Search Documents

By Judy K. Todd

Double benching has been utilized as an excavation technique in open pit mines for many years. This process involves drilling, blasting, and excavating the material for the design bench height. A second bench is then excavated without the creation of a catch bench, i.e. only minimal offset from the first bench face is allowed when drilling off the second bench. The result is a double high bench face or double bench. When drilling off the second bench, the offset of the drill from the bench face projects the lower bench face into the pit up to an extra five meters. This reduces the maximum attainable bench angle, enhances the probability of rock escaping the catch bench and increases the overall strip ratio. The generally utilized process of trim blasting also can impact on the final bench profile by contributing to blast damage of the face. BHP Billiton Diamonds Inc., Ekati Mine Diamond MineTM, has pioneered the usage of a technique that eliminates this offset. Double benching is accomplished by drilling a single, 30m pre-shear (two 15m benches) to define and protect the final bench profile. This article provides a comparison of the attained face angles obtained in the field utilizing both of the above methods, as well as a comparison with the analytically predicted angles prior to excavation.

May 1, 2002

By X. Y. Yu, X. A. Wei, A. Zeng

"The flotation behaviors of diaspore and three kinds of silicate minerals - kaolinite, illite and pyrophyllite - using an organosilicon cationic surfactant as collector were investigated as functions of reagent concentration and pulp pH. The results show that the organosilicon cationic collector QAS122 is a suitable collector for the flotation of aluminosilicate minerals but has weak collecting ability with regard to diaspore, enabling the flotation separation of diaspore from silicate minerals using QAS122 as collector. The flotation of a bauxite ore was then studied in detail. Finally, a reverse flotation separation process was used to process a low-grade bauxite ore. It was concluded that use of the organosilicon cationic collector is effective. A concentrate with aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, of 9.67 was obtained from natural bauxite ore with A/S of 6.07 at pH of around 11. The Al2O3 recovery rate was 81.72 percent. IntroductionChina has abundant bauxite ore resources, but more than 98 percent of the bauxite ores are the diasporic type, with the characteristics of complex mineral composition, low aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, and difficulty of processing. The gangue minerals in bauxite ores are mainly kaolinite, pyrophyllite and illite, containing titanium and iron impurities (Zong et al., 2008). It is known that high-grade bauxite ore, with A/S greater than 8, can be processed directly by the Bayer process (Papanastassiou et al., 2002; Ma et al., 1996). However, Chinese diasporic ores have been processed mainly by the sintering process, which is environmentally damaging and energy intensive. Increasing the A/S of the diasporic ores using a flotation method is needed (Xia et al., 2010).Froth flotation is one of the most widely used processes to concentrate valuable minerals in beneficiation ores. It is particularly useful for separating finely ground ores from their associated gangue minerals. For diasporic bauxite ores, flotation is applied to obtain high-quality material for the Bayer process by increasing the A/S. Direct flotation has been shown to be an efficient method for the desilicating of diasporic bauxite ore (Wang et al., 2004; Xu et al., 2004), but reverse flotation has more advantages for this purpose, including less collector consumption, less foaming product and less effect on metallurgy (Liu et al., 2007; Hu et al., 2003; Hu, 2003; Luo et al., 2001)."

Jan 1, 2015

By Dan B. Kivari

A key operation of any milling circuit is grinding. Over the last two decades, large diameter semiautogenous grinding (SAG) mills have become the preferred primary grinding mills. The drive systems became more complex as the size of the mills became larger, during which time operating and design experience for SAG mill accumulated. Considerable reliance is now placed in power electronics to provide flexibility in SAG mill operation to meet the demands of lower operating costs. Most earlier SAG mills were designed to operate at fixed speeds. Present day SAG mills can operate at a fixed speed or variable speed through the use of an ac synchronous motor or dc motor. This flexibility, however, comes with an increase in capital and operating costs. Since the capital and operating costs of a project directly affect the project's rate of return, the selection of a SAG mill and its drive system should depend, in part, on the impact that the extra cost makes on the project. This impact can be measured by performing an economic analysis based on net present cost (NPC) calculations. Although the NPC calculation is an important factor in the grinding mill selection, other factors, such as reliability of mill drives and power source, are important elements in the decision making process. This article examines how the NPC calculation, plus reliability and power source, influence SAG mill selection.

