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By K. Nielsen

The paper presents a brief overview of the mineral industry in Norway, followed by a description of the mineral policy and relevant legislation including the roles of the Norwegian Directorate of Mining and Geological Survey of Norway in this context. The discussion then proceeds to describe the land use planning framework on a national, regional and local level, the interaction between land use planning and the Directorate of Mining and the Geological Survey respectively, and how this impacts on the mineral industry and the exploitation of mineral resources. Some recent Norwegian examples of land use planning conflicts are also presented.

Jan 1, 2005

By James V. Errico

On October 1, 1993 the regulations for assessing and cleaning up contaminated soil and groundwater in the Commonwealth of Massachusetts were revised. These new regulations, known as the Massachusetts Contingency Plan (MCP) 310 CMR 40.0000, were developed to keep routine releases out of the regulatory system and rely on private parties to handle most releases without Department of Environmental Protection (DEP) oversight. An integral part of the new MCP is the Licensed Site Professional (LSP). An LSP is required to handle activities and render opinions once a site enters the MCP. These regulations must be adhered to where ever a release has occurred, including construction sites. A brief overview of the new MCP is given below; see attached MCP Flowchart for graphical summary. Entering the MCP Process A release of oil or hazardous material (OHM) to the soil or groundwater above applicable reportable quantities (RQ's) or reportable concentrations (RC's) will require notification to the DEP and compliance with applicable provisions of the MCP. RQ's and RC's are listed in the MCP (310 CMR 40.1600) for most compounds that are typically encountered. For each compound there are two RC's for soil (S-1 and S-2) and two for groundwater (GW-1 and GW-2). The S-1 and GW-1 RC's apply to sites that are environmentally more sensitive, as a result they are lower than the S-2 and GW-2 RC's.

Jan 1, 1994

By Daniel Hodouin, Bruno Girard, Claude Bazin

"Mineral processing and smelting operations have the reputation of being complex processes. Process operators of these unit operations have acquired from experience and basic training a superficial understanding of the relationships between process output and manipulated variables. This understanding, which is a very valuable know-how for process control and optimization as well as for operator training, is however difficult to extract. This paper describes a time series based approach that can be used to extract this know-how, which can subsequently be used for operator training. The method is illustrated with an example taken from a smelting process.IntroductionThe emergence of Total Quality Management and Statistical Process Control philosophies in the North American industry (Brown, 1991 ), as well as the increasing popularity of the IS0- 900x standard accreditation, provide a strong incentive to review the training procedures for plant operators. The importance of employees training is acknowledged in two of the 14 points of Deming's road to quality (Deming, 1982) as well as by control engineering consultants (Hendricks et al., 1994). However guidelines for the operation of industrial processes are often transferred from an operator to another one with allowance for flexible interpretation of many operating rules. Such transfer is typical of complex industrial processes to which particulate processes of ore dressing and extractive metallurgy belong.Capturing the knowledge of experienced operators is often a difficult task. Cognition engineers are able to extract this knowledge and transfer it into rules that ultimately are implemented into expert systems. Cognition engineers are however not always available and plant supervisors may prefer to keep training as an internal liability. Another difficulty through interviewing of the process operator is its lack of willingness to transfer what he has learned by hard working to other people, whose ultimate goals are to develop computerized applications that may replace him in a near future, or reduce its importance in the production line.This paper shows that time series can be advantageously used to capture the average process understanding of plant operators and to help reviewing training procedures. The method s illustrated with data collected during normal operation of electric arc furnaces and it is shown how the approach has led to a fruitful discussion between process engineers and operators that ultimately provided savings of more that $200,000 per year per furnace. There are 9 furnaces in the studied foundry. Such savings are not the results of application of advanced control strategies nor of ""miracle press button software», but of an improve awareness by engineers and operators of the importance of properly defining the operating procedures to control a process."

