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By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting, lime roasting, is being tested fro retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04), oldhamite (CaS), calcium sulfite (CaS03), hematite (FenOs), magnetite (Fe304), and minor amoupts of pyrrhotite (Fel.,S) and pyrite. At 600°C, 650°C and 700°C the main constituents are anhydrite, oldhamite, and hematite. At 750°C, 800°C, and 850°C anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides, calcium sulfite, hematite, and minor oldhamite, magnetite, and pyrrhotite. At 650°C 700°C 750°C and 800°C, anhydrite, oldhamite, arsenic sulfides, and hematite are present. At 850°C, the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CLM) in the determination of the calcium-sulfur- oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RLM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1993

By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting. lime roasting. is being tested for retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04). oldhamite (CaS). calcium sulfite (CaS03). hematite (Fe2O:J), magnetite (Fe304). and minor amounts of pyrrhotite (Fe1.xS) and pyrite. At 600°C. 650°C and 700°C. the main constituents are anhydrite. oldhamite. and hematite. At 750°C. 800°C. and 850°C. anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides. calcium sulfite. hematite. and minor oldhamite. magnetite. and pyrrhotite. At 650°C. 700°C, 750°C. and 800°C, anhydrite, oldhamite. arsenic sulfides, and hematite are present. At 850°C. the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CIM) in the determination of the calcium-sulfur-oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RIM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1991

By R. M. Gooding

This paper presents a short history of the production of mineral-energy fuels and energy from waterpower in the United States, with brief discussions of the utilization of each of the fuels and hydropower, and a look at fuels competition and interchangeability. Basic data, in figures and tables, are brought together in this publication for the production of coal in the United States from 1800 to 1960, for crude petroleum, natural gas liquids, and natural gas from 1859 to 1960, and for hydropower since 1900. Production for each segment of the fuels complex in the principal producing States from 1946 to 1960 is shown. Data are not included for consumption as such or for imports and exports.

Jan 1, 1963

By D. L. Boreck

With increasing land development, the potential of fatalities from abandoned mine shafts increases. To minimize potential liability, shaft closure should be a critical part of mined land reclamation. The Bureau of Mines is conducting research into using lightweight foam concrete in sealing abandoned coal mine shafts. A demonstration seal consisted of a 3m thick foam concrete plug to provide lateral stability inside the shaft. A high density concrete cap provided load-bearing capacity for a 100-year service life. The USBM has also completed research into changes in foam concrete when it is pumped or dropped from different heights. It is concluded from the research that foam concrete can undergo significant air loss with pumping or dropping. This foretells significant changes in the characteristics of the concrete as well as an increase in the weight and cost of the in-place concrete seal. When using foam concrete to seal abandoned mine shafts, care must be taken to minimize air loss during placement.

Jan 1, 1994

By Guillermo J. Román

The precipitation of copper and zinc as cements from a copper alloys' spent pickling solution has been studied at laboratory and pilot scale, with the objective of designing an economic process to recover both metals and render a solution to be either recycled to the pickling process or treated in a standard fashion and produce a non-hazardous sludge. The sulfuric acid spent pickling solution already containing copper and zinc was used first to dissolve another solid residue originated in the copper alloys foundry to neutralize part of the acidity. The resulting enriched solution was treated separately with two reductants,; sodium borohydride and iron powder varying pH and excess of reductant under constant agitation. Under the best conditions, precipitation of over 95 percent of zinc and copper was achieved together with the reduction of lead and cadmium contents respectively. A process for the combined residues treatment is proposed.

Jan 1, 1995

By Vadim J. Jabotinski

Electron beam processing is potentially very attractive for the high temperature treatment of hazardous materials. The very high power efficiency of the electron beam energy source (80- 90% of the power from the electric power line is converted to useable energy) is one of the positive features of this technique. This paper will consider advanced electron beam concepts for solid, liquid, and gaseous waste treatment such as stabilization of radioactive solid and liquid hazardous streams. Fundamental aspects and applications including an analysis of the economic potential of electron beam processing of waste treatment will be presented.

Jan 1, 2000

By A. M. Bell

General Summary THIS paper attempts to describe in a preliminary and general manner the nature of certain copper discoveries now being developed by Gaspe Copper Mines, Limited, in Holland township, in the interior of the Gaspe peninsula. Some copper mineralization appears to have been known here at the time of the earliest French explorations, was rediscovered in 1921, and has been under intermittent development by Noranda Mines since 1938. In the last two years discoveries have enhanced the picture so that the deposit now promises to develop into one of the important Canadian copper producers. As ideas are constantly changing with continuing development, any picture given now is very partial and tentative and must be subject to future revision. The nature of these copper occurrences differs from others known in eastern America. In many respects they have unique features but they are most closely akin to some copper deposits found away from the intrusive rocks in the porphyry copper districts of the western United States. The most important orebodies are replacement deposits in a limestone horizon in which the ore gangue is converted to skarn. These lie at considerable distances from any known intrusive but seem to have been derived from a buried stock of granite that intrudes the sedimentary rocks of Lower Devonian age. This intrusive has produced alteration effects in the overlying rocks that may afford a key to locating other ore areas in the Peninsula.

