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By Joe Dannenberg

One must be cautious in talking about blasting safety, because the very act of making a blast involves the creation of an infernal machine. You are setting up for the instant release of tremendous energy. Inherently this is a hazardous act. It has always been hazardous. It will stay hazardous.

Jan 1, 1975

By W. K. Tolley

The Bureau of Mines is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from CdTe scrap produced in the manufacture of infrared optic devices. Sulfation, ferric chloride leaching, and oxygen-pressure leaching have been tested. Cadmium dissolution was achieved using oxygen-pressure leaching in dilute sulfuric acid. However, no satisfactory scheme for dissolution of the higher valued tellurium has been devised. Leaching the ground CdTe for 75 min at 110°C in 1.1M H2S0, under 120 psig 0, yielded 99.5% Cd extraction. Tellurium remained in the leach residue as TeO, and elemental tellurium; residual cadmium was less than 0.5%. The cadmium in the leach liquor was purified of coextracted metals such as gallium and iron by adjusting the pH. The cadmium was recovered as cadmium sulfate crystals by evaporating the solution. Recovery of by product metals, notably gallium, is possible.

Jan 1, 1991

Coal-derived flue gases contain CO2/SO2 and these contaminants preferably have to be captured by cheap sorbents. This remediation approach is from the standpoint of addressing issues such as global warming, acid rain and development of Advanced Power Generation Systems and to realize the economic gain as well. Conventional and existing dry scrubbing technologies use regenerable sorbents which are pollutant specific and require expensive stabilizers in order to attain versatility. This paper discusses the use a novel class of sorbents prepared from the heavy metal contaminated Berkeley Pit water (Butte, Montana) by a proprietary process developed at The University of Nevada, Reno. These sorbents are activated mixed spinel ferrite (MxFe,_X04)' Preliminary experimental results show that the sorbents have good desulfurization and CO2 decomposition capacities. The decomposition effectiveness of these mixed spinel ferrites was studied at 300°C and compared against the synthetic magnetite obtained from ferrous sulfate solution in our laboratory. The results indicated that the mixed spinel ferrite had good affinity for the adsorption and decomposition. The CO2 decomposition data of both sorbents fitted the first order reaction kinetics. Even though the surface area of the magnetite was higher than that of mixed spinel ferrite, the CO2 decomposition rate of the mixed spinel ferrite was estimated to be 2.5 times higher than that of magnetite under identical conditions. The carbon analysis deposited on the sample indicated that the CO2 was 100% decomposed into carbon and other carbon! hydrogen compounds by the mixed spinel ferrite whereas the conversion was 43% by the magnetite. In terms of specific adsorption of carbon, ferrite was 3-5 times more efficient than magnetite.

Jan 1, 1996

By R. L. Peyton

Risk analysis is used extensively in many engineering applications. Although its use in the field of dam safety has been limited in practice, it has received considerable attention in recent years in the dam safety literature. Thus far, it has been shown that risk analysis in the evaluation of existing dams has the potential for providing a more rational basis for decision- making because of its focus on the direct issues--likelihood of failure, likelihood of loss of life, and risk cost of damages. It provides for a logical balance between the risk a dam imposes and the degree to which rehabilitation is required, compared to traditional evaluations based on somewhat arbitrarily chosen design events applied to large classes of dams. Dam owners could benefit by optimizing the cost of remedial measures. Downstream landowners could benefit by minimizing the likelihood of flood damages. However, it is also clear that significant technical and policy issues remain to be resolved before risk analysis in dam safety is accepted and routinely implemented in engineering practice. An obvious and important potential application of risk analysis is its use by the state regulatory agency as an in-house evaluation tool, or even as part of regulatory policy, in the implementation of its state dam safety program. Adoption of such a policy would have an important impact on the mining industry. .Although no state dam safety programs are known by the writers to have officially incorporated risk analysis into their regulations, there appears to be considerable interest in the concept. In recent surveys 47 states agreed that the development and promotion of a risk assessment methodology for state dam safety programs should be encouraged (Tschantz, 1983; Tschantz, 1984). The issue has also received important attention within the Association of State Dam Safety Officials (1986). One state-Illinois-proposed regulations during 1986 to allow risk analysis to justify lower spillway requirements for existing dams (Illinois Department of Transportation, 1986). At the Federal level, the National Research Council has found risk analysis especially appropriate for assessing dam safety at high-hazard dams (National Research Council, 19851, the Bureau of Reclamation has published guidelines for incorporating risk analysis into their dam safety grogram (U.S. Department of the Interior, 1986), and the Federal Emergency Management Agency has recently sponsored workshops and supported research related to risk analysis in dam safety (Federal Emergency Management Agency, 1985a ; Federal Emergency Management Agency, 1985b; - - McCann, et. al., 1985a, 1985b).

