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By J. Petersen, H. Naderi, H. Zare, M. H. Nikzad, M. Karimi

In the copper electrorefining process, the dissolution of anodes is significantly reduced or even stopped when the passivation phenomenon occurs. The results of this phenomenon are increasing energy consumption, residual formatting, and voltage levels in the cell. In this study, the electrochemical behaviour of blister copper in the presence of sodium persulfate (PDS) was studied. The electrochemical methods of LPR, Tafel, and Electrochemical Impedance Spectroscopy (EIS) were used. The results showed that the addition of sodium persulfate activates the electrode surface and increases the open circuit potential. In the presence of PDS, the polarisation resistance of the electrode shows an increasing or decreasing tendency, based on the PDS concentration. This tendency is probably due to the formation of surface layers (such as slime layer or copper sulfate) and dissolution of this layer at various concentrations of PDS. The lowest polarisation resistance of 1.8 ohms and the highest corrosion current of 60.6×10-3 and 36.6×10-3 A/cm2 from LPR and Tafel techniques respectively were obtained at the concentration of 40 g/l PDS. Based on the results of potentiodynamic and electrochemical impedance spectroscopy tests, the addition of sodium persulfate to the solution reduces the corrosion resistance, therefore the passivation time of the blister copper anode increases. Keywords: Blister copper, electrorefining, sodium persulfate, anodic passivation

Jan 1, 2020

By Natal Nerímio Regone

Pelo processo de anodização forma-se uma camada de óxido sobre o substrato de alumínio através de um processo eletrolítico. Após a anodização do alumínio, pode-se colori-lo para obter um bom acabamento externo, aliado a maior durabilidade. O objetivo deste trabalho foi determinar as condições de anodização e colorimento por corrente contínua e pulsada no alumínio, e avaliar as vantagens da anodização e colorimento em função das propriedades do filme. A camada de óxido de alumínio e o revestimento colorido foram caracterizados por potencial de circuito aberto, polarização potenciodinâmica, e por espectroscopia de impedância eletroquímica. Pela solução utilizada na eletrodeposição obteve-se uma cor marrom sobre a camada anódica. As medidas eletroquímicas mostraram que a anodização e o colorimento processados por corrente pulsada tiveram melhores resultados de resistência a corrosão.

Aug 8, 2018

By Michel Rodrigues Leite

A origem do enxofre no aço está relacionada com a utilização do coque para a produção de ferro-gusa. Para a maioria dos aços são requeridos baixos teores de enxofre porque este elemento afeta a isotropia das propriedades mecânicas, notadamente a tenacidade. Este trabalho tem como objetivo avaliar o impacto do teor de enxofre dos carvões metalúrgicos no seu valor em uso. Valor em uso é o preço máximo que uma determinada empresa está disposta a pagar por um material de substituição, sem deteriorar os resultados econômicos. A dessulfuração de ferrogusa e o impacto do teor de enxofre dos carvões no seu valor em uso foram avaliados considerando utilização de escórias sintéticas. Os resultados mostraram que para 4 das 5 condições avaliadas os valores em uso dos carvões foram maiores que a referência do mercado. Considerando o preço do carvão de referência igual a 120,00 $/t o valor em uso referência do mercado, assumindo 0,10% de enxofre adicional no carvão é de 118,80 $/t. Nas simulações de dessulfuração com escória sintética os valores em uso foram estimados entre 118,55 $/t e 119,34 $/t.

Aug 16, 2017

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014

By Henry W. Brandt

What is the most practical method for storing a huge quantity of crude oil for a long period of time to assure availability if conditions curtail the source of supply? Underground storage is a logical answer. But can abandoned mines be used for this purpose? That is the proposal Fenix & Scisson International, Inc. submitted to the S.F.F. Association (acting in behalf of the Department of Industries of the Republic of South Africa), Johannesburg, South Africa, in October 1966. This engineering and contracting firm with headquarters in Tulsa, Oklahoma, specializes in underground storage; and based upon previous experiences their engineers were reasonably certain that a mine could be used for storing crude oil. The answer subsequently proved to be "yes." The result was con- version of a coal mine to provide storage for a quantity of crude oil which is the equivalent of a sizeable oil field. The total cost of purchasing, testing, and converting the mine was less than 15 percent of the cost of conventional steel tanks. Operating and maintenance costs are proving to be about 2 percent of those experienced at two large tank farms owned and operated by the Association.