Jan 1, 1951

By Bülent Erdem, Zekeriya Duran, Tuğba Doğan

The objective of this study was to evaluate the potential health risk associated with exposure of dozer operators to whole-body vibration. Measurements were made on 31 dozers used in different surface mines in Turkey. Predictions of adverse health effects of vibration were based on the standards BS 6841:1987, ISO 2631–1:1997, ISO 2631–5:2004, and the EU Vibration Directive:2002. Operators experienced high and comparable levels of vibration acceleration and dose during all dozer tasks: pushing the material (DOZE), moving forward (FORWARD), moving backward (REVERSE), and ripping (RIP). Specifically, DOZE, FORWARD, REVERSE, and RIP showed high potential of adverse health effects in terms of vibration dose according to the worst-case axis and vector sum criteria and a moderate adverse health effect for acceleration according to the worst-case axis criterion. Operators of large dozers were exposed to lower levels of vibration. However, no statistically significant relationship between vibration exposure levels and the propelling mechanism and the service time of dozers, operator experience, operator age, and ground type was found.

Jun 16, 2022

By J. Ritchey

This report describes the engineering feasibility and economic advantages of using a mobile bridge-type cross-pit belt conveyor system in conjunction with a large dragline to excavate and transport spoils in a typical Western surface coal mine. The studies show that such a system could be built to survive operational and climatic mining conditions, and that its implementation would offer a reduction in both acquisition and operating costs versus conventional mining units of comparable rapacity. Reclamation costs can also be significantly reduced, and the total reclamation process accelerated, making the cross-pit conveyor system attractive to mine Owners and environmentalists alike.

Jan 1, 1976

By David A. Lipton

In the summer of 1985, at the request of the U.S. Forest Service, the U.5. Bureau of Mines examined the 109,000-acre West Big Hole study area to evaluate its identified mineral resources. The study area is in Beaverhead County, about 50 mi west of Dillon, MT. Four lode properties within or adjacent to the study area contain an estimated 452,000 tons of identified subeconomic gold-silver resources. Resources ranged from 900 to 302,000 tons, with estimated grades between 0.02 and 0.23 oz/ton gold and as much as 4.8 oz/ton silver. Gold, silver, and base-metal content in samples of poorly exposed mineralized structures indicate that exploration may identify resources on 18 additional lode properties within the study area and 5 properties adjacent to it.

Jan 1, 1988

By A. W. D. Hills, M. R. Moore

An apparatus has been developed in which metals can bc solidified under closely controlled unidirectional heat flow conditions. The metals are cooled by a multiple-air jet system, designed so that the heat transfer coefficient is uniformly distributed over the cooled surface. They are contained in a special furnace system of low thermal mass which enables unidirectional heat flow conditions to be rigorously maintained for certain specific cooling rates. This apparatus has been used to study the solidijication of pure lead and pure tin at zero superheat, solid metal thicknesses being determined by thermal analysis, and by dipstick readings. Detailed thermal balances have been drawn up on the experiments in order to determzne the cooling conditions that most rigorously correspond to unidirectional heat flow. Solid metal thicknesses, measured experimentally for these conditions, have beetz shown to agree closely with the theoretical wedictzons of different integml-profile methods. lt is concluded that any errors inherent in the integval-profile method are no greater than the errors inherent in experimental investigations of solidification. A knowledge of the influence of heat transfer rates on the solidification of metals is essential to the understanding and control of industrial casting processes. Since very few formal methods are available for solving the heat conduction equation under solidification conditions several authors have developed approximate techniques for doing so. One of the most promising is the integral-profile technique that has been used by Goodman,1 Hills,2,3 Tien4 and Hills and ~oore' to predict solidification rates under certain specific heat transfer coniditions. In the first of this present series of papers6 Hills has further generalized the method and developed a universal integral-profile technique that can be used to predict solidification rates under a wide variety of unidirectional heat flow conditions. Since the method is approximate it is necessary to investigate the accuracy with which it predicts actual solidification rates. A review of the literature7 shows that solidification rates have seldom been measured under accurately known heat transfer conditions and it was therefore decided to develop experimental techniques that would enable this to be done. Results obtained would then be available as a check on the approximate solutions already developed, and in the development of further solutions that would be applicable under more complicated conditions. The initial work in this experimental program which is described here, is concerned with the solidification of pure metals at zero superheat under unidirectional heat flow conditions. Subsequent experiments have been concerned with the solidification of pure metals at appreciable superheats, under varying unidirectional heat flow conditions and under two dimensional heat flow conditions. In a series of experiments recently initiated, the solidification of binary alloys is also being investigated. The results of these subsequent experiments, together with relevant theory, will be described in later papers. The solidifying metal has been cooled in all the experiments, by a multiple air jet system designed so that the heat transfer coefficient to the cooled surface is constant and is uniformly distributed over the surface. This type of system has been chosen since only one parameter is needed to specify the heat transfer conditions and since these conditions are analogous to those met in certain continuous casting processes.' Air cooling was chosen in preference to water cooling, however, since it offers a wider range of heat transfer conditions, and since it can be investigated by analogous mass transfer techniques. The first part of this paper discusses the existing integral-profile solutions that correspond to the heat transfer conditions used in the experiments, and describes the development and use of the experimental apparatus. In subsequent sections the heat transfer and solidification results are presented, and the various theoretical predictions are compared with them, and with one another.

