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By N. Kanarin

A thermodynamic study is reported on the chlorination of Fe(1-x.)O, Fe2O3, Cr2O3, MgO, Mg2SiO4 with chlorine in the presence or the absence of reducing atmospheres. The reactivities of these compounds as well as that of Mg3Si2O5(OH)4 using Cl2+N2, Cl2+air, and Cl2+CO gas mixtures were studied by non isothermal thermogravimetric analysis between 20 and 1000 °C. The same solids were chlorinated in a horizontal experimental set, during two hours between 350 and 1000 °C, in reducing and oxidizing atmospheres: The chlorination products were examined by XRD and SEM, and possible reaction paths were examined. Results indicate that the carbochlorination of these solids was better than their chlorination; Furthermore, the carbochlorination was performed at lower temperatures than those of the chlorination. Finally, the reaction extent was higher in the case of carbo-chlorination of these compounds. Based on these results, a process was suggested for the selective recovery of chromium compounds from the chromite concentrate.

Jan 1, 1995

By D. P. Harris

This paper surveys a few of the quantitative exploration models that might be of interest to an ex-plorationist seeking to apply methods of operations research to mineral exploration. A general development of each model is presented, and the model is evaluated relative to the exploration activity. Finally, a philosophy of exploration and mineral resources is presented, and a possible exploration strategy incorporating concepts of some of these models consistent with this philosophy is proposed. The high cost of conducting an effective exploration program has generated an increasing interest in methods of optimizing the allocation of the resources of a firm engaged in mineral exploration. As a step towards this, mathematical models have been formulated which are designed to quantify those variables of mineral exploration in such a manner that they can be integrated with all phases of the firm's operations so as to optimize its profit objective. QUANTITATIVE MODELS General: Exploration models express at least two concepts: mineral occurrence and effectiveness of search. In simplest terms, an exploration model might be formulated mathematically as follows: P(X) = F(X) . G(X), where P(X) = the unconditional probability of discovery of X deposits, F(X) = the probability of occurrence of X deposits, and G(X) = the probability of discovery of X deposits, conditional upon their existence in the search area. With these general models as a basis of reference, some of the specific exploration models are examined below. The Allais Model: DEVELOPMENT - M. Allaisl performed the first study in which a philosophy of exploration was formulated into a probability framework. His objective was to estimate the economic profitability of the exploration of the Algerian Sahara. Allais divided the Algerian Sahara into blocks of land (called cells) 10 km square and defined the random variable, X, as the number of mining districts per cell. Thus, F(X) would describe the probability of 1, 2, or n mining districts occurring within any cell of the search area. Allais reasoned that his best information as to the form of the distribution, F(X), was the number of mining districts per cell that had been found in well explored areas in the world, such as the Western States of the U.S. He found that the Poisson function produced a reasonably good fit to the distribution of districts in these explored areas: where? is a parameter, such as the average number of districts per cell. Thus, by determining the value

Jan 1, 1968

By Anderson JDC

Opencast Lignite Mining requires topwall strata of seams to be fully depleted and footwall aquifers sufficiently depressurized. To prevent a spread of the cone of depression into protected wetlands some distance away, alternatives had been investigated such as closing water works, underground slurry wall barriers and recharge by infiltration. As a result of these investigations, the infiltration method has been chosen and in a first phase during the next decade it will utilize as much as 55 x 106 m3/year. Using this approach, the survival of the wet lands is assured.

