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By A. R. Khodabandeh, T. Nematkhah

Correct selection of forging parameters is very important to produce sound superalloy parts. In this investigation nickel-iron base superalloy IN901 successfully forged and seal spacer, which is a part of airplane with about 11 kg weight has been produced. Forging has been performed on the basis of hot compression results, which show deformation above 1100°C associated with dynamic recrystallization (DRX) which can increase the workability of material. On the other hand annealing at 1100°C decreases the flow stress during hot compression, and then increases the material formability. Then billets annealed at 1100°C in electrical furnace for 24 hours and reheated again to 1100°C before forging. Initial square cross section billet with 128mm side and 202mm length forged immediately after reheating by 80MN mechanical press. Specimens forged in five steps: upsetting, three steps molding and finishing. Preformed and molded specimens reheated in electrical furnace before later step of forming. Finally specimens trimmed by 1 OMn mechanical press and hot set by hydraulic press and then cooled in air to room temperature. Results show that reheating temperatures has been selected correctly because there isn't any surface crack and die cavities filled completely by forging material. Material flow has been carried out properly and there isn't any defect in critical points especially in extradoses and intradoses. Microstructural examinations show that grain boundaries contain Ti-rich globular particles that formed during cooling.

Jan 1, 2006

By LeEtta M. Shaffner, John R. Marks

INTRODUCTION In the last twelve years, underground stoping methods at the Homestake Gold Mine have evolved from open cut-and-fill with jacklegs, cribbed raises and electric slushers to ramp-based mechanized cut-and-fill (MCF) and vertical crater retreat (VCR) with dieselpowered loaders, trucks and drill jumbos. The evolution was swift. Unfortunately, ventilation practices have had trouble keeping pace. Stope ventilation is still too dependent on auxiliary fans and coolers. A single large MCF stope might contain up to eight headings, each of which requires significant ventilation resources when a diesel loader is present. Air is shortcircuited all too frequently through mined-out VCR panels. These factors and the recent rapid decent of the center of mining prompted a study to improve ventilation practices and to more accurately project future requirements. BACKGROUND In 1992, the underground portion of the Homestake Gold Mine produced 8336 kg of gold from 1407 ktons of ore (268,000 oz from 1,551,000 st). The ore is hosted in low to medium grade meta-sediments. Stoping took place from 420 to 2347 m below the surface (1400 to 7700-ft levels). The weighted center of mining was 1662 m deep (5450-ft level) in 1990 and is projected to be 1890 m (6200-ft) in 1993. The deepest level is 2440 m (8000-ft) where the virgin rock temperature (VRT) is 56.1°C (133F). The mine is ventilated by 504 m3/s (1,069,000 cfm) measured at mid-exhaust-circuit density. The air-conditioning system includes an 8.1 MWR (2300 ton) controlled recirculation plant, a 2.0 MWR (580 ton) chilled water plant, a 1.0 MWR (290 ton) exploration drift refrigeration plant, 28 spot-coolers totaling 3.4 MWR (960 tons) and 35 spray coolers totaling 1.5 MWR (420 tons). The mine employs 117 diesel units with a total nameplate rating of 7961 kW (10,672 hp). These units include twenty-four 1.5m3 (2-yd) loaders, twenty-six 2.7m3 (3.5-yd) loaders, fourteen 3.8m3 (5-yd) and two 7.6m3 (10-yd) trucks, and assorted utility vehicles and drill jumbos. THE STUDY In April 1991, the University of Nevada-Reno (Mackay School of Mines) and the South Dakota School of Mines and Technology cooperated with Homestake on an MCF study. Mackay instrumented a stope with thermocouples, air velocity meters and hygrometers (Duckworth, 1992). South Dakota Tech conducted a finite-elements computer analysis of a back-filled MCF stope with/without light-weight shotcrete insulation on the sidewalls and back (Chellam, 1992). Homestake conducted an empirical analysis of deep-level MCF stoping. This paper describes the Homestake study. Twenty-three of the forty MCF stopes deeper than 1800 m were surveyed at least once during the last quarter of 1992. The stopes not included were being cable-bolted or back-filled. Figure 1 shows the complexity of one of the ramp-based stoping areas included in the survey. This particular stope has six separate production headings. A baseline wallrock heat load was derived for each stope or heading from psychrometric calculations. Broken ore, waste rock fill and fissure water were noted when present and the effects included in the baseline heat load. Other heat sources often mentioned in the literature such as metabolic heat from workers, heat from explosives and small electric loads were neglected. Fan heat was considered part of the ramp & crosscut heat load and thus not included in the study. Diesel heat was addressed separately. RESULTS Survey results, plotted as the heat flux against VRT, are shown in Figure 2. The equation for the regression line is: W/m2 = 2.1236*VRT - 75.405 The 0.31 correlation coefficient is poor which implies that the results should be used cautiously. Previous experience strongly suggests that differences in productivity are most likely responsible for the scatter in data points. A rapidly advancing stope will have a

