Search Documents

By Irven A. Jacobson

This literature survey consists of references dealing with gaseous state thermal decomposition reactions of organic nitrogen and sulfur compounds. The reference source for the survey was the Chemical Abstracts from 1930 to 1956, inclusive. Original articles were not studied. The starting date was set at 1930 because previous to this time much of the work is questionable. This report is in three parts: Part I lists nitrogen compounds; Part II, sulfur compounds; and Part III, compounds containing both nitrogen and sulfur. The organization of the classes of compounds is alphabetical: Part I - amides, amines, amino acids, ammonia, azides, azines, azo compounds, heterocyclic nltrogen compounds, hydrazine, nitrates, nitriles, nitrites, nitro compounds and miscellaneous nitrogen compounds; Part II - disulfides, sulfides (including double and triple sulfides), thiols, thiophenes and xanthates; Part III - thioacid amides, thiazoles, thiocyanates and thiuram disulfides. A class formula is included with each class name. The R's used in these class formulas may refer to hydrogen or to the same or different radicals when more than one R appears.

Jan 1, 1960

By F. Q. Su

Underground Coal Gasification (UCG) is a promising environmentally acceptable clean-coal technology. A typical UCG system has two wells drilled from the surface into a coal seam with some separation of injection from production. The wells are connected underground by various linking techniques. After creating a combustion reactor in an underground coal seam, air and oxygen flow through the injection well. Heat energy and gases are collected from the production well. As gasification progresses, the combustion reactor is moved along the linking hole. Using this process, the fracturing activity inside the coal seam serves an important role for enlargement of the gasification zone because the surface area oxidization increases continuously by coal cracking. For effective coal gasification, fracturing activity must be controlled. Moreover, excess fractures inside the coal seam and surrounding rock can induce gas leakage, underground water contamination, subsidence, etc. Therefore, monitoring and control of fracturing activity in underground areas constitute key technologies for efficient and safe UCG. To monitor fracturing activity, we conducted laboratory and small-scale field experiments of UCG using acoustic emission (AE) measurements. UCG model tests were conducted for linking and coaxial types UCG models. Coaxial UCG systems are compact and are anticipated for application in underground coal seams having a complex geological structure. The UCG model consists of a coal block molded in a steel canister (20 liter capacity) with heat-resistant mortar, with a linking hole or a coaxial-hole passing through the coal block. During coal combustion, coal temperatures, production gas contents, and AE activity were monitored under the control of injection-air and oxygen flow rates. Results show that the combustion propagated inside the specimen along the linking hole. Many AE events were generated during coal combustion. The AE activity was related closely to temperature changes inside the coal block. This AE generation apparently results from crack initiation and extension around the coal combustion area under the influence of thermal stress. However, comparing the results from UCG models of linking and coaxial types, the gasification of the linking type model showed an average calorific value as high as 11.3 MJ/m3. The coaxial type yielded an average calorific value of produced gas as only 5.79 MJ/m3. In the coaxial type of UCG model, the combustion region was limited to the area around the coaxial hole. The AE activity was lower than in the linking type model. For small-scale UCG field experiments, linking and coaxial types were tested at an open pit coal mine in Hokkaido, Japan. Using a linking type UCG, 58.2 kg coal was processed in 39 h, with the calorific value estimated as 11 MJ/m3. However, the coaxial type UCG processed 7.0 kg coal in 9 h, yielding an estimated calorific value of 6.0 MJ/m3. These tendencies resemble those of results of laboratory UCG experiments. Results of these experiments demonstrate that AE monitoring is a useful tool to evaluate combustion reactors for efficient and safe UCG systems. To develop a coaxial UCG system, results show that fracture control around combustion reactors is indispensable.

Aug 1, 2013

By M. S. Celik

Despite its importance in various diverse industries, research on beneficiation strategies of boron minerals has not received enough attention. Boron minerals are primarily upgraded by wet processing methods. However, severe environmental constrains have accelerated the development of dry processing techniques such as calcination. Interestingly, boron minerals, colemanite, ulexite and borax undergo respectively decrepitation (fragmentation), shrinkage and expansion upon heat treatment. Each mineral then requires a different beneficiation scheme. In this study, laboratory and pilot plant studies on calcination of boron minerals conducted in our laboratories are reviewed along with their implications in commercial operations.