Jan 1, 1988

By B. M. England, M. V. Swain, N. Bristow, R. D. Dukino

The toughness and fracture mechanisms of ores with significantly different microstructures from Yandi, Koolan and Mount Whaleback were studied with a view to understanding their degradation behaviour. Bulk fracture toughness was determined by the 3-point single-edge notch beam test and the results interpreted using Weibull statistical analysis; indentation fracture mechanics was also used to measure fracture toughness of the different mineral forms and to understand their response to contact fracture

Apr 1, 1995

Mining companies in Australia have grown in size and complexity over the past 20 years. The same period has seen exten- sive changes in the operating environment, with greater competition and intensified in- dustrial and social pressures placing new demands 'on mining activity. The new condi- tions require a management approach that emphasises strategic planning rather than operational efficiency. Strategic management evolves through four distinct phases, namely, financial planning, forecast-based planning, externally oriented planning and 'true' stra- tegic management. The most difficult transi- tion to make is from Phase 2 (forecast-based planning) to Phase 3 (externally oriented plan- ning) since management is often too involved in operations to find time to develop and main- tain a strategic orientation towards the mar- ket and competitors. Reorganisation of re- sponsibility for operations and improved op- erational processes enable management to concentrate on external opportunities.

Jan 1, 1980

By Leonard Waldo

PROBABLY some of the views advanced in this paper will appear, from a metallurgical standpoint, little less than revolutionary. It is with considerable hesitancy that I venture to offer a few thoughts concerning what, seems to me to be perhaps the most important development of metallurgy since the introduction of Bessemer steel. Dr. John Percy, with that rare insight which characterizes the epoch-making man, described in a communication to the Royal Society, about 1855, an alloy of duminum and copper which he called aluminum-bronze. The name has "stuck." The term "bronze" has been so variously used that I confess I do not know exactly what constitutes a bronze; but I know that in the great materials of engineering simplicity of composition is a cardinal excellence; and I wish to venture the suggestion that aluminum-bronze is not an alloy of aluminum and copper in any such sense as the compounds of tin and zinc with copper (except the copper-tin compound SnCn3) are alloys. There are several reasons which lead me to this view. In the first place, if a series of bars be prepared containing varying percentages of aluminum and copper, and the electrical conductivity of these bars be carefully determined, a curve of conductivity will be obtained, as shown in Fig. 1, which represents the result of such experiments. While I am not sure, at this time, that the values of conductivity shown in this diagram are wholly dependent upon the percentage of aluminum added, the assumption is a probable one; and the curve indicates that an extremely small percentage of aluminum affects the conductivity in a ratio out of all proportion to the amount of that metal. Another reason is drawn directly from experience in the foundry. If we take from the furnace a crucible containing melted aluminum and one containing melted copper, both at a little more than a red heat, and pour them together, the reaction is so intense that the

Jan 1, 1895

By Vasil Kopaleishvili

The bainitic Fe-C-Si alloys with optimum content of retained austenite serve as ?containers? for storing of hydrogen. Both the vacancies of fcc lattice and the possibility of forming hydrides of silicon and other alloying elements will be used. The idea is based on our scientific hypothesis. There is the silicon threshold (Si=0,50%) in "Fe-Si" system and Fe-C bainitic alloys, above which it causes self-organized phenomena: sudden increase of hydrogen solubility and amount of retained austenite in the alloy after ??ß transformation, formation of two supersaturated solid solutions <a??r>, "rejuvenation? and its reverse process. Rapprochement of iron atoms when Si=0,50%, causes appearance of new covalent forces where uncompensated electrons of 3d-subshell are involved and it provokes synergetic phenomena. They ?free? silicon atoms from the previous bonds. After that silicon itself becomes a getter of hydrogen using vacancies (14) of 3P2(6)d0(10) subshell and it results in sudden increase of hydrogen solubility in metal. Simultaneously sudden decrease of iron activity takes place. That in its turn ?releases? the carbon. Thus, its redistribution, controlling the bainitic transformation, is hastened. It stipulates for creation of ?brittle bainite" B[a(C,H)+?r(C,H)] after ??ß transformation. While weathering of metal, "rejuvenating", hydrogen diffuses in ?islets? of retained austenite and ?relaxed bainite? (B[(C)+?r(C,H+H)]) is obtained. When heating austenite ?(C,H) is obtained, and after cooling ?brittle bainite? is obtained, etc. Presented scientific hypothesis explains the available experimental facts ("rejuvenation? and its reverse process, graphitization, weldability, forming of flakes, reaching high strength, etc.) in a new manner, as well as, gives real opportunity for creating of new trends in many fields, e.g. iron based HAA. Provisional data having been obtained are encouraging.

