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By Lewis V. Wade

This paper summarizes the results of the rock mechanics monitoring program performed as part of Old Ben Coal Company's longwall coal mining demonstration project conducted in cooperation with the United States Bureau of Mines. The work described herein included installation of instruments, collection of data and data analysis performed during mining of the first longwall panel in Mine No. 24. The rock mechanics monitoring program included both surface and underground instrumentation and was designed to achieve the following purposes: 1 -To provide the capability to observe unusual situations during mining so that remedial measures could be instituted quickly 2 -To formulate design guidelines for future longwall mining efforts; 3 -To evaluate surface subsidence, and its character, rate and potential effects on cultural features, and to develop criteria to assist in predicting subsidence for other mines having similar roof conditions. Six previous attempts with longwall methods in Old Ben Coal Company's Hine 21 had been unsuccessful due to roof control problems. A description of these attempts is given by Moroni (1973). In preparation for the present longwall operation a study was performed to review existing data on the previous unsuccessful attempts, to establish coa1-and floor-strata bearing capacities in Mines Nos. 21 and

Jan 1, 1977

By S. E. Bretherton

Discussion of the paper of S. E. BRETHERTON, presented at. the San Francisco meeting, September, 1915, and printed in Bulletin No. 104, August, 1915, pp. 1595 to1599. ANTON EILERS, Brooklyn, N. Y. (communication to the Secretary*). While the advantages in the use of high-line siliceous slags in lead smelting which Mr. Bretherton discusses in this paper are obvious under certain economical conditions, he gives me credit for the introduction of such slags when it does not belong to me. It is true I did considerable experimental work, off and on, for the purpose of finding such slags, while at the Germania in 1877 and 1878, but I did not have occasion to introduce any such slags for regular work, because I had no ores which fitted the economical conditions for using high silica and high lime, except in isolated cases for very brief periods. On the contrary, the ores I had to treat were mostly very ferruginous and very low in silica, so that, economically, I was compelled to run nearly always on slags, which allowed me to use the abundant flux I had without cost. It was August Raht who first had occasion to establish and use for long periods a slag high in silica and line, and low in iron. This was when he was confronted with the task of smelting the. Horn-Silver ores at the smelting works at Franklin, Utah, with as little expenditure for fluxing material as possible. I was at that time in Leadville, Col., where, in the new works I had built, the Billings and Eilers smelters, I had occasion to use profitably many slags, but never anything as high in the earthy bases and in silica as Mr. Raht had to use.

Jan 12, 1915

By Daniel P. Stare, Lucian P. Spiteri, Christopher M. Hallahan, James C. Myers

Buckeye Lake Dam was substantially remediated between 2015 and 2018 as a result of unacceptable dam safety performance. A permanent seepage cutoff, consisting primarily of a soil mixed cutoff wall (SMCW) with occasional sections of steel sheet piling, was constructed along the dam alignment. Closures were required at the terminus of the soil mix elements with existing structures or coffer cells, and at locations where new sheet piling was constructed parallel to the new soil mixed cutoff wall, creating a short circuit seepage path. The original proposed design to construct these closures included permeation grouting methods with chemical grouts. However, a combination of multiple chemical grout types, multiple grout pipes, and an extensive post-grouting verification program was required to ensure the design intent was achieved. After award of the project, the specialty grouting contractor elected to evaluate jet grouting as an alternative closure construction method. The advantages of the jet grouting option offered potential schedule and cost savings to the project as well as a superior product for seepage reduction, given the mixed soil conditions at the site. This paper presents an examination of the site conditions and project goals for the construction of the proposed closure elements for the rehabilitation of Buckeye Lake Dam. Descriptions of the original and alternative treatment methods are provided, with expected performance results. A description of the relative strengths and deficiencies of each method, as well as the feasibility and constructability of each method is provided. The implementation of the jet grouting program is presented, including a discussion of the design elements, quality control test methods, movement monitoring, and verification test methods. This paper also examines the risks associated with jet grouting and how those risks were mitigated during the grouting operations. HISTORY Buckeye Lake is situated approximately 28 miles east of Columbus, Ohio and is managed and operated by the Ohio Department of Natural Resources (ODNR) as part of the Ohio State Parks system. The lake is impounded by natural features that exist along the south and east banks of the reservoir, and by the embankment structure constructed along the north and west banks of the reservoir (see Fig. 1). The reservoir site was originally a natural swamp and the original purpose of the constructed dam and reservoir was to provide water to the Ohio and Erie Canal System. Several dam alignments and configurations were constructed during its early history; however, the original embankment is comprised of homogeneous earthen fill. The embankment is 15 ft (4.6 m) high and extends 4.1 miles (6.6 km) from the North Shore abutment along the east, continuing to the abutment at Lieb’s Island to the West. Several spillway and outlet structures exist along the embankment alignment. Most noteworthy are Seller’s Spillway and Amil Spillway. Fig. 2 is a Plan View of the embankment alignment and appurtenant structures at Buckeye Lake.

