Search Documents

By V. Vallyathan, Xianglin Shi, N. S. Dalai

While Cr(VI) is a known carcinogen, the underlying biochemical mechanism is still not fully understood (1). In a pioneering study Jennette (2) utilized electron spin resonance (ESR) spectroscopy to demonstrate that a long-lived Cr(V) species is generated during the reduction of Cr(VI) by microsomes in the presence of NADPH. Later Wetterhahn and co-workers (3, 4) showed that incubation of chromate with isolated rat liver mitochondria causes the reduction of Cr(VI), as well as the formation of a Cr(V) species. Analogous Cr(V) species have also been detected in the reduction of Cr(VI) by other cellular systems such as Hanserulla polymorphared (5) and blood cells (6, 7). All these as well as other studies (8-12) have suggested that this Cr(V) species plays a significant role in the mechanism of Cr(VI) toxicity. Thus far, however, the chemical structure of this dominant Cr(V) species formed in cellular systems has not been identified, and this observation provided an impetus for the present investigation. Another reason for undertaking this study was that some recent reports (10-16) suggest that hydroxyl ('OH) radicals may also play an important role in the mechanism of Cr(VI) toxicity. In particular, it has been shown that OH radicals are formed in reactions between Cr(V) species and H2O2 (13-16), and that the radical yield depends on the chemical structure of the Cr(V) species (15). For example, while Cr(V)-diol complexes efficiently generate OH radicals, another Cr(V) species, the tetraperoxochromate (CrO3/8) ion, does not (15). Thus in the present study, we focused our attention on the following: (a) structural identification of the Cr(V) species generated in the reduction of Cr(VI) by subcellular as well as cellular systems, using microsomes, mitochondria, and Escherichia coli; (b) possible detection of OH radical in the same systems since there is no earlier report of chromium-mediated generation of 'OH radicals in a cellular system; (c) possible involvement of molecular oxygen in chromium-related OH radical generation since a recent report (17) indicated that Cr(VI) mutagenesis is strongly oxygen dependent; and (d) elucidation of the mechanism of OH radical formation in these systems.