Jan 1, 1992

By James J. Halbouty

The restraining effects of war conditions on oil-field development are well illustrated by statistics on South Texas † fields for the year 1942. Statistics also show a decline in wildcatting, but this decrease is much smaller than that shown by field activity. In comparison with results in 1941, there was a reduction of about 44 per cent in the total number of wells drilled in the area (802 in 1942 against 1452 in 1941) This 44 per cent drop represents declines of 50.4 per cent in field wells and of 17.4 per cent in rank wildcats. Field wells (exclusive of 18 wildcats that discovered fields) totaled 598; also, 204 rank wildcats were drilled (see Tables 3 and 4). The corresponding figures for 1941 are 1205 field and extension wells and 247 rank wildcats. In this connection, it should be noted that whereas in 1941 the rank wildcats made up only 17 per cent of all wells drilled in the area, their percentage of the 1942 total was 25.4 per cent. In spite of the decrease of 43 in the number of rank wildcatst drilled, there were 18 new productive areas discavered, one more than the 17 new fields found in 1941. Thus the field-discovery rate for 1942, one new field for every 11.3 wildcats drilled, compares favorably with the I to 14.5 rate of 1941. Thirteen new producing levels were opened in fields; this includes the finding of 44' gravity crude on the west flank of the Sejita field in a 5700-ft. sand, which produccs distillate higher on the structure. Interesting, and showing the general scarcity of sand discoveries, is the fact that of the 13 new sands discovered, 7 were found in Jim Wells County. The year's sand-discovery rate of one new level for every 46 field wells compares very unfavorably with the I to 19.7 rate of 1941, during which 61 new producing horizons were found. Developmeilt of new fields was on a small scale. In several instances activity in these areas was not carried beyond the drilling of the discovery well. The field discoveries of 1942, together with the type of production obtained from the discovery wells and the total number of wells (productive and dry) drilled in them, are given below: Discovery Num- Field.I County Well her Produced Wells I. Cadena....... Duval Oil 2 a. Garza......... Duval Oil I 3. Dinn......... Duval Gas I 4. Keller......... Duval Gas I 5. East.......... Tim 0 11 I 6. Green Branch . McMullen Gas 3 7. Frost. .GreenBranch........ Starr Oil I 8. Garcia........ Starr Oil 6 9. Ulrich........ Starr Oil 4 10. Lykes......... Webb Oil 2 11. McLean....... Webb Oil 9 Iz. Alamo........ Hidalgo Distillate 2 and gas 13. Penitas....... Hidalgo Distillate 2 and gas 14. Xmpnan..... Jim wells i a 15. South Premont Jim Wells Distillate i and gas 16. Quinto Creek.. Jim Wells Gas 4 17. Roth.. . :..... Jim Wells Gas I I 18. South Sinton.. San Distillate I Patricio and gas . • See Table 2 for data on discovery wells and Table I for information on these fields. • See Table 4.

Jan 1, 1943

By James J. Halbouty

The restraining effects of war conditions on oil-field development are well illustrated by statistics on South Texas † fields for the year 1942. Statistics also show a decline in wildcatting, but this decrease is much smaller than that shown by field activity. In comparison with results in 1941, there was a reduction of about 44 per cent in the total number of wells drilled in the area (802 in 1942 against 1452 in 1941) This 44 per cent drop represents declines of 50.4 per cent in field wells and of 17.4 per cent in rank wildcats. Field wells (exclusive of 18 wildcats that discovered fields) totaled 598; also, 204 rank wildcats were drilled (see Tables 3 and 4). The corresponding figures for 1941 are 1205 field and extension wells and 247 rank wildcats. In this connection, it should be noted that whereas in 1941 the rank wildcats made up only 17 per cent of all wells drilled in the area, their percentage of the 1942 total was 25.4 per cent. In spite of the decrease of 43 in the number of rank wildcatst drilled, there were 18 new productive areas discavered, one more than the 17 new fields found in 1941. Thus the field-discovery rate for 1942, one new field for every 11.3 wildcats drilled, compares favorably with the I to 14.5 rate of 1941. Thirteen new producing levels were opened in fields; this includes the finding of 44' gravity crude on the west flank of the Sejita field in a 5700-ft. sand, which produccs distillate higher on the structure. Interesting, and showing the general scarcity of sand discoveries, is the fact that of the 13 new sands discovered, 7 were found in Jim Wells County. The year's sand-discovery rate of one new level for every 46 field wells compares very unfavorably with the I to 19.7 rate of 1941, during which 61 new producing horizons were found. Developmeilt of new fields was on a small scale. In several instances activity in these areas was not carried beyond the drilling of the discovery well. The field discoveries of 1942, together with the type of production obtained from the discovery wells and the total number of wells (productive and dry) drilled in them, are given below: Discovery Num- Field.I County Well her Produced Wells I. Cadena....... Duval Oil 2 a. Garza......... Duval Oil I 3. Dinn......... Duval Gas I 4. Keller......... Duval Gas I 5. East.......... Tim 0 11 I 6. Green Branch . McMullen Gas 3 7. Frost. .GreenBranch........ Starr Oil I 8. Garcia........ Starr Oil 6 9. Ulrich........ Starr Oil 4 10. Lykes......... Webb Oil 2 11. McLean....... Webb Oil 9 Iz. Alamo........ Hidalgo Distillate 2 and gas 13. Penitas....... Hidalgo Distillate 2 and gas 14. Xmpnan..... Jim wells i a 15. South Premont Jim Wells Distillate i and gas 16. Quinto Creek.. Jim Wells Gas 4 17. Roth.. . :..... Jim Wells Gas I I 18. South Sinton.. San Distillate I Patricio and gas . • See Table 2 for data on discovery wells and Table I for information on these fields. • See Table 4.