Jan 1, 2019

By S. S. Shen, M. J. Pool, P. J. Spencer, J. R. Guadagno

VERY few thermodynamic data are available for rare-earth alloys, partly because of the difficulties of obtaining the metals in sufficiently pure form and also because of their comparative scarcity up to the present time. The rare earths form a very interesting series in the periodic table in view of the progressive filling of their 4f subvalence electron shell and would be expected to provide useful information with regard to alloying characteristics of transition elements. It has been found in recent calorimetric investigations that the heats of solution of a number of the rare-earth metals in liquid tin are highly exothermic.1-4 Exceptionally strong bonding between rare-earth and tin atoms is clearly indicated in the liquid solutions. Continued thermodynamic studies of the behavior of rare earths in solution could thus contribute a great deal to present theoretical knowledge of alloying behavior and would yield an insight into bonding of a strength hitherto unencountered in liquid alloys. The determination of the heats of solution of the pure components in liquid tin is an essential preliminary to calorimetric work of this nature. Heats of solution of praseodymium, neodymium, and samarium in liquid tin at 750" ' and the heats of mixing of Pr-Nd solid solutions' have already been determined in this laboratory. The present investigations with lanthanum continue the study of rare-earth elements. Details of the construction and operation of the liquid metal solution calorimeter used in this work have been published previously by Pool and Peluso and no further description will be given here. The lanthanum used in heat of solution determinations was supplied by Lunex who quoted the purity as 99.9 pct. Their detailed analysis of the material is given in Table I. Samples of 0.0003 to 0.0005 g-atom were used for each run and great care was taken to remove all surface oxide prior to weighing. The samples were stored at all other times in a beaker of oil to prevent their otherwise rapid oxidation. The compounds LaSn (Cudu, L1P type structure) and La&, (structure not classified) were prepared from the appropriate quantities of the two pure components by arc melting under a purified argon atmosphere and once again great precautions were taken to avoid any subsequent oxidation of the specimens. Although no structural examination of the compounds was made, the consistency of thermodynarnic measurements carried out on twenty or so individual samples of each indicates that the compounds were in fact homogeneous, single phase alloys. Samples of the compounds consisting of 0.0003 to 0.002 moles were used in the calorimetric measurements. A solvent bath consisting of approximately 80 g of 99.9 pct pure Sn was used for each series of runs and its heat capacity was determined at regular intervals throughout the experiments using pure tin or tungsten calibration samples. Measurements were made of the heat of solution of lanthanum in liquid tin at 725", 750C, and 775°K and at compositions up to 2.21, 4.76, and 5.25 at. pct La at the three temperatures respectively. In every case, the heat of solution of lanthanum remained constant at its limiting value, within experimental limits, up to the highest lanthanum concentration investigated. Since no change in was observed, it was concluded that the liquid/liquid + LaSn, phase boundary had not been

