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By J. L. Thompson

The combustion of pulverized coal is a century-old practice. Many people have investigated coal dust and the residual fly ash particles that re-main after combustion. But the combustion process and fly ash formation mechanism are not under-stood. Working at our Maysville, Kentucky lime plant, the Dravo Lime Company Research team has collected samples of partially burned coal dust from the flame of a pulverized coal burner. Specimens were placed in a scanning electron microscope (SEM) equipped with an energy dispersive spectrometer (EDS). Microscopic examination of the particles, together with a large collection of micrographs of lime dust fused to fly ash particles, now make it possible to theorize as to how combustion advances through a piece of coal dust. Coal is a physical mixture of carbon-based compounds interspersed with bits of ash-forming materials, primarily alumina-silicate compounds. The alumina-silicate materials are commonly in angular nodules measuring 100 A to 700 A across their major dimension. It would appear that if the coal particle is in a well mixed gas stream, combustion starts at the surface and advances radially toward the particle center. With poor gas mixing, it is common that combustion moves from one end of a particle and advances on a broad front almost normal to some axis. In either case the combustion process and ash-forming mechanism are the same. As combustion occurs the carbon-based compounds oxidize in a highly exothermic reaction. Heat from the re-action melts the alumina-silicate nodules causing them to flow together and coalesce into an open sponge-like structure. As melting continues surface tension of the liquid and free surface energy causes the sponge-like structure to simplify into fewer, larger pores. Most likely the lighter molecular weight hydro-carbons burn before the heavier species. This means that as the melting ash structure is metamorphosing to a single large pore, there continues to be out-gasing throughout the structure due to combustion. Surface tension will form a spherical piece of fly ash if the ash material is liquid for a sufficient period of time. Out-gasing from combustion of the heavier hydro-carbons will provide internal gas pressure to keep the particle spherical until it freezes.

Jan 1, 1978

By Wantae Kim, Furnia Saito, Qiwu Zhang

"A novel mechanochemical processing technique for the preparation of zeolites from kaolinite in NaOH solution was investigated. Dry and wet mechanochemical treatments combined by subsequent moderate heat treatment could accelerate the synthetic reaction for zeolites from kaolinite. This stimulating process produced zeolite-A and zeolite-X from activated kaolinite at extremely lower reaction temperature than conventionally applied for zeolites production. Conversion to zeolite-A and zeolite-X was strongly dependent on the activated state of kaolinite. Wet mechanochemical treatment modified the chemical composition of activated solids. Rapid dissolution of AIO species rather than SiO ones in the reactant solution was accelerated by wet milling together with NaOH that promoted the formation of zeolite-X of high specific surface area.IntroductionZeolites are a family of hydrated alumina-silicate minerals contains alkali and alkaline earth metals. They have a framework structure that encloses inter-connected cavities occupied by large metal cations and water molecules. Zeolites are characterized for their ability toward ion exchange and reversible dehydration. Properties of them are exploited through commercial productions of particular structural and chemical features. Zeolites are used as commercial uses for catalysis for FCC (fluidized catalytic cracking) of petroleum refining, drying reagents of gases and liquids, and selective adsorbent for pollution control [1-3]. In such purposes, artificially synthesized zeolites are employed, although natural ones are associated with hydrothermal and hot spring alteration of volcanic materials. Commercially, a hydrothermal process has been used for the preparation of zeolite synthesis. This preparation method gives zeolites of high chemical homogeneity and purity, however, this wet-chemistry-based processing is significantly influenced by reaction temperature, pH, concentration, and composition of starting substances [4]."

Jan 1, 2000

By G. Delagrammatikas, M. Karmis, J. Mastoris

The evaluation of raw materials in terms of quality profile, mineralogical character and mechanical properties is of great importance to the cement industry. The variability of their chemistry and structure is among the decisive design parameters in the choice of any mining, handling and preblending systems. Furthermore, clinker and cement production require sound estimates of the above parameters, to help produce some appropriate and realistic raw mix configurations and achieve minimum standard deviation of the major components. This paper addresses this subject from the perspective of a cement producer and presents the principles of a methodology aimed at optimizing mine planning and process design. Finally, results from case studies on actual sedimentary deposits currently in operation are discussed.

Jan 1, 2002

By Paykan Safe

Computational Fluid Dynamic (CFD) modeling provides a powerful tool to assist with the design of ventilation and fume control systems in smelters and other high temperature metallurgical facilities. For this paper, this tool has been used to analyze the off-gas flow patterns exiting the mouth of a Peirce-Smith converter into a water-cooled hood and drop out box. The effects of various process and physical plant design parameters on process gas and fume capture and potential build up on the converter hoods was examined, and the optimum design and operating parameters were determined.