Jan 1, 1996

By Roger Lacroix

L?arrivée de nouvelles technologies sur le marché des foreuses portables combinée au besoin des mines à mieux consommer l?énergie électrique ont permis d?identifier le potentiel de deux nouveaux type de foreuses présentement utilisées en Afrique du Sud, à savoir les foreuses électriques et les foreuses hydrauliques actionnées à l?eau. Grâce à la collaboration de mines Niobec et Géant Dormant de Cambior Inc., ainsi que d?Hydro-Québec, le potentiel réel d?économie énergétique des foreuses portables hydrauliques et électriques par rapport aux foreuses conventionnelles à air comprimé a été évalué pour des roches dures et moles. Ainsi, cet article a pour objectif d faire ressortir ces potentiels d?économie énergétiques. En outre, les résultats pour une mine mécanisée et une autre mine de type filonien, dans lesquelles on retrouve des conditions de terrain différentes, seront présentés. Les résultats montrent un potentiel d?économie énergétique d?environ 70% pour la foreuse électrique et d?environ 50% pour la foreuse actionnée à l?eau. Ces résultats montrent qu?il est possible d?obtenir une meilleure efficacité énergétique par mètre foré. Ainsi, il apparaît maintenant intéressant de poursuivre les travaux de développement des deux technologies pour les applications de forage vertical et de tensionnement des boulons, et de viser à accroitre le taux de pénétration de la foreuse électrique pour le rendre équivalent à celui de la foreuse à air comprimé.

May 1, 2007

By B. Tanda

A process has been developed at Curtin University whereby glycine is used in an alkaline environment to leach gold, silver and copper from their ores, concentrates, process intermediates and wastes. Copper mineralisation investigated includes various oxides, sulfides and native copper. The leach process utilises an oxidising environment such as oxygen. Glycine is a non-toxic, non-volatile, edible, low cost reagent which is produced in large industrial quantities for use in several industries. Glycine and its copper and precious metals complexes are stable over wide pH, Eh and temperature ranges. Other than losses in leach residues, the glycine is recovered and recycled for leaching. Iron dissolution is insignificant in the pregnant leach solution. Iron in pyrite remains unaffected, whereas iron associated with base metal sulfides (e.g. chalcopyrite and bornite) is converted to a readily filterable iron hydroxide. Efficient separation of copper by solvent extraction and conventional electrowinning has been shown to be feasible for a number of organic extractants, whereas gold and silver glycinates adsorb very well onto carbon allowing CIP/CIL/CIC (carbon-in-column) based processes. The process is ideal for ores containing acid-consuming gangue, concentrates with high arsenic or halide contents and for copper-gold ores with significant sulfide mineralisation. The process eliminates many of the problems associated with the processing of copper-gold-silver ores, such as elemental sulfur formation, silica gels, unwanted metal co-dissolution, and jarosite precipitation. The reagents used and process residues are much safer and environmentally benign than conventional process options. The processing technology can be applied to in-situ, heap and vat, or agitated tank leaching at temperatures ranging from ambient to below 100?C at atmospheric pressure and is currently being commercialised. This paper will focus on copper leaching and recovery and iron rejection from a chalcopyrite flotation concentrate.

Jan 1, 2016

By John E. Feddcck

New York City's $360 million North River Water Pollution Control Project is part of New York State's plan to clean up the Hudson River. The project is to provide a sewage treatment facility capable of accomodating a peak waste water flow of 330 MGD which will in great measure eliminate the 192 MGD of raw sewage that N. Y. C. discharges into its surrounding waters. Eleven miles of intercepting sewer lines must be constructed along the west side of Manhattan Island to service approximately one-half of the island. The first contract award was for a 4134 ft. sewer tunnel with a finished inside dimension of 16' x 16'. This main intercepting sewer will feed a sewage treatment plant located on and adjacent to the Hudson River. The tunnel is parallel to the river and is located under 12th Avenue between 125th Street and 143rd Street. The Penn- Central Railroad tracks are above and just to one side of the tunnel location. The working tunnel diameter is 21 ft. and numerous problems of support, mining method, and ground control have been encountered. (see Dwg. 1)

