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Compare the fire endurance of paneled steel stoppings with that of traditional concrete block Stoppings. Background Permanent stoppings or partitions arc used in mines to separate ventilation airways. The ability of stoppings to retain their structural integrity for a minimum length of time under lire conditions and prevent the spread of flame and toxic combustion products to an adjacent airway is critical. The success of miners in reaching safety during a fire depends largely on the presence of uncontaminated airways. Traditionally, permanent stoppings for coal mines are constructed of concrete blocks. Recently, paneled steel stoppings that satisfy many of the requirements demanded of permanent stoppings, such as incombustibility and strength, have been introduced. Their use also introduced concerns such as the ability of a steel stopping to maintain its ventilation control function when exposed to a fire and the potential that the fire could transmit enough heat through the stopping to ignite combustible materials on the unexposed side. To address these concerns, the Bureau of Mines investigated the fire endurance of galvanized steel and concrete block stoppings.

Jan 1, 1989

By M Fylak, R Wenda

Advanced preparation techniques open new ways for SEM and X-ray diffraction (XRD) investigations on hydrating cementitious systems. In this paper the early time hydration of Portland cement is studied with advanced cryo scanning electron microscopy techniques in combination with in situ X-ray diffraction and heat-flow calorimetry. The application of preparation techniques and analytical methods to Portland cement hydration are presented and discussed. Some aspects of hydration reactions are focused. The reaction products of the first minutes, changes in ettringite morphology, AFm formation during the deceleration period and the visualisation of C-S-H microstructures were special points of interest. X-ray diffraction analyses and Cryo-SEM images gave essential information about phase development, reaction kinetics, microstructure and morphology of hydration products. Portlandite, AFt and AFm phases were detected by in situ XRD. Cryo-SEM analyses enabled high resolution imaging and EDX-analyses of cement particles and reaction products. The results of the different analytical methods were compared to obtain detailed information about crystallisation processes and microstructural development during the first three days of Portland cement hydration.

Jan 1, 2008

By R. E. Reed, R. D. Leggett, Paxton, H. W.

TECHNIQUES have been developed for growing monocrystals and bicrystals of Fe-20 Cr, Fe-20 Cr-20 Ni, and Fe-18 Cr-8 Ni alloys by both the strain-anneal and the Bridgeman techniques. None of the techniques are new but since they are simple and many people have expressed interest, they are described here quantitatively as they could be modified for other single-phase "commercial" materials of high melting point. CRYSTAL GROWTH BY STRAIN ANNEAL Flat tensile specimens with a tapered gage length were initially studied to deduce the approximate critical strain. Normal flat tensile specimens were then used. The optimum procedure for the austenitic steels (Fe-Cr-Ni) deduced from a variety of cold reductions, recrystallization treatments, tensile strain, and growth anneals was as follows: cold reduce 70 pct, recrystallize (after machining tensile specimens) at 1000°C for 1 hr, strain in tension 2.5 pct, and then heat to 1350°C as rapidly as possible. A time of 100 hr at 1350°C is usually sufficient to pro-

Jan 1, 1960

By P. D. Merica

Certain compositions of the light, i:e., aluminum-rich, alloys of aluminum with magnesium and copper have become quite well known within the past ten years under the name of duralumin. These alloys are used for rolling and forging and can be so treated as to develop quite remarkable mechanical properties. Thus a properly heat-treated alloy containing about 4 per cent. of copper and about 0.5 per cent. of magnesium, rolled into sheet or rod, will have a tensile strength of approximately 55,000 lb. per sq. in. (3866 kg. per sq. cm.) with an elongation in 2 in. (50.8 mm:) of about 15 per cent. This alloy, duralumin, was developed by Wilm,1 and its properties more fully described by Cohn.2 The authors considered it worth while to investigate the mechanical possibilities of the light alloys of two somewhat analogous ternary series; namely, of aluminum-magnesium-nickel and of aluminum-magnesium-manganese, to study the effect of variation of composition upon mechanical properties within the alumimum-rich group of the aluminum-magne-

Jan 7, 1919

By E. G. Davis

The flash reduction of fine iron ore in a dilute-phase system was investigated at 500° to 900° C within a heated stainless steel tubular coil. Alabama brown iron ore and Mesabi semitaconite ore were fed into the coil concurrently with reducing gases of hydrogen and reformed natural gas, so that the velocity of the gas at the reaction temperature was sufficient to entrain and pneumatically transport the solids through the coil. Reduction is very rapid with retention time of the ore in the coil varying from 4 to 15 seconds. Variables affecting reduction are temperature, ore feed rate, and gas flow or velocity. Results of the studies show that a partially reduced product (10-to 25-percent reduction) can be made which, on subsequent magnetic concentration, yields a concentrate containing 64 to 70 percent iron with a 90-to 94-percent iron recovery. Maximum reduction of 77 percent was obtained when hydrogen was used in a four-stage reduction test to yield a product containing 61 percent metallic iron.