Jan 1, 1969

By Paul N. Freeman

This paper describes the in-situ performance of two IFS powered support installations at Betws and Penallta Collieries in the South Wales Coalfield, United Kingdom. Intensive monitoring of all powered support functions, strata movement, support/strata interaction and coal seam disturbance permitted an extensive evaluation of powered support performance for all periods of the mining cycle. The influence of support design, support rating, face design, proximate strata and scam section upon support and operating performance are discussed. In-situ performance is compared to design specification and to the requirements of Production Instruction 1982/6. Aspects which show significant variation are highlighted. Particular attention is drawn to the precise analysis of support/strata interaction in the form of canopy and base loading profiles. This illustrates the influence of support rating and configuration in determining the interaction of the canopy and base with the proximate strata. Extensometric monitoring of the coalface highlights the potential zones of disturbance within the seam which allied with support position monitoring provides an accurate basis for theoretical considerations of support loading. Conclusions are drawn, the application of which may enhance the performance and operation of IFS supports in thin to medium sections.

Jan 1, 1992

By Robert W. Bartlett, Keith A. Prisbrey

"Natural biooxidation of shallow, refractory ore heaps, relying on gaseous oxygen diffusion from the heap surface is attractive because of its simplicity and potential low cost, especially without using a lined pad, which is possible if percolation of leachate through the heap is avoided. In this case, the excess oxidation enthalpy must be removed by water evaporation from within the wet ore heap, and the rising water vapor flux within it will impede the downward oxygen flux. An analysis of this process shows that for typical values of pyrite grades and limited temperature increases in the ore heap, the oxidation rate and penetration into the heap is reduced to values between about 30 percent and 50 percent of those obtained when leachate percolation occurs and water evaporation is not a significant mechanism of heat removal.IntroductionHeap biooxidation of refractory gold ores, needed as a pretreatment step to liberate the gold for subsequent extraction by leaching, requires large amounts of oxygen for the normal amounts of sulfide minerals that are typically present, one to two percent pyrite and/or arsenopyrite.The importance and potential limitations of oxygen transport into commercial ore heaps, which are much larger than encountered with column tests of ore and with pilot heaps, has been recognized111 • Commercial ore heaps using radial stacking conveyors are typically about nine meters high and may be 100 meters or more in lateral dimension. Three oxygen transport mechanisms have been identified and analyzed: ( 1) natural convection, which arises from an increase in buoyancy caused by the temperature rise and gas composition changes associated with the exothermic oxidation of the sulfide minerals within the ore heap, (2) forced air ventilation, using low pressure fans and air distribution pipes within the heap, and (3) diffusion of oxygen in the gas-filled void spaces within the ore heap driven by the oxygen concentration gradient from the surface of the heap to the mineral oxidation loci within it."

Jan 1, 1997

The US Bureau of Mines' dictionary of mining terms defines productivity as "the efficiency with which economic resources (men, material, and machines) are employed to produce goods and services." Or, the relationship between the physical outputs and the physical inputs used to produce those outputs. As demand for mine materials dropped, mining companies and equipment manufacturers discovered that ratios between the inputs and the final products were disproportionate to the profits realized. Some companies are fighting for survival. The US, while still the most productive country in the world in absolute terms, is looking over its shoulder as other industrialized nations continue to exceed its yearly productive growth rate. According to John Belcher, Jr., of the American Productivity Center in Houston, TX, the US has seen a steady decrease in productivity growth since the mid-1960s. During the post World War II period, the US labor productivity growth rate was 3.2% annually. The slowdown began in 1965 and by the mid-1970s, the country's annual growth rate was 1%. By 1978, labor productivity growth ceased to gain at all and from 1978 to 1980 a 2% decline occurred. Solutions to the productivity decrease are increasing product prices or improving productivity. By increasing prices, though, the producer runs the risk of pricing himself out of the competitive market. To maintain an acceptable profit level, prices must increase proportionately higher than required to offset production cost increases, Belcher says. Many companies are turning to in-house productivity improvement programs as an answer to increased costs and declining profits. These programs are geared toward management commitment and employee awareness of what productivity means. Companies are finding ways of measuring productivity levels in financial reporting, budgeting, and planning. Organizational teams have been formed to coordinate activities and oversee product management, and improve productivity of materials and capital investments. This special issue of Mining Engineering examines productivity in the mining industry. First, there are articles about various, and different, factors that affect productivity in each of ME's five main readership areas - exploration, mining, processing, coal, and industrial minerals. There is also a look at mining industry productivity from the manufacturer's view. The next section of this special issue is devoted to some topics that affect all areas and sectors of mining: research, management practices, computers, maintenance, and energy management. Then follows case studies in exploration, coal, and iron and steel. These studies provide examples of practices and strategies used by companies and operations to boost productivity.