Jan 1, 2006

By R. K. Mehta, C. W. Schultz, R. R. Mallepali

Stirred ball mill feeds used for ultrafine grinding applications require a fine size separation step to avoid overgrinding. This paper presents the selectivity curves obtained for oil shale and complex sulfide ore using a 460-mesh (30-µm) Derrick vibrating screen. The selectivity curves generated from the experimental data show increasing selectivity with larger size for the oil shale but not for the sulfide ore. These unusual selectivity curves are similar to the mechanical air separator, fishhook selectivity curves described by Luckie and Austin. A two-stage, in series, classification model describing the fishhook selectivity curve has been used in proposing the classification mechanism for fine vibrating screens when a heterogeneous, multicomponent sulfide ore undergoes size separation.

Jan 1, 1994

By B Brown, P J. Hommert, B J. Thorne

"Early attempts at estimation of stress wave damage in blasting by use of finite element analysis met with limited success due to numerical instabilities that prevented calculations from being carried to late times. A"" improved damage model based on microcrack growth in tension allows finite elementcalculations which remain stable at late times. Estimation of crater profiles for blasting experiments in granite demonstrate successful simulations with this model."

Jan 1, 1990

By I. S. Escobar

Copper, particularly the oxygen-free grade Cu-OFP, is a candidate material for containers for the long-term isolation and disposal of high-level radioactive waste (HLW) in underground repositories. After having been buried for a few hundred years, all oxygen will have been consumed in the repository, and corrosion of the copper will be caused entirely by contact with dissolved sulfides. Chloride is another potential corrodant, but in deep repositories where groundwater is neutral or slightly alkaline, the effect of chlorides can be ignored on thermodynamic grounds. Thus, the corrosion of copper in the presence of sulfide ion and under reducing conditions has been studied using cyclic voltammetry and Tafel slope measurements. It is possible to determine the effect of sulphide ion on copper corrosion resistance which is minimized at low temperature and also at low sulphide concentration. The presence of anions such as HCO3 under environmental conditions produces a beneficial effect because these ions are inhibitors.

Jan 1, 1999

By Abbas Zaidi, Betty L. W. Ou

Wastewaters generated during the extraction of gold from the ore can contain a variety of contaminants such as cyanide, heavy metals and arsenic. Proper management of these wastewaters is therefore necessary to minimize the negative impact of gold mining and milling operations on the environment. The Wastewater Technology Centre (WTC),located in Burlington, Ontario, Canada, has been involved in several studies related to the evaluation of various effluent treatment technologies which are relevant to the treatment and proper management of gold mill effluents. These studies have included bench and pilot scale tests, and the evaluation offull-scale systems. Furthermore, the WTC staff developed protocols for cyanide analysis in gold mill effluents, and a mathematical model for predicting the degradation of cyanide in tailings ponds. The information generated by the WTC staff has been referenced in several reports and papers published over the last ten years (Schmidt et.al. 1982, Simovic & Snodgrass 1989, Whittle et.al. 1989, Zaidi et.al. 1989, Zaidi et.al. 1991). Recently, the WTC has started to develop a micro­computer based expert system for use by decision makers in the gold mining industry and relevant government agencies who are involved in process design, process evaluation, costing, evaluation of the best practicable technology, approval of suggested effluent management systems, and so on. This paper presents some relevant background information and a discussion of the latest version of the expert system being developed by the WTC.