Jan 1, 1970

By C. Newman, N. Schaefer

"As underground mining continues to operate at deeper depths and in more complex geologic and geometric conditions, there has been an increased demand for mine designs to better reflect site-specific conditions, measurements, and observations with respect to ground control safety and stability. During the past 20 years, the National Institute for Occupational Safety and Health (NIOSH) has developed, validated and distributed a number of free software packages (ALPS, ARMPS, AMSS, ARBS, etc.) specifically aimed at providing the industry with ground control design tools for the evaluation of underground stability in coal mines. While these programs were initially developed as stand-alone software packages where all data reside on an individual or workgroup computer, modern day web applications have begun to migrate toward a “multiple-tier” architecture, allowing multiple users to access an application by means of an Internet connection.This article introduces a new Web-based platform for ground control software applications, webGroundControl (webGC). webGC provides users with a platform through which one can access NIOSH and other ground control design software utilizing a Webbased, multiple-tier architecture. This provides users with easy access to ground control designs, the ability to perform on-demand calculations, as well as increase online collaboration between operational personnel and engineers through a web server. The basic framework and, more specifically, the user-interface of webGC are defined and outlined within this paper. It is expected that the mining industry will rapidly embrace this new product and webGroundControl will be a new paradigm for mining engineering computer applications. Platform architectureAs Web-based computing technologies continue to advance and cloud computing gains momentum, web-based platforms for software applications are growing in popularity across all industries due to ease of product accessibility and distribution as well as data security. With the expansion of Internet connectivity on the surface and underground, there is an industry need to develop Internet-based applications for mine and ground control design (Barczak et al., 2016). Cloud-based products are already available for many industries and are slowly being developed for the mining and geotechnical industry. A notable example is the drillysis package, which is a cloud-based borehole logging database (Geosysta, 2017) or the Dynonobel package for on the fly blasting calculations (Dyno Nobel, 2013)."

Jan 10, 2017

By Jeffrey K. Whyatt

The Crandall Canyon accident investigation included an interesting and unexplained observation by rescuers that the ?barrier rib had shifted northward as a unit, as much as 10 feet.? This is not the first mention of such a movement, although such reports are rare. Historical accounts describe unusual movement and displacement of intact coal, cribs and timbers. Two movements of particular interest are the creation of gaps above coal pillars and falling of standing support elements without apparent damage. A dynamic boundary element program was used to explore movements induced by slip on geologic features removed from the affected panel. While the resulting models are much too simple to fully replicate these observations, they do show that the types of phenomena observed are possible. They can also provide insight into the types of motions that ground support elements are subjected to during large bump events. This was demonstrated for the case of a large bump in a Book Cliffs coal mine. Seismic information suggested the source mechanism to be normal slip on a fault. A model of that source showed initial dilation of the panel followed by dynamic compression and rebound ? consistent with underground observations. The initial dilation is important as it may allow slender standing support to shift or fall.

Jan 1, 2009

By M. G. Goudge

IT IS ENOOURAGING indeed to note during the past year that, despite a slackening off in many markets and with numerous major difficulties and problems to solve, the mining industry of Nova Scotia was maintained at a very high level. The value of the Province's mineral production for 1957 amounted to approximately $65,000,000. This represents a drop of only 1.5 per cent from the figure of the previous year. Coal Atlantic Collieries, Ltd., opened a new coal mine during the year at Bras d'Or. This colliery is equipped with the most modern type of mechanical equipment available, with transport of the ?coal by a belt-conveyor system. Other mines in the Province continued to mechanize their operations by the addition of Diesel haulage locomotives and other mechanized mining equipment. New wash plants are in operation and .an additional one is planned.