Jan 11, 1983

By AIME AIME

UNQUESTIONABLY the Coal Division has never had a meeting in which so many outstanding technical papers were presented of immediate practical application to problems of personnel, mining, safety, preparation, combustion, and carbonization. Should there have been those present with the lingering idea that all that was needed for success in the coal industry was a strong back and a weak mind they must have had a rude awakening.

Jan 1, 1942

By L. C. Zhou

The floatability of andalusite and associated minerals are studied and their action mechanisms of andalusite and associated minerals with collector alkyl benzene sulphonate are also studied. Through the mensuration of electrical potential and the infrared spectroscopy, as well as desorption tests, it is confirmed that the interaction of andalusite with sodium dodecyl benzene sulphonate (SDBS), is in addition to physical adsorption, but also is chemical adsorption. The study results of the pure minerals are used for the flotation of actual andalusite mineral. By flotation from contain-ing 45.68% andalusite ore, the fine andalusite concentrate is gained which Andalusite grade is 85.88%, containing Al2O355.29% and Fe2O3 less than 1.5%.

Jan 1, 2014

By Fernando Henrique Gomes de Souza

Techniques which use a spring to supply the bias force to actuator are well adopted since they are inexpensive and simple to construct. In this work it was design an actuator concept using bias-type device technique, which comprises two coils that mutually push against each other to supply the stroke. For the coils springs, it was used a wire of NiTi shape memory alloys (SMA) and a wire of 400 grade maraging steel as construction materials.

Aug 8, 2018

By Wm. Reuben Webster

BRASS is an alloy of copper and zinc. The brasses (using this term to denote all useful proportions of the two constituents) are the most valuable and widely employed of all [ ] nonferrous alloys, because of their high resistance to ordinary corrosive agencies and the very wide range of properties that may be imparted to them by variations in the proportions of the constituents and by variations in mechanical treatment and heat-treatment. Fig. I shows the normal physical properties, as determined by standard tensile tests, of the series when in the annealed condition. Fig. 2 shows the effect of varying amounts of cold-working on an almost pure brass containing 70 per cent copper and 30 per cent zinc. Fig. 3 shows the effect of annealing at various temperatures on the same alloy. This effect is somewhat modi- [ ] fied by the degree of cold-working to which a brass has been subjected, as shown by Fig. 4. A fourth test, which is empirical, has been found useful because of its simplicity the hot hammer test. Samples 1/2 in. in diameter and 3/4 in. long are placed in a suitable furnace. These are withdrawn one at a time at successively higher temperatures and are subjected to the blow of a drop hammer weighing 50 lb. with a drop of 4 ft. The percentages of reduction in length of the cylinders are plotted against temperatures and give a comparative measure of plasticity at different temperatures. The results of this test on several

Jan 1, 1942

By A. B. Campbell

The mines in the eastern part of the now active region of the Tri-State zinc district of Missouri, Kansas, and Oklahoma have unusually acid water, which during periods of moderate or no rainfall As used in the mills to replace losses from evaporation, seepage, and tailings disposal. Its use has caused difficulties by corrosion of equipment and by interference with flotation. The growing importance of flotation- Which requires good water, and the increasing troubles caused by the corrosion of the milling equipment have prompted the Mississippi Valley Experiment Station of the United States Bureau of Mines, in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Mo., to investigate the action of the waters on flotation and to undertake to develop means of obviating their harmful effects.