Jan 1, 1972

By G. R. Doughty

It is shown that sodium can be removed very readily from molten aluminium by the use of a beta"-alumina, the more highly conducting form of beta-alumina, provided that the surface of the tube is wetted by a layer of salt. From current/time plots the theoretical amount of sodium removed has been calculated and excellent agreement obtained. The beta"-alumina tubes can be immersed directly in the Al without fracturing if they are pre-heated for a few minutes prior to immersion. According to its stability beta"-alumina should be attacked by molten Al at low Na contents, but in these experiments the salt acted as a protective layer. Magnesium chloride is a relatively cheap salt, whose Mg product can be used within a foundry. The only other product is NaCl, which can be used in-house as a flux or sent for disposal. No polluting gases are used or produced and no drosses created. The time for removal of sodium was quite short, comparable to that for chlorination

Jun 21, 1905

By C. W. Vaupell

THE Huitzuco mines lie in north central Guerrero, Mexico; production has been about 90,000 flasks of quicksilver since 1873. Near-surface ores fill extinct mud geysers and the deep deposits are chambered veins, stock-works in brecciated blocks, and replacements in limestone. The epigenetic minerals livingstonite, stibnite and sulphur occur in limestone, gypsum and dolomite through a developed vertical range of 260 meters. The deepest workings expose an increased amount of stibnite, which probably indicates that the lower limit of mercury mineralization is being approached. A resur-gence of heat and water formed geysers over an extended area after the period of mercury mineralization. Mud geysers, which are situated, in the outcrops, contain the secondary mercury minerals, cinnabar and barcenite in the gravel and mud filling the vents. A 150-ton flotation plant is in operation concentrating stope fills that assay 3.0 kg. of mercury per ton. In one open stope, which is more than one hectare in area and 60 m. high, 150,000 tons are available.

Jan 1, 1937

By Khosrow Nikkhah

Increasingly ion exchange systems are being included in design of hydrometallurgical plants for metal extraction or impurity removal. Because such systems operate sequentially and are based on resins that exchange one ion for another, store it temporarily and release it to a regenerating solution, the usual steady state heat and mass balancing tools and spreadsheets cannot be used to design them successfully. This paper outlines the role of dynamic simulation in design of ion exchange systems. Examples are given for use of dynamic simulation in design and investigation of equipment based on consideration of the effect of input criteria such as expected ion loading and elution profiles. The methodology for dynamic modeling using IDEAS in design of multi column ion exchange trains operating in parallel is presented. Results shown include the non-steady state distribution of extracted metal and limitations imposed on operating conditions. These conditions include proposed sequencing of columns for loading and elution cycles, loading, elution and recycle flow rates as well as size and choice of related ion exchange plant equipment.

Jan 1, 2003

By E. Buehler

THE floating zone refining technique'-4 has provided a new experimental approach to the purification of many reactive materials especially those with high melting points. The method avoids the use of a crucible and at the same time it provides a favorable environment at the freezing interface for the growth of single crystals. The physical properties of refractory metals such as molybdenum and tungsten have long been of interest from a fundamental point of view and because of their widespread use in vacuum electronics. Single crystals are often desirable for study. Prior to the introduction of zone melting, single crystals of these metals were usually grown in the solid state at temperatures slightly below the melting point by strain annealing3 or by the application of a moving temperature gradient. Such techniques were mostly successful on wires, ribbons, or rods having small cross-sectional areas. Recently, larger samples of tungsten, molydbenum, tantalum, columbium, and rhenium were melted by a floating zone process which employed electron bombardment heating.10 Single crystals were obtained in many instances

Jan 1, 1959

By P. D. Merica, A. N. Finn, R. G. Waltenberg

CeRtain compositions of the light, i.e., aluminum-rich, alloys of aluminum with magnesium and copper have become quite well known within the past ten years under the name of duralumin. These alloys are used for rolling and forging and can be so treated as to develop quite remarkable mechanical properties. Thus a properly heat-treated alloy containing about 4 per cent. of copper and about 0.5 per cent. of magnesium, rolled into sheet or rod, will have a tensile strength of approximately 55,000 1b. per sq. in. (3866 kg. per sq. cm.) with an elongation in 2 in. (50.8 mm.) of about 15 per cent. This alloy, duralumin, was developed by Wilm,1 and its properties more fully described by Cohn.2, The authors considered it worth while to investigate the mechanical possibilities of the light alloys of two somewhat analogous ternary series; namely, of aluminum-magnesium-nickel and aluminum-magnesium-manganese, to study the effect of variation of composition upon mechanical properties within the alumimum-rich group of the aluminum-magne-