Jan 1, 1997

By H. Y. Sohn, M. K. McCarter, Bradley C. Paul

"A computer model was constructed for bacterial leaching of the major sulfides found in porphyry deposits, including bornite, chalcocite, chalcopyrite, covellite, cubanite, enargite, native copper, pyrite, and pyrrhotite. The model incorporates equations for the sulfide minerals dispersed in the rock matrix. Leaching occurs by reactions with ferric ion diffusing into the rock fragment: Ferrous ion is resenerated to ferric with oxygen by bacteria at a temperature dependent rate. The model keeps track of the net acid generated, oxygen consumed by the bacterial oxidation of ferrous ion, heat generated, jarosite and hematite precipitated, and copper leached. The model was used to predict the rate of copper recovery, heat generation and oxygen demand for a variety of run-of-mine sized porphyry ores. These results were used in the design of a ventilation system and the economic analysis of a modified in situ extraction method that may be cost competitive with conventional copper production involving open pit mining.IntroductionA study was undertaken at the University of Utah to evaluate the technological and economic feasibility of mining copper by a method referred to as Flood Drain Leach Cell (FDLC) mining. Cells 60 by 75 meters in plan and 70 meters in height are created throughout the ore body by a modified Vertical Retreat Mining technique that includes the removal of 25% swell material. The swell material is leached in finger dumps on the surface while the cells underground are bulkheaded, flooded, drained, and artificially aerated to promote bacterial ferric sulfate leaching. Solutions are cycled through several cells to reach pregnant grade of 1 gram copper per liter of solution. These solutions are then fed to an underground solvent extraction plant and then a surface electrowinning tankhouse."

Jan 1, 1988

By E. W. Murbach

The oxidation of uranium carbide by oxygen at various pressures, and by air, has been investigated at temperatures up to 600°C. Arc-melted and cast uranium carbide displays oxidation behavior that appears to be dependent on its treatment after melting. ccReactive" uranium carbide, which results from exposure of freshly melted material to laboratory air, ignites in oxygen at about 275° to 350°C depending on pressure, and in air at about 350°C. The product of the initial oxidation appears to be UO2+.. Continued heating produces U30,. The initial oxidation rate is poportional, roughly, to the square root of the oxygen pressure. The activation energy determined for the initial oxidation reaction is 7.1 kcal, from 400° to 600°C in 10 mm of oxygen. AN investigation of low-decontamination methods for reprocessing uranium carbide reactor fuels is being carried out at Atomics International. One of the reprocessing cycles includes oxidation of the fuel at relatively low temperature (300° to 500°C) and reaction of the product oxide with carbon at elevated temperatures (above 1500°C) to produce uranium carbide. A number of small-scale experiments have been carried out in which uranium carbide was oxidized in air and oxygen at various pressures to measure reaction rates and to obtain other information concerning the oxidation process. In initial experiments with arc-melted UC, ignition was observed at about 275°C in oxygen or 350°C in air. However, similar experiments by Neymark' at 426°C in air showed no ignition. It was soon determined that the difference in oxidation behavior was due to the treatment of the UC following arc-melting. Neymark's experiments were carried out with freshly melted UC while those reported in the

Jan 1, 1963

By Alastair Torrance, Gary Cavanough

Approximately 1.5 million tonnes of ammonium nitrate are transported annually across Queensland, Australia—equivalent to nearly 100 truckloads per day. This is in the form of both AN prill and ammonium nitrate based emulsions (ANE). In a recent incident, a collision involving an ANE tanker resulted in a detonation that caused extensive blast-related damage and led to the closure of a major highway. Had this event occurred within a populated area, the consequences would have been catastrophic. For over a century, investigations into the causes of such spontaneous detonations have been inconclusive. A recently completed industry supported research project has made a pivotal discovery: a surface reaction mechanism leading to hydrogen generation has been identified as a precursor to detonation. If sufficient hydrogen accumulates and subsequently ignites, it can release enough energy to initiate the detonation of bulk ammonium nitrate and ANE. Controlled experiments conducted during the project successfully demonstrated hydrogen-driven detonation events. Previous work by Proulx and Scovira, presented at the 2000 ISEE Conference, described spontaneous detonations in hot, reactive ground and the mitigating effects of buffered emulsions and ANFO. Building upon their observations, this study reproduces similar incidents under laboratory conditions, confirming that hydrogen generation also results from reactive ground interactions. Importantly, the findings challenge traditional assumptions, demonstrating that ammonium nitrate and ANE detonation in reactive environments does not require an ignition temperature threshold, confinement, or a classical chemical decomposition pathway.