Jan 1, 1992

By A. J. S. Spearing, M. Sharifzadeh, K. V. Jessu

Empirical pillar design methods are commonly used in the mining industry. The parameters within which these methods are valid are frequently unknown to the user or ignored. In addition, empirical design may not consider essential parameters such as blasting effects, orebody dip and the presence of geological structures, which all adversely affect the stability of the pillars. This can result in potentially serious pillar design strength over-estimates. Although the commonly based tributary area method is generally conservative, as the spans are seldom that large relative to the depth, failing to consider other relevant parameters can result in errors. Problems associated with an under-designed pillar can range from a local pillar collapse to a catastrophic chain reaction collapse (or run). Over-designed pillars are generally safe but reduce the extraction of the orebody, thus adversely affecting the profitability of the mining operation. We used laboratory tests and numerical modelling to understand the effects of pillar orientation, blasting and the presence of discontinuities on pillar strength. Reduction factors were developed with these models to be implemented in conjunction with the existing empirical pillar design methods. For any pillar or mine design, once it is implemented, the actual performance of the system must be checked regularly by observation and monitoring and adjusted if needed. The pillar design approach outlined in this paper can better optimize the pillar mining method by considering other generally ignored but important parameters, thus improving safety, productivity, and economic aspects.

Oct 1, 2022

By C. S. Finney, John Mitchell

There is no field of human thought or endeavor which does not owe much to the past. Yet, surrounded by the prodigious scientific and technological achievements of our day, it is all too easy to forget the extent to which we have stood on the shoulders of giants. The coking industry of the United States is now a little more than one hundred years old. As with the American nation itself, the earliest beginnings of the industry owe a great deal to British influences, and its development owes much to those influences of continental Europe. No serious contribution to the history of coking in the United States can be written, therefore, which does not mention the work of the pioneers of the Old World. It is believed that the use of metallurgical coke dates back to antiquity. The fact that certain coals would soften under the influence of heat to yield a porous solid was known to the ancients of China and India, where a very crude coking operation was carried out by simply setting fire to piles of coal. After active combustion had started, turf or wet straw was used to seal off the pile. The coke obtained was used to forge iron and steel implements and weapons. Perhaps the earliest reference to the coking phenomenon is to be found in the writings of Theophrastus, pupil of Aristotle. In his History of Stones, which was written in or about the year 371 B.C., there appears the following observation. "But the Lipara stone empties itself, as it were, in burning and becomes like the pumice, changing at once both its colour and density; for before burning it is black, smooth and compact.... Certain stones there are about Tetras, in Sicily, which is over against Lipara, which empty themselves in the same manner in the fire." The first comparatively modern reference to coke is to be found in a recommendation for carbonization made in 1584 by Julius, Duke of Braunschweig-Luneberg, owner of the Hohenbuchen mine in the Harz district of Germany. In 1587, Sir Francis Willoughby of. Wollaton, England wrote: "There are twenty rooks broughte into charcoal and laid up in store." A rook of coal was equivalent to some 25 tons, and the coking would probably have been carried out in a manner similar, to that used for the production of charcoal. In 1589, Thomas Proctor attempted to carbonize coal, and in the year 1590 an English patent was granted to John Thornborough, Dean of York, in order that he might "purify pit coal and free it of its offensive smell". Sir Robert Cecil (1595), Robert Chantrell (1607), Simon Sturtevant (1611) and John Rovenzon (1613) were all granted patents for the use of coal or coke

Jan 1, 1961

By Howard Eavenson

THE mines of the United States Coal & Coke Co. are located in the Pocahontas coal field, in McDowell County, West Virginia. Twelve plants have been opened and equipped, of which, by reason of the present business depression, only nine are now in operation. These twelve plants serve eighteen mines; some of the plants having several openings, in either the same seam or in different seams, tributary to the same tipple. Only nine of these mines are now being worked at the plants in operation. Construction work was begun in 1902, and coal from the first three plants started was shipped in December of that year. An additional plant was opened in 1903, two in 1904, two in 1905, two in 1907 and the last two in 1908. On Jan. 1, 1915, the plants have been in operation an average period of 8.8 years. The rules of the company, which have been in operation since work was first begun, are similar to those in use by the H. C. Frick Coke Co. at its mines in Pennsylvania, in which "Safety First" was incorporated as early as 1907; and it has always been the policy of both companies to look carefully after the safety of their employees. Although the field is an extension of the old Pocahontas field, the mines, located upon a new branch railroad, are away by themselves, and, as is usual in such cases, the class of labor attracted at first was temporary in character. The rapid development of the mines required the employment of many new men and officials each year; and, while the accident record from 1904 to 1909 was as good as the average of the field, it was felt to be not as good as it could be made, and a determined campaign was inaugurated for preventing accidents of all kinds. Fig. .1 shows the tonnage of coal produced per fatality, both total and for inside accidents only, at our mines; the tonnage per fatality of all West Virginia mines, and of those in the Pocahontas field.