Jan 1, 1921

By D. W. Breck

Zeolites were first recognized as a new group of minerals by Cronstedt with the discovery of stilbite in 1756. The word zeolite was coined from the two Greek words meaning "to boil" and "a stone" because of the loss of water when heated in the mineralogist's blowpipe (Breck, 1974). In 1845 it was discovered that certain soils lave the power of retaining ammonium salts Way, 1850). These were the first ion exchange experiments. Later it was discovered that it was the hydrated silicates in the soil that produced this phenomenon. Several years later a paper was published dealing with the action of dilute salt solutions on silicates which showed that this base-exchange principle, which we now call cation exchange, is reversible. The quantitative cation exchange behavior of zeolite minerals, such as chabazite, was studied. As a result any aluminosilicate which exhibited the property of ion exchange was referred to as a "zeolite," even today the term has been applied to clay minerals as well as synthetic organic ion exchange resins.

Jan 1, 1975

It is now 32 years since Walsh's classic publication (1) heralded the beginning of atomic absorption spectrophotometry (AA) as we know it today. During this time, AA has developed into the most widely used analytical techniques for the determination of the metallic elements. The years have seen progressive changes in instrumentation so that today it is a highly sophisticated technique. One area of development in AA that is experiencing renewed attention is in the area of electrothermal excitation. In this technique a flame is not used by the analyte solution is atomised by an electrically heated graphite furnace. For a large number of elements the graphite furnace atomic absorption spectrophotometer (GFAA) is considerably more sensitive than flame work. It is common to be able to detect concentrations one hundred times smaller than those possible by flame. Today's geochemists are finding that they can gain valuable information out of very low limits of detection. Electrothermal atomic absorption spectrophotometry (or GFAA) allows for low limits of detection and can be seen to be a valuable aid to geochemical prospecting Analysis.

Jan 1, 1987

By John G. Whellock

Over the last decade new constraints have emerged in the metallurgical industry which challenge the very basis of design and construction of smelters and refineries. The hackneyed designs of the past will not now serve the revised objectives of: - minimal cost of ownership - improved productivity - reduced energy consumption - greater flexibility in feed or product - minimized recycle loops and by-products - more stringent environmental control The impact of these constraints has been channeled constructively into process intensification - exemplified at the large scale by the introduction of flash smelting technology and at the smaller scale by the application of rotary process vessels and converters for augmented heat and mass transfer. The design of successful process plants depends on the understanding of the unit operations and their interactions which is the discipline of systems engineering. With the advent of increased process intensification the importance of a systems approach to process design and implementation becomes paramount. This paper describes the systems approach with specific reference to medium scale projects in the primary and secondary metallurgical industry.

Jan 1, 1985

By R. G. Robins, O. J. Kwok

The application of chemical thermodynamic theory to high temperature aqueous systems is discussed as a basis for the explanation of thermal precipitation. The derivation of high temperature potential/ pH diagrams is briefly outlined in order to show a temperature/pH relationship for hydrolytic precipitation, which is an effect that is caused simply by heating an aqueous solution. Various examples of thermal precipitation are given, with particular reference to separation of metal values from leach solutions. Metal sulphate solutions are shown to precipitate basic sulphates, hydrated sulphates , oxides, hydroxides, and oxydroxides of the metal depending largely on the pH, the concentration of metal ion, and the concentration of sulphate or bisulphate. The CuS04-H2S04-H20 system is treated in some detail, and the separation of copper from other metal ions is investigated. Other separations involving Fe, Ni, Zn, Cd, and Cr are considered. Other advantages of thermal precipitation, such as the formation of high purity, large particle size and easily filterable materials, are presented. The kinetics of thermal precipitation are also briefly examined.

Jan 1, 1973

In underground coal mining, one of the biggest challenges is spontaneous combustion, which will not only present safety hazards but result in reserve losses as a result of burnt coal. The released heat coupled with other combustible gases commonly encountered underground will significantly increase the risk of explosion. In this paper, three-phase foam as an environment-friendly fire fighting agent composed of nitrogen, water and fly ash is introduced. The nitrogen facilitates inertization of the fire zone; the water helps cool down the fire and the fly ash can closely cover the coal to isolate the oxygen. What's more, the fly ash and the foaming agent are good free radical absorption. The comprehensive merits mentioned above make three-phase foam quite effective in quenching spontaneous combustion. Experiments indicate that three-phase foam can significantly slow down the temperature rise of coal during oxidation. The comparison between slurry and three-phase foam shows that the latter one is capable of flowing upward in the porous media so as to extinguish the high-point fire and concealed fire.

