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Equilibrium calculational software programs can be effectively utilized to illustrate the importance of activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation to students studying hydrometallurgy. The calculational program STABCAL will be demonstrated. illustrative examples for the creation of diagrams such as EH-pH, activity or concentration-pH and activity or concentration-EH will be presented to demonstrate the fundamentals of real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Applications will include treatment of Acid Mine Drainage (Berkeley Pitlake water and sediments), mass balance potential/pH diagrams, leaching and selective separation of metals from electroplating sludge, metal adsorption at femhydrite surfaces, and flowsheet development for treating mercury sulfide K106 sludge.

Jan 1, 2002

By Edward D. Thimons

A remote-actuated stench gas fire-warning system has been designed and tested by the Bureau of Mines. This system makes use of the hard-wire network for the mine's phone pager system, thus greatly reducing the system cost. By locating stench gas canisters with remote-actuation release capabilities near working sections, the fire-warning time can be greatly reduced. In a test of the system in a Missouri lead mine, the time required to warn miners of a fire at two working faces was reduced from about 20min with the conventional system to less than 4 min with the remote-actuated system.

Jan 1, 1984

By G. E. Anderson

THE Asientos-Tepezala district is in the north of the State of Aguascalientes, about 30 miles north of the city of Aguascalientes, the capital. The district is reached by a standard-gage railway on the west side through the junction, Rincon de Romos, which is on the main line of the National Railways of Mexico from El Paso to Aguascalientes. The terminal is Tepezala. On the east side a narrow gage connects Asientos with the junction, San Gil, on the main line, Asientos to San Luis Potosi. Tepezala on the west side of the Asientos hills is about 2 miles from Asientos on the east side. The area between the two mining centers is separated by a low subued divide which forms the central part of the hills. The district is in a group of isolated hills surrounded by characteristic bolson plains. The hills rise above the surrounding plains about 6500 to 10,000 ft.; the highest peak is Alta Mira. The two mining districts lie somewhat upon the flanks of the hills at about the same elevation, 7200 ft. The district is an old one and has been known since early in the 17th Century when the mines were worked by the Franciscan Monks. Their mining operations which were limited to the oxidized ore above the water level, consisted chiefly in extracting silver from the Santa Francisca vein. To judge from the old workings and the remains of surface plant, the operations were on a large scale. By modern mining operations since about 1900, the various mines of the district have been one of the principal sources of ore for the smelter located at Aguascalientes.

Jan 2, 1926

By P. Zhang

The use of phosphate depressants in the cationic flotation of silica from francolite in the Florida phosphate industry is rarely practiced. The occasional use of gelatinized starch derivatives and pH adjustments to assure a slightly alkaline flotation feed slurry pH have been used in some processing plants to improve selectivity. This paper presents a preliminary laboratory comparison of several potential phosphate depressants for use with the flotation of siliceous phosphates. It was found that starch is ideal for floating fine (-35 mesh) silica from phosphate, while sodium tripolyphosphate may be the best for coarser (+35 mesh) feeds.

Jan 1, 2009

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

By R. G. Robins

The processing of gold bearing sulphide minerals which contain arsenopyrite and various complex arsenic sulphides results in arsenic containing emissions and effluents which are suspect in relation to clean air and clean water standards. Removal of arsenic from gaseous emissions is briefly reviewed. The use of lime to stabilise aqueous residues as either calcium arsenate or calcium arsenite is shown to be inadequate for long term disposal since both compounds are converted into calcium carbonate due to the influence of carbon dioxide in the atmosphere. Mixed calcium arsenate-phosphate residues are similarly unstable, but present better stability than the straight calcium compounds. Alternative disposal methods are reviewed whereby the arsenic is converted to more stable compounds, such as barium arsenate, titanium (IV) arsenate, and arsenic sulphide.

Jan 1, 1984

By R Small, S Combrinck, R Lindsay

Maintaining your competitive edge in the growing Australian mining sector today is an arduous task. With an ever increasing demand to extract more ore, safely, complete visibility throughout the blasting cycle has become vital to any operation. To achieve this requires full two way communication with every detonator during the testing and programming cycle, as well as, inside the firing window. Concerned with an increase in the number of incidents involving mining equipment, uncovering and digging into unknown misfires on-sites across Australia, Black Star Mine made the decision to embark on the use of electronic detonators to eliminate this hazard. With this safety goal achieved, the mine set about using the added benefits of electronic detonators to improve their drill and blast processes with impressive results.CITATION:Combrinck, S, Lindsay, R and Small, R, 2012. Eliminating unidentified misfires at Xstrata ZincÆs open pits through the application of electronic detonators, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 27-30 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By R. W. Lawrence