Jan 1, 1986

By C. J. Wilhelm

The disposal of brines produced with crude petroleum and natural gas has been a long-continuing problem to oil and gas operators as well as to farmers and stock-raisers in the vicinity of producing fields. An impartial appraisal of conditions pertaining to the problem of brine disposal leads to the conclusion that study of the technical consideration, with proper weight given to the economic and social factors, is the most desirable approach to this problem. Brine disposal is a problem of such magnitude in certain areas in the State of Kansas that in August 1934 a cooperative agreement was made between the Kansas State Board of Health and the U. S. Bureau of Mines for a cooperative technical study of methods of brine disposal.

Jan 1, 1935

By Martin J. Gavin

"Before discussing oil shales it may be well to consider briefly the conditions surrounding the petroleum industry in the United States, because these largely explain why so much interest is being manifested in oil shales. The United States is not only the greatest producer of petroleum in the world, its output amounting to about 65 per cent of the world's total production; but is also the world's greatest consumer, using more petroleum than it produces within its own borders. For the past four or five years it has been necessary to import oil at a continually increasing rate to make up the deficit between domestic production and domestic consumption. Experts who have made a close study of the future supply and demand for, crude petroleum are satisfied that under present production practice and with the development of possible undeveloped productive areas, the gap between domestic consumption and production will steadily .increase.As possible solutions for the impending domestic shortage of oil, various expedients are receiving attention. These may be grouped under three heads, as follows:(1) Temporary measures, such as curtailment of consumption, development of more efficient methods of production, and more efficient utilization of supplies of petroleum still available. It is unlikely that there will be any great curtailment in consumption of petroleum in the United States; rather, consumption will continue to increase unless a real shortage of oil actually forces curtailment of consumption. The other two possibilities mentioned deserve, and are resolving, serious thought. Much experimental work along these lines, some of which has already yielded excellent results, is being done. Obviously, however, any of these remedies are temporary ones only, so far as regards domestic production of petroleum."

Oct 1, 1920

By A. L. Ling, A. K. Janzen

"Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software and water quality calculations provided by PHREEQC, and is well-suited to modeling parameters of interest in the mining industry, especially metals and sulfate. Physical processes such as membrane separation and greensand filtration are modeled by defining mass rejections for each parameter and flow routing based on vendor projections and bench- or pilot-scale equipment testing. GoldPHREEQC models chemical precipitation processes such as HDS metals removal and gypsum precipitation by (1) performing surface-aging and solubility calculations in PHREEQC and (2) using the GoldSim framework to direct supernatant and precipitate to subsequent process steps. Users can apply this modeling framework to predict effluent water quality, chemical requirements, sludge production, and required equipment capacity to support design, troubleshooting, and cost estimating. INTRODUCTION Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software (1) and water quality calculations provided by PHREEQC (2), and is well-suited to modeling treatment of parameters of interest in the mining industry, especially metals and sulfate. GoldPHREEQC can also be applied to other water treatment scenarios using inorganic reactions and processes. The GoldPHREEQC model framework moves water and mass between specified model nodes and calculates specified reaction and water quality outcomes. It can be organized to provide flow, load, and concentration information for each location, including effluent and byproduct streams, and outputs can be adapted to include power and chemical costs."

Jan 1, 2018

By Theodore R. Butkovich, Jesse L. Yow

Geological storage of spent-fuel assemblies from an operating nuclear reactor has been underway since the Spring of 1980 at the U.S. Department of Energy's Nevada Test Site. The primary objective of this generic test is to evaluate granite as a medium for deep geological storage of high level reactor waste and to provide data on thermal and thermomechanical behavior of granite from imposed heat loads.(l) The underground installation in the Climax stock granite was sited at about 420 m below the surface and 145 m above the existing water table. As shown in Figure 1, three parallel drifts were excavated spaced on approximately 10 m centers. Seventeen storage holes were drilled at the central drift on 3 m centers in which eleven spent fuel canisters and six thermally identical electrical simulators were emplaced. Electrical resistance heaters were emplaced in vertical holes in the floor of the side drifts on 6 m centers. The thermal output of these heaters is being periodically adjusted to simulate the thermal response of a large storage array. Rock and ventilation air temperatures are being measured continuously in the drifts and throughout the rock surrounding the excavations. Measurements of drift deformation have been made routinely since the emplacement of the spent fuel. Both vertical and horizontal measurements are being taken at five locations along the heater drifts and at six locations along the central canister drift (Fig. 1). Two types of instrumentaton are being used: convergence wire extensometers which are monitored automatically, and a manually operated tape extensometer with which measurements are taken periodically. The tape extensometer measurements were initiated about 6 weeks following fuel emplacement. The lack of a temperature correcting capability for the convergence wire extensometers make that data unavailable for analysis at this time.