Jan 1, 1958

By Yoshinori Kurumada, Masaya Watanabe, Kenji Sasa

"The Port of Yokohama is strengthening its international competitiveness as a strategic container port in order to respond appropriately to global exchange and shipping demands. Thus, the Minami Honmoku main Pier is currently being developed. The high-standard container terminals MC-1 and MC-2 have already started their service, and the development of the container terminals MC-3 and MC-4 is currently in progress.Because the South Honmoku Pier plays an important role in waste disposal management of Yokohama, a final waste disposal site (controlled final landfill site) is being developed in Block 5 to provide long-term and stable reception of waste that will be generated in the city. For this project, a revetment with water-blocking properties and an extension approximately 1.7 km in length is being built in order to prevent water from leaking from the disposal site. The base part of the revetment will be subjected to foundation improvement using the Cement Deep Mixing (CDM) method in order to secure water shielding of the soft sediment underneath the water, prevent slipping of the seawall, reduce the amount of subsidence, and increase the foundation support force.This report presents a preliminary study on using CDM on reclaimed soil and the construction process of the development project of the disposal site in Block 5 of the Minami Honmoku Pier, which has been underway since 2007.ABOUT MINAMI HONMOKU PIERThe development of the Minami Honmoku Pier started in 1990. It was designed to develop high-standard berths with greater water depths in order to handle the increasing volume of foreign container cargo and growing size of vessels. Figure 1 shows the layout of Minami Honmoku Pier. In April 2001, the Phase 1 (MC-1 and MC-2) began services. This is the newest pier in Port of Yokohama.This pier has one of Japan’s largest terminal areas (40 ha) and is equipped with 22 row-type mega gantry cranes capable of handling the newest ultralarge container ships. The pier has a quay with a water depth of 16 m, which is the first in Japan. The pier is equipped with advanced facilities and equipment to let Port of Yokohama be internationally competitive and function as an international commercial hub. An innovative system for high-efficiency transport is currently being introduced; it includes the installation of waiting vehicle lanes and a reservation-based loading and unloading system.Since the fiscal year 2007, a new container terminal (MC-3) with a -20m deep quay capable of handling the increased size of container ships and the diversification of port logistics has been under construction and is nearly completed."

Jan 1, 2015

1994 estimates for Porgera are probable and proven reserves of 58 200 000 t of ore grading 5 g/t Au. Gold mineralisation is related to an intrusive complex emplaced at shallow levels in poorly consolidated sedimentary rocks. The complex is located in a zone of fold-and-thrust deformation, whose formation may have been initiated shortly before emplacement and continues locally today. Abundant primary magnetite in the complex gives an intense, 5 km wide aeromagnetic anomaly. The deposit formed during two main stages of mineralisation, the first related to early magmatic-hydrothermal activity and the second representing later epithermal overprinting centred on the Roamane fault. Hydrothermal alteration followed closely on emplacement indicating a close genetic relationship between magmatism and mineralisation. Both stages of hydrothermal activity post-date and overprint early propylitic alteration. Several factors have acted in unison or sequentially to concentrate metals at the deposit, including an extensional or trans-tensional tectonic setting within an arc or collisional environment, the exsolution of a magmatic hydrothermal fluid prior to sulphur saturation in the melt, the development of the hydrothermal system into one favourable for transporting gold, the action of late-stage faulting in focusing epithermal fluid flow, and the role of dissolved gases in promoting fluid phase separation and high-grade ore deposition

Jun 19, 1905

By Caibin Wu, Bin Xie, Jiaqi Tong, Ningning Liao, Chong Zeng

Understanding the energy-size reduction relationship is vital to grinding process; therefore, this paper aims to show the energy-size reduction of magnetite-calcite binary mixture in a laboratory wet conical ball mill. Single magnetite, single calcite, and blended magnetite-calcite mixture at three weight ratios in four particle sizes were ground in a laboratory wet conical ball mill at four grinding time periods. The results showed that the particle size distribution of both fine particles and coarse particles of single and mixture ground product fitted well with the PSD computed by Rosin–Rammler-Benne function. The larger mass percentage of calcite is, the higher t10 of binary mixture ground product is. On the contrary, t10 in the mixture decreases as the percentage of magnetite in the mixture increases. The different breakage behaviors in blended samples are due to the hardness and particle size. The results of calculated ratio of energy absorption factor showed that the calcite consumed more energy in the breakage process of binary mixture than ground alone. The JK size-dependent breakage model based on the t10 method fits all the experiment data, be it generated from pure minerals, mixtures at different weight ratios, or each component separated from the mixture.

