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By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By C Catania

Mining companies and operations across the globe typically target best practice financial management, along with a focus on economically driven mine plans. Not only is this inherent in running a successful mining business, but also critical in addressing investor scrutiny. The standards for social and environmental practices is less consistent than this, with most companies adopting standards that are driven through legislative and compliance requirements of the nations in which they operate. Although there is still room for improvement, Australian is a country that stands at the forefront of social and environmental legislation, driving more sustainable planning practices for mining operations, with an ever-increasing focus on mine closure considerations. Of the many nations yet to reach such a legislative position, Kazakhstan is a place where some companies are driving towards world class standards beyond what is government mandated. CITATION:Catania, C, 2018. World-class mine planning for a sustainable future in Kazakhstan Mining, in Proceedings Life-of-Mine 2018, pp 6–7 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By Sarah K. DeBono, Alan J. Monaghan, Emmanuel V. Manlapig, Gregory J. Harbort

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber."

Jan 1, 2003

In undertaking to write a few notes on practical mining in Bendigo, the great quartz mining centre of Victoria, which just now is celebrating its fiftieth anniversary of gold mining, satisfaction must be expressed which is, no doubt, shared by all mining men and inyestors, that Bendigo has not lagged behind other Australian mining districts in the evolution of mining from its crude state, subsequent to the discovery of gold in 185 to its present more perfect state; and though it may be said that it has not yet reached the high pinnacle of perfection towards which advanced science and change of conditions may yet lead it in the course of future progress, yet, what has already been done in this respect, the adoption of the most approved methods appliances and modern machinery, tending towards greater and still greater efficiency, facility, and economy in our mining industry, must be accepted as a guarantee that in tne future as well as in the past, progress in our means of developing our mining resources will ever remain our watchword, by means of which future difficulties will be overcome as well as they have been removed in the past.The adoption of this principal, combined with a study of rigid economy, has raised gold mining here, as well as in other places, from a state of speculation, and sometimes wild speculation, to the status of a solid, stable industry, the strong supportand backbone of the country in which it flourishes. Two of the principal factors which have been to a great extent instrumental in bringing about this satisfactory state, must be specially mentioned.

Jan 1, 1902

By M Pyle, T Vizcarra, G Ballantyne, B Foggiatto

Bulk Ore Sorting (BOS) has the potential to add significant value to mining operations by manipulating the feed grade and throughput to the processing plant. However, assessing the performance of BOS is complex, as it is influenced by geology, equipment, spatial and time domains. This increases the risk (real and perceived) of the technology. To manage risk, brownfield operations have the option to: (a) first test the variability in feed grade using a detector on the feed conveyor and subsequently construct the diverter and associated materials handling equipment when the value is established; or (b) conduct site trials with standalone sorting plants. The approaches described for brownfield projects are not available for greenfield projects where the in-situ heterogeneity needs to be quantified and translated into an economic evaluation to test the viability of BOS. Ausenco has developed a methodology that allows assessing the in-situ ore heterogeneity and uses an in-house technoeconomic model to determine the value of BOS for greenfield projects and assess the effects of sorting performance on project economics. The in-situ grade heterogeneity can be measured on a length of drill core and fitted to a mathematical model to assign a heterogeneity index. Given the spatial location, this heterogeneity index can be mapped across a deposit in combination with the average grade. Linking this information with relevant mixing models can determine the likely technical performance of BOS at an operation. However, the real value is only realised when this technical understanding is linked with an economic model and used to optimise the mine plan. Three case studies will be presented that show how Ausenco applies this methodology to assess the value of bulk ore sorting for greenfield studies.