Jan 1, 2011

By T. B. Gyles

Zinc is made by the National Smelting Co. and its associates by both the horizontal retort process and the vertical retort process developed by the New Jersey Zinc Co. This paper deals only with the horizontal retort practice at Avonmouth. That the horizontal retort process does survive in all countries in some form or other is due to at least partial success in overcoming some of the inherent difficulties of the process. The horizontal retort furnaces ran into considerable difficulties when the product of the selective flotation of mixed lead and zinc ores became the normal material for treatment. It is necessary, therefore, to make some reference in connection with the process to the preliminary treatment of the ore prior to distillation.. Therefore we include some small reference to this aspect in our description. Furnace Design and Structure Of the types of furnaces in operation at the company's various works, those at Avonmouth are perhaps more typical of the trend to utilize large units, with a subsequent saving in costs, such as heating and supervision.

Jan 1, 1937

By Yael Miron

Ammonium nitrate-fuel oil (AN-FO) mixtures are used as blasting agents in mining pyrite-bearing ores. The temperature of these ores can increase by the continuous, though at times slow, oxidation weathering of the pyrites. At elevated temperatures, AN-FO reacts exothermally with pyrite, and the reaction becomes self-sustained at 120° C ± 10° C. The Bureau of Mines has conducted an investigation to determine the reactivity of mixtures of AN-FO with pyrite containing ferrous sulfate. The results of tests in a heated vessel simulating a hot borehole demonstrate that small amounts of ferrous sulfate, a major product of pyrite weathering, initiate a self-sustained exothermic reaction with AN-FO at 80° C. Five pct by weight of urea was found sufficient to prevent a reaction among the three ingredients, at least within the limits of the test, which reached 180° C. Smaller amounts of urea and of potassium oxalate slowed down the reaction and delayed its onset to higher temperatures, but did not prevent it.

Jan 1, 1979

By I. A. Jacobson

In a closely controlled laboratory retorting system for oil shale, a relationship was developed by the Bureau of Mines between the temperature in the retort and the weight ratio of ethylene to ethane in the gases produced. Reciprocal temperature was shown to be directly proportional to the log ([ethylene]/[ethane]). From this relationship a number, called retorting index, was developed. The retorting index has the dimension of temperature, but its magnitude depends on both temperature and residence time for the reactants in the heated zone in the oil-shale retort. The slopes of the lines relating reciprocal temperature and the logarithm of the ethylene-ethane ratios are nearly constant for each of the retorting processes for which data have been presented. The retorting index should be a valuable tool to control the operation of oil-shale retorts, either aboveground or in situ. If an optimum operating condition can be established, the maintenance of the optimum or the departure from it should be easily monitored by use of the index.

Jan 1, 1974

By J. J. Craron

MR. J. J. CRARON: If Ross Weber rings that bell of his, I think I have a few secrets on him that I will tell. It is not such a long time ago when the sales and executive departments of the coal industry were constantly urging the operating department to increase their output, and this cry for increased production resulted in vast development work and increased capacity to the point where the operating departments are today in position to produce coal upon sudden demand far in excess of the ability of their sales departments to dispose of it. So today our ability to produce coal is away ahead of our ability to market it. There are many reasons, of course, for this condition. First, the present economic situation, which has prevented even a normal consumption of coal. Secondly, the over-development and production of every commodity and industry as the result of war time and post-war time prosperity. Thirdly, the inroads made by competitive fields, particularly oil and gas, because of the desire of the public for automatic heat.

Jan 1, 1934

By Morrison AL

The volume changes occurring during the reduction by hydrogen of single, high-grade hematite pellets under isothermal and non- isothermal conditions were investigated using a time-lapse photographic technique. The major cause of swelling during iso- thermal reduction at temperatures in the range 600-1000¦C, was the disruptive stresses set up during the transformation of hematite to mag- netite. The severity of the disruption was temperature dependent; the degree of swelling increased with increases in the reduction temp erature. Under non-isothermal reduction conditions, in which the pellet temperatures were increased at constant heating rates over the temperature range 500-1000¦C, minor swelling (6-8%) occurred in the initial stages of reduction followed by pellet contractions of up to 15% in the final reduction stages. The low initial swelling and high final pellet shrinkages were due to a com- bination of the temperature dependence of the swelling mechanism, and the sintering of fine pores in the reduced iron in the latter stages of reduction at higher temperatures.

Jan 1, 1980