Jan 1, 1943

By Yoginder P. Chugh

Subsidence may be observed above partial extraction shallow room-and-pillar mines where the coal seam(s) is associated with weak and thick claystone in the floor. This paper presents results of subsidence studies at such a mine. During the 26-month study period, a time dependent subsidence causing a maximum vertical movement of 50 mn was observed. After a subsidence rate of 6.0-6.5 m/month for the first two months after development of mine workings, the rate decreased to 0.8-0.9 mm/month after 17 months. However, presumably due to settlement of barrier pillars, it increased therafter to 1.7 mm/month for the next 9 months. Angle of draw, based on zero subsidence, was calculated to be about 29 degrees. Maximum tensile strain and compressive strain values observed were 0.040 pct and 0.039 pct respectively. A hypothesis was fomlated to correlate surface subsidence movements with observed underground movments. The data collected to date fits reasonably well within the formulated hypothesis.

Jan 1, 1989

By J. Sanchidrián, A. Fernández, P. Segarra

The combination of chemical analysis techniques as XRF and measurement-while-drilling (MWD) technology in underground mining is a novel approach to gather comprehensive on-line information about physical and mineralogical data. In this work their integration is investigated aiming to delineate the ore/waste boundary. The input data analyzed come from a narrow vein underground mine, where the ore correspond to fluorite, and gathered in two production levels with complex mineralogical characteristics. Two approaches are followed to build a generalizable classification methodology and a site-specific model: a k-means clustering heuristic algorithm to define rock classes based on their physicochemical features, and a machine learning (ML) ensemble model trained with drilling parameters. For an imbalance class problem, a good recognition is obtained for the ore when is related to a high content of silica and for the waste. To predict the ore with low silica content it is necessary to integrate an analysis-while-drilling method to recognize the fluorite content when this mineral is embedded in different rocks. MWD can be employing for the lithologies recognition when representing different structural and mechanical properties between them.

Jan 1, 2024

By W. Haibei, Lei. Z., Z. Bangsheng, W. Yufang, J. Kaixi

In 2007 output of zinc was more than 3.71 million tons in China. Some new projects have finished FS and several new zinc plants are building now. In recent ten years it happened great changes in zinc industry. For zinc concentrates one pressure leaching plant was built with capacity 10,000t/a and at least four companies are carrying out FS or engineering design now. Direct atmospheric leaching will put into used in China in 2008 with capacity 100,000t/a. It is estimated that until 2010 the output of direct leaching will be 400,000t/a.

Jan 1, 2008

By A. J. Kwitowski

Teleoperation is a technology that can provide significant health and safety improvements in mining, by relocating machine operators hundreds of meters away from the face area. The U. S. Bureau of Mines (USBM) has recently developed a teleoperation system for continuous mining and haulage equipment. This system features near-real-time closed-loop control. A prototype system was developed and demonstrated on the surface. This system could be used in thin-seam applications down to 914 mm. Details are provided on the developed teleoperation system, results of testing, and expected, future applications of this technology for improved safety.