Jan 1, 1982

By D. G. Collins

As part of its effort to develop ways to maximize resource recovery, the Bureau of Mines investigated the extraction of vanadium from Western phosphate beneficiation tailings with H2S04 and/or H3P04. Dissolution of the vanadium was accomplished by digesting a mixture of acid and a 50-pet-solids, tailings-water slurry. In the most effective method investigated, vanadium and phosphorus were leached by digesting the slurry at a constant boiling temperature (1000-1100 C) in a stirred reactor. In batch tests, maximum vanadium dissolution was 95 pet. In continuous-circuit tests designed to further evaluate vanadium dissolution at con-stant boiling temperature in a continuously stirred reactor, vanadium dissolution ranged from 70 to 85 pet. An economic evaluation of the process demonstrated that H2S04 consumption is the major cost factor. Based on the value of the vanadium product with no allowance for a phos-phate product, the cost of producing the V205 is more than twice its value. The potential for profit would depend upon the value of the phosphate fertilizer produced from the impure H3P04 remaining after vanadium extraction.

Jan 1, 1985

By H. Tan

The effect of carbonaceous matter on gold extraction was investigated in cyanide systems with pure gold as well as pre-robbing sulfide gold ores. Auger studies demonstrated that the carbonaceous matter preferentially smeared on iron sulfide rather than aluminosilicate surfaces during wet or dry grinding. During mechanically mixed leaching, coating of sulfides and silicates and stripping of carbonaceous matter occurred simultaneously. TEM and XPS studies indicated preferential coating in the form of elemental (graphitic) carbon at the edges and the defect sites of particles. Interestingly, carbonaceous matter extracted from the gold ore was predominantly graphite and not preg-robbing in a solution with a high KCN concentration. However, the carbonaceous coating had a significantly detrimental effect on gold dissolution when gold was pre-ground with the gold ore. Artificial coating on gold surfaces with the natural carbonaceous matter from the ore was also found to substantially retard gold dissolution. With the addition of the natural carbonaceous matter from the gold ore, gold extraction from two non preg-robbing sulfide gold ores was inhibited owing to carbonaceous coating. The presence of carbonaceous matter significantly reduced the current density for gold oxidation and increased the current density for pyrite oxidation. This could explain the fact that carbonaceous coating hindered gold dissolution while enhanced sulfide preg-robbing.

Jan 1, 2005

By Robert J. Brennan, Edward R. Navrocky, John W. Buch

In an effort to establish a highly productive mechanized mining system for anthracite beds pitching between 10 ° and 20 ° , for which conventional mobile equipment is not adaptable , the Bureau carried out an experiment in longwall mining using an Anderton- type drum cutter loader and friction - type yielding steel roof supports . The roof- support system proved to be inadequate for breaking the overhanging roof at the break line supports , with the result that the roof broke over the solid coal . The accompanying subsidence destroyed the continuity of the roof in the work area , and the project was discontinued .

Jan 1, 1964

By Johne Jesus Mol Peixoto, Ciro Azevedo Silva, Itavahn Alves da Silva, Weslei Viana Gabriel, Leticia Queiroz Ribeiro, Carlos Antonio da Silva, Varadarajan Seshadri

In this study,the influence of the immersion depth, casting speed on the flow characteristics in a beam blank mold with two tubular nozzles have been investigated using a physical model as well as CFD simulations.The results of CFD simulations were found to be consistent with the results of experiments in the physical model.The liquid jet spreads faster the flange region compared to the web region. This can lead to a non-uniform shell thickness along the cross section resulting in uneven solidification of the skin. The jet penetration depth ranged between 66 and 77 cm. The average intensity of meniscus fluctuation was 0.22 mm, and the maximum fluctuation was found to be 0.85 mm. Based on these results, the suggested optimum operating parameters for immersion depth and casting speed were 75 mm and maximum casting speed of 1 m/min.