Jan 1, 1993

By Suresh K. Bhatt

Although overall worker productivity for U.S. underground coal mines is available, productivity by mining method and seam thickness is not. Mining technology has gone through dramatic changes in the past decade, and the industry has experienced a lack of accurate productivity Figures addressing these changes. This information is of great interest in planning for future mining systems as thick and shallow coal seams currently being mined are depleted and exploitation of thinner, deeper, and better quality seams is considered to partially meet the requirements of the 1990 Clean Air Act Amendments. In a cooperative program, the U.S. Bureau of Mines obtained raw mine level production and related data from U.S. Energy Information Administration for 1989 and 1990 and performed the needed statistical analysis. Base criteria, parameters, and salient results of the mine productivity analysis are presented in this report.

Jan 1, 1994

By Verne E. Hooker

This Bureau of Mines report summarizes the results of modifications in the borehole deformation gage design and subsequent changes in the overcoring techniques. Modifications in the borehole deformation gage have greatly improved the creep characteristics and enhanced the versatility of the gage. In situ field tests in competent rock near St. Cloud, Minn., provided sufficient data to compare the reliability between gages and new techniques in obtaining good engineering estimates of stresses. Near-surface horizontal stresses at the test sites are compressive and biaxial in nature.

Jan 1, 1974

By Dipankar Gorain, A K. Vishwakarma, Vivek K. Himanshu, Murari P. Roy, Shubham Singh, R S. Yadav

The industrial establishments of a power plant consist of many important structures viz. cooling tower, wagon tippler, track hopper, plants and offices. The leveled foundation is the utmost need for erecting these structures. The leveling of the foundation is done by rock excavation, when the establishments have to be setup in hilly/rocky areas. Drilling and blasting is the cheapest and most dominant method of rock excavation. However, this method has associated hazards in terms of blast induced ground vibration, air overpressure, flyrocks etc. The foundation work and erection of the industrial buildings are done in parallel to achieve the faster construction of the establishment. The challenges to reduce the induced hazards in such cases are more. This paper presents a case study on the controlled blasting method devised for the rock excavation for construction of 2 × 660 MW Obra-C thermal power plant. The foundation work for this power plant was made by excavation of Dolomitic rock. The excavation work was performed in the proximity of the existing residence of the local people and Obra market. With the advancement of project, the excavation was also performed in the proximity to the ongoing construction work of various industrial buildings. Accordingly, the controlled blasting pattern was devised suitable to the specific sites. The pattern consisted of variations in blasthole diameter, burden-spacing, maximum explosive charge per delay, total explosive in a blasting round, initiation system and direction of initiation. The suitable muffling arrangements were also used, when the blast was conducted in the close proximity to the structures. The initial blasting pattern was established by analysis of blast vibration wave propagation characteristics. Thereafter, the final pattern was adopted for the safe excavation at the site. The safe excavation for the foundation work of this power plant has been completed successfully based on the devised controlled blasting pattern.

Feb 6, 2023

By Susan G. Bilhorn

A number of studies have been conducted in active and inactive mine environments using continuous monitoring and data acquisition systems to detect various parameters. In addition to the information obtained for research purposes, these monitoring systems can provide a means to remotely collect required information (such as radon daughter concentrations and air velocity) and control various conditions (such as fan operation and air door position) in numerous working sections of an active mine. Selection of detector locations and placement, which are critical to obtain the information and control desired while not inhibiting mine operations and influencing the detector readings, are covered in this paper.