Jan 26, 2026

By S-L. Jämsä-Jounela

Fault diagnosis systems have attracted growing interest in a number of engineering fields. The number of applications has increased and successful results have been widely reported. The fault diagnosis system presented in this paper is integrated, and it monitors the states of the process and performs fault detection and diagnosis on the process equipment. The monitoring of process states is carried out by means of Kohonen Self-Organising Maps that is a powerful tool in visualisation and analysis of high dimensional data in engineering applications. This paper presents the results of SOM analysis carried out on the Outokumpu flash smelting process. The subsystems analyzed in more detail are the condition of the concentrate burner, the condition of the gas line on the basis of the pressure distribution in the process and the cooling water circulation of the waste heat boiler, and the condition of the furnace and furnace equipment on the basis of the temperature distribution in the furnace and gas line. Keywords: Fault diagnosis, Process monitoring, Kohonen Self-Organising Maps, flash smelting

Jan 1, 2001

By J. B. De Hart

In the September issue of the Bulletin, 1923, there is a paper by J. A. H. Church on "The Spontaneous Combustion of Coal in Mines", which is more or less a general discussion of the subject. Mr. Church gives a list of mine fires which have occurred in Alberta. Of the total of thirteen fires, six are attributed to spontaneous combustion. Of these six fires, it will be noted that five are in thick pitching seams. These fires occurred in the following mines during the years shown, at Frank in 1909; at Lovett in 1916; at Cadomin in 1920; at Yellowhead in 1922, and at Cadomin in 1923. Every one of these fires has occurred, as Mr. Church points out, in a seam of over 12 feet in thickness, and furthermore not one of these fires has been extinguished, although in every case large sums of money were expended and considerable risks . taken in fire fighting. Now it is quite evident from these facts that mines working seams of this nature are faced with a very grave danger and it behooves us to study the matter and endeavor to arrive at some practical method of preventing the loss of our coal mines from this cause.

Jan 1, 1924

By Z. Huda

The effect of various percentages of cold-working and recrystallization on the microstructure and hardness of commercially-pure aluminum plate, has been studied. The 'A critical deformation for the aluminum, has been determined. Experimentation involved cold rolling and recrystallization processes followed by quantitative metallographic practice and the hardness measurements. The raw material chosen was a plate of commercial aluminum which was cold rolled to different percentage of cold-work and then recrystallized by heat treatment at 150°C. The critical deformation percentage of aluminum was computed to be around 30% of cold-worked.

Jan 1, 2007

By Paul H. Atkinson

"Sampling in the mineral processing industry has always been a subject which has received considerable discussion. There have been many volumes written on theory, techniques and practical application of sampling. However, until recently, the companies were not completely aware of the potential savings available with properly designed sampling systems both to assist in pieces: control and final product values.Definition In our discussion today, we will define sampling as the operation of removing a part, convenient in quantity for analysis, from a whole, which is of much greater hulk, and removing it in such a way that the proportion and distribution of the quality to be tested, i.e. size of particle, moisture content, specific gravity content, mineral and chemical composition, are the same in both the sample and the whole.Application It has been well established that undetected errors can result in large economic losses, thus most firms depend upon some type of sampling and sample analysis as a control in their continuous processing of materials. Despite the large investment in facilities and personnel the ""analysis"" of a sample can be no more accurate or reliable than the sample on which it is being based. The importance of sampling is recognized by a great many but it is appreciated by only a few, largely because it is sometimes one of the items which is taken for granted."

Jan 1, 1976

By Wang Chen

COREX process is briefly introduced. A static model combining a set of mass and heat balance equations has been developed. Taking the specified inputs from the graphical user interfaces, the model is capable of calculating the consumption of raw materials and fluxes, the volume and composition of the slag and the volume and composition of the generator gas. The model enables the examination of the changes of materials and energy flows induced by the variations of operational parameters and raw materials chemical analysis. The model allows a detailed process analysis and adjustment of the plant operation and can thus be used to improve plant operation.