Jun 4, 2022

By M. K. Mohanty

Over the years, screen bowl centrifuges have been widely used for dewatering fine coal in coal preparation plants in the United States and elsewhere. Its popularity is attributed to its relatively low cost, its high capacity of providing low moisture content product and its relative ease of operation and maintenance. It is generally recognized in the engineering and scientific communities that screen bowl centrifuges provide some degree of particle size separation while dewatering fine coal in a common application. However, the extent of differential partitioning of coarse and fine particles achievable by a screen bowl centrifuge has not been systematically studied in the past. The present investigation was aimed at conducting a parametric study using a statistically designed experimental program to better understand and optimize the size classification performance of a screen bowl centrifuge. A continuously operating screen bowl centrifuge having a bowl diameter of 0.5 m was used for this study at the Illinois Coal Development Park. Three key operating parameters, i.e., feed flow rate, feed solid content and pool depth, were varied to conduct a total of 17 experiments using a three-level factorial test matrix. Some of the best size separation performances achieved in this study may be described as having an imperfection value of 0.13 at an effective separation size (d50c) of 38 µm and an imperfection value of 0.27 at an effective separation size (d50c) of 2.8 µm. Due to an effective separation of ultrafine high ash materials, the ash content of the screen bowl feed was reduced from 22.3% to a minimum of 8.84% with a combustible recovery of 84.1% and an ash rejection of 71.6%. A higher combustible recovery of 92.1% was achieved at a product ash content of 12.5% with a d50c of 2.8 µm and imperfection of 0.27.

Jan 1, 2008

Updraft sintering of lead concentrates was introduced at Port Pirie in 1955 and since that time a considerable amount of investigational work has been carried out in the laboratory and on the plant with the objective of improving both the understanding of the process and its practical application.From this work it is now possible to predict trends in design and operation, which should result in capital savings and increased efficiency of future updraught plants.INTRODUCTIONOver the last 70 years a remarkable advance has been made in the method of preparing lead concentrates for smelting in the Port Pide blast furnaces of The Broken Hill Associated Smelters Pty. Ltd. (RH.A.S.). Beginning in 1889 with heap roasting, the process progressed to Ropp roasters and Huntington-Heberlein pots in various combinations, then to multiple small Dwight Lloyd (D.L.) downdraught machines. In 1940 two large 10 ft by 50 ft D.L. downdraught machines were installed, and finally in 1955 updraught sintering was ,introduced with the installation of the present 10 ft by 99 ft sinter machine.At the time this last machine was built it was the first unit of its type and thus, of necessity, an experimental machine. During the eight years it has been operating a considerable amount of investigational work on sintering has been carried out both on the plant and in the laboratory.It is now felt that sufficient information is on hand to predict at least tentatively, some of the future developments in lead sintering, whereby both the quality of the sinter and the rate of production may be improved. This will result in a considerable reduction in smelting costs.

Jan 1, 1964

By C. G. Snavely

Martin County Coal Corporation produces coal from seven continuous miner sections in two coal seams which are often interlaced with rock partings. Because of high clay content and coal oxidation, all minus 100 mesh material is discarded in the preparation process. We began experimenting with various drum lacings on continuous miners in 1983 to improve product size consist and increase machine cutting rates. To date, + 6.35 mm material has increased from 61 to 73% of mined product, minus 0.15 mm material has decreased from 6% to 4% of product, and machine cutting rates have increased by 50 percent.

