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By Bruno Gomes Silva

O Distribuidor é um equipamento indispensável e de grande importância no processo de solidificação do aço via Lingotamento Contínuo. Os distribuidores são revestidos por um material refratário de trabalho que entrará em contato com o aço líquido. Atualmente é utilizado um revestimento que possui a necessidade de adição de água durante a aplicação, que poderá ser manual ou automática. Com o distribuidor disponível para lingotamento, o mesmo é direcionado para as máquinas de lingotamento onde serão pré-aquecidos visando retirar o excesso de umidade e promover a sinterização do refratário. O presente trabalho apresenta uma alternativa de revestimento, onde não é utilizada água na aplicação do produto, ou seja, um refratário com características de auto-endurecimento que permite iniciar o lingotamento sem haver necessidade de pré-aquecimento, o que significa partir a frio com o distribuidor.

Aug 16, 2017

By Larry G. Twidwell, Jannette L. Chorney, Bryce D. Ruffier, Katelyn M. Lyons, Daniel W. Gaede, Ryan J. Foy, Jerome P. Downey

The Army Research Laboratory (ARL) has an interest in the recovery and processing of rare earth elements. At Montana Tech, elevated temperature chlorination of rare earth oxides is presently being investigated as a potential methods leading to the selective separation and recovery of rare earth elements from mineral ores and concentrates. After preliminary evaluation, ytterbium oxide was selected as a representative surrogate material for more extensive chlorination studies. Methods used to determine the conversion and recovery include X-ray diffraction (XRD) and inductively coupled plasma (ICP) analysis. These data have been used to establish and confirm process conditions that consistently yield high conversion efficiencies. Based on the promising results, further experimentation is underway to ascertain the metallurgical response of other rare earth oxides and carbonates to the roasting process. The end goal is to create a robust process for industrial application that has greater efficiency and reduced costs as compared to current practice.

Jan 1, 2015

By Xiaoyan Xiang, Wenqiang Yang, Wentang Xia

Magnesium aluminate spinel is widely used in the metallurgical industry as refractory material, however, natural magnesium aluminate spinel is rare and most of the magnesium aluminate spinel is synthetic. The traditional synthesis of magnesium aluminate spinel often needs high temperature, which leads to more energyconsumption. In this article, solid phase sintering process was employed to synthesize magnesium aluminate spinel, in which, magnesium and aluminum oxide were used as raw materials and magnesium and aluminum powder were used as composite additives. The mass ratio of magnesium and aluminum on the effect of synthesis of magnesium aluminate spinel and the characteristic of the synthesis at different temperature and time was discussed. Experiment found that the synthesis temperature was observably lowered when the addition of magnesium and aluminum was 2.0% and 1.0% respectively.

Jan 1, 2016

By Giovanna Agarelli

Avaliou-se a suscetibilidade à corrosão intergranular de juntas soldadas dos aços inoxidáveis ferríticos AISI 409 e AISI 439 utilizados na fabricação de escapamentos automotivos. A possível sensitização nas zonas termicamente afetadas (ZTA) e os seus efeitos nas propriedades mecânicas das juntas foram avaliados por meio de metalografia e ensaios de tração e corrosão. Observou-se um crescimento dos contornos de grão com a ocorrência de valas na ZTA e a presença de precipitados sensitizados. Também se registrou um limite de resistência e alongamento maiores nas amostras de soldagem manual do que na automática. Concluiu-se que quanto maior o aporte de calor na soldagem, maior o tempo de exposição da ZTA a altas temperaturas, maiores os contornos de grão, menores a resistência mecânica e a ductilidade das juntas. Adicionalmente, a precipitação de carbonetos e nitretos nos contornos de grão comprovou a influência térmica sobre a sensitização.