Jan 1, 1984

By Willard P. Ward

Having been engaged during the past year in the manufacture of ferro-manganese in a blast furnace, I have imagined that some further information on this subject might be of interest to that large number of members of the Institute who are engaged in the iron and steel industries. The great question of the economical production of good steel, ingot metal, or homogeneous iron (we scarcely know now what to call it) from good materials, and at reasonable prices, has, thanks to the intelligence and energy of a few American engineers, been successfully solved in this country. Nearly all first-class railroads, and many that would not rank so high, have adopted the Bessemer rail. Martin boiler-plates are rapidly gaining ground, in competition with

By Euler De Souza, J. Daniel Stinnette, Julian Varaschin

"This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and of electric equipment and examines how they can be applied in determining reasonable ventilation rates for Tier IV compliant diesel equipment and for electric equipment operating in mining environments. Airflow calculations for modern diesel-powered equipment and for electric equipment are more complex and must be based on a combination of factors that are unique to each mine. Methodologies for ventilation rate determinations for each case are proposed in this paper.INTRODUCTIONTraditionally, airflow requirements for production and support equipment operating in underground mines have been determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations or determined empirically from known quantities. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is still a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. The question remains, what ventilation rates should the ventilation system designer apply for modern diesel equipment?Also, given the ongoing development of grid/battery-electric equipment and active construction of fully electric mines, it has become critical to determine adequate airflow rates per brake kilowatt of electric engine power. One of the most important criteria for determining ventilation rates for electric equipment is the amount of heat they generate, as this is the most significant emission produced by electric equipment (which do not produce exhaust gases or particulates). Therefore, ventilation rates required to dissipate heat from electric equipment must be suitably determined for all electric vehicle fleets operating in underground mines."

Jan 1, 2019

By L. M. Yokum

Tremendous strides have been made in front end loaders in the last 15 years. Fifteen years ago a 21/4-cu-yd front end loader was the largest standard machine you could purchase. Today there are two commercially available 15-yd front end loaders and many 10-yd loaders. The estimated total worldwide market for all front end loaders over 1 cu yd has increased to over 30,000 units yearly. The trend for front end loaders, in general, and for the mining market, in particular, is to larger and larger loaders. Today there are 18 and 24-cu-yd front end loaders in prototype form. It is not inconceivable that within another 15 years there will be front end loaders in the 50-cu-yd class with design features quite different from today's. These larger loaders are being designed at the demand of the mining industry, and the design criteria are being directed at this market area. The costs of these larger loaders may be greater per unit of capacity, but it is the intent of the various manufacturers that they will be more reliable, be easier to service, give greater availability, live longer, and cost less to maintain, than previous loaders. It is also the intent of the manufacturers to compete directly with the large mining shovel as the front end loaders become appropriately larger and more reliable. There has been some trend in this direction in the past with smaller shovels and loaders. In Table 1 are data for U.S. production of front end loaders (5 to 6-cu-yd class and 10-cu-yd class) and U.S. production of cable-operated, crawler-mounted power shovels, draglines, and cranes (11/z to 5-cu-yd class) for the years 1965 and 1970 (Source: Bureau of Census, U.S. Department of Commerce). Many believe that the decline in shovel production, in particular, is due at least in part to the acceptance of the front end loader as a primary production tool. However, the foregoing comparison is for a smaller shovel class than for front end loaders. It has generally been a rule of thumb that a front end loader is competitive on a cost and production basis with a shovel when it is approximately twice as large as the shovel. This same relationship may not hold true with the larger 10 to 15-cu-yd electric shovels, but at some point, direct competition will probably occur. Current Trends There are many trends today that are significant. One major usage trend in large front end loaders involves load and carry operations. This application is defined as "performing the functions of loading, hauling and dumping with one machine over distances within its economical limits." Many people are using front end loaders to transport material as well as load it. It is estimated that nearly half of all 10-cu-yd front end loaders sold in 1970 went into primary load and carry work. Many times, significant savings result from using the load and carry system, instead of small truck and shovel operations, for distances in excess of 1000 ft. Strip mining in coal utilizes great numbers of front end loaders in this manner. In-pit crushing of limestone is developing on an ever-increasing level, especially in Europe, and this stimulates interest in load and carry operations. In Table 2 is a cost example for 10-cu-yd front end loader in a limestone quarry. More than likely, load and carry use will continue to increase over the next few years. While some types of mining do not lend themselves to load and carry in the pit, such areas as surge piles are applicable and should be studied. In the area of machine operating cost reduction, there