Jan 1, 1932

By CHRIS A. HARTNAGEL

For the second consecutive year, the production of crude petroleum in New York has fallen below the 5,000,000-bbl. Mark that had prevailed previously since 1937. In 1945, the output totaled 4,658,000 bbl., a decrease of slightly more, than one per cent from the 1944 production. This total represents 2 per cent of the stripper-well production of the United States, which in turn is I 3 per cent of the total annual yield of the nation's petroleum.

Jan 1, 1946

By Longjiang Li, Mao Jiang, Zhihui Shen, Guizhou University, Yin Pan

This paper aims to study the influence and action mechanism of collector Y-89 on the flotation of auriferous pyrite. The measurement to identify adsorption quantity, IR and XPS spectrum analysis and flotation experiment made on the pure mineral were conducted. The research results show that when the dosage of MIBC is 20 mg/L, and pH of 8, the dosage of Y-89 over 60 mg/L, the pyrite recovery rate is greater than 80%.And when the dosage of Y-89is 60 mg/L, dosage of MIBC 20 mg/L, the pH in a wider range (pH=4~9), the recovery is greater than 75%. When the pH is above 10, the pyrite is depressed and its recovery rate is found to be dramatically dropping. Adsorption quantity measurement also shows that the strong alkaline conditions inhibit the adsorption of Y-89 on the surface of auriferous pyrite. IR measurement indicates that chemisorption of Y-89 occurs on the surface of auriferous pyrite. XPS spectrum analysis indicates that without adding Y-89, oxidation reaction occurs on the surface of pyrite. But when Y-89 is added, the chemical environment of Fe on the surface of pyrite has changed. Such findings indicate that with Y-89, chemisorption occurs on the surface of auriferous pyrite.

Jan 1, 2014

By John Birkinbine

(New Haven 'Meeting, February, 1909.) AWAKENED public interest in efforts to conserve natural resources will certainly be appreciated by the members of the American Institute of Mining Engineers, and a discussion upon conservation may well form a part of one of the Institute meetings, for the records of papers and discussions which appear in the 38 volumes of its Transactions are replete with evidence of effort's in this direction. Every process which reduces the fuel consumed or the power applied per unit of product; every utilization of waste material, or employment of that formerly rejected, to obtain something of value ; every feature of construction or operation which lessens the labor required or increases the output per employee, is an advance in the direction of true conservation. This may not appear from the records of late conferences or from published articles, in which the effort seems to be concentrated upon reducing the consumption and presenting to the people of the country estimates of exhaustion of natural resources. I rejoice in the awakening of public interest in a matter so important for the present and future welfare of our nation; I appreciate the possibility of much good following conferences of the Governors and delegates from various States and from national societies; and I recognize the interdependence, not only of different States, but of contiguous nations. In fact, the marvelous development of transportation by land and by water, and the decreasing rates at which commodities can be moved great distances, have in many cases practically obliterated geographical boundaries, and nearly every country on the globe can either market its product in other lands or draw upon them for raw or manufactured materials ; hence, conservation is an international subject.