Jan 1, 2008

By Guoqiang Lv, Xi Yang, Wenhui Ma

Cast multicrystalline silicon ingots are widely used in photovoltaic manufacturing. A key issue to achieve high solar cell efficiencies is to attain an optimized temperature field during directional solidification (DS) process. This paper reports numerical investigation of multicrystalline silicon (mc-Si) ingot production using two major types of DS furnace. Specific examination is made on thermal distribution, interface shape and stress field. Evaluation is performed for the applicability of thermal system design to reduce thermal stress, improve crystal quality and enhance energy efficiency. The effects of procedure parameters and geometric configuration on temperature distribution are discussed as well to provide the viable solutions for systems optimization.

Jan 1, 2015

By Manfred K. Walther

"Tests were conducted on instrumented plates cast in the Abex Experimental Foundry to compare recorded solidification histories with results computed for corresponding models simulated with the C.A.S.T. program. The first plate was cast of low alloy steel and the second of carbon steel with a graphite chill at one end. Both were cast in molds of bonded silica sand. Temperature histories were recorded in the castings, molds and chill. Exceptionally good agreement was achieved between computed and experimental data. Other investigators will find the results useful as a benchmark against which they can compare the results of their own calculations.IntroductionSince the early 1970's our foundry engineers have used both two- and three-dimensional versions of the G.A.S.T. program to gain knowledge of the solidification process [1,2,3]. Study of the computed data gave insight as to how the rigging and risering of specific castings might be changed or adjusted to improve quality and yield. New schemes based on such analyses were then recommended for implementation on the foundry floor. The degree of success of the new practice was subsequently evaluated after the part had been poured, shaken out and examined. Similar conditions were noted in the sectioned castings whenever porosity and voids had been predicted by the computations. Appropriate modifications, when found successful in the model, were applied to the process. This led to a reduction, if not complete elimination, of the defects. Such results gave credence to the use of these programs as an aid in the production of better castings.Earlier investigations on simple shapes revealed excellent correlation between output derived with the G.A.S.T. program and exact solutions. Results also compared favorably with data calculated using other codes as reported in the literature [4] and summarized in the Appendix. However, since the computer program had not been verified by direct experiment, it was decided to run instrumented tests to check the theoretical predictions with actual measurements."

Jan 1, 1986

By Onuralp Yucel, Ahmet Turan, K. Can Candeger

Exothermic riser sleeves are important tools to increase solidification duration, particularly for iron-steel casting. Increasing the time to solidus improved casting product quality by minimizing cavities. Therefore, process costs were significantly reduced. In comparison with the use of unsleeved risers, exothermic riser sleeves retain up to 30–35% of the heat and increase the duration to solidus by nearly 50%. Exothermic riser sleeves are a mixture of metallothermic-based exothermic and insulating materials that are manufactured in different sizes and shapes. Various suppliers produce these sleeves in different compositions. However, the designers must clearly understand the thermochemical and thermophysical properties. The purpose of the present study was to experimentally determine the effects of varying experimental parameters such as reaction duration, flammability and temperature change etc. on selected exothermic sleeves. The results were compared with thermodynamical simulations which were performed using the contents and the corresponding thermophysical properties of exothermic sleeves.

Mar 1, 2018

By Lara de Assis Moreira, Vinicius Thiago Lecco Rampinelli

The energy efficiency of reheating furnaces is a continuous challenge, as these equipment consume a representative portion of the total fuel of an integrated steel plant. Therefore, any investigation and implementation which brings improvement in this figure become an important issue for the mill competitiveness. In the case of production delays due to external factors (the condition addressed in this work), whether predicted or unforeseen, the slabs remain inside the furnace with high temperatures in order to avoid production delay during the production restart, elevating the specific consumption and scale formation. This work increased the energy efficiency of the two ArcelorMittal Tubarão’s walking beam reheating furnaces, by reducing the consumption of mixed gas during production delays (either scheduled or not) lasting less than 3 hours. The objectives were achieved through improvements, among them, tuning of Level 2 automation system parameters, automatization of procedures and operational training. The work resulted in a 34.4% fuel gas consumption reduction during the delays.

Oct 1, 2019

By H. L. Gilbert

Improvements in production of high-purity chromium metal by magnesium reduction of anhydrous chlorides and by hydrogen treatment of electrolytic chromium are reported. Hydrogen-treated chromium has been arc-melted, and the arc-melted material has been successfully forged, rolled, and swaged. The material also has been forged at liquid-air temperatures. X-ray and metallographic studies indicate the recrystallization temperature of rolled chromium sheet to be about 750° C. Preliminary investigation of hot-bending characteristics of rolled chromium sheet shows the minimum bending temperature to be about 325° C. The heat resistance of chromium has been investigated.