Oct 30, 2017

By Sueli Aguiar Barros

A água utilizada para refrigerar grandes equipamentos de produção, tais como Alto fornos, Fornos do Laminador de Tiras a Quente, Trocadores de Calor das Laminações de Tiras a Frio é originada de diversas torres de resfriamento da Usina, denominadas CBR´s (Casas de Bomba de Refrigeração). A água refrigerada necessita de tratamento químico para proteger os equipamentos de corrosão, deposição e crescimento microbiológico. Este tratamento químico usualmente na CSN é obtido por uma empresa contratada fornecedora de produtos químicos e serviços nestes sistemas. Dentre os serviços destacam-se as análises físico químicas, monitoramento automático das dosagens, avaliação diária dos tratamentos, etc. Recentemente, em Agosto de 2014 houve o início do novo contrato deste tratamento nas nossas CBR´s, mudando-se o fornecedor, os produtos e a equipe de atuação nestes sistemas. Este trabalho visa descrever como foi realizada esta mudança, as dificuldades enfrentadas inicialmente e os ganhos obtidos com esta alteração do tratamento. Destacamos os ganhos no monitoramento em certos sistemas que anteriormente não era realizado, como nos Staves do Alto Forno 3 e os ganhos financeiros em relação ao tratamento.

Aug 17, 2017

By Thiago Marques Ivaniski

A fabricação de componentes para conformação mecânica possui uma gama de exigências devido aos esforços cíclicos, como por exemplo, fadiga térmica. Devido à capacidade de formar geometrias complexas e usinar metais de alta dureza, a eletroerosão (EDM- Eletrical Discharge Machining) possui eficiência na produção destas matrizes. O estudo da integridade superficial do material erodido torna-se importante para avaliarmos qual são as condições ideais para tratamentos termoquímicos que visam a otimização da superfície da matriz usinada. Neste trabalho, foi investigada a integridade superficial do AISI H13, utilizadas para a fabricação de matrizes de forjamento a quente. Foram avaliadas a rugosidade e camada afetada pela técnica de Perfilometria Mecânica,Microscopia Ótica (MO) e Microscopia Eletrônica de Varredura (MEV). Verificaram-se diferentes superfícies, em diferentes parâmetros de usinagem e profundidades estabelecidas, observandose a subsuperfície do material.

Aug 17, 2017

By João Batista Ribeiro Martins, Érica Simões Rodrigues, Ramiro da Conceição do Nascimento Júnior, Marcos Tadeu D’Azeredo Orlando

In order to guarantee the quality of the sinter and process control some measurements are made such as RDI and FeO (Fe2+). However, the behavior of sinter during reduction in the blast furnace is not always understood, when it is analyzed only metallurgical, physical and chemical quality. Therefore, it is necessary to find alternative techniques to understand more this behavior. In this work four experimental trials were performed to obtain sinter samples with different FeO (Fe2+) contents. Optical microscopy was performed to identify and quantify the phases in sinter and to evaluate the magnetic behavior of each one, the Magnetic Susceptibility technique was used. The results obtained between Optical Microscopy, Magnetic Susceptibility and quality parameters were compared and then was identified that Magnetic Susceptibility may be an alternative to help the understanding of sinter behavior in Blast Furnace.

Oct 1, 2019

By Ralph L. Brown

The chemical properties of the unsaturated members of the aliphatic series of hydrocarbons are such as to render them " made to order" starting points or basic . materials for the synthesis of hundreds of important organic chemicals . The tremendous quantities of these unsaturated compounds that are being produced daily in the various coal carbonization and oil refining processes , and which at present have little value other than that of fuel , render a survey of the identity and ex- tent of occurrence of these compounds important from the viewpoint of economic utilization and resource conservation The increased need of liquid fuel and the relatively early exhaustion of petroleum resources will eventually require every utilization of liquid fuel products obtainable directly or indirectly from coal . Accordingly , the Bureau of Mines took advantage of an opportunity for examining the gaseous unsaturated hydrocarbons found in the gas obtained when a mixture of water- Collection of the material gas tar and coal is distilled in a gas-making retort . for examination was made possible through the courtesy of the Trent Process Corporation , Washington , D.C. , which was at that time carrying on at the Georgetown Gas Works , distillation of " amal gams " prepared from various coals and oils by the Trent process for cleaning coals . Kanawha gas coal ( 70%) and water gas tar ( 30 % ) from the Washington Gas Light plant were used in the " amal gam" being distilled at that time . The results obtained in this examination are presented here .

