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By Jian Li, Pei Liu

In recent years FIB has become a powerful instrument to perform ion beam sectioning and site-specific TEM specimen preparation. However, there are still gaps in understanding FIB-induced artifacts. Gallium ion beam damage and specimen heating during FIB milling can produce unwanted artifacts during FIB work.Calculations ofmaximumspecimentemperature increaseshavemostlybeen based on the assumption that ion beam implantation into substrate of infinite size. This deviates from finite specimen volume in FIB TEM specimen preparation that impedes specimen heat dissipation. In this paper, the authors will demonstrate a few commonly observed FIB artifacts, and discuss the concerns of specimen temperature rise during FIB milling process.

Mar 1, 2017

By Edgar Stanfield

Since April, 1923, the Scientific & Industrial Research Council of Alberta has had an analyst, Mr. W. P. Campbell, steadily employed analyzing coal samples taken by the provincial Mine Inspectors. Mr. Campbell has also analyzed a number of coal samples taken by one of the Council's Geological Survey parties. We have thus, at the time of writing, over four hundred analyses of Alberta coal, made by the same analyst, and strictly comparable. These samples come from widely distributed points, some 88 townships being represented. The stream of samples is still flowing in, and it is hoped by the end of this year that the number of townships represented will be increased at least fifty percent. The time has arrived to publish some of the data collected; but it must be clearly understood that this is merely a progress report, subject to revision as further information is obtained. Three hundred and fifty-three coal mines in the province were operated during 1923. The production per mine varied from 5 up to 500,000 tons. With this number of mines to examine (and fresh mines are being opened every year) it is a large task to make even a proximate analysis of representative samples from every mine. Any chemist will appreciate the fact that to make ultimate analyses representative of even the larger mines will be a long and tedious task. It has seemed better to make a comprehensive survey by proximate analysis and determination of calorific value before beginning the more thorough survey by ultimate analysis. This paper, therefore, deals only with proximate analyses and calorific values; and, owing to limitations of time and space, does not deal with other chemical and physical characteristics of coal, such as storage quality and fusibility of ash, important though these are.

Jan 1, 1925

By Howard S. Avery

The wear resistance of an alloy in heavy mill liner sections may be quite different from that of the same alloy in small balls and other light sections. This fact was established by means of a well standardized laboratory test that was validated for ball mill service. The salient properties of mill liner alloys, including austenitic manganese steels, medium alloy hardenable steels, and abrasion resistance cast irons are described, critically compared, and quantitatively ranked in terms of mill liner service. Where they are tough enough the high-chromium and other martensitic cast irons (e.g. Ni-Hard) promise maximum economy, but their section sensitivity is a limitation. To overcome this an extensive research program studied over a hundred experimental alloys, ranking them for heavy section abrasion resistance by means of the laboratory test. Computer analysis of the results provided a parabolic formula in terms of composition, the apexes of the parabolas providing optimum wear resistance. From the extensive family of parabolas one apex was selected for intensive study in experimental liners, pilot plant production, development of quality controls, and finally full scale production. This is a 19% chromium iron critically alloyed with nickel and molybdenum and hardened by heat treatment. It has excellent resistance to various types of abrasion, but its chief advantage is in heavy mill liner sections, where it has about 25% better abrasion resistance than the best of the quality controlled chilled Ni-Hards. It is also tougher. After production problems were solved, a number of ball and rod mill tests were arranged on a guaranteed performance basis. Two of these, representing about 138,000 pounds of mill liner castings, have recently confirmed in service the superiority that was predicted by the laboratory tests.

Jan 1, 1969

By T. R. West

Planning for urban development in many locations is based largely on 0.10 factors, 1) soil conditions and 2) socio-political aspects of the region. A more widely based approach is necessary, however, if a complete and functional plan is to be obtained. Under this unified approach, the overall field of earth science is included in the planning process. As considered here, the earth sciences comprise a large segment of the natural sciences; that is, geology, pedology, geomorphology, reengineering geology and ground water hydrology. A number of shortcomings can develop when using the restrictive, two-factor approach for urban development planning. These deficiencies are discussed in the paper. The specific considerations for each earth science area are examined and land use considerations for various urban requirements reviewed in light of these specialties. To illustrate the potential of the unified or earth science approach, Tippecanoe County, Indiana is presented as an example. The current area planning system for Tippecanoe County is examined to determine how well it compares with the unified approach and some of the shortcomings of the current plans are discussed.