"In the past year, BioteQ Environmental Technologies Inc. have initiated design and construction of new plants to add to an existing list of plants that utilize the BioSulphide® and ChemSulphide™ process technologies for metal recovery and water treatment. In these plants, low cost biogenic sulfide or, in some cases, chemical sulfide reagent is used to selectively remove metals from contaminated water. The process produces high grade, marketable, metal sulfide products even from low grade feed solutions. The revenues generated from the sale of products can allow for water treatment at a profit in some cases, offset treatment costs in others, and generally reduce sludge disposal and management costs. The effluents produced from the process can meet stringent environmental standards. Current plants in operation and under construction range in sulphide demand from 50 kg/day to 3.7 tonnes/day, with the feasibility of larger plants with sulfide demands ranging from 6 to 43 tonnes/day under review.Biogenic sulfide reagent can also be considered for other applications in hydrometallurgy and mineral processing. Uses under consideration by a number of mining companies include: (1) replacement of sodium hydrosulphide in the SART process for cyanide regeneration and copper recovery in the processing of gold-copper ores, and (2) replacement of sodium hydrosulphide for use in the separation of copper and molybdenum in flotation. Biogenic sulphide, produced on demand at site, offers significant cost savings and provides the additional benefit of improved safety due to the elimination of the transportation, handling and storage required for chemical sulphide reagents.This paper reviews the applications of the BioSulphide® and ChemSulphide™ technologies for water treatment and metal recovery, and introduces projects where biogenic sulfide can be applied in hydrometallurgy and mineral processing."

Jan 1, 2007

By R. K. Netolitzky

The Weedy Lake, Tower Lake, and Wedge Lake gold deposits illustrate contrasting styles and different ages of mineralization within the same district. The discovery of these deposits was the result of systematic exploration of gold occurrences noted during research of assessment files. The Weedy Lake and Tower Lake depo its reflect a late-stage gold mineralizing event. The e deposits developed along the same major structural break, and also display simi lar mineralogy and alteration patterns. Mineralization is developed in all the lithologies present. The Wedge Lake property, while having occurrences similar to the Weedy and Tower deposits. has the more important Twin Zone which best fits a volcanogenic exhalative model. The Twin Zone has a complex structural history without a recognizable alteration halo. The setting may be proximal to a hydrothermal vent. Mineralization is hosted within a mixed ulphide/oxide/silicate facies iron formation breccia. and the gold is intimately associated with arsenopyrite. The origin and age of the brecciation is key to understanding the mineralizing event. Traditional prospecting procedures in conjunction with conventional B-horizon soil geochemistry were instrumental in the Twin Zone and Weedy lake disco,•eries. Tower Lake was a prospecting discovery partially defined by previous drill programs. This deposit was also identified by B-horizon oil sampling.

Jan 1, 1986

By A. L. Worthen

This is one of a series of pacers being published by the United States Bureau of Mines, describing mining and milling methods at crushed-stone plants throughout the United States. These pacers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. Although the publication of total production cost might not be advisable in some instances, yet a knowledge of operating costs is essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called o this differentiation in order that there will be no misunderstanding of the scope of the cost tabulations. This paper deals with the quarrying and crushing methods used at the Plainville plant of the New Haven Trap Rock Co., which produces annually between 275,000 and 300,000 tons of trap rock, Although pct the largest quarry operated by the company, it typifies the standard methods used by all the quarries in producing crushed stone and has one or two rather unique operating features. The cost of production at this plant is close to the average cost at all quarries of the company.

Jan 1, 1936

By Douglas R. Piteau

"Assessing the stability of a slope cut in rock is basically a problem of engineering geology - geology, because it involves a sound understanding of the important aspects of geology, such as geological structure, ground water, weathering and other natural phenomena, which all relate to or exist in a geological environment, and engineering, in that quantitative evaluations and calculations are necessary, these being based on mechanics and relating to the strength of the geological materials and the forces causing instability of the slopes. The engineering geologist must make every attempt to. provide, in a quantitative way, information on those geological factors which are necessary for making calculations of the probable stability of the slope. These include numerical assessments of quantities relating to the characteristics of structural discontinuities, rock types, topography, hydrogeology, tectonic history and other environmental factors. Based on the development and extension of these general principles, both preliminary and final slope stability studies of some open pits in South Africa, Swaziland and Zambia have been conducted. Some of the basic concepts and techniques developed to carry these studies out are described."

Jan 1, 1972

By Richard F. Link, George S. Koch

About 50,000 assays of mine samples were required in a preliminary investigation of the distribution of gold, silver, lead, copper, and zinc in two large Mexican mines, the Frisco mine at San Francisco del Oro (Chihuahua) and the Fresnillo mine at Fresnillo (Zacatecas). The feasibility of working with so many assays rests directly on the use of machine processing methods. The purpose of this article is to describe the methods used because machine (or data) processing can also be used efficiently to make the many calculations from mine assays needed in mining operations. No particular originality is claimed for these methods, which are straightforward applications of standard procedures for machine processing. Inasmuch as machine processing is essentially a routine job once it is begun, procedures must be organized more completely than is the case where human judgment can be inserted at every step. Before undertaking any work, it is necessary to decide carefully just which data must be processed as well as the exact results desired.