Jan 1, 1994

By P Kappen, R N. Collins, K M. Spiers

X-ray absorption spectroscopy (XAS) is a synchrotron-only technique used to determine chemical speciation, providing a powerful alternative to most traditional ‘wet chemistry’ and lab-based speciation methods. XAS is an element specific method that can be used to address a variety of systems, ranging from heterogeneous to homogeneous, polycrystalline to amorphous, and solid to liquid. The strength of XAS in identifying and managing chemical species in tailings and mine waste is demonstrated, with the presentation of highly relevant studies into lead, uranium, chromium and arsenic speciation. In each example, waste samples are compared with known standards, allowing an assessment to be made of the quantity of particular chemical species in each.CITATION:Spiers, K M, Collins, R N and Kappen, P, 2015. ‘Forget the wet chemistry’ – how the Australian Synchrotron can help with tailings and mine waste management, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 145–148 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By C. Opoku-Ware, M. Kukay, P. Conrad, F. Inkoom, R. Pal

Researchers at Montana Tech are investigating the potential for developing trees tolerable to degraded un-reclaimed mine site tailings and soils as a solution to re-establishing long-term tree growth on those sites. This project involves growing tree seedlings from seeds planted in the degraded mine tailings and soils in which they will eventually be planted. The outcome of the project is expected to lead to a successful solution for re-establishing tree growth in degraded tailings and soils in Butte, Montana with minimal post-planting human intervention. Work conducted on the project to date has shown successful growth of seedlings in degraded tailings and soils. INTRODUCTION In an effort to improve Butte Area One natural resources, this research project is working to help restore tree growth in the Butte Priority Soils Operable Unit Boundary (BPSOU) (Opoku-Ware, et al 2018). Research by Blicker, et al (2003) found that, the BPSOU, which is part of the Silver Bow Creek/Butte Area National Priorities List (Superfund) Site within and near Butte, Montana has multiple historic mining sites situated entirely within the urban setting of Butte. Mine wastes and mill tailings, accumulated from over 100 years of gold, silver, and especially copper mining are dispersed throughout Butte, posing health risks to human and environmental receptors. Stabilization of tailings sites is needed to control fugitive dust, prevent run-off of toxic material resulting in subsequent sediment deposition in streams, reducing the volume of water seepage through acidic and heavy metal contaminated material, and improving land productivity and aesthetic values (Watkin and Watkin, 1982). If successful, the project will help restore water quality and maintain stream flow in Silver Bow Creek where it flows through Butte Area One. Trees native to Butte are being grown to seedlings in a greenhouse located on Montana Tech’s campus which will be planted in degraded soils located within the BPSOU. Growing trees is expected to help restore vegetative ground cover within the watershed contributing to stream flow in Silver Bow Creek. The trees will prevent soil and tailings from eroding and being deposited in Silver Bow Creek where they could degrade water quality and choke stream flow. The project combines research with tree seedling growth to provide a resource for Butte that could produce thousands of tree seedlings each year adapted to the harsh climate, soil, and tailings conditions that exist in the BPSOU where they will grow. It is anticipated that the trees developed by the project will have the capability for long-term survival and growth because they will be germinated and grown into seedlings in the degraded soils and tailings collected from the BPSOU where they will be planted. Soils and tailings collected for the project have been evaluated to determine if they lack nutrients or contain substances potentially toxic to the long-term growth and survival of the trees. Toxic levels of metals, high concentrations of soluble salts, extremes in pH, nutrient deficiencies and imbalances, surface crusting, high bulk density, low infiltration rates, high surface temperatures, low cation exchange capacity, restricted microbial activity, low water retention, harsh climatic conditions and surface particle movement are some of the traits of mine tailings sites that restrict revegetation efforts (Barth, 1986).

Jan 1, 2019

By Alan R. Buehler

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied part of the 256,430-acre Alvord Desert and part of the 22,240-acre East Alvord Wilderness Study Area (OR-002-074 and OR-002-073A, respectively), in order to evaluate their identified mineral resources. The study areas are located in Harney and Malheur Counties, OR, about 25 mi northeast of the small village of Fields. There are no mines, prospects, or identified mineral resources inside the study areas. Basalt flows within the study areas contain chalcedony-lined vugs and banded agate which may be of interest to rock hounds. An ignimbrite flow contains perlitic material, but crystalline contaminants make it unsuitable for commercial uses. Lacustrine (lake) sediments contain diatomite and clays, and evaporite crusts contain boron too low grade to profitably mine. Small quantities of common opal and petrified wood occur which might be of possible interest to rock hounds. Some of the petrified wood is black, free of fractures, and polishes well; it may be suitable as backing material for soft, thin, and brittle gemstones, such as precious opal. The lacustrine sediments also contain black, fetid layers which have above background, but economically insignificant concentrations of zinc, cobalt, nickel, barium, iron, manganese, aluminum, and potassium. Large quantities of fine-grained dune sands within the study areas are too far from markets for economic consideration. Ephemeral streams in the study areas contain small amounts of placer gold of no economic interest. The western portions of both study areas are reported to have moderate favorability for occurrences of natural gas, and both study areas are reported to have high favorability for the occurrence of geothermal resources. As of December 1986, oil and gas leases covered 3,100 acres in the study areas.