Feb 2, 1922

By Alexandre Furtado Ferreira

O presente trabalho descreve o desenvolvimento de um modelo matemático de conservação de massa e energia tendo como base a medição intermediária da sublança (Modelo Dinâmico). O modelo utiliza como dados de entrada informações sobre massa e composição da carga metálica, valores adicionados de fundentes na corrida e as informações obtidas com a medição intermediária aos 88% do sopro de oxigênio calculado pelo Modelo Estático. O algoritmo foi desenvolvido em C# e está integrado na rede de Nível 2 da CSN. Os resultados de acerto simultâneo de temperatura e carbono final de sopro obtido pelo modelo dinâmico foram superiores ao Modelo Estatístico até então utilizado. Tal fato permitiu a redução do ressopro decorrentes de imprecisão do modelo e ganho em produtividade.

Aug 17, 2017

By João Domingos Guimarães de Athayde Júnior

A prática de desoxidação dos aços durante o vazamento, na qual se utiliza o alumínio como desoxidante é bastante difundida entre os aciaristas. Entretanto, gera-se como produto da desoxidação a alumina 2 Al + 3 O = Al2O3(s). Na maioria das vezes, a alumina compromete a qualidade interna do produto, assim como a lingotabilidade do aço líquido elaborado. Estas inclusões não metálicas contribuem para a obstrução da válvula submersa durante o lingotamento. Visou-se neste trabalho avaliar o potencial da substituição de parte do alumínio pelo coque na desoxidação parcial dos aços baixo carbono acalmados ao alumínio durante o vazamento do metal dos convertedores para a panela. Após o desenvolvimento da metodologia e do procedimento operacional, utilizou-se o coque como pré desoxidante em 868 corridas, no período de 09/2014 a 02/2015, sem a ocorrência de reações durante a adição de coque no vazamento e sem o comprometimento do acerto da composição química.

Aug 16, 2017

By Guangshi Li, Xionggang Lu, Xueliang Xie, Xingli Zou, Yuyang Bian, Hongwei Cheng, Kai Zheng, Changyuan Lu

The corrosion resistance and corroded microstructure of MgO-C refractory in molten slag are investigated by immersion test in muffle furnace at 1600 °C . The microstructure and chemical compositions of the specimens after erosion experiment are characterized by scanning electron microscope (SEM) and energy dispersive X-ray (EDX). The results confirm that the oxidation of graphite is the most important degradation mode of MgO-C refractory. The structure of the refractory material is damaged due to the decrease of graphite, as a result, the periclase substrate reacts with the molten slag directly. The corrosion process is controlled by the dissolution of the refractory materials into slag, low melting point oxides are therefore generated which lead to the damage of MgO-C refractory finally.

Jan 1, 2015

By Luiz Afonso Andrade, Pablo Amâncio de Freitas, Ana Patrícia Andrade Jaccard, Eduardo Cezar Ribeiro, Ana Christina Pitard Lima, Rodrigo Ribeiro de Souza

A análise dos carvões em mistura é de suma importância para redução dos custos e controle de qualidade de uma coqueria, esse trabalho trata da influência da cominuição comum de carvões de diferentes ranks, assim como suas implicações no processo de amostragem e consequentes desvios nas análises. O processo de produção da mistura de carvões na Ternium Brasil possuía um desvio não rastreado entre matéria volátil resultante da amostragem automática da mistura de carvões e a matéria volátil esperada pelo resultado da média ponderada dos carvões individuais no recebimento, para tal foram estudadas todas as etapas do processo de produção da mistura de carvões desde a variação dos carvões em pilha, escoamento em silos e na etapa anterior e posterior a britagem. Os dados foram comparados e foi feito um plano de ação para redução do desvio.

Oct 1, 2019

By P. Lan

Gold is often associated with arsenopyrite in many refractory gold ores. The selective recovery of arsenopyrite by flotation is therefore necessary in order to maximize the recovery of gold. However, the complexity of arsenopyrite flotation often makes it difficult to obtain a high recovery from real lean gold ore. This paper presents the results of arsenopyrite flotation by ultrasonic pretreatment in micro flotation experiments and bench scale flotation tests. The tests showed that pure arsenopyrite exhibited low natural floatability due to the oxidation on the mineral surface under ambient conditions. Using ultrasonic pretreatment, the oxidation film was ruptured and the floatability was enhanced greatly. The presence of Fe (III) was found to inhibit the flotation of arsenopyrite and this depression was also removed by the ultrasonic pretreatment. This result explained why the arsenopyrite in real ore is often difficult to float and how ultrasonic pretreatment can effectively improve the arsenopyrite flotation in real gold ores. Guanidine (GMM) was found to be a superior collector for arsenopyrite in acidic medium and xanthate in alkaline medium.