Jan 1, 1972

By S. Castro, P. Alfaro, C. Moctezuma

IMMSA operates a conventional roasting-leaching-purification-electrolysis plant for the production of zinc from concentrates in San Luis Potosi, Mexico. The leaching circuit was designed to take into consideration a feed mixture to the roaster with a maximum iron content of 7%. Since the start-up of the plant in 1982, the zinc recovery increased to 94.5%. However, an increase in the iron content in 1997 caused an important decrease in the global zinc recovery. Two new steps were added to the leaching circuit and modifications were made to the other steps in order to increase zinc extraction. Two new automated press filters were installed to replace the original vacuum drum filters and to minimize soluble zinc losses. Additionally, the residue treatment steps in purification were modified and a calcium removal circuit is just starting operation. These actions, besides improving the operations, have as the main objective to increase the global zinc recovery to levels above 94.5%.

Jan 1, 2000

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By M Morey

Ok Tedi Mine is located eighteen kilometers from the Irian Jaya border in the Star Mountains, Western Province, Papua New Guinea. Sequential flotation concentrators produce a copper / gold concentrate for market, and a pyrite concentrate for environmental containment, with low sulphur tailings from the pyrite flotation sequence being discharged to river. Strict sulphur assay targets are set for the riverine discharge. Current porphyry and skarn ore blends from open pit operations at Mt. Fubilan will cease by 2017. However, drill cores indicate an economic ore body in the skarn ores surrounding and below the current pit limits. With proposed mining from a western pit wall ‘cut back’ and an eastern pit wall underground operation, potential for ore ageing in sub level cave underground stockpiles is apparent. With little information in the literature, Ore Ageing test work at prefeasibility level consisted of multiple one tonne stockpiles of -50 mm crushed rock. For the bankable feasibility study, a successful test work program was implemented utilizing 40 tonne ROM ore stockpiles composed of exposed pit extensions of future ores. Realistic ageing profiles of Skarn ores were obtained from one tonne monthly samples subjected to laboratory testing. Test work outcomes included:• Similar ore ageing profiles from both the pre feasibility study (PFS) and feasibility study (FS) programs, suggesting ore susceptibility to oxidation has greater effect in ore ageing than rock size for Ok Tedi skarns. • Laboratory rougher flotation of pyrite showed significant variation in sulphur recovery rate, suggesting three classes of pyrite floatability.• Laboratory rougher flotation of both copper and pyrite for up to 19 months ore ageing from 11 stockpiles, suggested three stages in the ore ageing process.

Aug 8, 2011

By Gabriel G. Walton

Conventional numerical modelling tools for analyses of underground excavations are well suited for modelling elastic behaviour and yield response of geomaterials with very simple constitutive behaviour. Non-dilatant elastic and perfectly plastic behaviour is most commonly used for preliminary analyses in the absence of the data required to consider more complex behaviours such as strainweakening and dilation. For truly brittle models, this deficiency is more acute. Current state of practice allows only for reliable estimation of the volume of failure, but not for any prediction of displacement. In fact, there is no consensus in rock engineering regarding the most accurate approach or most suitable tool to model the magnitude of the plastic deformation that strain-weakening or brittle rocks experience at tunnel boundaries, particularly when support is incorporated into these models. This problem is largely a function of a poor understanding of how inelastic dilation occurs in different types of rockmasses, the rate controls on strength loss and volume change during yield, and the complexities of rock-support interaction in yielding conditions.