Jan 1, 1987

By Lin Li

A reliability based analysis method for a drilled shaft stabilized slope system is presented in this paper. In the past effort, a deterministic method using the limiting equilibrium method of slices for determining the global factor of safety of a slope reinforced by a row of drilled shafts was developed using the soil arching concept. The drilled shaft stabilization mechanisms for the slope were treated as the drilled shaft induced soil arching, which reduces the driving forces on the down slope side of the drilled shaft. The effect of drilled shafts induced soil arching on the reduction of the driving stresses in the limiting equilibrium slope stability analysis was quantified by the load transfer factor through extensive finite element simulation studies. A semi-empirical equation was also developed for expressing the load transfer factor as a function of the soil properties, including strength parameters and unit weight as well as the slope geometry and soil profile, the location and spacing of the drilled shaft, and the dimension of the drilled shaft. However, due to the inherent uncertainties of the soil properties and the model error of the semi-empirical load transfer equation, a modification of the deterministic method into a probabilistic method is developed in this paper. The Monte Carlo statistical method is used to generate random variables for the soil strength parameters based on the prescribed probability characteristics, including mean, COV, and the probability distribution function. In addition, the modeling error of the load transfer factor is also treated as a random variable in the Monte Carlo simulation method, in which the mean, COV, and probability distribution function for the bias of the semi-empirical equation are used. The developed theories were coded into a computer program for analyzing complex slope geometry and slope profile conditions. Two examples are shown in the paper to illustrate the analysis results of the developed probability approach for determining the reliability of a drilled shaft stabilized slope system.

Jan 1, 2017

By B Firth, G OÆBrien, B Jenkins

In coal flotation, particles of different components of the coal such as maceral groups and mineral matter and their associations have different hydrophobicities and therefore different flotation responses. By using a new coal grain analysis method for characterising individual grains, more detailed flotation performance analysis and modelling approaches have been developed. The method involves the use of microscopic imaging techniques to obtain estimates of size, compositional and density information on individual grains of fine coal. The density and composition partitioning of coal processed through different flotation systems provides an avenue to pinpoint the actual cause of poor process performance so that corrective action may be initiated. The information on grain size, density and composition is being used as input data to develop more detailed flotation process models to provide better predictions of process performance for both mechanical and column flotation devices. A number of approaches may be taken to flotation modelling such as the probability approach and the kinetic model approach or a combination of the two. In the work reported here, a simple probability approach has been taken, which will be further refined in due course. The use of grain data to map the responses of different types of coal grains through various fine coal cleaning processes provided a more advanced diagnostic capability for fine coal cleaning circuits. This enabled flotation performance curves analogous to partition curves for density separators to be produced for flotation devices.

Jan 1, 2005

The Bureau of Mines annually publishes statistical data reflecting technological trends in the minerals industry (metals and nonmetals except fuels). This report outlines recent developments and trends and the technology outlook for mining practices and metallurgical processing based on a review of the minerals industry during the past 2 years. A historical statistical series which indicates trends in the minerals industry has been extended with 1970 data. In addition, data are given from a 5-year Bureau of Mines cyclic canvass of froth flotation plants. Data for 1970 are compared with those of 1960 and 1965.

Jan 1, 1972

By D. Ouellet, G. Gagnon, B. Simser, V. Falmagne

The mining sequence at Noranda’s Bell- Allard mine calls for two mining fronts retreating toward a central pillar known as the Retreat Zone between pyramids A and C. It is clear from numerical modelling and rock mass characterization that the induced stress level in the pillar will exceed the rock mass capacity. A mining plan was developed including the redimensioning of stopes in the Retreat Zone, additional ground support and instrumentation in order to ensure the safety of the workforce and to maximize ore recovery while minimizing production delays. The mining strategy consists in allowing the rock mass to fracture and fail progressively while maintaining control of the existing openings with the appropriate support. A systematic analysis of rockbursting and caving hazards was conducted for all accesses and stopes in order to plan ground support and instrumentation needs.