Mar 1, 1992

By W. A. Backofen, R. L. Fleischer

Single crystal, bicrystal, and polycrystal tensile tests of aluminum at 4.2°K, 77°K, and 300°K have been used to examine the role of grain boundaries in the deformation process. Results indicate that a grain boundary may affect the extent and slope of easy glide. The stage II hardening rate, on the other hand, is independent of the presence or absence of grain boundaries. This conclusion allows the size of the region of multiple slip caused by an incompatible grain boundary to be determined. For the size of bicyystal sample used in this study, multiple slip occurs in about half of the cross section. PREVIOUS studies of the stress-strain characteristics of bicrystals of face-centered-cubic metals have been limited to aluminuml-5 at room temperature. Recent results, however, indicate that the stress-strain curves of single crystals of such metals may be separated into at least three stages6 in which different deformation processes are occurring7 provided testing is done at sufficiently low temperatures.' Since for aluminum a well-defined stage II develops only below room temperature, previous studies have not been able to relate effects of grain boundaries to all of the three stages of deformation. It is therefore to be expected that low-temperature deformation of aluminum single crystals and bicrystals should clarify the effects of grain boundaries on the different processes of deformation. EXPERIMENTAL PROCEDURE Single crystals and bicrystals were grown from the melt by the standard techniqueg with aluminum reported by Alcoa to be 99.993 pct pure. Ridges in the boat were used to guide the grain boundary during growth, assuring that the boundary would bisect the sample.10 The rate of furnace motion during growth was 1.0 cm per hr. During growth zone purification resulted, as evidenced by the ability of the first material to freeze to recrystallize at room temperature following severe deformation. Samples were approximately 4.4 X 6.6 mm in cross section and 103.5 mm in length between grips. Samples were annealed at 635" i 5°C for 40 hr and furnace cooled over a 7-hr period. They were then electropolished in a solution of 5 parts methanol to 1 part perchloric acid at a current density of 15 amp per sq dm for about 30 min at temperatures below 0°C. Tensile testing was performed at 295" (room temperature), 77" (sample in liquid nitrogen), and 4.2"K (sample in liquid helium) on the hard-type machine indicated schematically in Fig. 1. The machine con- sists basically of a tube surrounding a rod; one end of the sample is attached to each member, and the rod is pulled up the tube to extend the sample. The rod is rigidly mounted and is moved vertically by a system described by asinski." The pulling force is measured continuously by an electrical strain gage load cell, and the relative displacement of the tube and rod is also recorded continuously by a soft cantilever beam with electrical strain gages. Maximum stress and strain sensitivities were ±2g per sq mm and * 3-10-5. In all tests the strain rate was approximately 5.10-5 per sec. The thin wires in the tensile apparatus introduce softness, which may be corrected for, however, by measuring load vs displacement with the sample replaced by an elastic member. For loads greater than 15 kg the spring constant is 1.875.106 g per cm. The flexible wires also served to reduce substantially the large shearing forces which may arise in the case of grips having horizontal rigidity.'' As in any gripping system, however, bending moments will arise in the course of deformation by single slip. Engineering stress, s = (load)/(original cross-sectional area), and strain, E = (increase in length)/ (original length), are used for stress-strain curves unless otherwise indicated. Tables list resolved shear stress, T=mo and shear strain ? = dm, where m is the usual Schmid resolved shear stress factor for the primary slip system at the start of deformation. The first group of samples to be described forms an isoaxial set, all of the crystals making up the single crystals or bicrystals having the same tensile axis, the orientation of which is indicated by the cross in Fig. 2. For this orientation the primary slip plane and slip direction make angles of 45 deg with the tensile axis and the Schmid factor m has its maximum possible value of 0.5. Rotations about the tensile axis are indexed by means of an angle 0 between the small-area surface of the samples and the projection of the primary slip direction onto the cross section, as defined in Fig. 3. In single crystals, values of 0 were 0 and 90 deg, while in bicrystals 0 values were (0 deg, 180 deg), (90 deg, 270 deg), and (0 deg, 90 deg) as indicated in Fig. 4.

Jan 1, 1961

By Hamid Maleki

Prudent design of coal pillars in any mining system requires an estimation of in-situ pillar strength, overburden lateral load transfer capability, and a failure criterion. Pillar strength is typically determined using one of several different empirical pillar strength formulas. For coal reserves in the U.S., a new pillar design method was proposed based on extensive U.S. field measurements in underground mines (7) which accounted for confinement effects. Field measurements in seven U.S. seams indicated highest strength for some Utah mines where the coal seam developed high confining stresses. Lower strength was measured in structurally controlled seams. This method is expanded here including the data from the weaker tertiary coal measure rocks and lower confinement for pillars with low width-to-height ratios. The determination of how much load a pillar is expected to take is partially dependent on the ability of overburden to transfer load laterally; this is useful for selection of panel width and barrier pillars size in select mining applications where long-term stability is required in conservative designs. In caving mining systems, caving of the strata is influenced by geologic, mining and stress conditions and the released energies influences how the pillars react at loads approaching pillar strengths. Overburden deformation and caving mechanisms are analyzed in this paper in multi-panel extractions to enhance the understanding of load transfer, seismicity and coal bump control in deep western U.S. operations.

Jan 1, 2008

By R. A. Beall, W. E. Anable

The purification of hafnium by electron- beam melting at moderate energy inputs and at low pressures was examined in detail . Most metallic impurities and hydrogen were removed in the first few minutes of operation ; oxygen , carbon , and nitrogen were removed at a slower rate . Samples treated by electron bombardment suffered a small loss of weight and a gradual lowering of hardness . The magnitude of each change varied with the energy input and the duration of the melt . Analysis of the data confirms the loss of oxygen as a hafnium monoxide . Approximate activity coefficients for other contaminants are given .