Jan 1, 1998

By G. Y. Chin, M. T. Dolan, W. L. Mammel

We have obtained by computer methods the solutions of the Taylor analysis1 for axisymmetric flow in bcc metals. Four modes of slip have been treated in detail:2-4 (111), {112}(111), {123}( 111), and a mixture of all three. In addition to obtaining anisotropy of strength data for randomly oriented or textured polycrystalline material,4 we have also obtained the lattice rotation resulting from slip on the predicted systems. The patterns of lattice rotation are essential to an improved understanding of texture development during deformation. The present note shows the results of lattice rotation for 5 pct axisymmetric compression, for fifty-two axial orientations distributed at 5-deg intervals throughout the standard stereographic triangle. The data are presented in Figs. 1 to 4 for the four modes of slip. The lattice rotation is indicated by a vector, the ends of which correspond to the positions before and after the deformation. The different vectors emanated from a given orientation represent different combinations of five slip systems that satisfy Taylor&apos;s minimum shear criterion.&apos; Fig. 1 shows the results for {110}< 111> slip. They are similar to those obtained by Bishop5 for the case of (111 )(110) slip in axisymrnetric tension, since in axisymmetric flow the sense of lattice rotation for {111)( 110) in tension is the same as that for (110) (111) in compression. The pattern of lattice rotation may be divided into three regions: region A in which the rotation is toward [100]; region B, toward [lll]; and region C, toward either [ loo] or L lll]. Although some slip combinations in region C lead to [1101, the latter is not stable as continued activity of the same combinations will eventually move the axis toward [loo] or Llll]. It may also be noted that [loo] is itself not stable. However, close inspection of the vectors in region A shows that it is impossible for an axial orientation within A to rotate outside its boundary. Hence after heavy compression, all orientations from A and some from C are expected to form a diffuse band in the [100] vicinity. By far the largest region is B. Here all orientations rotate to [lll], which is a truly stable position. Thus the [111] texture component is expected to be rather sharp. For the case of (112 }( 111) slip, Fig. 2, region C is enlarged at the expense of A, with B about the same as for {110}( 111) slip. A significant difference, however, is that [loo], as well as [Ill], is now truly stable. Fig. 3 shows the results of slip on {123}( 111) systems. Region B is substantially enlarged at the expense of C, with A being intermediate in size between the {110}(111) and {112}(111) cases. Like the case of {110)( 111) slip, [100] is itself unstable. However, the lattice rotations here are confined to less than 5 deg; hence it may be considered "stable" for practical purposes. Finally, Fig. 4 shows the results of mixed slip. Here region B is the largest, and C the smallest, of all the cases considered. Both [loo] and [ill] are stable. The behavior of the three corner positions is, in fact, identical to the case of {112)( 111) slip, Fig. 2; it turns out that in these positions for the mixed slip case, all the active slip systems (based on Taylor&apos;s criterion) belong to pure {112}( 111) .4 In summing up the results for the four modes of

