, to semi-quantitatively characterize the adhesion to the alumina.

Jan 1, 1998

By Valentine Chanturiya, Irina Khabarova, Maria Ryazantseva, Igor Bunin

"XPS investigations of the influence of HPEMP - treatment duration on the surface composition for natural chalcopyrite and sphalerite are described. HPEMP is a video pulse with a nanosecond front lasting between 5 and 10 ns. The electrical field component can reach 30 kV, whereas pulses repetition frequency is 100 Hz. In general, the formation of metal-deficient surfaces, polysulphides or elemental sulphur and oxides/hydroxides, were determined during the treatment for both sulphides as well as the essential differences of the way of mineral surface transformation during the treatment. The chalcopyrite surface shows the formation of elemental sulphur under the HPEMP treatment at 103 pulses while appearance of unstable sulphite species was detected at the chalcopyrite surface within 5 seconds (0.5•103 pulses) under the same treatment conditions. The results indicate that the quantity of adsorbed water (at.%) is changed considerably during the HPEM - treatment depending on treatment duration for both minerals. The concentration of water onto the chalcopyrite surface decreased during 30 seconds (3•103 pulses) of the HPEMP - treatment and it rose after the treatment at 5•103 pulses. The inverse dependency was obtained for sphalerite surface. Single mineral flotation tests have shown the significant increasing of the minerals recovery."

Jan 1, 2014

By R. M. Mashishi, T. Malehase, O. J. Okonkwo

The concentrations of selected trace elements (As, Cd, Hg, and Pb in run-of-mine (ROM) coal, discard, and coal product were investigated to assess the efficiency of beneficiation in reducing trace element concentrations and ascertain any implications regarding environmental compliance to regulatory frameworks. Samples were collected from a colliery in Mpumalanga Province twice a month for a period of 24 months. The samples were ashed to approximately 0.21 mm, then digested in a mixture of 70% HNO3 and 40% HF and analysed using inductively coupled plasma-mass spectrometry (ICP-MS). Except for Pb, the mean concentration of all elements decreased from the ROM stage to the coal product stage. The order in which trace elements occurred from the highest to lowest throughout the production chain was Pb>As>Hg>Cd. With the exception of Cd, the mean trace element concentrations in the discard were above the total concentration threshold (TCT) set for landfill disposal. The As, Hg, and Cd concentrations in the product were well below the thresholds for all land uses. However, Pb concentrations in the product coal were above legal limits, which is of concern with regard to environmental compliance and the performance and marketability of the product.

Dec 13, 2023

By W. T. lsbell

HERCULANEUM, MO., about thirty miles south of St. Louis on the Mississippi River, is the site of the lead smelter of the St. Joseph Lead Co. The lead concentrates come by rail from the Flat River district and from three properties in Madison County, Missouri; from the Balmat division in St. Lawrence County, New York; a small tonnage from the Tri-State district; and occasionally from the Aguilar property in Argentina. The average grade is 67 to 68 percent lead and 1 to 3 oz of silver. The bulk of the material is flotation concentrate, with some gravity or table concentrate. No secondary metals, outside drosses, or any materials high in bismuth, arsenic, or antimony are treated. All concentrate is received in box-caps and is unloaded directly from a trestle into the concentrate bins at the roaster plant. Flux, coke, and any miscellaneous lead-bearing material is either unloaded directly into bins or unloaded with a locomotive crane. All moving and switching of cars is done with two thirty-ton steam locomotives. Shipping facilities for the plant are provided by the Missouri-Illinois Railroad. Water for the plant and for fire protection is obtained from a dam built in a near-by creek. Drinking water both for plant and town is obtained from

Jan 1, 1947

By W. W. Adams

Lower accident rates were the outstanding feature. of the second annual sand and gravel safety competition conducted in 1930 by the United States Bureau of Mines in cooperation with the National Sand and Gravel Association. Both the frequency and, severity rates for accidents were greatly reduced as compared with those shown by the first year&apos;s contest, that for 1929. Three times as many plants were enrolled, and the number of man-hours of work represented wad more than doubled. Seventy-six sand-and-gravel plants, situated in 20 States, participated in the competition, as compared with 26 plants, located in 13 States, in the year before. The number of man-hours of employment, which indicated the amount of exposure to occupational hazards, was 4,915,592 an increase of more than 100 per cent over, the previous year&apos;s total of 2.259,572 hours. The frequents of accidents declined from 74.4 per million hours for all plants enrolled in the first year&apos;s contest to 42.7 per million man-hours for all plants enrolled in 1930. The accident-severity rate was reduced from 9.7 days of disability per thousand man-hours of exposure in 1929 to 5.9 days of disability per thousand man-hours of exposure in 1930.