Jun 1, 2012

By Yang Zhao, Tao Xiu-xiang, Chen Song-jiang

"China is rich in low-rank coals that account for 45.68% of existing coal reserves in China. The clean and efficient utilization of low rank coals is of great significance for ensuring the effective energy supply and promoting economic development and environmental protection. In order to solve the difficult problem in flotation of low rank coal, it has become the focus of research in the related field that oily bubbles instead of air bubbles are taken as a carrier in flotation to improve the attachment efficiency and recovery of low rank coal. In this paper, low rank coal slime collected from Shendong mining area was used as the experimental material, and it focused on the characteristics of oily-bubble flotation process of low rank coal. Additionally, difference in conventional flotation and oily-bubble flotation was discussed. The induction time between air bubbles, oily-bubbles and fine low rank coal particles was measured. The results indicated that the induction time between oily-bubbles and coal particles was obviously lower than that of air bubbles. By comparing the foam height of air and oily bubbles, it was found that the amount of oily bubbles is less than air bubbles, causing relative low flotation rate of oily-bubble flotation at initial stage. Besides, the maximum foam height and half-life of air bubbles and oily-bubbles were measured respectively. The results showed that the stability of oily-bubbles was higher than that of air bubbles, which is benefit for the enrichment of concentrates. The clean coal water recovery of oily-bubble flotation is lower than that of air bubble flotation, which indicated oily-bubble flotation is lower in water entrainment. INTRODUCTION China is the largest energy consumer in the world, accounting for 23% of global energy consumption in 2016 and 27% of global energy consumption growth. Whereas coal is taken as the major primary energy source and its share of China’s primary energy consumption is 62% in 2016, in which the low rank coals, such as lignite, long-flame coal, weakly caking coal, and non-caking coal, accounted for about 50% of total coal production capacity (China’s energy market in 2016, BP). Moreover, the exploitation and utilization of low rank coals and other coals that are difficult to float have been an important strategy for China’s sustainable development of the coal industry (Liu et al., 2014). However, the combustion of low-quality coals leads to a serious environmental pollution. In addition, the deterioration in geological conditions of coal resources, and the increasing improvement in the mechanization for mining significantly caused the increased amount of fine coal."

Jan 1, 2018

By Oscar H. Hershey

COMPLAINT has been made that in the literature of economic geology the work of the "company or practical" mining geologists does not get enough attention. I propose to attempt to overcome this com¬plaint in reference to one important lead-mining district, that of the Coeur d'Alene in northern Idaho. Furthermore, I will assume that the reader is not so much interested in the geology of the district as in the methods of application used and incidents that have arisen in the work. All the important discoveries of ore in the Coeur d'Alene were made without benefit of geology. Certainly I would not claim the reputed discoverer of the Bunker Hill mine as a fellow geologist. It appears also that the mines were operated quite successfully for many years without geological specialists, though doubtless certain properties were visited at long intervals by such men as Waldemar Lindgren. It was known that the ores occur in quartzite, graywackes and slates as stated by J. R. Finlay in 1903. (TRANS., VOL. 33.) He described the ore as occurring in typical fissure veins that occupy fault-planes of indeterminate displacement. The Bunker Hill lode was based on a definite fissure with the mineralization all on the hanging-wall side, extending as far as 300 ft. from the fissure.

Jan 1, 1933

By Georges Fleming

The new burden preparation plant of ARBED Luxembourg, Belval- Works, which comprises 2 large sinter strands, is equipped with a process computer connected to a comprehensive process control system. The main jobs done by the computer are the control of the raw mix composition, and thus the monitoring of the stacking of the piles at the bed-blending plant, and the optimization of the sintering process. Among the optimization criteria, quality is considered as the most important. The sinter quality, characterized by the mechanical strength and the state of oxidation, is controlled automatically. The control system which we have dev loped is highly reliable; as a result, the standard deviation of Fe++, for the control of bivalent iron, has been narrowed to 0,5 % and the standard deviation of the IS0 + 6, 3 mm index, for the control of the mechanical strength, has been kept within 1 %. Thanks to these results, the combined savings in fuel consumption at the sinter plant and at the blast furnaces have covered the total costs of the optimization project in 2 years. By applying automatic control, the optimum driving range of the sinter plant has been defined and these new guidelines are used for monitoring the sinter production.

Jan 1, 1977

By Do-Hyeong Kim, Tae-Jung Kim, Seung-Yeon Won, Jong-Jin Pak, Min-Kyu Paek

Liquid iron alloys containing V, Mo, and Ni can be produced by the carbothermic reduction of spent catalysts used in petrochemical industry. Thermodynamics of carbon in these alloy melts is important for refining these alloys. In the present study, the carbon solubility in Fe-V, Fe-Mo, Fe-Ni, Fe-V-Mo, Fe-V-Ni, Fe-Mo-Ni and Fe-V-Mo-Ni alloy melts of various compositions was measured at 1873 K. The temperature dependency of vanadium effect on carbon solubility in liquid iron was also measured in the temperature range from 1823K to 1923K. The additions of vanadium and molybdenum significantly increased the carbon solubility in liquid iron alloys while nickel decreased the solubility. The experimental results were thermodynamically analyzed using Lupis’ relation at constant activity to determine the first- and the second-order interaction parameters of vanadium, nickel and molybdenum on carbon at carbon saturated condition. Using thermodynamic parameters determined in the present study, the carbon solubility in Fe-V-Mo-Ni alloy melts of various composition were accurately predicted and verified experimentally at 1873 K.