Nov 10, 2020

By Paul Nicholas, Raju Gottumukkala

"India’s economy is expanding with rapid urbanization. Improvement in infrastructure is a keystone to the Indian government’s economic plans, including expansion of transit systems. Most of these systems are designed with elevated and underground sections. New Delhi, a city of 23 million people, suffers from heavy traffic congestion and pollution. The transit (metro) system is seen to be of critical importance. Phase 3 of the Delhi transit system project is 140 kilometers (km), with 40 km of twin-bore tunnels requiring 35 tunnel boring machines (TBMs) for construction. Transit systems are also under design or construction in Chennai, Bangalore, Kolkata, Hyderabad, Jaipur and Mumbai. Most have twin-bore tunnels. At present, 55 TBMs are operating on underground metro construction, and future projects will increase this number. This paper highlights the unique challenges of construction of underground metro systems in highly congested urban environments, using Kolkata and Delhi systems as examples. INTRODUCTION The first transit system in India was constructed in Kolkata (India’s third-largest city by population.) This line is 28 kilometers (km) in length, has underground and at-grade sections, was built in phases, runs north/south, and has 24 stations. This project was sanctioned in 1972, started construction in 1984, and was completed in 1995. The tunnels were constructed primarily by cut and cover methods with some open-face, compressed air shield tunneling. In 2006, the urban transport policy recommended construction of transit rail systems in all urban cities with a population exceeding 2 million. Further, in 2014 the central government stated that it would assist in financing transit systems in all cities with a population of over 1 million. In 2015, the central government approved the development of transit systems in 50 additional cities across India with a budget of $75 billion (see Figure 1). Transit development is just part of a huge expansion in planned rapid transport systems, which include metro, bus, high-speed rail, and monorail systems. Metro systems will include elevated and underground sections with twin-bore tunnels and underground stations. In the Delhi/National Capital Region (NCR), now the largest city in India by population, Delhi Metro Rail Corp (DMRC) was formed in 1995 as a joint venture company between the central government and Delhi state. DMRC operates the Delhi metro system. (see the case studies described later in this paper). DMRC has developed an external function to carry out studies and to offer consultancy to other cities planning transits. Since its inception, DMRC has produced Detailed Project Reports (DPRs) for every metro and monorail project in India. In 2012, DMRC became a partner in the management consultancy for Jakarta Mass Rapid Transit System, its first project overseas. DMRC became a model organization for other cities to follow. These cities have included Chennai, Hyderabad, Kolkata, Bangalore, Jaipur, Mumbai, Ahmedabad, and Nagpur. Other cities (e.g., Lucknow and Patna) are in the metro planning phase. Metro systems are under construction or partially operating in Hyderabad, Bangalore, and Jaipur."

Jan 1, 2016

By Donald H. McLaughlin

THE activity and enthusiasm of pioneers still prevail among workers in applied geophysics1.- Within the year, new devices have .been tried out, instruments and technique have been improved and the methods of application to commercial problems have been increased in many ingenious ways. There is still great need for more skillful interpretation of results in terms of geology, but oil the whole geophysical prospecting is making encouraging progress toward finding its proper place and function in engineering and geological practice. Spectacular successes continue to be reported, particularly .from the Gulf Coast, where the race for salt domes has not slackened, and encouraging results have been giined elsewhere in the mapping of structures in the search for oil. In the mining field, however, it can hardly be claimed that the same measure of success has been obtained, for brilliant efforts worthy of wide recognition have been overshadowed to some eatent by the unfortunate outcome of surveys undertaken unwisely without recognition of the limitations of the work. Consequently, hopes were aroused that could not be fulfilled, and it must be admitted in an impartial survey that there are a few regions, chiefly in the far north, where the standing of geophysical prospecting is somewhat doubtful and where the course of public opinion regarding it shows a certain similarity to the history of the market during the past few months. Reliable work, however, is steadily going 011 and it can confidently be expected that the methods will eventually be regarded in many regions as an essential part of the technique of securing geologic data needed for intelligent exploration.

Jan 1, 1930

By P. Kawahata

Newmont?s Twin Creeks Mine, located in northern Nevada, is producing gold ore from surface mining operations. The ore is currently processed at three different on-site facilities depending on ore type and grade. Processing facilities operate under stringent geochemical blending constraints that must be met from mine ore deliveries and off-site sourced ore. To analyze various strategic options, the technical team utilizes the mathematical optimization approach. However, due to the size and complexity of the operation, there are unique challenges in optimizing life-of-mine production scheduling. This paper describes those challenges and methods developed to take advantage of different scheduling software to effectively compensate each other and result in reasonable guidance. This paper also describes how those scheduling results are reflected in detailed mine plan and cost estimate work.