Jan 1, 1973

By E. Szelag

The adsorption and stabilization of mineral dispersed systems by using Pluronic copolymers with different molecular weights and EO content has been studied. The role of sequential adsorption of EO-PO copolymers and cationic surfactant (CTAB) on the carbonate particle properties and in determining the stability of their suspension was studied with particular attention to the conformation of the polymer at the solid-liquid interface. The purpose of this work was to investigate the flocculation phenomena, influence of polymer molecular size on stability of suspensions of magnesite and dolomite and the effect of addition mode of polymer and surfactant. The suspension stability measurements and the determination of sedimentation speed were carried out using an optical analyser (Turbiscan). In most of investigated cases, the biggest floccs and the fastest sedimentation were found for low concentrations of copolymers.

Jan 1, 2014

By D. F. Scott

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE REGION of Western Canada covered by this re-port lies between the Precambrian rocks of the Canadian Shield and the structurally deformed rocks of the eastern Cordillera, extending northward from the international border to the 60th parallel. It is some 487,000 square miles in area, with a total sedimentary fill of about 535,000 cubic miles0>. It includes parts of the prairie provinces of Manitoba, Saskatchewan and Alberta and the northeast corner of British Columbia and forms part of the geological region known as the Interior Platform, commonly referred to as the Western Canada Sedimentary Basin. The bedrock comprises carbonates and evaporites of Paleozoic age that lie on Precambrian crystalline rocks and are over-lain by a relatively thick blanket of Mesozoic and Tertiary elastic rocks. The nearly flat-lying bedrock, covered by a thick mantle of glacial drift, forms the Interior Plains physiographic province."

Jan 1, 1970

By Russell Levens

A strategy for prioritizing mining health and safety research by evaluating the potential for risk reduction through interventions is proposed. Mining has one of the highest incidence rates of injury and disease found in major industries. The main premise of this paper is that often the best opportunities to reduce these rates are not revealed by retrospective analysis of injury and illness data. Instead, a proactive approach is needed that accounts for risks to specific hazards that can be abated by engineering or behavioral interventions. The process proposed here begins with development of prospective interventions. The degree of reduction in risk to be expected from an intervention then is determined from statistics on the mining worker population, the expected degree of success of the intervention, and the expected change in the severity of injuries resulting from the intervention. Three disparate mining health and safety concerns are presented to demonstrate common problems in assessing risks of injury and illness and describe additional data needs. Information on events preceding injuries and illnesses and more detailed demographic data on the mining work force are needed to analyze injury and illness data more precisely. Detailed information on exposure to specific hazards is necessary to evaluate the potential for an intervention to reduce risk of injury or illness.

By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013

By W. M. Deaton

[Knowledge of the ten?erat~rre to wkich n gas ullder3atur~ted xith re- srplc t to water vapor may be cooled before the water p?f 11 3egin to condense 8 is desirable .and frec-uently iq neceTsarp in nWy resenrch c~d industri~J activities. This tenperrture, the dew point, i s 2 nrrticulnrly innortmt factor in high-pressure gas transmission, PS water cox?-ensate any interfere i with the flow of gos in the line. Sonetimes this interfexnce is due only to the yresence of the liquid water. At other tfncs, under certain condi- tions of pressure and teriperature, the cogdense;? water cn!nhines with the 93 to farm solid .y2: hydrctes. These solid coar~ouncis ma:/ ccllect in sufficient quantit;. to rehce materially the c~xrying cap.citg of the pipe line or ever, to ply thc line coimletelp. ]