Jan 1, 2014

By David H. Dahlem

Uranium is a very mobile element geochemically and is widely dispersed in the lithosphere and hydrosphere. Under oxidizing conditions, it is particularly widespread and appears in all parts of the surface hydrologic system. As a result, this system is a leading candidate in uranium-resource assessments as a new base from which total resources might be estimated. No other sampling system provides the large volume geochemical capture as the continental hydrosphere and is as pervasive and non-selective regardless of rock type. However, the water system as a uranium metal sampler is not without drawbacks as the development of a National sampling program based on it has shown, In spring 1973, the National Uranium Resource Evaluation (NURE) was announced by the U. S. Atomic Energy Commission (AEC). The program was conceived to provide an evaluation of the domestic uranium resources and to identify areas favorable for uranium exploration. The specific NURE objectives are as follows (Bowyer, 1974): 1. To provide a preliminary evaluation of domestic resources and favorable exploration areas by early 1976, based on existing data. 2. To conduct a comprehensive evaluation of domestic resources and favorable areas by 1980, based on advanced state-of-the-art information. 3. To conduct an R&D program into new and improved procedures, equipment, and technology for uranium exploration and assessment. 4. To disseminate information on new exploration concepts and technology.

Jan 1, 1976

By I. R. Kramer

In his technical note entitled "Specimen Temperature During Electropolishing of Aluminum Crystals" Dr. Nakada 1 reported that the temperature of his aluminum specimen increased 65°C when it was polished electrolytically; he therefore concluded that the temperature of the specimens used in our work (Nakada's Refs. 4 and 5) similarly increased by this amount. From this he further concluded that the change in plastic-flow characteristics associated with the removal of the surface by electropolishing during deformation were due solely to a temperature effect. We believe that these conclusions are not justified. It is, of course, realized that the amount of the temperature increase is associated with the total heat transfer of the entire system, including the efficiency of the stirring action, heat flow through the grip on the specimen, and so forth. Of great importance is the type of electrolyte used for polishing. For example, in Dr. Nakada's experiment a methanol-perchloric acid solution was used. This solution has a relatively low conductivity and for the current densities of 0.3 amp per sq cm the electrical input appears to be 30 to 40 w. In our research a methanol-nitric acid solution was employed and for the size of specimen employed by Dr. Nakada the power never exceeded 7 w. There are major differences in his test apparatus which also appear to affect the temperature rise. In our case a steel specimen holder was used in order to provide a good heat sink and conduction path. The cathode was a coiled aluminum tube through which a coolant was passed to provide additional cooling capacity near the specimen. The stirrer was placed in a position to obtain maximum cooling efficiency. On the other hand Dr. Nakada used a teflon grip to support the specimen at one end only and a flat copper cathode, thus providing a much less efficient heat sink as compared with the metal grips used in our studies. The relationship between current density and the temperature increase for two sizes of aluminum crystals tested in our tensile apparatus is shown in Fig. 1. The temperature measurements were determined from a thermocouple spot-welded to the surface of the specimen. The thermocouple was protected from the acid by means of a thin film of stop-off lacquer which covered just the outer surface of the thermocouple junction. Whereas Dr. Nakada reported a time delay of 8 min to obtain thermal equilibrium, our temperature change occurred in less than 15 sec. This emphasizes the importance of the heat transfer in the entire system. However, readings were taken over a period in excess of 5 min to assure thermal equilibrium. The data given in Fig. 1 were also confirmed by determining the thermal expansion of the specimen in a sensitive creep apparatus. As may be seen, for the smaller specimen the increase in temperature is 8°C for a current density of 1.5 amp per sq in. The majority of our data on the effects of surface removal on the plastic behavior of aluminum were obtained at current-density values at or below this value. Above 1.5 amp per sq in. the temperature rise is uncertain; for under certain conditions, especially in the vicinity of 2 amp per sq in., the anode can become polarized and the current flow is erratic. This condition is easily recognized because wide fluctuations in the creep and stress-strain data make it virtually impossible to obtain reliable results, a condition which was always avoided in our work. The temperature increase for the larger specimen is less than that of the smaller specimens below a current density of 1.5 amp per sq in. At a current density of 2 amp per sq in. the temperature increased 13°C. The above temperature data are in accord with observations made during creep experiments. Using a transducer capable of detecting strain in the order of 10 -6, temperature changes in excess of 8°C were not detected when the current density was increased to as high a value as 1.5 amp per sq in. Finally we wish to point out that our experimental data cannot be explained solely in terms of a heat effect. For example in Fig. 1 of Ref. 2, the change in slope of Stage II as a function of the rate of re-