Jan 1, 1974

By Schebek, J. Warsen

"Data and information from sustainable development (SD) reports can be seen as a promising and easily accessible source for an Life Cycle Assessment (LCA), i.e. for generic Life Cycle Inventory (LCI) data in particular. The reliability and comparability of LCA results crucially depends on the quality of LCI data, that is defined by specific normative requirements. In parallel the GRI (Global Reporting Initiative) provides a set of guidance documents for enhancing the quality, rigor, and utility of SD reporting with specific reporting principles that address similar issues on a company level comparable to LCI data quality requirements on the process level. In order to assess the general suitability of the fundamental reporting principles for LCI data quality purposes selected reports from mining and minerals (M&M) sector are assessed within a detailed analysis."

Jan 1, 2005

By Walter S. Weeks

CONFUSION appears to exist in the discussions of fan testing because engineers do not agree on what energy should be credited to the fan in certain cases, and because certain terms that are used in the discussions seem to have double meanings. The purpose of this paper, therefore, is to discuss the useful energy that should be credited to the fan and the methods of determining this energy, and to suggest changes in nomenclature for the sake of clearness. The instruments commonly used in the measurement of fan pressures are the manometer, the static tube, and the impact tube. The static tube is a tube with small pinholes in it. When connected to one leg of the manometer and placed in the air current with the holes facing at right angles to the direction of the current, this tube causes the manometer to register the static pressure, unaffected by the impact of the air. The impact tube is a tube with an opening that faces the air current. When connected to one leg of the manometer, this tube causes the manometer to register a pressure which is the static pressure modified by the impact of the flowing' air on the end of the tube. If the static tube is connected to one leg of the manometer and the impact tube to the other leg, and both instruments are inserted close together in the air current, the static pressure is eliminated and the manometer registers the impact pressure. The efficiency of a fan is the percentage of the expended power utilized in useful work. The items to be included as useful work are a matter of convention, and as the conventions are not universal I feel that the matter is open to discussion.

Jan 1, 1929

By P. Louis

Gécamines is the world largest cobalt producer with about 60 % of the Western World production. During the last ten years, its annual production varied from 5,400 to 14,600 t/year. The actual cobalt production capacity of Gécarnines is 18,000 t/year and could be increased in the near future if necessary. Cobalt is presently produced at the Shituru plant by an old in-pulp electrolysis process and in Luilu, by electrolysis of a clear weakly acidic solution. The Shituru Cobalt quality is lower than the Luilu one. For that reason, part of the Shituru Cobalt is fire refined and cast into granules. Large efforts have been succesfully accomplished to improve the cobalt quality. This has been made possible by a better knowledge of the purification processes and of the electrolysis parameters.

Jan 1, 1988

By J. H. Desautels

The modern coal mining industry is subject to a vast array of regulations affecting virtually all aspects of its operations. Probably the most significant over-sight role involves the Office of Surface Mining Reclamation and Enforcement (OSH) established by the Surface Mining Control and Reclamation Act, or SHCRA.1 Although complying and coping with SHCRA can be difficult for coal operators, this complex regulatory process has helped insulate the industry from ongoing efforts to extend regulation under the Resource Conservation and Recovery Act, or RCRA, 2 to aspects of the mining industry in general. The Environ-mental Protection Agency (EPA) has struggled with regulation of mining wastes under RCRA since the mid-1970's, but RCRA itself places most coal mining wastes firmly under the control of OSH and SHCRA. Despite the general exemption from RCRA regulation for waste materials that result from extraction and processing of coal itself, there may be circumstances under which coal mining operators could find themselves subject to regulation under RCRA or a number of other statutes administered by EPA. This paper will review briefly the history of mine waste regulation under RCRA, as well as touch on the policy decisions that led to the exemptions from RCRA regulation. The paper will summarize coal waste requirements under SHCRA, and also will review what operations at coal mines need to be controlled, in order to avoid potential liability under RCRA. In addition, it will mention requirements under other federal laws, including CERCLA, or the "Superfund" law,3 and describe how they may impose restrictions or liability on coal operations for waste or other materials commonly found at surface and underground coal mines.