Jan 1, 1970

By Donald R. Lamont

The paper outlines the reasons for and research behind the recent decision to adopt oxygen decompression in the UK. Currently used measures of decompression illness are critically appraised. The paper describes the main precautions to be taken on site to manage the fire risk from the use of oxygen underground. A summary of the initial results from the use of oxygen decompression in the UK is presented.

Jan 1, 2003

By Hai-Peng Guo, Lu Jiang, Xiao-Man Yan, Bing Xie, Hong-Yi Li

Traditional, calcium compounds cannot be used in vanadium extraction processing due to the limitation of sodium roasting technology, which results in unsatisfied dephosphorization for vanadium-containing hot metal in converter and thus increasing the dephosphorization burden for subsequent steelmaking. The calcium roasting technology is an alternative for vanadium extraction and allows adding lime into vanadium slag in converter. In the present study, vanadium was leached by soda from roasted vanadium slag with high calcium content. Effects of roasting temperature and time, leaching temperature, Na2CO3 concentration andliquid to solid ratio on vanadium leaching rate were studied. The results show that 94% of vanadium was extracted by roasting the vanadium slag at 950℃ for 2.5h and then leaching in 160g/L Na2CO3 liquid at 95℃ for 1h with liquid to solid ratio of 10:1 ml/g. Impurities of Si and P reacted with calcium and formed insoluble Ca2SiO4 and Ca3(PO4)2 respectively.

Jan 1, 2015

By W Patton, I Minniakhmetov, H Talebi, U Mueller

The sustainability of mining projects is linked to informed investment decisions based on public reporting of exploration and mineral resource estimation results. In Australia, public reporting guidelines are established by the Joint Ore Reserves Committee reporting code through the JORC Code (2012). Although the assessment of uncertainty in the results reported is a requirement, this is often communicated qualitatively and evaluated subjectively. This can become a liability particularly in the early stages of mining projects when spatial domains of geological interpretation and mineralisation envelopes inform resource estimations’ reliability. A recent review of JORC reports found no reports used quantitative assessments of the geological interpretation or mineral resource estimation envelopes, and 27 per cent of reports did not address the question of quality of geological interpretation. Reports that did address the quality used 19 different terms to communicate quality. This work presents methodologies for quantitative uncertainty assessment and communication and explores how they could be applied in public reporting practice. Quantitative uncertainty reporting would benefit mine planning and financial modelling as they normally assume the geology is 100 per cent right (since no error is reported or only a single deterministic model is provided). The complexity, cost, and additional work of doing a quantitative assessment could hinder a straightforward implementation. This could be overcome if mining companies budget for quantitative uncertainty assessment and associated professional development. A compulsory requirement for the inclusion of uncertainty assessments in public reporting or adopting standardised subjective language would improve industry practice.

Mar 22, 2022

By J. B. Littlefield

The Greenburg-Smith impinger was developed at the Bureau of Mines in cooperation with the United States Public Health Service in 1922 in the course of an investigation of dust-sampling instruments available at that time. Although it is not used extensively outside of the United States, it is now soused in this country to collect samples for the determination of any dustiness, and most of the information correlating degree of dustiness with physiological effect has been obtained by the impinger method. The chief disadvantages in the use of the regular impinger, especially in mines and other places accessible with difficulty, are its bulk, weight, and power requirements. It requires a source either of electricity or of compressed air, which necessitates connections and extension of existing supply lines to each sampling point; the only alternative is the use of a relatively large pump hand-operated with considerable effort.