Jan 2, 1915

The Clyde Power Project, and its Clutha Valley Development forerunner, has taken widespread investigations for various hydroelectric purposes both along the valley floors upstream from Alexandra and on the higher schist terrain. As part of this work the nature and extent of many of the alluvial deposits have been resolved and the ages established with&nbsp;varying precision. Gold values have been approximately appraised in some areas as an element of environmental assessment.

Jan 1, 1992

By Paul D. Tomlingson

Part one of this two-part series covers conceptualizing and developing a maintenance information system. It explains what information is necessary to manage such a system. Next month, part two will discuss using this type of system with administrative information, including error and absentee reports as well as open work files. Introduction There is no doubt that quality, timely, and accurate information can make a solid contribution to maintenance cost reduction objectives. Yet, despite obvious benefits, methods being used to acquire information systems are proving costly, frustrating, and often unsuccessful. Those needing the information are disappointed. Mine managers, hoping to reduce costs with quality information, are instead seeing no system, no savings, and massive spending on information endeavors of questionable benefit. Options Any software vendor will happily sell you his program. Numerous mining organizations, having "gone to the cleaners" themselves, will gladly make their programs available to help cover huge trial and error development costs. Any package can only be a generalization. Any program bought from some other organization must undergo numerous modifications to make it work properly. In the process the initial cost is doubled. Many mining maintenance organizations do not know how to go about the task of conceptualizing, developing, installing, and effectively using a maintenance management information system. Consequently, many have hedged their primary responsibility of specifying what information they want, how they will get it, and how they will use it effectively. Into this void have jumped many who claim they can help. But some may not understand the special information needs of maintenance in the mining industry. By default, the whole scene of maintenance information systems has become confused and in need of clarification. A Starting Point Four broad phases are used to organize the steps by which maintenance acquires an effective maintenance management information system and initiates its use. Conceptualization is an identification of needs, factors that influence development, and an assessment of support for the system. Development is a plan of action for bringing the conceptualized information system to life. Consideration is given to the practical aspects of collecting field data, processing it, and converting it into useful information. Implementation consists of those actions by which the newly developed system is integrated into the organization and put in the hands of its personnel so that its value can be derived. Use addresses the means by which personnel use the information to accomplish maintenance improvement objectives. These phases are preceded by establishing the need for the information system. They are followed by a requirement to measure its success (Fig. 1). Conceptualizing the Information System Responsibilities - The information system user must acquire the system best suited for its use. A step-by-step process is essential to avoid many serious problems than can easily occur. The most important step is to clearly identify its objectives and lay out a course of action to achieve those objectives. The major reason for the failure to achieve information objectives is not carrying out this responsibility. Maintenance cannot delegate the task to data processing. It can obtain technical assistance but it must retain responsibility. Nor can maintenance purchase