Apr 1, 1909

By S. H. Amini, A. Noble

"While many classic mineral processing circuit design approaches rely on deterministic methods, numerous studies have shown that the uncertainty inherent to the various input parameters can significantly influence design decisions. In a separation circuit, many of the technical uncertainties can be mathematically represented as statistical distributions for the unit recovery and feed grade. These uncertainties are then propagated by the circuit design and reflected in the circuit performance indicators, such as product grade and global recovery. An effective design strategy entails identifying which units are most influential in this uncertainty propagation and thus merit further consideration. Unfortunately, few analytical tools provide this information, particularly those that rely solely on deterministic methods. However, one promising approach is through the application of Taguchi’s method, in a fashion similar to statistical tolerancing of manufactured products. Since the technical challenges are fundamentally similar, Taguchi’s method shows promise in evaluating the level of compounded uncertainty by various circuit designs while determining the role of each separation stage on the overall selectivity and variability of separation circuits. This paper demonstrates Taguchi’s method in several two and three unit circuit designs. INTRODUCTION AND METHOD DESCRIPTION Uncertainty in Mineral Processing Circuit Design Analysis and estimation of uncertainty propagation in mineral processing separation circuits is an essential and significant aspect of an optimal circuit design procedure. Most of the current circuit design methodologies have been constructed, implemented, and validated using a deterministic modeling approach. However, numerous studies have shown that the inherent uncertainty induced by uncertain design parameters can be a significant factor in many mineral processing applications (e.g. Kraslawski 1989; Xiao and Vien 2003; Ghaffari et al. 2012). Thus, an effective circuit design methodology must be able to quantify uncertainty in separation circuits with limited input data. This paper describes Taguchi’s method, as an experimental design technique, to approximate uncertainty in mineral processing applications, and then the similarity of results between Taguchi’s method and Monte Carlo Simulation is investigated. Monte Carlo Simulation The term “Monte Carlo Simulation” has been used to refer to a variety of stochastic simulation methods spanning a broad array of business, technical, and scientific domains. Most generally, Monte Carlo Simulation refers to numerical analysis which is based on (pseudo) random sampling from a domain of input parameters with a known statistical distribution. This methodology allows one to determine the distribution of expected results from a standard deterministic process model. Execution of a Monte Carlo simulation begins by identifying the domain of input parameters, statistical distributions for each parameter, and a deterministic process model which describes the anticipated result as a function of the inputs. Next, one discrete random sample is taken for each input parameter, considering the input distributions. The process model is then solved for this mix of input parameters, producing a single simulation result. This procedure is then repeated a “large” number of times, utilizing new randomly sampled input parameters for each simulation iteration. Once the desired number of iterations is reached, the results of each independent simulation are aggregated to produce descriptive statistics such as minimum, maximum, mean, standard deviation, kurtosis, and other distribution parameters. Given enough iterations, the Monte Carlo method fully explores potential synergies between the input parameters. The methodology does not require the process model to be differentiable, continuous, or even analytically defined. While the number of required iterations varies in relation to th"

Jan 1, 2017

By R. Winand, M. Degrez, C. Temmerman

"The influence of the copper electro crystallization inhibitors (mainly thiourea, gelatin and chloride ions) is studied in a new fully automatic pilot plan. This paper describes the conception and the building of this plan. The new approach is to reproduce the experimental conditions observed in the industry with the three additives present simultaneously in the electrolyte and secondly to study the influence of a slight modification of the concentration of one inhibitor, the others being present in the electrolyte with their industrial nominalconcentrations.1. INTRODUCTIONDespite the fact that gelatine, thiourea and chloride ions have been used in copper electrorefining for a long time, precise knowledge concerning their influence on the cathode deposit, metallographic structure and associated properties is still lacking.Many authors studied the influence of each additive separately, or of two added at a time. Only a few authors studied the combined influence of the three additives added simultaneously. The general conclusion that can be drawn is that the combined influence is far from that forseen from the influence of each additive separately, or even from two additives used at a time. Moreover most of the experiments described in the literature were performed by adding all additives at once initially. It is however, well known that gelatine looses a great part of its activity during the first half hour due to degradation by sulfuric acid (as shown by the cathode overpotential drop). Thiourea is rapidly replaced by a number of degradation mole,cules and complex ions including cations from the solution, changing even the equilibrium between Cu, Cu(I) and Cu(II).Chloride ions are consumed by precipitation.A number of successive research projects [1-9] led pregressively to the concept that, in order to obtain reproducible results representative of industrial cathodes, it was necessary to simulate as far as possible industrial conditions. It was essential that all additives were added continuously during the electrolysis, with, as consequence, a continuous bleed.The purpose of this paper is to describe the concept of a new fully automatic pilot plan for copper electrorefining and to present the first results."