Jan 1, 1937

By Z. Jin, D. DePaoli, P. Zhang

"Phosphate beneficiation in Florida generates more than one tonne of phosphatic clay, or slime, per tonne of phosphate rock produced. Since the start of the practice of large-scale washing and desliming for phosphate beneficiation, more than 2 Gt of slime has accumulated, containing approximately 600 Mt of phosphate rock, 600 kt of rare earth elements (REEs) and 80 million kilograms of uranium. The recovery of these valuable elements from the phosphatic clay is one of the most challenging endeavors in mineral processing, because the clay is extremely dilute, with an average solids concentration of 3 percent, and fine in size, with more than 50 percent having particle size smaller than 2 µm, and it contains nearly 50 percent clay minerals as well as large amounts of magnesium, iron and aluminum. With industry support and under funding from the Critical Materials Institute, the Florida Industrial and Phosphate Research Institute in conjunction with the Oak Ridge National Laboratory undertook the task to recover phosphorus, rare earths and uranium from Florida phosphatic clay. This paper presents the results from the preliminary testing of two approaches. The first approach involves three-stage cycloning using cyclones with diameters of 12.4 cm (5 in.), 5.08 cm (2 in.) and 2.54 cm (1 in.), respectively, to remove clay minerals followed by flotation and leaching. The second approach is a two-step leaching process. In the first step, selective leaching was conducted to remove magnesium, thus allowing the production of phosphoric acid suitable for the manufacture of diammonium phosphate (DAP) in the second leaching step. The results showed that multistage cycloning with small cyclones is necessary to remove clay minerals. Selective leaching at about pH 3.2 using sulfuric acid was found to be effective for removing more than 80 percent of magnesium from the feed with minimal loss of phosphorus.IntroductionFlorida phosphate ore, or “matrix,” as it is called locally, contains three different mineral groups that have to be separated from each other: (1) phosphate minerals, (2) clay minerals and (3) quartz, or sand. As mined, the phosphate and sand particles are embedded in compacted mud, or clay-balls. Before separation can begin, all of the particles must be liberated from the matrix of mud. The very first unit operation in the beneficiation process is to disaggregate the various particles. This actually starts while the matrix is flowing through the multimile pipeline from the mine to the beneficiation plant. While in the pipeline, the matrix is exposed to shear forces as it passes through the various centrifugal pumps along the pipeline. These intense shear forces cause a significant percentage of the sand and phosphate particles to be liberated from the clay-balls by the time they arrive at the plant. Once they reach the plant, the first goal is to finish disaggregating the clay, and follow that by making a size separation at 1 mm. This processing is conducted in the washer, consisting of a large rotating trammel screen and a few stages of log washer, screens and hydrocyclones. In all of the currently operating beneficiation plants, the washer is a large structure that receives the matrix, screens it and then discharges a pebble phosphate product sized larger than 1.0 mm and a slurry of liberated clay, sand and phosphate particles that are smaller than 1.0 mm."

Jan 1, 2017

By L. O. Thomas

THE Alaska Highway, in its course through British Columbia, traverses parts of two great physiographic divisions of Canada which are also distinctive geologically-the Cordillera in the western section and the Interior Plains in the eastern. The Cordilleran region in the portion of the Province with which this paper deals can be divided into four major northwest systems, known respectively from west to east as Coastal, Plateau, Cassiar-Omineca, and Rocky Mountains. The Coastal system consists solely of the Coast range except in the extreme northwest, where a part of the St. Elias range is included. The Coast range, characterized by mountains of great ruggedness,. is made up of an igneous complex of granitic rocks intruded chiefly as a great batholith. In places, spurs of these rocks extend into the Plateau heft, a partly mountainous tract largely occupied by quartzites, quartzose mica schists and their gneissic phases, and crystalline limestone with interbands and broad areas of chlorite, _hornblende, and sericite schists and bodies of intrusive granite gneiss-an assemblage of rocks known as the Yukon group. The Cassiar-Omineca system marks the divide between the Pacific and Arctic drainages. Its eastern boundary is well defined in the south by the Rocky Mountain Trench (see p. 229). The rocks of the system are, miainly, highly altered Palaeozoic sediments, but there are also Precambrian and Mesozoic rocks, the latter largely volcanic. The core of the system is granitic and there is evidence (see p. 221) to support the belief that it is of such a length as to constitute a batholith comparable to that of the Coastal system.