Jun 1, 2013

By James C. Barker

Alluvial cassiterite concentrations are widespread in river gravel and high level terraces within the Ray River watershed. The area lies in unglaciated terrain of Alaska's northern interior. Cassiterite originates from several calc-alkaline plutons of the Ruby batholith. Extensional stresses resulted in graben-like Tertiary basins that were flooded by a 200 ft thick section of mid-to late- Tertiary basalt flows. Basalt blocked local drainages, and 50- to 100-ft of terrace gravel was eventually deposited on top of the flows. Further downwarping and eventual fluvial downcutting of the flows resulted in cycles of accelerated sediment transport, deposition, and reconcentration. Repeated erosional cycles concentrated heavy minerals and resulted in development of tin placers. Preliminary resource estimates of contained tin in Recent alluvium range from 62 to as much as 172 million lbs-Sn in 300 million yd3. Grade of about 90% of the gravels is estimated to range between 0.2- to 0.5- lbs-Sn/yd3. Associated gold and rare earth elements (REE) in monazite and xenotime may be recoverable. Most of the tin is considered a subeconomic inferred resource, though, at least some of the gravels contain 2-to 6-lbs-sn/yd3. Estimates are projected on the basis of surface sampling and several auger drill holes and are provided for the purpose of land-use management planning.

Jan 1, 2011

By Reynold Q. Shotts

INTRODUCTION THE small domestic underfeed stoker as now designed is unusually sensitive to the coking and plastic properties of coals, and when the attempt is made to burn the high rank coking and caking coals of the Appalachian fields, serious trouble may occur. Part of the trouble may be caused by the ash content and clinkering characteristics of the particular coal in use, but more often it is the result of an excessive accumulation of coke in the form of "trees" or masses in the fuel bed. Often the zone of burning becomes so restricted that the fire goes out, and in extreme cases the fire may be lifted completely out of the fuel bed and away from the air ports. Even if the fire is preserved, excessive coking may cause response to subsequent heat demand to be slow and irregular. Coke trees seem to grow. most readily during periods of hold-fire operation, so that in order to preserve the fire in mild weather it is often necessary to set the timer for such a long operating period each hour that much unneeded and unwanted heat is developed, causing discomfort. During demand periods the fire may pick up so slowly that the intense burning which develops just before stoker cut-off causes a serious overshooting of the thermostat. Stoker coal performance tests which have been made in a number of laboratories 1, 2, 3, 4, 5 are one method of approach to the problem of selecting stoker coals. As yet these tests have not been standardized and they are expensive and time-consuming. The value of the results probably increases with the length of the test. Sherman and co-workers at Battelle Memorial Institute believe that even a one-week test is not too reliable a trial2 and it is quite likely that others will agree. A great advantage of such tests is that characteristics of coals, other than the tendency to form coke masses, may be evaluated from them. The selection of stoker coals would be greatly facilitated if there existed some simple measure of the tendency of a coal to form coke in a fuel bed. Although possessing all of the disadvantages of any small-scale laboratory test, the test for the free-swelling index of coal has been found useful for evaluating the probable effects of swelling properties upon combustion. 7 Ostborg, Limbacher and Sherman, have shown that the test can predict, roughly, the tendency of coke to accumulate in the fuel bed of a domestic stoker. They also gave instances of its value in predicting combustion behavior in some large installations. The use of the test for free-swelling index has become well established and has been adopted as a standard by the American Society for Testing Materials.8 When domestic stoker coal investigations began at the State Mine Experiment Station in the summer of 1944, it was decided

Jan 1, 1948

By Herschel H. Potter

Back injuries arising from such activities as lifting and handling objects have been and continue to be constant and undiminishing hazards of the occupational environment. Back pain in one form or another is experienced by almost a1 1 individuals. During the past 30 years, a great deal of accident prevention education has been directed toward the reduction of back injuries. However, it has not produced any great change in the incidence of the injury. The human spine remains the most vulnerable area of the muscul o-skeleta1 system. Back injuries account for about 400,000, or 18 percent, of all disabling work related injuries each year according to the National Safety Council estimates. These serious back injuries are estimated to have cost more than 1.9 billion dollars in 1976 in medical and lost time pay. 1