Jan 1, 1985

By Na Wang, Chao Du, Yao Zhang Shuqiang Jiao, Hongmin Zhu

"Na2NbAlO5 was synthesized using Nb2O5 and NaAlO2 as raw materials in molten NaCl-CaCl2 by a solid reaction. With an addition of sodium into the melts, Na2NbAlO5 was subsequently reduced to form NbAl3 intermetallic compound with a particle size of 50-300nm.IntroductionThe intermetallic compounds of niobium aluminides have been a subject of research interests as high temperature materials because of their properties such as high melting temperature, large specific strength at elevated temperature, good resistance to high temperature oxidation, low density and large ductility [1,2]. They are applicable for turbine blades in aircraft engines and stationary gas turbines [3,4].In recent years, the methods of powder synthesis have been widely discussed. There are many methods to synthesis intermetallic compounds such as conventional melting and solidification [5], powder metallurgy [6,7], reaction sintering [8] and reaction sintering with prior mechanical activation [9,10]. There is a prominent weakness in such methods that they use metal to produce intermetallic compounds by the means of diffusion reaction. Although the metal can diffusion sufficiently, it is still hard to avoid maldistribution of the constituents which impairs the properties of the materials."

Jan 1, 2012

By John E. Roberts

People are not a novelty. But the phenomenal numbers thereof, who have approached, settled, and been born in California in the past twenty-five years, are such a problem as to be a novelty in the broadest sense of the word. California, with less than 7,000,000 people in 1940, and over 19,000,000 in 1966. In 5 1/2 years, (1960-65) the southerly 14 counties of California, which together comprise one-half the land area of our state, had an increase in population greater than Colorado, or Arkansas, or Oregon, or any one of 19 other states.

Jan 1, 1967

By I. S. Parrish

One of the most common errors uncovered while performing a reserve, or resource, audit is not in the geological modeling or grade problems due to poor sampling, prepartion or assaying. The error most commonly found is in tonnage or, more specifically, in the tonnage factor - that factor applied to volume to derive tonnage. Tonnage factors In the metric system, the tonnage factor is the density, or specific gravity. Specific gravity (Sp.g.) is defined by Dana (1947): • "The specific gravity of a mineral is the ratio of its density to that of water at 4° C (39.2° F). • "Density is the mass of the unit volume or weight of the body divided by the weight of an equal volume of water." When Sp.g. is multiplied by the metric volume it yields metric tonnes. In the English system, the tonnage factor is usually expressed in cubic feet per short ton (cu ft/st). When the volume in cubic feet is divided by cu ft/st, the resulting figure is in English short tons. Table 1 gives the cu ft/st factors equivalent to specific gravities from 1.6 Sp.g. to 5.8 Sp.g. The table is based on the following equation: cu ft/st = 0.9072 divided by Sp.g. times 0.02832 The blase attitude that most geologists have toward tonnage factors is echoed in the prevailing definitions of Reserves and Ore, as provided by the US Securities and Exchange Commission (S.C Form S-18), Canadian National Policy 2A and the SME Proposal for Reporting Terminology (SME February 1991). In each case, it is stated that "quantity" (SEC, SME), or "tonnage" (Can.2A), "is computed from dimensions revealed in...." etc. Unfortunately, "dimensions" do not directly yield tonnage. Dimensions must be factored by density to derive tonnage.

Jan 1, 1993

In the past decade several significant intrusion-related gold deposits have been discovered in terranes historically exploited for tin-tungsten mineralization (eg Tintina Gold Province, Yukon and Alaska, Tasman Fold Belt, Australia and the Altaid orogenic collage in central Eurasia). This paper presents new data on the geological and geochemical characteristics of these deposits that links them to magmatic-hydrothermal processes and highlights their implications for exploration. New data from several intrusion-related gold provinces suggest that these deposits are found in areas that contain granodiorite to granite, but with a locally significant mafic component, have Rb/Sr ratios ranging between 0.1 and 1.0, and are moderately reduced (Fe2O3/FeO ~ 0.1 to 0.6) ilmenite series, metaluminous, I-types. The intrusions are distinct from porphyry copper intrusions and tin granites, but are more akin to tungsten granites. Hydrothermal fluid types vary with depth of emplacement in intrusion-related gold deposits and new proton induced X-ray emission (PIXE) data from syn-ore fluid inclusions in shallow and deep deposits provide fascinating insight into the variation in metal content between the different settings consistent with observed deposit metal associations. Exploration for intrusion-related gold deposits in tintungsten terranes should focus on regions that contain both mafic and felsic intrusion that are moderately reduced, metaluminous, I-type granites rather than terranes with dominantly highly fractionated, strongly reduced, peraluminous S-types. Intrusion-related gold systems occur in variety of deposit styles (in part controlled by host rock, proximity to granite, and depth of emplacement) and exploration geologists need to be aware of the variety of target types in and around the intrusive environment, and be able to recognise whether they are exploring a shallow or deep intrusion-related gold setting.