Mar 1, 2017

By T. Surkova

For the moment reserves of high-grade ores are practically depleted requiring ever-increased involvement of low assay raw materials, such as black-shale ores, in industrial operations. Black-shale ores are constituted of minerals containing such valuable components as vanadium, uranium, molybdenum, manganese, and rare-earth elements (REE). We studied technogenic solutions of black-shale ores processing, after uranium, molybdenum, and vanadium were recovered. Mentioned solutions contain rare-earth elements in substantial quantities (S REE 70-100 mg/dm3) that is very important factor taking into consideration the world demand ever-increasing last years. Higher concentrations of iron and aluminum inhibiting REE sorption and extraction recovery are found in solutions. We propose a method of hydrolytic deposition to cleaning solutions from impurity elements (Fe, Al). Study of hydrolytic deposition kinetics allowed identifying optimal conditions to run this process. Rare-earth elements may be recovered from purified solutions through sorption process followed by their further deposition from eluates in form of concentrates. Keywords: black-shale ores, rare-earth elements, a method of hydrolytic deposition, impurity elements, sorption

Sep 1, 2012

By Stevak D, Plesingerova B, Ellias K, Tkacova K

This paper presents information on the processing of minerals by decrepitation that can be an integral part of their mineral dressing. In the case of carbonates, processing by decrepitation is a special operation that has its objective as concentration of the oxide. Selective fragmentation of magnesite brought about by decrepitation uses pseudomorphosis which was observed at thermal decomposition of carbonates. By decrepitation of magnesite high-grade MgO concentrates were obtained with MgO contents above 80 per cent. With the sideritic ores a very important phenomenon was observed consisting in the removal of quartz in the fragmented fine-grained product which favourably affect pelletisation of the fines. The selective concentration of the MgO product brought about by thermal decomposition of dolomite accompanied with decrepitation was negligible.

Jan 1, 1993

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By Charles H. White

Methods in colorimetry are based on the assumption that the intensity of the&apos; color of a definite volume .of solution is directly proportional to the quantity of the color-producing substance present. In the preparation and examination of colored solutions there are three ways in which the depth of color may be varied. These variables are : (1) the quantity of&apos; the coloring matter; (2) the quantity of the solvent, or the dilution ; and (3) the thickness or depth of that portion of the solution examined. With these three variables as a basis, three general methods in colorimetry have been devised, all of which have been used in the determination of carbon in steel. In the first method, the quantity of the solution is kept the same for both the unknown steel and the standard, and the sections compared are of equal thickness, while the quantity of the standard is varied until the color obtained is of the same intensity as that produced by a definite quantity of the unknown steel. In laboratories where this method is used there is prepared and kept for permanent use a series of solutions with varying amounts of the standard, representing the percentages of carbon from the lowest to the highest demanded in that laboratory. These standard solutions are kept in bottles or test-tubes of equal diameter, and are arranged in series from the faintest to the most intense color, so that it is a simple matter to find the place of the unknown steel in the series, when the solution is of a definite volume and is contained in a tube of the same diameter as the standard tubes. In the second method, equal quantities of the standard and of the unknown steel are dissolved, the standard is diluted to a definite volume, and the solution of the unknown steel is di-

Jan 1, 1907

North Eastern Russia encompasses the northern part of the Circum Pacific. The region comprises various tectonostratigraphic terranes, including cratonic blocks, fragments of volcanic arcs, accretionary wedge terranes, oceanic crust and passive continental margins. The terranes have been accreted to the eastern margin of the Siberian Craton in the Late Mesozoic. The prominent structures of the region are extended zones of the Mesozoic flysch and turbidites. Another important structure is the 3000 km long Okhotsk-Chukotka volcanic arc which marks the Cretaceous active continental margin of northern Eurasia. The youngest structure of the region is the 2000 km long Late Cainozoic Kamchatka-Kuril island arc system. North Eastern Russia is the main gold producing region of the Russian Federation. Since the beginning of recorded gold production in 1932 until 1995 the region has produced 2575 t (83M oz) of gold. Most of it, 2439.5 t, has been produced from placers. Owing to depletion of alluvial gold resources, exploration and mining emphasis is currently switching to the development of the lode deposits. At least five distinct types of the gold mineralisation are reported in North Eastern Russia - mesothermal gold mineralisation in the Mesozoic fold belts, Paleozoic epithermal gold mineralisation occurring within Omolon block, epithermal gold mineralisation related to the Mesozoic volcanics, Cainozoic epithermal gold mineralisation, gold-bearing Cu-porphyry deposits. The current paper introduces the metallogeny of lode-gold deposits of North Eastern Russia. It provides the review of the regional geology, the selected gold provinces and representative deposits with an emphasis on the mineralisation styles and distribution control.