Jan 1, 2004

By Haotian Xue

A new process to extracted antimony directly from stibnite concentrate by reductive sulfur-fixation smelting in sodium molten salt has been presented. The influences of sodium salt content and composition, ferric oxide addition, temperature and time was investigated, respectively. The optimum conditions was determined as follows: W????: ??concentrate=40%, W??alt: ????concentrate =88.75%, WFe2O3 :Wconcentrate =55.13%, W??aCl: ????alt=40%, 1123K, 1h. Under above-mentioned optimum conditions, the average direct recovery ratio of antimony can reach 91.48%, and the main chemical composition of obtained crude antimony is Sb 94.31%, Fe 4.436%, Pb 0.502%, Au 0.0236%. In comparison to traditional antimony pyrometallurgical process, the smelting temperature of present process is reduced from 1423~1473K to 1123~1173K. During the smelting operation, SO2 emision can be avoided completely due to sulfur-fixation as FeS. Furthermore , S0 can be obtained when the molten slag is handled by water leaching with conditions of 323K, L/S=5/1, 2h.

Jan 1, 2014

By Julien Deby

The sinking of a deep shaft is always a serious undertaking, especially when the strata to be traversed are of great hardness, or when they are feebly coherent or highly saturated with water. In the. first case, that of solid rock, modern appliances, such as the rock-drill, put into motion by air-compressors, along with suitable explosives, will generally answer the purposes of the mining engineer until he has reached the main water-levels. When these have

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985

In this very interesting paper, Mr. Harrington mentions a considerable variety of materials suitable for use in the rock dusting of coal mines; this suggests that you may possibly be interested in same purely theoretical figures tending to show the superiority of gypsum for this purpose. Some of the gentlemen present have found difficulty in applying a thick, adherent coating of dry gypsum to the ribs and roofs of their workings, for which reason pulverized gypsum will perhaps be chiefly useful for the loading of barrier troughs. In view of the function that rock dust is expected to perform in case of a coal-dust explosion, it seems obvious that the most efficacious dust will be the one that can absorb the most heat and absorb it most rapidly. The customary rock dusting materials differ considerably in this respect, depending principally upon the facility with which they can be decomposed at the temperatures encountered in a coal-dust explosion. Such stable materials as silica, anhydrite and flue-dust vary but slightly in their heat-absorbing capacities, the specific heats of minerals in general ranging between 0.19 and 0.22; on the other hand, gypsum and limestone, as well as certain argillaceous materials such as shale, adobe, etc., are capable of absorbing additional heat through their chemical dissociation, although, as will appear later, it is questionable whether the amount of heat thus absorbed, in the case of limestone, shale, and adobe, is large enough to have any practical value. As to the temperature developed by a coal-dust explosion, the Bureau of Mines reports one test in which gold foil was melted, and others in which silver foil was melted, but not gold; hence 1832° F. (1000° C.) seems a reasonable figure to assume for purposes of calculation. Normal temperature is taken as 68° F. (20°C.). The other fundamental data required for the computations as cited by various authorities, are as follows: [Specific heats Gypsum : 0.259 Calcium sulphate, anhydrous. . .190 Limestone 0.216 Lime 0.239 Clay, shale, silica, etc. usually not exceeding 0.220 Carbon dioxide .:0.217 Steam (at atmospheric pressure)0.500 Heats of formation CaSO4+2H2O-4.606 Kg-cal. per gram molecule, or 48.2 B:t:u.' per pound of gypsum.- CaO +C0,42.5 Kg.-cal. per gram molecule, or 765 B.t.u. per pound of limestone. Latent heat of vaporization of water. from and at 100°C.. 535.9 Kg.-cal. per kilogram (964.6 B.t.u. per pound).] Computations will be based on the Fahrenheit scale and British thermal units, as probably more familiar in the coal industry. First as to the inert materials: their heat-absorbing capacity per pound is simply the product of their specific heat, say 0.22, multiplied by the assumed rise in temperature, 1764° F., or 388 B.t.u. per pound. Gypsum, CaS0, 2H.0, though apparently perfectly dry, contains 21% of combined water. When gradually heated it will have liberated three-quarters of its water freely by the time it reaches 250° F.; the remaining one-quarter is retained to a somewhat higher temperature, but the last of it will have been expelled at 482° F. For calculating the total heat absorbed in raising gypsum (or its products) to the temperature of a coal-dust explosion, no serious error will be intro-

Jan 1, 1925