Jan 1, 1938

By Emil Szaks

[A great number of papers have been presented at various Engineering Society meetings on the Unit Train subject. Moat are descriptions of facilities that have been constructed or are abort to be built. Many describe the facility as being the World's fastest, newest, largest, incorporating the latest technology and so forth, Many are duplications of installations that have been recently constructed, sort of carbon copies but perhaps arranged differently. The trend has been to incorporate loop tracks, rotary dumpers, indexers and, of course, the snivel coupler equipped unit train. How that the energy crisis has increased the use of coal, there has been a tremendous Increase in applications for permits to construct rail to river coal loading facilities. This paper is different. It does not describe any single existing facility, but is given to alert prospective terminal owners and engineers that there are items that require considerable study and evaluation beside merely selecting an indexer, car dumper, stacker, ship or berg loader and so on. An important item is the selection of the railway car which in turn can affect the selection of the method of loading and unloading. Let us list a few of the items that should be considered and discuss the areas that require examination:]

Jan 1, 1979

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018

By Ronald L. Haxby

This report presents a refractive seismic technique for evaluating the strength of rock within an open pit bench. A concept of correlating rock strength and seismic velocity is discussed and a method of predicting the degree of fragmentation of a pit bench is introduced, Figure 1 shows the area of interests [ ] Most of the work was performed while completing graduate studies at the University of Arizona.

Jan 1, 1967

By D. B. Dreisinger, M. R. Tavakoli

"Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the pregnant leach solution, and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. This paper reviews the purification of vanadium leaching solution using organophosphorus, solvating, and amine extractants. This review focuses on vanadium separation from iron, molybdenum, and uranium, which are often present in vanadium resources such as primary ores, fly ashes, and spent catalysts.RÉSUMÉ Le vanadium est produit à partir de diverses sources. Ce métal est connu pour permettre des solutions aqueuses de spéciations complexes en fonction de la concentration du vanadium et du pH. En tenant compte de la méthode de lixiviation, des impuretés dans la solution mère de lixiviation et du produit de vanadium planifié, divers agents d’extraction et schémas de traitement peuvent être mis en oeuvre pour purifier la solution. Le présent article étudie la purification de la solution de lixiviation du vanadium au moyen d’extractants organophosphorés, solvants et aminés. L’étude cible la séparation du vanadium du fer, du molybdène et de l’uranium, lesquels sont souvent présents dans les ressources de vanadium telles que les minerais primaires, les cendres volantes et les catalyseurs usés."

Jan 1, 2016

By D. Leeb

El presente texto describe el principio de ensayo de dureza para los materiales metálicos, el cual se basa en lanzar un cuerpo móvil con una energía constante contra la probeta en reposo, produciéndose un rebote. La medida de la energía que aún queda en el cuerpo (energía residual) después del rebote es una medida de dureza. Dicho proceso comprende tres etapas: disparo, choque y rebote. En la fase de disparo, la energía potencial del cuerpo móvil se transformará en energía cinética por caída libre o por distensión de un muelle y el cuerpo móvil choca contra la probeta, a la velocidad de choque. El proceso de choque propiamente dicho se verifica en dos períodos: comprensión y restitución. Finalmente, en la fase de rebote, la energía cinética existente en el cuerpo móvil se vuelve a transformar en la energía potencial correspondiente a la magnitud del recorrido de rebote, es decir, a la altura o recorrido máximos de rebote