Jan 1, 1981

By Y. Nishida, Y. Nara, T. Ishida

Understanding time-dependent deformation and fracturing in rock is essential, because the information of the long-term stability of rock is required for many sub-surface structures excavated in a rock mass. Time-dependent fracture propagation has been invoked as a potential key mechanism responsible for the increase in seismicity preceding earthquake ruptures. In engineering projects and in preventing natural hazards, the study of time-dependent fracturing is necessary. Subcritical crack growth is one of the main causes of time-dependent fracturing in rock. For silicate rocks, subcritical crack growth has been investigated by various researchers. It has been clarified that surrounding environmental conditions (temperature, humidity, and existence of water) have strong influence on subcritical crack growth in silicate rocks. Therefore, the information of subcritical crack growth in silicate rocks has already been enough. On the other hand, information of subcritical crack growth in carbonate rocks is not enough. Especially, the influence of surrounding environment on subcritical crack growth in carbonate rock has not been clarified yet. In this study, we investigate subcritical crack growth in carbonate rock experimentally using a fracture mechanics testing method. Marble obtained in Skopje in Macedonia is used as a carbonate rock sample. The Double Torsion method is used to measure the crack velocity and stress intensity factor. Especially, influence of water on subcritical crack growth in Macedonian marble is investigated. It was shown that the crack velocity in water is much higher than that in air at the same temperature. Based on the results of subcritical crack growth measurements, the long-term strength is evaluated for marble. It was clarified that the long-term strength in water is lower than that in air in marble. It is concluded that water has a remarkable influence on subcritical crack growth in marble. It is also considered that the long-term stability of carbonate rock masses should be ensured in a dry environment.

Jan 1, 2015

By Gutsche O, Kapur PC

Experimental data on the production of fines as a function of specific grinding energy consumption show that in general the energy utilisation in a choke fed high-pressure roll mill is higher than in a ball mill, but lower than in the single-particle mode of comminution under slow compressive loading. There is some evidence to suggest that the presence of water in feeds improves the energy efficiency of pressurised roll milling somewhat. Within a wide range of energy input, the size distributions of the ground product are self-similar, the logarithmic median size decreases linearly with the amount of fines produced and the inverse of the median size increases linearly with the energy spent. The production of fines as a function of energy expended follows essentially the same pattern as the one frequently encountered in media mills. The kinetics of grinding in the high-pressure roll mill can be simulated satisfactorily by modifying the standard particle population balance equation in order to account for energy dissipation in the tightly compressed bed. Common characteristics and important differences in grinding by the media mill and the high-pressure roll mill are highlighted.

Jan 1, 1993

By B. H. Bergstram, C. L. Sollenberger

When glass spheres are crushed by slow compression loading, the outer lune-shaped fragments resulting from the fracture consistently fly outward at high velocity. About 45 pct of the strain energy fed into the sphere-platen system reappears in the form of the kinetic energy possessed by these fragments. These measurements were obtained from high-speed photographs. This kinetic energy can be utilized for addtional comminution if the fragments are allowed to impact against a suitable structure. Comminution theory has advanced considerably in recent years by the study of this unit operation under laboratory conditions. Some of the parameters have been isolated, but the experimental measurements of the pertinent quantities, such as energy, particle size, etc., are still only made prior to and after the conclusion of a fracture sequence. The catastrophic fracture process itself has not been adequately studied from a comminution point of view. It has recently been suggested by Gilvarry that the fragments which result from the free crushing of a single glass sphere by slow compression contain a considerable amount of kinetic energy after fracture. This kinetic energy, if properly directed, possibly can be partially utilized to cause additional fracture. In this paper a hypothesis will be presented which suggests that this kinetic energy is necessarily present and that its dissipation is the process by which a large part of the thermal energy imparted to the crushed product is generated. Evidence supporting the existence of kinetic energy and its utilization for secondary fracture will also be presented. THEORETICAL A previous paper4 has shown that the load-deformation curve of a system composed of an elastic sphere gripped by a pair of parallel platens, can be predicted by a consideration of the theories of Hertz as summarized by Timoshenko.' The deformation A, of one half of the system is given by which states that the deformation is a function of the mutually applied load, P, the radius of the sphere, R; and the respective physical properties of Poisson's ratio, v, and Young's modulus of elasticity, Y. The shape of experimental load-deformation curves conform to this relationship. The energy input to the sphere-platen system, can be predicted from the integral of the load acting through the appropriate distance, dA. Since dA can be evaluated in terms of P from the derivative of Eq. 1, this integral can be integrated between limits of 0 and P. The test sphere, however, is loaded at not one but at two points of contact, i.e., at both ends of a diameter, and hence the total energy input, E, is twice the energy input at each end, or The energy input to the system calculated from this equation corresponds to the energy computed from the measured area under the load-deformation curve. Timoshenko, considering the impact of two perfectly elastic spheres, has shown that the inter-penetration distance A is given by - m f (D (^ * ^t w as modified for the special case where one sphere is of infinite radius, i.e., its surface is a plane; where M is the mass of the finite sphere of radius R, and V is the velocity of approach at the start of an impact and also equals the final velocity of separation for perfectly elastic bodies. Because A is also a function of the load and the elastic properties, as shown in Eq. 1, the velocity, V, can also be calculated in terms of the elastic properties and maximum load, P, or