Jan 1, 1965

By Gary Peach, Khalid Saif Al-Khayareen, Vigil Fernandez, Furqan Hameed

The Musaimeer pump station and outfall project (MPSO) is in Doha Qatar. This technical paper will discuss and explain the three major stages of geotechnical investigation employed. Stage one the tender geotechnical data and how this was used to design the TBM and identify various areas of risk. Stage two was the selection of supplementary geotechnical investigation methodologies. Stage three was the geotechnical investigation by specialist equipment installed on the TBM and providing further data on a real time basis as the TBM was advancing. Analysis of all the data will be provided along with the lessons learned.

Jun 23, 2024

By T. E. Bernard

"Refuge alternatives provide shelter to miners trapped underground during a disaster. Manufacturers must demonstrate that their refuge alternatives meet the U.S. Mine Safety and Health Administration (MSHA) requirements for oxygen supply, carbon dioxide removal, and management of heat from the occupants and mechanical/chemical systems. In this study, miner size and activity level were used to determine the metabolic heat rate, oxygen requirements and carbon dioxide generation that are representative of miners in a refuge situation. A convenience sample of 198 male miners was used for the distribution of current U.S. coal miners, and the composite 95th percentile height and weight were determined to be 193 cm (76 in.) and 133 kg (293 lb). The resting metabolic rate (RMR) was determined to be representative of activity level in a refuge alternative. The highest likely metabolic heat generation ranged from 113 to 134 W, depending on occupancy. The highest required oxygen supply and carbon dioxide removal were estimated to be 23 L (0.81 cu ft) of oxygen per hour per person and 20 L (0.71 cu ft) of carbon dioxide per hour per person, which means the margin of safety is 50 percent or more compared with the MSHA requirements. The information on metabolic heat generation can be used to assess refuge alternative thermal environments by testing or simulation. The required oxygen supply and carbon dioxide removal can be used to assess refuge alternative requirements. IntroductionRefuge alternatives provide shelter to miners trapped underground during a disaster. Manufacturers must demonstrate that their refuge alternatives meet U.S. Mine Safety and Health Administration (MSHA) requirements for the supply of oxygen (O2), removal of carbon dioxide (CO2) and management of heat resulting from the refuge alternatives’ occupants and mechanical/ chemical systems (MSHA, 2008)."

Jan 8, 2018

By Cyril S., Smith

THE phenomenon of air-hardening is well known in connection with special steels. It occurs when the rate of decomposition of austenite to marten- site is so retarded that it takes place on free cooling in air rather than on more rapid cooling in a quenching bath. If an air-hardening steel is quenched sufficiently rapidly it will remain in the soft austenitic state, while if it is cooled very slowly it will again become soft owing to growth of the carbide particles. It depends on a critical adjustment of the decomposition velocity and diffusion rate, and such alloys are rather rare, especially in the non-ferrous field. In carrying out some experiments on some copper- rich copper-cobalt alloys, the author found that these possess very marked air-hardening properties. The alloys are covered by a patent issued to M. G. Corson (1,723,022-1919), which states that an alloy containing between 2 and 5 per cent cobalt is hardened by simple quenching from above 850° C.

Jan 1, 1930

By J. Cayouette, . Blatter, P. Cousin

The Laronde mill was commissioned in 1988 and has been treating the Laronde Perim ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually. In 2008, the Goldex plant began trucking high wade (35-45 Wt Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold wade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine. Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa)

Jan 1, 2011

By M. Faure

The experiment with backfill at Harmony was mainly an attempt to improve the ground conditions in a particularly tricky section of the mine. A deslimed tailings system was selected for financial reasons, ease of installation, ease of operation and its low level of mechanization. The design of the system has three aspects: firstly, to define the parameters of the backfill material itself; secondly, to design a reliable plant which could consistently produce the desired material in sufficient quantities; and, thirdly, to design a fill distribution system for maximum reliability in the shaft, minimum pipe line velocity, pressure and cost in the horizontal sections and consistency and reliability at the delivery end. The system was successfully constructed and commissioned in a short space of time at a relatively low cost. It has now reached its full potential, and very encouraging results have been achieved with regard to cost savings, ground conditions, ventilation and accident statistics.

Jan 1, 1988