Jan 1, 1944

By B. K. Larkin, H. R. Bailey

A model Of heat flow in an underground combustion process is studied. This model includes convection effects and thus is more general than previous studies which considered conduction as the only mechanistn for heat transfer. Both linear (tube run) and radial (field application) geometries are considered. The effects of ignition heaters, vertical losses and finite source width are considered for the linear case. The results are in the form of equations and are presented in graphical form for a number of cases. Convection effects increase frontal temperatures about 25 per cent over those computed for conductive transfer for typical field operating conditions. This increase in temperature is a result of heat being transported toward the front by the injection gas. Even greater temperature increases are realized as the per cent oxygen in the injection gas decreases. It is well known that compression costs are of considerable importance in estimating the economic feasibility of underground combustion. By assuming an ignition temperature for the combustion fuel, predictions of limiting conditions on fuel density and injection rate necessary to sustain the combustion zone are made. For typical field conditions, at least 0.75 lb/cu ft of fuel are needed with air as the injection gas. If the injection gas is 10 per cent oxygen and 90 per cent nitrogen, this figure is 0.69 lb/cu ft. INTRODUCTION The possibility of increasing oil recovery by underground combustion has been considered for many years. Recent field tests indicate that the underground combustion process is technically feasible. The economic feasibility depends to a large extent on the amount of air which must be injected to sustain combustion. Prediction of the success of employing underground combustion in a particular reservoir must be based on existing field tests, laboratory tube runs"' and solutions of mathematical or analog models. Vogel and Krueger5 devised an electrical analog of the heat transfer problem in an underground combus-ion process. They considered the problem of heat conduction from a cylindrical source with increasing radius assuming no vertical losses. Bailey and Larkin and Ramey solved the corresponding problem including vertical losses by considering a mathematical model of the conduction process. Ref. 9, 10 and 11 also present information related to the subject study. The present paper generalizes these results to include both conduction and convection mechanisms for heat flow. A model of the conduction-convection process is described. The partial differential equations governing this model are written and solved for a number of cases of interest. The formulas are evaluated and the results are presented graphically. A CONDUCTION-CONVECTION MODEL Description of the Model A number of models are employed in this paper, each of which approximate a particular physical situation depending on the geometry, i.e., linear or radial flow, the type of vertical heat losses, the nature of the source, etc. The geometry for both the linear and radial case is shown in Fig. 1. A particular linear model is described in this section, and variations from this model are described in later sections of the paper. Consider a homogeneous, semi-infinite porous prism with lateral sides insulated as shown in Fig. 1. The left end, x = 0, is heated for a time t, with a plane heater supplying a constant heat flux and during this time; gas (nitrogen) is passed through the pores of the prism at a constant mass flux. At time t, the heater is turned off and air is injected in place of the nitrogen. This causes combustion to take place, and a uniform source of width 1 is formed which moves at a constant velocity v, to the right. The frontal velocity v, is related to the gas velocity v,, through stoichiometric considerations

By Jillian Spindura

This work investigates the carbothermic reduction of the complex sulphide mineral, pentlandite, in the presence of lime. The effects of change in temperature and the use of different carbon sources are studied and the role of these variables on the reducibility of pentlandite mineral is discussed. The microstructures of the heat-treated pellets are examined using X-ray diffraction and scanning electron microscopic techniques. The latter analytical method also allows any variation in the morphology and composition of the metallic phases formed, with temperature, to be considered. The kinetics of the reduction process is studied and the magnitude of the overall activation energy is determined from the plots of percentage reduction versus time.

Jan 1, 1996

By F. J. Tozer

Canal communication between Lake Erie and Lake Ontario has been one of almost constant enlargement and reconstruction to meet the rapid growth of trade and commerce, and the consequent steady increase in the size of vessels plying the Great Lakes. The original canal was built by the Welland Canal Company. The first sod was turned in 1824 and the first vessel passed through in. 1829. There were 36 lift-locks, built of oak timber, 110 feet long and 22 feet wide, with a depth of water over the sills of 8 feet. The second canal, now known as the 'Old Welland Canal' was built by the Dominion of Canada (1842 to 1850). There were 26 masonry locks, 150 feet long, 26.5 feet wide and with a depth of water over the sills of 9 feet. The walls and banks were raised in 1853 to give a 10-foot draught. The third canal, known as the 'New Welland Canal, built by the Dominion of Canada, was started in June 1874 and the first boat passed through in the spring of 1882. There are 25 masonry lift-locks, 270 feet long, 45 feet wide and with a depth of water over the sills of 12 feet. The walls and banks were raised in 1891 to give a 14-foot draught. This is the canal in use at present.

Jan 1, 1926