Jan 1, 1993

By T van Zyl

Some standards are being used by the corrosion industry on a daily basis. This talk will cover how a standard comes into existence, the different types of standards and the voluntary/ compulsory nature of different standards. The maintenance of standards is discussed This talk also looks at how standards should be referenced, what reference to the mark scheme can be made and which national and international standards might be of value in the corrosion industry.

Jan 1, 2006

By Y. Q. Li, Z. C. Shen, C. H. Zhao

The dynamic properties of the KYF-320 flotation machine which is one of the biggest flotation machines in the world were tested and then verified by the computational fluid dynamics (CFD) simulation. Aeration rate testing results suggest that he effect of circulation holes on the fluid state in the flotation cell becomes gradually smaller when the impeller speed is greater than 107 r/min. The dispersion degree of air increases with the increasing impeller speed and decreases with the increasing aeration rate, and it increases slightly when the impeller speed is greater than 107 r/min. The air holdup increases and then decreases with the increasing impeller speeds and aeration rates, and a maximum value of air holdup is shown at impeller speed of 107 r/min with a value of 12.28%. CFD simulation results are in good agreement with these testing results. Industrial-scale test was carried out using this 320 m3 flotation machine for the flotation of Cu ores. The results show that Cu content increases from 0.06% of crude ore to 1.26% of concentrate, and the S content increases from 0.39% of crude ore to 24.83% of concentrate. Moreover, using this flotation machine 5.88% of power is saved compared to other type of large flotation machine.

Jan 1, 2015

By Jenny Alsén, Hans Hogard

"Construction of large facilities underground in urban areas has many advantages. In order to show the advantages, a case study of the Norsborg metro depot in Stockholm Sweden has been made. The Norsborg metro depot will be the largest and most modern underground metro depot in northern Europe. The depot has been built in hard rock in an urban area with small impact on the environment and local residents. The paper describes how it is possible to build underground facilities in a cost efficient way and take care of the challenges regarding working environment that comes with locating a permanent working place underground. INTRODUCTION The Stockholm area is one of the five fastest growing regions in Europe and home to more than a fifth of Sweden's population on just two percent of Sweden's surface. The population is growing rapidly, with about 35,000 people per year and is expected to reach 2.6 million in 2030. In order to meet the development and enable continued growth, housing projects and expansion of infrastructure need to keep the same pace; this is an easy conclusion to make but much more difficult to realize in practice. The main challenge is to accomplish development in a sustainable and efficient manner, minimizing the use of resources and land. By constructing facilities underground more urban space will be made available for development and/or for greening of city centers. Considering sustainability factors such as land value in decision making for placing of structures or facilities, underground locations could become a first choice alternative. During 2015 and 2016, several major underground infrastructure projects in the city of Stockholm will start, including a 14 km sewage tunnel and an 18 km by-pass highway tunnel. Furthermore the Stockholm metro system is currently undergoing the largest expansion since the 1970’s, a 19 kilometers extension of the metro system including new trains and new stations is planned. During 2013 - 2015 Skanska Sweden took part in the construction of a new metro depot placed underground in the southern part of Stockholm; the Norsborg metro depot. This is a top modern urban underground facility that in 2017 will serve as depot for 17 new metro trains. The project was selected for “Outstanding Project of The Year” at the ITA Tunneling Awards 2015."

Jan 1, 2016

By G. P. Salas

I.- In order to keep pace feeding its fast growing population, Mexico with only about 20% of its surface suitable for intensive agriculture, will need the application of modern foodgrowing techniques. To assure greater crop yields it will be necessary to apply more fertilizers than used at present (yearly average of 29 Kgs/hectare)** For its fertilizers production Mexico still depends mostly on imports of phosphate concentrates from Florida, U.S.A., Morocco and Spain. To reduce or eliminate this dependence on foreign providers, the Consejo de Recursos Minerales -a Federal Government exploration Institute- started in 1974 an exhaustive exploration program for phosphate deposits more amenable to commercial exploitation than the phosphatic limestones contained within the La Caja Formation of Upper Jurassic, found along the Sierra Madre Oriental. After studying literature on the origin and deposition of marine phosphate and visits to deposits in Florida, U.S.A., the Baja California peninsula was selected as most favorable for starting this program because of its geologic and sedimentary history and also for its geographic location, where the cold California and warm Counterequatorial currents meet. Exploration activities executed by FORNOS, S. A. (1956) led to the disco very of low grade phosphate (3 to 5% P2O5) in the recent beach sands along the Bahia de Magdalena (Fig. # 1). In his doctoral thesis Bruno D'Anglejan Chatillon (1965) reports the presence of nodular phosphate on the continental shelf, between Isla Margarita and the Vizcaino peninsula. He estimated reserves of up to 1.5 million tons. A Mexican-American marine exploration company attempted in 1966 the evaluation of this deposit with negative results.