Jan 1, 1964

By Eduardo Viedo Moreira

Analisou-se o tratamento térmico de revenimento de grampos ferroviários, modelo E2039AV, feitos a partir de barras redondas com aproximadamente 20 mm de diâmetro do aço SAE 9254 tendo como objetivo reduzir o tempo do processo de fabricação. A temperatura do forno foi mantida em 490ºC e 18 grampos foram imersos no sal fundido. Em grupos de 3, os grampos foram retirados em intervalos de 10 minutos, tendo o último grupo permanecido no forno por 60 minutos. Após cada retirada foram feitos os ensaios necessários para aferir a qualidade das peças: carga estática, dureza e fadiga. Após apenas 10 minutos de revenimento os grampos já resistiam ao mínimo de 1.000 kgf sem fraturar e apresentaram medidas de dureza próximas ao limite superior de especificação, ou seja, a dureza que era aproximadamente 58 HRC antes do revenido, atingiu valores próximos a 48 HRC. O último teste, fadiga, foi feito apenas nos grupos de grampos revenidos por 30 e 50 minutos. Pôde-se concluir que é possível reduzir o tempo de revenimento do grampo E2039AV feito de aço SAE 9254 de 60 minutos para pelo menos 50 minutos mantendo-se a qualidade dos grampos sem a necessidade de aumentar a temperatura do forno.

Aug 17, 2017

By K. T. Valsaraj

The separation process called solvent sublation for the removal of two hydrophobic compounds (penta-and tri-chlorophenols) from the aqueous phase is discussed. A steady state mathematical model for the process is discussed. The process was conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1992

By G. R. Fitterer, C. H. Herty

"INTRODUCTION Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis in easy to obtain, provided that a normal top discard is taken, as is always the case in steels poured with hot—top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel.For a large tonnage of steels which go into articles manufactured by deep—drawing processes, killed steel has never been successfully applied because with the present deoxidation practice, low—carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, — that is to say, deoxidized with manganese and perhaps a small amount of aluminum, — the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper—central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low—carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel. These defects would be minimized by clean killed steel."

Feb 1, 1931

By H. Colijn

Belt conveyors have proven themselves for many years as a dependable and low cost method of handling bulk materials at high flow rates. The success of a belt conveyor system greatly depends on the initial loading of the material on the belt. If the material is loaded on the belt at the center, at approximately the same speed and with minimum impact, then most of all belt conveyor problems disappear. Proper belt loading is primarily determined by the engineering and design of the conveyor transfer point. This paper will establish and discuss some general design criteria required for proper loading and transfer of materials from one conveyor to another. Specific attention is given to loading points, chutes, skirt board length and general design of transfer structures.

Jan 1, 1971

By J. L. Jambor

Previous crystal-structure determination of magnesian annabergite (Ni,MgMAsO4)2 8H2O indicated that ordering of Ni and Mg occurs in non-equivalent octahedral sites; such ordering supports the possibility of miscibility gaps on the Ni3(AsO4)2 8H2O -MgiAs04)2 8H2O. (annabergite-hornesite) join. In a predecessor study based on analyses of natural specimens, it was proposed that solid solution is incomplete both for annabergite-hornesite and annabergite-erythrite [Co, (AsO4)2 8H2O]. In the current study, syntheses by use of a slow-addition technique and aging of the precipitates indicated that the annabergite-erythrite solid solution is complete, and that no miscibility gap is present on the annabergite-hornesite join to at least 58 mol % Mg. Thus, interpretation of the compositions of these phases in oxidized mill-tailings impoundments can be done with the normal precautions for homogeneity, and without the added concern of the possible presence of miscibility gaps in the ternary system.