Jan 1, 1999

By Elias Macedo de Oliveira

Este trabalho tem por objetivo realizar a avaliação das propriedades mecânicas da zona termicamente afetada (ZTA) de junta soldada de aço fundido de alta resistência, obtida pelo processo eletrodo revestido, analisando o efeito da variação do tempo de tratamento térmico pós-soldagem. Foram soldadas juntas multipasses para avaliação de propriedades mecânicas de um aço fundido de alta resistência mecânica, com preaquecimento de 200°C, corrente contínua, posição plana e aporte térmico médio de 1,5 kJ/mm. Após a soldagem, realizaram-se ensaios mecânicos e metalográficos em corpos-de-prova retirados da ZTA e metal base, tanto na condição de como soldado quanto após tratamentos térmicos pós-soldagem. Os tratamentos térmicos pós-soldagem foram realizados à 600°C, por 1, 2 e 3 horas, visando avaliar o efeito destes tratamentos nas propriedades da ZTA. Os resultados mostraram que as propriedades mecânicas não apresentaram diferenças significativas em relação ao metal base com os tratamentos térmicos realizados, propiciando resultados satisfatórios em relação aos requisitos da norma IACS W22 Grau R4.

Aug 7, 2018

By K. J. Griffin, G. W. Rosval

"In our increasingly competitive market, attempts to improve productivity by increasing axle loads have placed more severe demands on rails. CP Rail thus requires stronger, tougher, and more wear-resistant rails from steel manufacturers. The choice of any rail steel is always a compromise between technical and economic factors. The technical assessment of a candidate rail consists of laboratory and field testing. Laboratory evaluation of rail steels cannot adequately model many service conditions and must, therefore, be supplemented by long-term field testing. The field testing conducted on CP Rail is the subject of this paper.Long-term, in-track, assessment of candidate rail steels begins with the selection and re-laying of a test curve representative of the intended service with both the candidate rail and a control rail steel (i.e. the present intermediate or premium rail standard). The wear performance of the candidate rail is evaluated, in relation to that of the control rail, using data obtained with a rail profilometer developed by the Research and Development Department of CP Rail. Qualitative observations are also periodically made to evaluate the relative susceptibilities of the two rail types to surface defect formation. Testing continues until stable metal loss patterns are achieved. Relative life predictions are then made and detailed monitoring of the test site is discontinued.CP Rail&apos;s in-track assessment program for premium rails has resulted in the establishment of a new CP Rail premium rail standard - low-alloy, head-hardened, rails have replaced high alloy rails. The wear/fatigue lives of these new premium rails exceed those of our previous standard by more than 50%, and they also exhibit excellent weldability. CP Rail will continue to evaluate new premium and intermediate strength rail products."

Jan 1, 1988

By J. A. Mielczarski

An infrared external reflection spectroscopy (ERS) technique has been developed to study the structure of the adsorbed layer of ethyl xanthate formed on copper and natural chalcocite (Cu2S) electrodes. The infrared technique provides information concerning the identity and the orientation of the adsorbed species at monolayer and submonolayer coverages. X-ray photoelectron spectroscopy (XPS) studies have also been conducted to monitor changes at the surface. The results show that the first oxidation peak on the voltammograms for copper and the first and second oxidation peaks on the voltammograms for chalcocite electrodes are not characteristic of a chemisorbed xanthate species, which is contrary to what has been reported by other investigators previously. As evidenced by the XPS spectra, there was an increase in sulfur relative to copper on the copper and chalcocite surfaces over the potential region where these oxidation processes occur. The spectroscopic results (ERS, XPS) indicate that the second and third (on copper) and the third and fourth (on chalcocite) oxidation processes recorded on the voltammograms are due to cuprous ethyl xanthate adsorption. The orientation of the adsorbed molecules of xanthate was observed to change with increasing surface coverage. Therefore, it has been concluded that xanthate can modify the copper and chalcocite surface in two different ways. At lower potentials, xanthate is a source of sulfur for the formation of a sulfur-rich surface. At higher potentials, an adsorption layer of cuprous ethyl xanthate is formed. Contact angle measurements show that both of these processes of xanthate surface modification lead to an increase in the hydrophobicity of the substrates.

Jan 1, 1990