Jan 1, 1978

By Robert Snow, Shibo Zheng, Wenyi Song, Xiaoqing Ma, Patrick Zhang

Numerous phosphate mineral depressants have been reported in the literature for use during anionic flotation of dolomite from carbonate fluorapatite in slightly acid circuits. In one part of this research, laboratory flotation experiments were conducted to compare the effectiveness of phosphate depressants to process ground, deslimed high-MgO Florida phosphate pebbles. Ten potential phosphate depressants were evaluated during laboratory anionic flotation of dolomite from phosphate in a slightly acid circuit using a sulfonated oleic acid soap plus oil as the dolomite collector. Eight of the depressants have been used by various investigators with foreign and domestic carbonate-phosphate ores. Four of the depressants were found to be reasonably effective during the current flotation study, namely: sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP), tetrasodium pyrophosphate (TSPP) and diphosphonic acid (DPA). Without depressants, the sulfonate collector required to produce cell underflow phosphate products containing <0.80% MgO and MgO/ P2O5 ratio <.033 was 1.13 kg/ton of flotation feed at a flotation pH range = 5.5-6.0. Using this collector level with 0.91 - 1.36 kg/ton of feed of STPP, SHMP or TSPP yielded phosphate products analyzing 0.73-0.92% MgO and MgO/ P2O5 ratios = .027-.034 at 90.0-96.8% P2O5 recovery. Similar grade phosphate products were obtained using DPA as the phosphate depressant at 84.1-87.5% P2O5 recovery. When no depressant was used, a similar grade phosphate product was obtained at only 65.9% P2O5 recovery. Another part of the research aimed at reducing MgO content in the final concentrate from Florida phosphate plants by conducting dolomite flotation on the final concentrate. Numerous phosphate depressants were tested for this purpose, including acidic, neutral and alkaline reagents. The most effective phosphate depressant was found to be phosphoric acid, giving both high grade and recovery.

Jan 1, 2014

By Ashish Ranjan Kumar, Steven Schafrik, Oscar Velasquez

Flooded-bed dust scrubbers installed on continuous miners use fibrous type multi-layered filters to capture dust from the airstream. Prolonged operations of the scrubber could lead to filter clogging due to dust accumulation. This results in reduced flow through the scrubber and elevated dust levels in the mine environment. This paper compares the performance of a conventional fibrous screen filter and a novel impingement type dust filter. The impingement filter is a self-cleaning system and was designed to have a resistance similar to the fibrous filter. The cleaning efficiencies for these filters were computed using iso-kinetic sampling and optical counting of coal dust particles in a clean unclogged state. The cleaning efficiency of the impingement filter also increased with an increase in particle size and was comparable with the conventional fibrous filter. The cleaning efficiency of the fibrous filter improved significantly with an increase in water flow. The non-clogging nature of the impingement filter and minimal maintenance requirement makes it an attractive alternative to the conventional fibrous type filter in mining applications. The research also proposes a term called ‘filter performance factor’ to compare the performance of different filters under similar operating conditions.

Sep 19, 2020

By C. F. Davidson

The Bureau of Mines studied the extraction of lithium from lithium-containing clays by chlorination with hydrogen chloride (HC1). In bench-scale laboratory investigations, HC1-H20 mixtures were used to selectively chlorinate lithium, but not calcium or magnesium, in lithium-containing clays. The addition of calcium carbonate to the clay was found to improve the lithium recovery. Reaction conditions found to affect the lithium recovery were ratio of clay to carbonate, reaction temperature, and HC1 concentration. The best conditions for selective chlorination of the lithium were 2:1 clay-carbonate, 750° C, and 20 wt-pct HC1. The experimental results and trends in lithium extraction are explained using thermodynamic relationships.

Jan 1, 1981