Jan 1, 1995

By G. H. Gale, M. A. F. Fedikow, L. B. Dabek

Abstract-Rare earth element (REE) data are reported for ores, sulfide-bearing rocks and host rocks from massive sulfide deposits and barren sulfide facies iron formations in Proterozoic volcanic rocks of the Flin Flon-Snow Lake area, Manitoba. Some of the rare earth elements (e.g., Eu), are selectively leached in zones of intense alteration and redeposited together with the sulfides and silicates in the uppermost parts of the alteration zones and at the rock-water interface. Chondrite normalized REE profiles of layered sulfide ores and exhalites proximal to the deposits typically have positive europium anomalies and are enriched in light REE. In contrast, barren sulfide facies iron formations exhibit negative or ‘normal’ Eu profiles. REE data are useful to explorationists in determining the presence of ‘off-hole’ metal-bearing sulfide zones, in distinguishing metal-poor sulfidic layers related to ‘economic’ hydrothermal activity from barren sulfide facies iron formation and in some instances as a means of establishing ‘ore-equivalent’ strata.

Jan 1, 1997

While international coal trading operations often involve relatively small contract quantities, delivered over short periods or even in single shipments, most coal is supplied under long term arrangements. In entering into these arrangements the customer needs to be assured that coal of suitable and consistent quality can be supplied for their duration in the volume required. A detailed knowledge of the mine and transport system is required and must be presented from the customer's perspective.

Jan 1, 1983

By Derrick Chambers, George Kevin Chapin, M. Shawn Boltz

Seismic monitoring is one of the few noninvasive technologies with the potential to provide sub-surface geomechanical information to operators of large open-pit mines. Although passive seismic data has been used to refine emerging failure geometries and provide advance indication of surface deformations in the literature, doing so reliably in an operational context is much more difficult. This is due in part to difficulties in estimating and interpreting source locations and parameters in complex, low-stress open-pit environments. Additionally, the high costs associated with implementing, operating, and maintaining deep borehole seismic networks, which are most commonly used to monitor large open pits, can be difficult to justify, especially if monitoring benefits are not readily apparent. In this study, we explore the use of a near-surface nodal seismic deployment, which is commonly used in oil and gas exploration, for monitoring open-pit mining-related seismicity on a short-term basis. A deployment of 18 geophones was conducted on the surface in and around the Bingham Canyon Mine, a large open-pit mine near Salt Lake City, Utah, USA, where we find the small seismic array can detect and locate a variety of mining-related seismic sources, even with an extremely simplified velocity model. We outline the process of creating an idealized velocity model, developing a local magnitude scale, and interpreting the observed seismicity. Of note, we analyze a sequence of mining-induced events associated with a known structure on the south pit wall. We conclude with discussion on how surface-based deployments may be used to augment, or in some cases supplant, borehole seismic networks at large open-pit mines depending on monitoring requirements and objectives.

Apr 26, 2022

By Roy A. White

The development of a fire and rot-resistant coating treatment for mine timbers, along with the associated processing technology, is described. Included are a literature search, laboratory studies of polyimide-fungicide coatings, and leaching and fungus growth studies on coated wood blocks. Finally, an economic analysis is performed tor various levels of production.

Jan 1, 1977

By William G. Pariseau

Safety of mine ramps begins with an analysis of stress that almost certainly must be done numerically to take into account ramp geometry, route geology, rock properties, and pre-ramp stresses. The popular finite element method serves analysis purposes quite well. As a practical matter several obstacles to implementation need to be addressed including collection of rock and joint properties along the proposed ramp route, selection of ramp type, and specification of cross-section shape, size, and route grade. Additionally, stresses along the proposed route must be specified, preferably from in situ measurements. One need not be an expert in numerical methods to proceed to ramp design, although a background in mechanics of materials and rock mechanics is essential, and a first course in numerical methods is quite helpful. The necessary software is easily brought to the design task, more accurately, to the task of design evaluation. This software also addresses other important mine design problems including design of safe (1) main entries in stratified ground, (2) barrier pillars, (3) bleeder entries, (4) inter-panel barrier pillars, (5) room and pillar mines, (6) shafts, and (7) “tunnels” (Pariseau 2022).