Jan 1, 2005

By J. P. Neumann, L. Raymond

At temperatures near 1000°C, only the (112) (111) slip systems are operatire in tungsten. Therefore, the substructure introduced into the billet upon rleforming a single crystal by rolling at 1000 "C can be controlled by proper selection 01. processing ral'iubles. Using a reduction of 10 pct pel- pass, the (001)[110] and the (110)[001] crystals will deform by duplex slip rip to a 50 pet reduction in thickuess. These rolled single-crystal sheels are characlerized by anisotropic hardening, retention of ductility with warm working, lattice bending which is related to the conlacl (angle, and macroscopic dimensional changecs in the length bid not the width of the billet. When several slip systems become operative, a greater degree of work hardening is itztvoducetl into the crystal. This rolling- condition is characlerized by isotropic hardening, loss of ductilily with warm working, complex lattice distortions, and macro-scopic dimensional changes in both the length rind Width of the billel. IN tungsten, the {1 10}(111) slip systems are operative below room temperature,' while above 700°C only the {112{ (111) slip systems are observed.2,3 In the transition region, i.e., room temperature. both systems appear. It is the purpose of this investigation to show that tungsten single crystals deformed by rolling at a temperature where only one slip system is operative generate dislocation substructure which depends on the crystal orientation. For a specific crystal orientation. the resulting dislocation substructure can be further influenced by modifying the rolling procedure. Crystals oriented for multiple slip display less substructural sensi- tivity to modifications in processing techniques than do single crystals oriented for duplex slip. Under simple slip modes of deformation, very little work hardening is introduced into a rolled single-crystal sheet. Mechanical properties such as room-temperature strength. ductility, and hardness are used to confirm the existence of the different work-hardened conditions generated within the crystal by modified warm-rolling techniques. EXPERIMENTAL PROCEDURE Material. Single-crystal billets of four different crystal orientations. grown by the Arc-Verneuil technique. were ground to a size of 0.25 by 0.375 by 3 in. In terms of their rolling plane and rolling direction, the billets had the following orientations: (1101 [001 ] (110) [110] (001) [110] (001) [100] The actual orientation of all crystals was within 5 deg of the ideal orientations. The typical impurity content of the crystals is given in Table I. Polishing and Etching. Polishing was done elec-trolytically in a 20 g per liter aqueous solution of NaOH at approximately 10 v. It was established by the Laue back-reflection X-ray technique that the surface damage due to grinding and cutting operations with a diamond wheel did not exceed 0.001 in. Therefore after each cutting or grinding operation at least 0.002 in. was removed electrolytically from the surface in order to eliminate surface effects. By lowering the voltage to 3 v, subgrain boundaries and individual dislocations are identified in agreement with Berlec 4 where the etch-pit traces on a cubic plane form a square. The etching time was about 5 sec at room temperature. Rolling. Rolling was carried out on a Loma 2-high mill (Model 600). The peripheral velocity of the 6-in.-diameter rolls was 500 in. per min, with the surface temperature of the rolls about 400° to 450° C The billets were heated before each pass for 30 min in argon to 1000 C. Oxidation of the crystals during rolling in air resulted in a thin layer of greenish-yellow WO 3 This oxide was removed after each pass by immersing the crystals for a few minutes in a boiling NaOH solution. Prior to the initial rolling pass, a surface layer of 0.001 in. was removed by polishing. The crystals were then annealed in vacuum (10-4 torr) at 2400 C for 30 min. All crystals were rolled in the same direction; i.e., the same end was always introduced into the rolls. The rolling program was conducted in

Jan 1, 1965