Jan 1, 1968

By Kim Verbeken, Evelien Van de Steene, Marc Verhaege, Jeriffa De Clercq

"AbstractThe industry is confronted with stricter discharge levels and an increasing awareness to avoid toxic waste (such as heavy metal containing sludge obtained in physicochemical water treatment) and recover valuable metals. This can be realized by ion exchange or by electrodeposition. Both techniques however show an optimum concentration range to efficiently remove and/or recover metals: electrolysis can recover the metal in its metallic form but suffers from low efficiency when applied to diluted solutions, whereas ion exchange can only be applied economically in the low ppm range.A combination of ion exchange followed by electrodeposition was applied to an industrial wastewater. The strong acidic ion exchange resin was stripped with H2SO4 giving a solution of 9g/L nickel. From this solution, nickel was electrodeposited in an ammonia buffer on a Ti-mesh cathode with high current efficiency. It is shown that organic compounds (surfactants, brighteners, …) present in the industrial wastewater do not influence the recovery process.IntroductionAlmost all rinse waters emerging from metal plating plants are generated during the washing operation of plated materials. These solutions with low metal content must either be recycled within the process or be discarded to the surface water after decreasing their metal content to acceptable levels determined by the local environmental regulations, which become more and more stringent. Today, the most commonly used practice is a physico-chemical treatment (precipitation) and a resin post treatment to meet the standards. A more sustainable approach should use a technology to recover efficiently the metal or metal salt without the production of sludge and the effluent should be consistent with environmental regulations."

Jan 1, 2008

By Donn A. Calder, Wayne C. Henderson

The Calmet Process for extraction and recovery of gold and silver from concentrates and high:grade ores has been a commercial reality for over two years. During that time period, almost seventy-five different concentrate (or ore) types have been processed in approximately 200 separate lots (a total of almost 2000 short tons). During commercial operation of the process at the plant in Fountain, Colorado, recovery of gold and silver into <lore' has averaged almost 93% for gold (range 81-98%) and over 90% for silver (range 76-97%) based on a fire assay target and calculated head values.

Jan 1, 1998

By WILLIAM M. CROSS, ALBERT ROMKES, BERNARDO MORENO BAQUEIRO SANSAO, Jon J. Kellar

In this research study, the interaction of particles with substrates of different roughness magnitude was investigated. Particle surface treatment, relative humidity (RH), and surface roughness levels were controlled in order to achieve separation of different particles by applying removal forces. Three different approaches to reproducibly roughen surfaces were used. Initially, glass disks were laser engraved to create a reproducible, controlled roughness substrate. However, the laser engraving method produced surface features that were much greater in scale than the particles. These scale differences were such that the substrates produced were not of value to this research. The second option investigated to induce reproducible substrate roughness was to scratch the glass disk using sandpapers of known grain size. A third approach to establish reproducible roughness was to use fine stainless-steel wire mesh substrates. In tests with sanded glass disks, the interfacial energy of plasma-cleaned (hydrophilic) glass beads had a high variation at 40% RH, showing non-uniformity of area of contact between particles and substrates. As the RH increased, it was expected that the interfacial energy of hydrophilic particles would increase, but this behavior was not observed. In addition, comparing the interfacial energy results of hydrophilic particles with hydrophobic particles, a region with significant interfacial energy difference was not identified. In the case of the stainless-steel mesh substrate, the mesh asperities and particle dimensions were comparable. Thus, the smaller particles had more area of contact with the substrate than the larger particles. For the plasma-cleaned (hydrophilic) beads, the recovery values had an average of 92.5% recovery when the RH was between 46 and 85%. For the hydrophobic beads, the average recovery was 19.0% when the RH was between 46 and 75%. Thus, the hydrophobic characteristic of the particle influenced its lower interaction with the mesh substrate. The difference in recovery can be exploited to achieve separation of particles based upon adhesive forces.

Nov 30, 2021

By E. W. Garner

THE greatest problem confronting business managers in modern times is not production, but distribution. It would be easy to expand productive output, but it is difficult to find markets for all that is produced. The fundamental source of economic difficulty, in the view of many observers, is a lack of proper balance between productive capacity and consumptive capacity. The studies conducted by the Brookings Institution on the general subject, "The Distribution of Income in Relation to Economic Progress", have led to conclusions of far-reaching significance, which may be summarized briefly as follows: (1) We have never lived beyond our economic means or capacity. (2) We have not been suffering from general overproduction. (3) We have not as yet reached a stage in our economic evolution at which it is possible to provide adequate standards of living for everybody. ( 4) It would require less than a 25 per cent increase in purchasing power among the masses to absorb our full productive capacity. (5) Production-curtailment programmes-whatever their merit in meeting temporary maladjustments-can only lead to national impoverishment. (6) Our inability to find markets adequate to absorb the full output of our productive establishments is explained by the unequal distribution of income and consequent restricted flow of purchasing power through consumptive channels. (7) The slow rate of growth of consumptive demand serves to retard the rate at which new capital is constructed, and hence the rate of economic progress. (8) The primary need is a rapidly expanding total income, and a broader diffusion of this income among the masses of the people. (9) A broader diffusion of income can best be achieved by reducing prices as rapidly as increasing efficiency will permit. That is to say, the benefits of technological progress, mass production, and low unit costs must be promptly passed on to consumers in the form of lower prices-giving more for each dollar.