Feb 1, 2024

By S. Davis

It has been accepted almost as dogma that sampling contributes most of the error to fluctuations in gold fire assays. Differences in assay results on pulp material from the same sample interval are frequently regarded as evidence of the presence of the so called "nugget effect" or relatively coarse gold particles. It is true that if coarse gold particles are present they contribute to substantial sampling fluctuations, but while the process of sampling is probably the major source, the analytical process cannot -be completely ignored as a possible contributor to erratic assay results. In order to maintain a stable assay process, the analytic part of the system must be kept in control as well as the sampling and preparation part. One way of monitoring the performance of the analytic system is to systematically assay standard material whose sampling characteristics are carefully controlled. Gold assay standards are not prepared nor can they be prepared to account for both sampling and analytical errors. It is not possible to send coarse material to a lab for preparation (which includes both the processes of comminution and splitting) followed by fire assay, to make inferences only about the fire assay process. Because most gold ores are very heterogeneous, sampling errors would in most cases completely mask the contribution of the analytical errors. Assay standard material is prepared only to assess the accuracy and variability in the fire assay process.

Jan 1, 1995

By B. J. Moore

This Bureau of Mines publication estimates that U.S. helium resources as of January 1977 were 710 billion cubic feet. These resources are broken down into four classifications, as follows: Helium in measured natural gas resources and in storage, 201 billion cubic feet; helium in indicated natural gas resources, 150 billion cubic feet; helium in hypothetical natural gas resources, 175 billion cubic feet; and helium in speculative natural gas resources, 184 billion cubic feet.2 Most of the helium in natural gas is presently dissipated as natural gas is consumed as fuel and for other purposes. Helium resources of the United States may also be divided into three other categories: (1) Depleting and undiscovered natural gas resources, 589 billion cubic feet; (2) nondepleting natural gas, 83 billion cubic feet; and (3) storage, 38 billion cubic feet, of which 37 billion cubic feet is federally owned and 1 billion cubic feet is privately owned. The United States does not have any significant leasehold rights in the depleting fuel gas resources. However, through the Department of the Interior, it does have leasehold rights to about 70 percent of the helium found in nondepleting natural gas, and it owns over 90 percent of the helium in storage.

Jan 1, 1979

By Victor Li, Joley Lam

"INTRODUCTIONJacked piles are piles that are pressed into the ground, usually by hydraulic jacks. For this reason, jacked piles are also known as pressed in piles. Jacked piles are mainly used for the following applications.• Underpinning worksJacked piles have been commonly used for strengthening the foundation of existing structures. In pressing the pile into the ground, the hydraulic jacks will jack against existing pile caps or ground beams that support the structure or against a steel frame connected to the floor slabs or structural walls of the structure. The self weight of the structure provides the reaction force for pile jacking. Jacked piles used for underpinning works usually have lower design ultimate capacities, typically less than 2000 kN (225 tons).• New foundationsJacked piles can be used to support new structures. A heavy pile jacking machine is employed to provide the reaction force for jacking the piles into the ground.• Retaining structuresJacked piles can be installed at close spacings to form a retaining wall. For relatively large and easily accessible sites, the piles can be installed using a conventional pile jacking machine. For sites that are smaller and are more difficult to access, a more compact patented equipment called the Silent-Piler developed by Giken Seisakusho Co. Ltd. in Japan can be used.Jacked piles have several distinct advantages. The vibration and noise induced during pile jacking are minimal. Jacked piles are 100 percent proof-tested to a load level equal to the maximum applied jacking force. The pile jacking machine can also be treated as mobile kentledge for static loading test. In this article, discussion will focus on jacked piles used for supporting new structures.HISTORICAL DEVELOPMENTThe People’s Republic of China (PRC) is perhaps one of the earliest countries in which jacked piles were used as new foundations. Jacked piles had been installed in the PRC since the 1960s. The capacities of jacked piling machines used in the country are usually in the range of 3000 to 6000kN (337 to 675 tons). High capacity jacking machines with a capacity of 9000 kN (1000 tons), presently used by the construction industry in Hong Kong, were also manufactured in the PRC. There are also plans to produce machines with a capacity exceeding 10000 kN (1125 tons). It was projected by Wang (1999) that jacked prestressed spun concrete piles would become one of the most popular pile types in the PRC in the 21st century."