Jan 1, 1961

By C. Schlumberger, M. Schlumberger

In order to explore electrically a terrain composed of a succession of horizontal beds, a current of known intensity i is caused to flow between two grounds A and B, and the resultant drop of potential , caused by the resistance of the earth, is measured between two given points in the soil, M and N. In practice it is convenient to choose the two points M and N so that they lie on the line AB and their midpoint coincides with the middle 0, of that line, although this is not imperative. When the lengths L and I of the two lines AB and MN are varied, equations are obtained which may be solved for the resistivity p of the subsoil at various depths. Recall briefly that the formula 4 x l gives the average resistivity, in the horizontal direction, of a layer of earth which extends to a depth1 about equal to L/4. This elementary concept is adequate for numerous practical applications. Nevertheless, it must be said that, in many cases, a rigorous mathematical analysis may be made, provided it is always a question of homogeneous, superposed horizontal beds. The authors expect to publish, later on, appropriate methods of calculation for some specific cases.

Jan 1, 1932

By Gerald W. Longenecker

For decades, traditional hydraulic engineering approaches have been used for sizing stream channels when stream relocation efforts have been necessary to allow for the advancement of quarry and other surface mining operations. These approaches have been based on various ydraulic models to design channel cross sections and slopes that could pass the required regulatory design storm such as the 2-, 5, lo-, 25-, 50-, or even loo-year events. Designing the stream channel to handle these more extreme ,storm events would often lead to large channel designs which required extensive bank and channel bottom stabilization techniques including concrete, rip rap, gabions, or other expensive approaches. The constructed channels often required ongoing maintenance to remove accumulated sediment and other debris which would settle out and reduce the hydraulic capacity of the channel.

Jan 1, 1998

By V. Coetzee

In 1992, a paper was compiled highlighting a common-sense approach to electric smelting at Impala Platinum. Since then, the smelter complex has undergone considerable changes. Mineral economics, UG2 exploitation, and changing environmental legislation have enforced numerous process upgrades, yet a common-sense approach has always been adopted. This document details the major changes in the smelter complex at Mineral Processes (Minpro) over the past 15 years, and provides the rationale for the changes. Keywords: Pyrometallurgy, furnace, PGM, platinum, nickel, copper, electric smelting, six-in-line, Peirce-Smith, Impala Platinum.

Jan 1, 2006

By T. Saastamoinen, N. Heino

"The Olserum deposit located in Sweden hosts an indicated mineral resource of 4.5 million tonnes over 0.6 % TREO, exhibiting a relatively high proportion of HREE. Beneficiation of a composite drill core sample was studied in the flowsheet of magnetic separation of magnetite followed by REE minerals flotation. Primary testwork was performed to select an effective REE mineral collector and then the parameters of grinding size, collector and depressant dosages, slurry pH and density, conditioning time and temperature, and flotation time were tested for optimization of REE flotation. The studies of process mineralogy showed that the REE-bearing minerals monazite, xenotime and apatite were successfully enriched from the concentrations of 0.6%, 0.31% and 2.6% in the feed to those of 17.0%, 8.9% and 65.0% in the concentrate with the recoveries of 79.0%, 81.3% and 71.0%, respectively. INTRODUCTION The Olserum deposit located in Sweden comprises lower grade placer material with higher grade apatite-magnetite veins and hosts an indicated mineral resource of 4.5 million tonnes at 0.6% TREO, with 34% of that being HREO (EURARE, 2017). The mineralization was studied by Andersson et al. (2018). At early stage, high-temperature REE is characterized by abundant monazite-(Ce) and xenotime-(Y) coexisting with fluorapatite and subordinate amounts of (Y,REE,U,Fe)-(Nb,Ta) oxides. During a subsequent stage, allanite-(Ce) and ferriallanite-(Ce) formed locally, partly resulting from the breakdown of primary monazite-(Ce). Alteration of allanite-(Ce) or ferriallanite-(Ce) to bastnäsite-(Ce) and minor synchysite-(Ce) at lower temperatures represents the latest stage of REE mineral formation. The mineralogy and beneficiation were firstly studied by GTK Mintec in the EURARE project for a composite drill core sample. The Olserum is considerably smaller than the Norra Kärr deposit. However, REE are hosted by xenotime and monazite, both of which have well established processing pathways, and meanwhile, the Olserum has a high contribution of the high value critical REE (dysprosium (Dy), yttrium (Y), neodymium (Nd) and terbium (Tb)), which provide a unique advantage for its exploration (Tasman Metals Ltd., 2013). In this paper, flotation of the REE minerals in the Olserum ore was studied."