Jan 7, 1985

By Mark Godfrey, Wickus Slabbert, Debra Miller, Dave Dew

Sao Bento Mlnerai;;ao Mine (SBM), located 100 kms northwest of Belo Horlzante, Brazil, was commissioned In 1987t1l to produce 185 kg per month of gold from 240 tpd of refractory sulphide flotation concentrate. The concentrate Is processed by a Sherrill Gordon design pressure oxidation circuit followed by conventional CIL gold recovery process (Flgur .. J). The original plant design foresaw expansion to 480 tpd, and In this regard the acidic effluent neutralisation, CIL and carbon circuits were designed for future expansion to treat the higher tonnage. The pressure oxidation section was sized for 240 tpd with the Intention to double the Installed plant equipment to provide 480 tpd capacity when required. This decision was based In part on the novelty of pressure oxidation to treat refractory sulphide concentrates in 1984 when the process design was finalised. General Mining, Metals & Minerals (Pty) Ltd (GENMIN), has been actively Involved for the past 30 years in the development of bacterial process for the oxidation of refractory gold concentrates; the results of this development program have provided the registered process BIOx®. The successful Implementation of BIOx® technology for treatment of refractory gold concentrates at GENMIN's Fairview Mine In October 1986t2l, as well as the substantial experience accumulated in laboratory and pilot testing of some 40 other sulphide concentrates, Justified reconsideration of the oxidation process best suited to provide the Incremental sulphide oxidation capacity planned for SBM.

Jan 1, 1992

By P. Kiruthika, A. Murali Krishna

Soil liquefaction is a dangerous phenomenon that involves huge damages during strong earthquake ground motion event. Stone columns (SCs) are widely used as liquefaction mitigation element which is expected to perform the improvements against liquefaction hazard by densifying, increasing the stiffness and rapid dissipation of excess pore water pressure in the surrounding soil. Although in the recent times few studies on the behaviour of stone columns in the seismic zone has evolved, the performance of SCs in the multi-layered soils is not extensively examined. This paper presents the numerical investigations on the performance of SCs installed in the multi-layered soils as a liquefaction mitigation measure against the seismic loading. The acceleration time histories, Excess Porewater Pressure (EPP), vertical displacement and stress ratio evaluated along different depths using PLAXIS 2D. With the installation of stone column there is a considerable reduction in the acceleration amplitude, which in turn reduces the EPP and vertical displacement at different locations and the amplitude of reduction depends on the soil stiffness levels at the depth.

Sep 1, 2022

By Meliton M. Garcia

The volume of gases produced in major and trace amounts following the detonation of two water gel and two emulsion explosives in a mine were determined. The volume .of the major gases (CO, CO2, NO, and NO2) was measured immediately following detonation, during the mucking operation, and following the removal of the muck. Tests to identify and quantify the gases produced in trace amounts were performed following the detonation only. The volume of each major gas per pound of explosive (ft /lb) ;ranged as follows: CO, 0.0424-0.3231; CO , 0.6819-1.5632; NO, 0.0129-0.1320; and NO2, 0.0019-0.1111.. An approximate average of 95% of the gases produced was found in the test chamber immediately following the detonation, while less that 2% was found in the chamber following removal of the muck. Benzene was the most significant compound found to occur in trace amounts. Scaling tests performed with a water gel and an emulsion explosive suggest that the volume of the gases per unit mass of explosive detonated diminishes as the amount of explosive per blast increases.

Jan 1, 1986

By Lawrence P. Bonicatto

The steel industry&apos;s increased demand for higher grade pellets has caused the pellet producers to investigate methods of upgrading their product and the Hanna Mining Co.&apos;s Groveland plant on the Upper Peninsula of Michigan is no exception. The low grade iron deposit is a complex mixture of magnetite and hematite with chert, quartz, jasper and various iron silicates.1 Beneficiation is by Humphrey spirals and anionic flotation of the iron minerals.2 Flotation of the spiral tailings makes up about 75% of the concentrate, while a minor amount of concentrate (less than 3%) is produced in magnetic circuits. The concentrate is pelletized at the rate of 1.6 million tpy. The initial concentrating facilities were constructed in 1958 and the concentrate was marketed as sinter feed until a pelletizing plant was added early in 1963. Grade improvement soon became a high priority research project, and several methods of concentration were investigated.

Jan 3, 1968