Jan 1, 1931

By Charles E. Mauk

In 1970, recognizing the great need for an economical, high capacity chemical oxidation process for wastewater treatment, Houston Research began a fundamental study of the available technology, Included was waste characterization; oxidation chemistry for molecular oxygen, ozone and catalyst initiators; kinetics of reaction; gas-liquid contacting methods; and optimization of staged reactors for mixed wastes. Although ozone is the most powerful oxidizer available, the literature contains contradictory reports of its speed and effectiveness. It is now felt to be most likely that many of these early investigations were limited by the ineffectual transfer of ozone from the gas phase into the liquid, and so the investigators were really observing the effects of mass transfer and erroneously trying to interpret the results as if they were chemical reaction data. HR&apos;s work considered the cost and effectiveness of gas-liquid contacting in a packed tower, gas sparged contactor, ejector with hold-up tank, and a completely mixed, sparged contactor. The sparged, mixed contactor was found to be most effective and least expensive, and a later investigation settled on the reactor configuration shown in Figure 1 because of its effectiveness of mass transfer and because it lends itself to direct scale-up techniques using laboratory data to design larger reactors.

Jan 1, 1975

By Robert L. Goehring, Fred Munene

This case history for three major additions to a tire manufacturing plant in north Georgia discusses the impact of highly variable Karst (sinkhole) geology on both foundation design and construction. For Phase 3, alternatives were considered for a heavily loaded mixing tower with up to 2,000 kip column loads. A non-traditional approach of using auger cast piles was adopted. To satisfy a risk-averse Owner, a pile load testing program including strain gauges was conducted. One test pile was cored full depth to demonstrate effective bearing on steeply inclined rock. For Phase 4, similar methodology was used at another critical mixing tower structure associated with that phase and the installation procedure was refined to reduce grout take. In Phase 5 construction, another mixing tower and the equipment pits were supported on auger cast piles. After pile installation, a sinkhole opened up between two equipment pits. Remedial grouting was performed. Development also required construction of a R&D building over a 96 inch diameter RCP storm sewer. Auger cast piles were used to support the building to avoid overstressing the existing pipe and risk separating joints. This case history outlines lessons learned while constructing auger cast piles in Karst and proving quality was built into the foundations.

By G. R. Webber

CHEMICAL AN AL YSIS by x-ray emission spectrometry has become increasingly important during the past few years. The method is analogous to optical spectrography ?with x-rays being used instead of light and should not be confused with methods of x-ray diffraction used? for identification of minerals and chemical compounds. X-ray emission spectrometry has many advantages for both qualitative and quantitative analysis. Its optimum concentration range is higher than that of the optical spectrograph, and the group of elements which can be detected is not identical to that which can be detected by the optical spectrograph. Elements which can be detected by the x-ray spectrometer are those elements from magnesium (atomic number 12) to uranium (atomic number 92) in the periodic table. The lightest elements in this range have low sensitivities and more specialized equipment is necessary for their detection than for the heavier elements. A large number of applications of x-ray analysis have been directed toward the analysis of ores, metallurgical products, and related materials (see References at end of paper). A more complete bibliography is presented in the Norelco Reporter, Vol. 3, 1956, pp. 37-39. The periodicals Analytical Chemistry and Applied Spectroscopy are a good source of current articles and references.

Jan 1, 1957

By Staia. Mariana H.

Thermochemical equilibria of the heterogeneous system Ti-N-H-CI-Fe-Cr-Mo-Ni-Mn-C were calculated by using a commercial software based on the minimization of the free energy. Equilibrium calculations were done for temperatures varying between 800" and l 100°C and an initial molar relationship between reactants, a=NJTiCI,, of 0.1 to 2. The deposition process was considered to occur at atmospheric pressure. The activities of the alloying elements of the stainless steel were considered equal to their molar fractions. It was shown that for the conditions studied the substrate is no inert with respect to the gaseous phase. The existence of liquid chlorides was predicted for temperatures between 800" and 850°C and a ratio between 0.3 and 0.9. The most important metallic chlorides which appears to be present from the calculations in appreciable quantities in the gaseous phase are iron dichloride and manganese dichloride. In the low-temperatures zone and for low initial nitrogen contents, it result that the appearance of the liquid chlorides seems that partially inhibits the production of gaseous HCI. The highest deposition process efficiency calculated is obtained at a temperature 2 900°C and a N2/TiCI, ratios 2 0.7.

Jan 1, 1995