Jan 1, 1997

By R. O. Suominen, P. A. Taskinen, K. R. Lilius, A. T. Jokilaakso

Chalcopyrite concentrate was flash-oxidised in a laminar-flow furnace in oxygen-nitrogen atmospheres that ranged in composition from N2 to N2 + 50 vol% O2. Gas pre-heating temperatures were 500-1100 degrees C and four particle-size fractions were studied: 28-38, 38-44, 44-62 and 62-74 micrometres. The effect of the residence time of the particles on sulphur removal was studied in the range 0.1-0.35 s. Scanning-electron microscopy combined with energy-dispersive analysis and back-scattered electron analysis was used to determine the morphology and mineralogy of the reacted particles. Total desulphurisation was achieved under the most oxidising conditions. Particles were observed to undergo fragmentation during oxidation, the violence of this depending on the iron and sulphur contents and the original particle-size fraction. The melting and/or reaction stages of the particles under different conditions were studied in powder samples. Polished sections were examined to follow the development of porosity and the mineralogy of the particles. A model for the fragmentation process is described

Jul 1, 1991

By A. H. Grobe, F. N. Rhines

AT elevated temperatures the oxide of silver is unstable in the air at atmospheric pressure, consequently no external oxide scale forms upon pure silver under conditions of high-temperature annealing When small quantities of certain alloying elements are present in the silver, the formation of a thin external scale is possible' and in addition there may form a subscale composed of the oxide of the solute element precipitated within the body of the silver Norbury2 and Leroux and Raub3 have reported internal oxidation (subscale formation) in alloys of silver with 2, 7 5, and 30 per cent of copper The presence of the subscale is believed to be responsible, at least in part, for the objectionable "fire mark" in Sterling silver' Several other alloys of silver, after oxidizing heat-treatments, are known to exhibit undesirable polishing characteristics that may be the result of internal oxidation Except for the absence of an external scale of silver oxide, it is to be anticipated that silver alloys will prove to be very similar in their oxidation behavior to the alloys of copper, the oxidation characteristics of which have been studied in some detail 5,6 The present research confirms this anticipation The oxidation of a series of 20 dilute alloys of silver has been studied metallographically, some types of subscale not encountered among the copper alloys have been found Instances of internal oxidation in alloys of most of the metals of the I-b and VIII groups of the periodic system are on record, but evidence of this type of oxidation in alloys of the metals of the intermediate groups is lacking A number of the metals of the intermediate group, among them cadmium, lead, tin, and zinc, appear to provide the conditions essential to subscale formation, i e , they form oxides with a relatively low negative free energy of formation, they dissolve other metals that form more stable oxides, and, presumably, oxygen will diffuse through them In a study of 4o alloys of these white metals only a few cases of internal oxidation have been found The probable reasons for this difference in behavior will be discussed presently EXPERIMENTAL PROCEDURE Silver -The silver alloys employed in the oxidation studies were prepared in heats of 30 grams each from high-purity silver (99 993 per cent Ag)* and the purest avail-

Jan 1, 1942

By P. Perruzza, R. Grandori, A. De Biase, A. Ciamei, A. Busillo

The Turin metro alluvium soil is mainly made of large boulders, cobbles and gravel , few sand and almost no fines. This grain size curve is out of the range of application for EPB and Slurry TBMs. In order to bore 5 of the total 7,5 kms of Line 1 tunnel, two specially designed Lovat EPB TBMs were utilised in combination with a systematic non structural pre-grouting of a small volume rectangular slab just above the tunnel section. The same pre-grouting was not however applicable for lack of access on surface in some sections of the remaining 2,5 km of tunnel that had to be bored below important buildings/structures, with under ground water pressure up to 1,5 bar, with curves radius of 180 m only. For these more critical sections it was necessary to study and implement a new technical solution and improve the capacity of the TBM to work efficiently in EPB mode even in this unsuitable ground and overall conditions. After months of studies the selected and adopted solution has been to inject inside the cutterhead chamber, in addition to the almost standard foams & polymers additive mixes, a suspension of limestone powders. This with the scope of compensating the lack of fines of the natural ground with rock powders.

Jan 1, 2005