Jan 9, 1960

By Ingo Kaundinya

"INTRODUCTION Tunnels are important elements of the German federal road network which have to cope with an increasing traffic load especially of heavy goods vehicles. In order to ensure a high availability and safety level for these key infrastructures, big efforts are required by owners and operators in order to keep all infrastructures up to date. This mainly relates to current European regulations regarding tunnel safety (Directive 2004/54/EG) [1] and their national implementation, which must be fulfilled by many existing tunnels. In this context the German Federal Government spends more than 1.1 billion € for the structural and operational retrofitting of more than 120 existing road tunnels. As many of these projects have recently been finished or are still under progress, experiences and best practices could be reported. After the description of current requirements in national standards regarding structural fire protection, the paper gives an example for an upgrade of a tunnel’s fire protection by installing an additional fire protection system, which is a quite costly measure. Another possibility to fulfill current requirements regarding structural fire protection could be the numerical proof of sufficient bearing capacity of a structure. The influence of different fire loads and fire durations on the bearing capacity of typical road tunnel structures have been investigated in a research project funded by the German Federal Ministry of Transport (BMVI) and coordinated by the Federal Highway Research Institute (BASt). The results of this research project have been used to define a procedure how to investigate existing tunnels regarding structural fire protection. Finally, the research results have also been the basis for a current update of national standards for tunnel construction. REQUIREMENTS REGARDING STRUCTURAL FIRE PROTECTION The structural fire protection design of road tunnels is usually based on temperature-time curves of exposure to fire, for simplicity called ""fire curves"". The fire development after fire growth is illustrated with fire curves. Fire curves can be subdivided into a heating-up phase, a fully developed fire phase, and if applicable, into a cooling-off phase (cf. Figure 1). During the fully developed fire, the fire remains at a certain temperature level."

Jan 1, 2016

By S Nie, I Bergqvist, F Ouchterlony

In blasting, a few or many cracks are driven from the borehole into the rock. But what causes the cracks? The most common theory of breakage consists of two stages; first the shock wave causes radial cracks to form around the hole then the gases penetrate into the cracks, and widen them and make them longer. Another theory presented by Brinkmann suggests that the back damage is primarily controlled by shock and that the gas penetration is the mechanism controlling breakout of the burden. He did his experimental work using blasthole liners. Recent research at SveBeFo has examined this matter further. In a quarry a number of benching holes have been blasted simultaneously. In some of these holes tubular Swellex bolts were inflated and decoupled charges put inside the tubes without stemming. Other holes were identically charged but without the lining. Finally some holes were also stemmed. After blasting the cracks in the remaining rock were studied. There was no difference in crack lengths between holes charged normally (no stemming) and holes where the charges were inside the bolts. On the other hand when stemming was used, the crack lengths increased for some explosives but remained the same for an emulsion explosive. In another set up blasted granite blocks were charged in the same way as above. Then we could also measure the bore hole pressure. The pressure gauge consists of a small carbon resistor inside a steel cylinder. It is called LHM (Location-fixed Hydrodynamic Measuring Cup) and is placed at the bottom of the hole. A smaller exit hole from the bottom is drilled for the cables. The paper presents the technique and the results obtained from both the quarry blasting and the blasting of the blocks.

Jan 1, 2001

By Joe B. Alford

Jan 1, 1971

By Khiva Haidar Shauma Tassno, Zulham Ahmad, Farhan Harist Maharesi, Abdullah Badawi Batubara

Blasting operations can use a bulk emulsion explosive (EE) with a formulation based on used oil as a replacement for refined fuel oil. The most commonly employed used oil for making EE is a mineral based used engine oil that passes an impurity content standard. It is known that not all types of used oil are easily incorporated into EE formulations. Impurities in used oil can disturb EE stability resulting in crystallization and phase separation and consequently led to poor detonation quality. In 2024, a poor blast result occurred at an Indonesian mine due to utilization of used oil that was not within specification. A research project conducted from February to April 2025 found that used transmission oil differs from used engine oil in hydrocarbon composition. Transmission oil contains more additives that affect EE stability due to polarity differences and the disruption of colloidal state stability. Lab tests including stress testing and crystal growth observation aided the development of a stable EE formulation based on used oil and used transmission oil. In mid-April 2025, blast evaluations were conducted using the EE that was formulated using used engine oil and used transmission oil. Measurements of velocity of detonation, fragmentation, and digging time, demonstrated high quality EE was produced. Application of used oil in EE revolutionized the capability of mining operations to improve blast sustainability and cleanliness. Through comprehensive research, robust testing, and effective supply chain management, it is possible to replace some portion of refined fuel oil with used oil without compromising blasting performance. The inclusion of used transmission oil broadens the overall used oil specification and increases the volume of recycled used oil available for blasting. The increased volume of used oil available can reduce the amount of waste generated by mining projects while maintaining operational efficiency.