Jan 1, 1952

By J. T. I. Poijärvi

The smelter off-gas cleaning and the weak acid treatment at Outokumpu Harjavalta Metals Oy are presented and described in this paper. The smelter consists of the copper and nickel smelters and the acid plant of three separate acid plants two of which are double contact and one single plant and of one liquid sulphur dioxide plant. The preliminary cooling and flue dust separation of the smelter off-gases from the copper and nickel flash smelting furnaces and converters in the waste heat boilers and in the hot electrostatic precipitators are described. The final cooling and cleaning of the gases in the scrubbers at the sulphuric acid plant and the treatment of the weak acid in the vacuum and in the submerged combustion evaporators for the removal of impurities are pre¬sented as well as the treatment of the condensates from the evaporators. The attention is paid to the generation of sulphur trioxide in the smelter off-gas and to the treatment of that in the weak acid bleed-off and to the utilization of the treated acid.

Jan 1, 1992

By John B. Hodgeson

AMMONIA is an essential constituent in the production of the ammonium-sulphate and ammonium-phosohate soil fertilizers manufactured by the Consolidated Mining and Smelting Company of Canada, Limited. The fertilizer plant, built in 1930 at Warfield, near Trail, provides a means of utilizing the large amount of sulphuric acid produced from the sulphur dioxide which is removed from the smelter smoke. The plant has an avail-able source of cheap power which makes the production of fertilizer economically possible. The fundamental operations involved in the production of ammonia at the Warfield plant are, first, the manufacture of hydrogen by the electrolytic dissociation of water; next, the recovery of nitrogen by the fractional distillation of liquid air; and finally, the combination of hydrogen and nitrogen in proper proportions and under suitable conditions to form ammonia.

Jan 1, 1938

By K. Murayama, M. Kawakami, T. Takenaka, S. Yokoyama

"Cokes play an important role of spacer in blast furnace. However, they degenerate during Boudouard reaction. Blast furnace cokes are reacted with pure C02 at I 072 to 1673 K. Reaction rate was obtained by the weight change of spherical specimen. The specimen after reaction was examined by microscopic observation. The reaction rate increased with temperature and was expressed by two Arrhenius type lines. The activation energy was 126 KJ/mol at higher temperature than 13 73 K and 202 KJ/mol at lower temperature range. At the higher temperature range, the reaction proceeded from the surface leaving unreacted core, whereas homogeneously whole inside at lower temperature. The porosity increased from the center to surface at higher temperature, whereas it was almost constant at lower temperature.IntroductionThe cokes have the function of fuel, reductant and spacer to keep gas and liquid flow in the blast furnace. Thus, the reaction mechanism of coke with several gas and the strength after the reaction should be important factor to control the blast furnace operation. The reaction mechanism of coke with C02 has been studied extensively. The rate equations were derived by Gadsby[ I], Ergun[2] and Turkdogan and Vinters[3]. They were compared and discussed by Kobayashi and Omori [ 4]. Effect of crystallization degree on the reaction rate was examined by Kashiwaya and Ishii[5]. Catalytic enhancement effect of ash componets have been clarified by Kashiwaya et. al. [6]. Although degradation of coke in blast furnace has been examined recently[7], however, the degradation of coke after the reaction with C02 has not been well clarified yet. In the present work, the metallurgical coke specimen was heated in N2 and C02 and the reaction mechanism and degradation behavior after the reaction was investigated."

Jan 1, 2000

By Nadia H. Rafat, Iman S. El-Mahallawi, Hussein Badr, N. Khattab, Ahmed A. Abdel-Rehim

The basic part of solar water heaters is the collector and the main functional part of the collector is the absorber layer. In this work, a commercial locally available black painting (PACEN code 10382 colour 890), used for swimming pools solar heating, was modified by adding nano-graphite dispersion. The effect of nano-graphite particles percentage on the spectral absorbance of the material was examined on samples containing two values of 1.5 and 2.5% nano-graphite particles by weight. Fourier transform spectroscopy (FTIR) analysis was also used to identify the functional groups in the developed material. A simple experimental setup was designed to evaluate the performance of the developed nanodispersed selective coating polymeric based material, by measuring the increase in temperature of circulating water. It was shown that adding 1.5–2.5% nano-graphite particles to a polymer based black coating causes an increase in the optical absorptance, and an increase in the circulating water temperature.

Mar 1, 2018