Jan 1, 2000

By W. B. Price

AT the New York meeting of the American Institute of Mining and Metallurgical Engineers held in February, 1926, W. H. Bassett and J. C. Bradley presented a paper entitled "Exudations on Copper Castings."' The purpose of the present paper, as the title suggests, is to call attention to somewhat similar phenomena which the authors have encountered in brass and bronze. From a study of the examples given, a more-or-less speculative theory of "inverse segregation" is advanced. Protuberances on Admiralty Brass In the rolling mill of the Scovill Manufacturing Co., there have been found quite commonly bars of certain alloys which had a sort of shaggy roughness on the surface due to slight metallic protuberances. No special attention was paid to these until some bars were found on which these protuberances were heavy enough at the bottom of the bars to produce a blistered appearance. A sample of the protuberances was milled off the surface of the bar illustrated (Fig. la) and upon analysis was found to contain 66.66 per cent. copper, 4.02 per cent. tin and 0.03 per cent. lead, whereas the average composition of the bar was 70.21 per cent. copper, 1.21 per cent. tin, and 0.01 per cent. lead. A sample of the shaggy-rough protuberances at the very top of a bar was also analyzed and was found to contain 2.45 per cent. tin, indicating that it was probably of the same origin as the blistered areas. These results were not entirely unexpected for previous analyses of this alloy had revealed that the surface was richer in tin than the rest of the bar. This, of course, is contrary to what we would expect from a consideration of the equilibrium diagram and has been called "inverse segregation." Fig. 16 is a cross-section of a bar through the protuberances on the surface. It reveals that there is a decidedly different structure through the raised areas and seems to indicate that the bar originally solidified

Jan 1, 1927

By T. Malvik

Norway is a big producer of ferrosilicon and silicon metal. The raw material is quartz and quartzite and large quantities from both Norwegian and foreign sources are used. The demands maade on both the chemical purity and the thermomechanical qualities of the quartz/quartzite have increased in recent years in an attempt to reduce energy consumption and to improve utilization. Control of the chemical quality of the raw material is relatively easy by means of routine analysis, but it is more difficult to find a suitable method for testing the thermomechanical properties. A rapid test method to define high quality quartzite deposits for use in the metallurgical industry has been developed. The method is based on a combination of chemical analysis, dilatometry, thermosonimetry and cathodoluminiscence.

Jan 1, 1989

By Ren Bryce

The ninth annual Mineral & Metallurgical Processing Division (MPD) student poster contest was held in February at the SME Annual Conference & Expo in Minneapolis, MN. A total of 33 students presented their work at the contest. The competition began in January when the students submitted a one-page abstract for judging. In February, they prepared and presented a poster that explained their research. A panel of judges went to each student and listened as the students explained their research in five minutes. The students worked hard at their research and then set aside time to complete all the necessary steps to enter the contest. The MPD recognizes the effort required to enter and, as a result, provides monetary rewards to all participants. As in past years, there are separate levels of competition for undergraduates and graduates, and the prizes are designated accordingly. At the graduate level, first place receives $1,000, second place $500, third through seventh $200 each, and all others $125 each. At the undergraduate level, first place receives $1,000, second place $500, third place $250, and all others $125 each.

By C. K. Kocsis, S. Hardcastle

Mine ventilation, requires electricity to operate the fans and fossil fuel for heating. Typically, this accounts for approximately 40% of the overall underground energy consumption. This is considerable, and one of the major causes of this expense is that most mine ventilation systems are designed for the "worst-case-scenario" with respect to ventilation demand, which is commonly dictated by diesel equipment usage. Once designed, mines tend to operate their ventilation system at this peak level despite their exceeding day-to-day development and production needs due to lack of appropriate ventilation controls. In underground metal mines, TeleminingTM, which includes the tele-remote operation of mobile development and production equipment from surface, will change the mine design criteria including its support infrastructure such as the ventilation system. With the removal of machine operators to surface control rooms, conventional ventilation systems designed to dilute and remove pollutants can become redundant. Depending on the ultimate need for ventilation, its cost in automated mines with tele-remote equipment operated from surface will be lower than the cost of ventilation in conventional mines. These cost savings, which could be significant, would not only come from the ability to reduce the amount of ventilation in the mine, but also through the capacity to automate its distribution. This paper provides an indication of the new airflow requirements in stopes and dead-end developments for the tele-remote and automated mining processes based on climatic modelling. Furthermore, this paper makes a cost benefit analysis by comparing the ventilation system operating cost of a conventional underground metal mine based on the mobile diesel powered equipment design criteria with the newly redesigned ventilation system operating cost of an automated mine based on the "heat management" design criteria.