Jan 26, 2026

By C Claassen, R Balusu

Computational fluid dynamics (CFD) models have been developed based upon field data collected from a longwall mine in New South Wales, Australia to study the behaviour of goaf gas flow in both active and sealed goaf areas. A base CFD model was built to represent the goaf situations when the active longwall retreats near the finish-off line. Results from the base model were calibrated and compared against field goaf gas monitoring data. The base model was then used to carry out parametric studies to investigate a number of operational scenarios and their impact on goaf gas behaviour. CFD modelling results indicate that the overall goaf gas flow pattern changes as the operating longwall retreats towards finish-off line. In all cases, oxygen penetration into the active goaf remains high, reaching 15 per cent or higher, even at some 800 m behind the longwall face.The modelling results also indicated that it would be difficult for early detection of an active goaf heating (on the maingate side) based upon CO readings in the return airflow, as the main stream of the gaseous product will be flowing into the sealed deep goafs in adjacent longwall (LW) panels. Monitoring points (such as tube bundles and bag sampling points) should be selected at deep seated seals along the active goaf so that abnormal CO or C2H6 readings can be picked up for early detection and location of potential heating spots; goaf inertisation can be better achieved by injecting inert gas such as nitrogen at deeper points (>200 m) behind the operating longwall; the injection of in-seam drainage methane into the goaf areas will only have a limited impact on goaf inertisation as much of the injected methane will migrate towards deep and higher parts of the goaf due to its buoyancy effect.

Sep 26, 2011

By Douglas J. Kramm

This paper discusses the history and development of the Rotary Kiln in improved fuel economy. It discusses latest technology to optimize fuel economy in a long Rotary Kiln. It discusses the limestone preheater, the SF process for cement manufacture, and the flash calciner with suspension preheat and. suspension deheat for fine limestone.

Jan 1, 1977

By H. B. Hill

The West Red River oil field, in Tillman County, Okla. (fig. 1), is approximately 8 miles northwest of the town of Burkburnett, Wichita County, Tex. The wells are in the river bed between the medial line and the south bank of the Red Diver. In the following discussion of the geology, development, and exploita-tion of the field, the authors have, by means of structure maps, crews sections through various parts of the reservoir and tabulated development data and production statistics, recorded salient information on a field whose development was unique and in some respects unusual for fields discovered and initially developed more than a quarter of a century ago. The total oil production from Government-operated leases; considered in the report was 6,900,440 barrels to January 1, 1947, from 3 proved acres developed by H1 oil-producing wells, 10 gas-injection wells, and 5 nonproductive wells. A calculated past recovery of 60P, barrels of oil per acre-foot and an estimated ultimate recovery of 6.S0 barrels of oil per acre-foot under present gas-injection methods begun in 1929 in shown.

Jan 1, 1949

By C. A. Pierce

STUDIES of roof and floor movement are of interest to those actively engaged in mining. This is especially true in the case of an entirely new area where there is no precedent for guidance. The potash deposit being mined is in the southeast corner of New Mexico, about 20 miles east of Carlsbad. The deposit was formed by the land-locked, shallow, Permian Sea that extended through parts of western Texas, Oklahoma, Kansas, southeastern Colorado, and eastern New Mexico. The saline deposits vary from 500 to 4000 ft. thick. Neither of the companies operating in this area has delimited its com-mercial ore bodies. As all production so far has been from Federal and State leases, the Department of the Interior and the State of New Mexico have a direct interest in the development and extraction of these ore horizons. The ore is composed of an intimate mechanical mixture of sylvite (potassium chloride) and halite (sodium chloride). It lies generally in a horizontal bed varying from 5 to 12 ft. in thickness, and has a cover of approximately 1000 ft., consisting of about 500 ft. of salt beds and 500 ft, of sediments. The immediate mine roof for several feet is principally salt with some potash and clayey material. The next 500 ft. above, from the standpoint of structure, may be considered rock salt with a few inter-bedded potash members. The upper 500 ft. is of sedimentary (Permian and Triassic) origin and contains several water-bearing formations with flows varying from 10 to 500 gal. per minute. This water intensifies the interest in convergence problems as the ore and surrounding for-mations are water soluble. Potash salt (sylvite) and rock salt (halite) are plastic minerals. Plasticity is defined as a "property of solids by virtue of which they hold their shape permanently under the action of small shearing stresses but are readily deformed, worked, or molded under larger stresses."1

Jan 1, 1938