Jan 1, 2018

By D Craw, L Cox, R J. Norris

The Rise and Shine Shear Zone is a mineralised low-angle deformation zone traceable for at least 7 km through biotite zone schist of the Dunstan Range, central Otago. The zone is commonly believed to be similar to the actively mined Macraes deposit. The Rise and Shine Shear Zone occurs in the immediate footwall of the Thomsons Gorge Fault, a regional scale Cretaceous normal fault that juxtaposes chlorite zone schist against biotite zone schist. Most mineralised rocks are deformed and record a progression from early stages of semiductile deformation to more brittle cataclasis. Folds in mineralised rocks trend northwards. The mineralised schist is hydrothermally altered with variable silicification, sericitisation, chloritisation, replacement of titanite by rutile and carbonate alteration. Gold is associated with pyrite and arsenopyrite and occurs in both ductile and brittle microstructures. Sheared and mineralised schist is cut by north-striking fault zones which host mineralised quartz veins. Veins in the shear zone contain hydrothermal albite. Trace element analyses show enrichment in As, U, Th and rare earth elements. Many of the above features are similar to Macraes deposit, but there are important differences. In particular, the Macraes deposit is hosted in lower grade rocks and truncated beneath by a normal fault, Macraes has no U or Th enrichment, Macraes veins have no albite and folds at Macraes trend NW-W. Rise and Shine mineralised rocks have no Cr enrichment and no hydrothermal graphite.

Jan 1, 2005

By E. R. Parker, D. L. Martin

In a previous paper one of the authors observed that the rate of cooling from the anneal prior to testing greatly influenced the life of copper under sustained load at 200°C. Furnace-cooled bars of oxygen-free copper (with and without silver) had a life four to twenty-five times that of the water-quenched specimens. The addition of 0.054 per cent silver to the oxygen-free copper increased the life at a stress of 20,000 lb. per sq. in. from about 2 hr. to 50 hr. Fractures in these bars were intercrystalline. An explanation was advanced to account for the profound influence of cooling rate on the rupture properties at 200°C. The suggestion offered was that at the high annealing temperature the minor constituents are distributed at random. By water quenching, this condition is maintained at room temperature, whereas furnace cooling permits some segregation at the grain boundaries. The higher concentration of the minor constituents in the grain boundaries results in a. strengthening, so that a longer life at a given stress and .temperature results. Small amounts of cadmium or manganese have also been found to increase the life of copper at 200°C., and to a much greater extent than silver.2 The increase in the long-time strength of copper resulting from small additions of cadmium or silver appears to be related, indirectly at least, to the higher softening temperatures of such alloys. The elements, such as silver or cadmium, which greatly increase the rupture life of copper also cause large increases in the softening temperature. As little as 0.05 per cent of cadmium or silver is sufficient to raise the softening temperature more than 100°.3,4 The effects of cooling rate and of minor constituents on the rupture properties are of considerable fundamental as well as practical interest; therefore a more detailed study of their nature was conducted and is reported in this paper. Experimental Procedure Materials The materials studied in this investigation may conveniently be classified in two groups: one consisting of a wide variety of commercial coppers, and the other composed of special high-purity, laboratory-prepared coppers. The commercial materials were tested to determine whether or not the effect of cooling rate occurred with all coppers, whereas the high-purity coppers were investigated in order to establish a basis for evaluating the effect of minor constituents on the rupture properties. In Table I are given the analyses of the coppers tested. The samples I to 6 are commercial materials and were obtained for the most part from stock supplies.*

Jan 1, 1944