Jan 1, 1936

By E. J. Gleim

An important phase in the Bureau of Mines investigation of electrical machines designed for operation in gassy coal mines is testing enclosures of electrical components for explosion-proof qualities. In brief, this testing consists of filling and surrounding the enclosure with an explosive atmosphere of methane and air and then igniting the atmosphere within the enclosure to determine (1) Whether the resulting explosion is confined without discharge of flame; (2) whether the enclosure walls are permanently distorted; and (3) whether excessive pressures are developed within the enclosure. Ordinarily, the pressures encountered in routine testing do not exceed 100 pounds per square inch gage. Hence, the designer of the machine does not have too much difficulty in taking corrective measures to prevent flame discharge and distortion of the enclosure. Occasionally, however, the explosion pressures greatly exceed 100 pounds. Then the goblet of the designer may not be solved so readily, From experience over the year 0, the testing personnel often can predict that certain construction will result in high. Pressures, but, only in a very general way, has it been possible to advise designers what modifications might be made to reduce the explosion pressures to normal values. For example, if high pressures were developed in a motor starter having a partition with an opening through it, some enlargement of the opening may appear to be the logical procedure, but it has not been- possible to give information concerning the exact amount the opening should be enlarged to prevent development of high pressures .

Jan 1, 1952

By Michael Tenenbaum

THE importance of semikilled steel as a high tonnage grade has long been recognized. The increasing severity of the applications for which semikilled steel is used makes it desirable to obtain further information regarding the features of open hearth practice and ingot structure that can affect steel performance in subsequent rolling and fabricating operations. Accordingly, an investigation is being carried out studying the structure of various types of semikilled steel ingots. This paper reviews some of the observations made and information gathered in this investigation. By definition, semikilled steel may be considered to include all nonrimming steels in which the natural shrinkage occurring during ingot solidification is offset to an appreciable degree by gas formation. Accordingly, this type of steel includes the entire range intermediate between rimmed and fully killed steel. The resultant ingot structures range from those of steels that have been capped to suppress a weak rimming action to those steels that have been killed in the furnace or ladle to the extent that no mold deoxidizer is required. A survey reported to the 1946 AIME Open Hearth Conference&apos; reviewed the practices being used at 28 major plants for the deoxidation of semikilled steel. It was found that most plants divide the deoxidizing additions between the ladle and the mold many of the plants adding only minor amounts of deoxidizer to the bath or none at all. Silicon, aluminum and titanium were the only elements used for ladle and mold deoxidation. Mold deoxidizers were added as capping additions or as uniformly fed additions. Several practices were reported in which the steel was deoxidized in the ladle to the extent that little or no mold deoxidation was needed. No reference was made to grades capped by using special mold designs or special closures over the top of molds. Accordingly, specific examples of this type of practice will not be considered in this paper. It appeared from this survey of deoxidation practice that semikilled steel can be divided into three types, namely, capped semikilled, in which aluminum is added near the end of pour or after shut-off, intermediate semikilled steels, in which aluminum is fed uniformly throughout the pour, and semikilled steels requiring no mold deoxidation. In an attempt to cover the ingot structures obtained by the range of practices reported in the preceding survey, three series of experimental heats were made using increasing amounts of aluminum, silicon and titanium for ladle deoxidizers. The ladle deoxidizers were added as stick aluminum, 50 pct ferrosilicon and 20 pct ferrotitanium (4 pct carbon), respectively. Two methods of studying ingot structures were used. Ingots were removed from production, burned longitudinally and machined to allow observation of the central pipe and coarse blowholes. During the machining operation much of the finely porous subsurface structure was obliterated. Accordingly, observations were also made

Jan 1, 1947