Mar 1, 1983

By Britta Schoesser, Zdenek Zizka, Markus Thewes

"The support pressure of a slurry shield corresponds to the in situ earth and groundwater pressure to ensure the stability of the tunnel face. The support fluid (bentonite suspension) penetrates from the excavation chamber into the pore space and transfers the support pressure to the granular structure of the soil within this zone. At the same time, the cutting tools rotate periodically with the cutting wheel and remove the penetrated soil up to a certain cutting depth at the face. Shortly after the tool passing, the penetration process starts again. Both, the support pressure and the soil excavation, act in the same direction at the tunnel face, but they are subject to different cyclic intervals. This relationship between the time needed for the transient penetration process and the interval of the cyclic passage of the cutting tools at a local point at the face is examined and the impact onto the global face stability is discussed. INTRODUCTION Slurry shields are usually deployed for excavations in soft ground. The main application range is in non-cohesive soils (DAUB Recommendations 2010). In non-cohesive granular soils, the tunnel face stability is one of the key design issues. The slurry shields make use of pressurized bentonite suspension (slurry) to support the unstable tunnel face. To support the tunnel face effectively, the slurry pressure has not only to counter the groundwater pressure, but also has to be transferred into an effective stress to support the soil grains. In general, the pressure transfer can be achieved in two ways: (1) with a thin flexible membrane or (2) a penetration zone. The membrane (1), called filter cake, creates a thin impermeable layer from bentonite particles directly on the tunnel face, and enables a transformation of excess slurry pressure into effective stress. In case of penetration zone formation (2), the excess slurry pressure is transferred onto the soil skeleton along the entire penetration depth by shear stresses between slurry and soil grains. These theories, presently applied to assess the pressure transfer on the grains within slurry shield tunnelling, are originating from diaphragm wall technology, e.g. Müller-Kirchenbauer (1977), Kilchert and Karstedt (1984). They assume that the support pressure transfer mechanism is built-up instantaneously on the whole tunnel face and is not damaged or influenced by the interaction with excavation tools. These assumptions are valid for conditions during the excavation of diaphragm wall trenches whose bottom is excavated and the walls of the trench are supported. At the tunnel face of a slurry shield, the support suspension acts on the same area as the soil excavation. Hence, the conditions on the tunnel face are transient (time dependent) due to the time period needed for the penetration process of the slurry and the periodical damage of the pressure transfer mechanism by excavation tools (Fig. 1a)."

Jan 1, 2016

By A. Andreas

The transportation of mine products incurs a cost which can have a significant bearing on the competitive position of the product. This statement not only holds true for the transportation of the finished product but certainly as much for the in- plant haulage of the raw materials. Extensive literature is available both in North America and Europe on all aspects 02 these questions and to cite only a few of them: Pipelining of slurries, oil and gas, shipping of minerals and oil from the Arctic by icebreaking tankers, airlifting of metals or concentrates, etc. This paper is concerned with movable crushing plants as opposed to stationary and their influence on the in-plant transportation, that is trucks vs. belts.

Jan 1, 1973

By Earl L. Rau

Although the Sagasca deposit has been known for 76 years, the property was never put into successful operation because of various adverse factors including low market price for copper, legal entanglements, unsuccessful financial arrangements, and an inadequate metallurgical process. Late in 1963, Continental Copper & Steel Industries, Inc., obtained legal control of this property. Since that time there has been a concentrated effort to complete the necessary mine appraisal, process development, and engineering design, and to solve the legal and financial problems to bring this property into production.

Jan 1, 1970

By M. P. Board

The U.S. Bureau of Mines, under a cooperative agreement with Hecla Mining Co., conducted a rock mechanics study at four widely spaced horizons in a deep mine shaft in northern Idaho. The objective of the project was to measure and analyze rock deformation and lining behavior during construction of a deep shaft in a high in situ stress field within an isotropic rock mass. Rock mass displacements were monitored with multiple-position borehole extensometers. Liner stress and strain were measured with concrete pressure cells and embedment strain gauges. This report discusses the general trends and magnitudes of data from the four test sites, and relates the data to a proposed anisotropic constitutive model for the rock mass. A design procedure is then outlined for specifications of liner thickness and support installation sequences for future shaft sinking.

Jan 1, 1989

By Mario Samamé Boggio

El presente texto señala el procedimiento adecuado para la aplicación de técnicas de información general al caso de empresas mineras. Para ello, se revisa a través del ordenamiento de los procesos, la explotación y el aprovechamiento minero. Las variables que revelan el comportamiento de estos procesos, son la base para construir y aplicar un modelo de información gerencial. Asimismo, los procesos son el conjunto de datos que facilita la toma de decisiones respecto al cumplimiento de los programas aplazados. Dentro de estos tenemos: el de abastecimiento y producción, así como se demuestra el sistema de información gerencial: objetivos y características y los reportes.

Jul 1, 1980