Jan 1, 2004

By Donald M. Keagy

How many times have you said or heard someone say, 'What are you doing right now?" And how many times have you heard the reply, "Breathing air!" Probably never, or at most only a few times in a facetious vein. Breathing air is absolutely necessary to sustain human life, and yet most of us take it completely for granted. Beginning ten to fifteen years ago there was growing concern on the part of the general public that pollution of the air is a threat to man's health and welfare. Concurrently much thought and effort was devoted to the task of defining and resolving the problem of air pollution. In the course of this effort it has become quite clear that our National policy in this regard should be founded upon three basic axioms: (1) Action should not be postponed until emergency conditions make it compulsory; (2) The air cannot be purified after it is polluted, and (3) Air pollution control cannot be accomplished without close cooperation among all levels of government, industry, and the public.

Jan 1, 1967

By S L. Nicol, B J. Hogg, O J. Mendoza, S Nikolic, A Burrows

The top submerged lance (TSL) technology, developed in the 1970s, is now widely used for the processing of a range of materials. The key advantage the ISASMELT™ TSL technology provided was the ability to process feed materials in a highly turbulent bath, reaching close to equilibrium conditions, uniquely allowing for operation below the liquidus of the molten slag phase. The details on what happened below the liquidus line in the phase diagram became critical for the successful operation of the technology. During the development of the ISASMELT™ technology this led to a collaboration between the Process Technology group of Mount Isa Mines, now part of Glencore Technology, and the Pyrometallurgy Research Centre (PYROSEARCH) at The University of Queensland. The fusion of the phase equilibria research into the technology development allowed for understanding of the behaviour of molten splash, reliable tapping of the furnace, and the ability to operate the furnace with a refractory lining and achieve a year campaign life in excess of four years. The outcome has allowed for the highly successful adaption of the ISASMELT™ technology to recycling of complex feed streams necessary to drive circularity in our modern global economy.

Aug 21, 2024

By M. Asghari, R. Amiri, A. Haratian, M. Noue Parast, S. Haji

Today the roller screen has a wide range of applications in the steel-making industry. It is used for screening of green pellets before using the kiln. Since the appropriate size of a green pellet is -16+9 mm, there are different gaps between rollers that make green pellets classified in three categories: -9 mm (undersize), -16+9 mm (onsize) and +16mm (oversize). The efficiency of a roller screen is specified according to the weight percent of undersize in onsize as a fine material, and weight percent of onsize in oversize (loss). This efficiency is influenced by different operational parameters such as roller diameter, roller speed, and roller gap, material type of rollers and inclination of roller screen. This study investigates the effect of different material types of rollers in efficiency of Ardakan roller screens, located in the Yazd province of Iran. The rollers of the existing roller screens in this pelletising plant are made of polyurethane which according to this investigation, has a maximum lifetime of about six months. Operating the polyurethane rollers beyond its lifetime generates serious problems such as high wear of rollers, and consequently, material buildup on the roller surface which then significantly decreases the roller screen efficiency. So, after examining different roller materials, stainless steel 304 with higher surface roughness to help pellets move properly on the roller screen surface was selected as a solution to this problem. The new roller screen was constructed by Fakoor Meghnatis Spadana (FMS) and replaced the previous one. In this way, the maximum capacity of the roller screen was increased about 17% and the roller screen efficiency was increased about 15%. Keywords: Roller screen, green pellets, efficiency, onsize, operational parameters

Jan 1, 2020