Jan 1, 2002

By R. W. Hiteshue, C. O. Hawk, H. H. Ginsberg, M. D. Schlesinger

The Bureau of Mines studied single - step catalytic vapor - phase hydrogenation of oils derived from coal and oil shale . Treatment of middle oil , from hydrogenation of bituminous coal , gave good yields of gasoline with a German - made molybdenum- zinc - chromium catalyst . The Bureau also achieved good results with duplicates of this catalyst made from domestic raw materials . In one set of experiments with the German catalyst , 38 to 52 wt pct of feed was converted to gasoline . The total liquid product was 91 to 98 wt pct of the feed . Not all this gasoline can be claimed as production , however , because about 20 pct of the feed was in the gasoline range , and part of it undoubtedly survived the hydrocracking treatment . Hydrogenation of crude shale oil in the presence of cobalt molybdate catalyst produced a total liquid product of 89 wt pct of feed . The hydrogenation converted 27 wt pct of feed to gasoline and 44 wt pct of feed to diesel fuel . The remaining liquid product , 18 wt pct of feed , was residue boiling above diesel fuel . The gasoline was of poor quality , with an octane number of 39.1 . The overall product seemed a suitable feed stock for a conventional refining operation . Coker distillate hydrogenation , using a cobalt molybdate catalyst , gave a total liquid product of 97 vol pct of feed ; of this product 60 vol pct was jet fuel and 40 vol pct was diesel fuel . High nitrogen and sulfur in all three of these raw materials severely poison the usual refining catalysts . Thus , the common objective in these

Jan 1, 1964

OWING to the gradual depletion of the hitherto plentiful supply of firewood in the immediate vieinity of Queenstown and Gormanston, which caused a steady increase in the cost of fuel for domestic purposes, the Mount Lyell Company took steps several years ago to make available as a substitute electric current from its Lake Margaret hydro-electric supply. In order to make this practicable it was necessary that the cost of electric power for heating purposes should compare favourably with the cost, of fuel, and the installation of domestic appliances brought within reach of the average householder, and efforts have been continuously directed towards this end since the year 1928.WATER HEATERSThe installation of electrical apparatus in local dwellings began with hot-water services, the heating elements being the types then procurable on the market and adapted to meet requirements.These, however, did not prove satisfactory, but the study of their bilure resulted in a type being developed locally which has overcome all difficulties. The first type of water heater evolved was an outside circulation one the element of which consisted of an iron pipe through which the water passed, insulated with micanite and wound with nichrome wire, the latter being covered with alundun cement to keep it in position and prevent oxidation. This was insulated on its outside surface with a layer of asbestos flour, and connected to the hot-water container as shown in Fig. 1. It was found, however, that the iron pipe had a short life, due to a certain amount of acidity in the water, and a copper pipe was substituted which proved very durable. Some heaters with this improved type of element are still operating after six years of use. The resistance wire is run at a very low current density, which ensures durability.

Jan 1, 1927

By William G. Pariseau

Few departments of mining, metallurgical or petroleum engineering in the United States have critical mass. Cost per student credit hour (SCH) in departments across the country are usually the highest among engineering departments, which are the highest on campus. Almost all departments are operating at fixed costs and enrollments could easily double without incurring much additional cost. However, the cost per SCH would remain unacceptably high and the probability of doubling enrollment is nil. Declining enrollment is a more likely future. The pressure to reduce SCH from university administration is unrelenting. And it has the potential for doing serious damage to program quality when standards and requirements are lowered in attempts to maintain enrollments and increase retention.

Jan 1, 2002

By R. Armstrong

Due to limited available level ground, Nkomati Nickel Mine cut a weathered rock slope at the base of a mountain spur in order to create a platform for construction of the primary crusher plant and run-of-mine stockpiles. As space is limited around the mining area, ore processing at Nkomati is based on a high reliability of flow of material through the crusher plant, with minimal usage of other and larger designed stockpiles. Evidently, any crusher plant shutdown will render the mine as a whole unproductive and put excessive strain on the medium- to long-term large ore stockpiles, the deposition rates for which are restricted by founding material consolidation requirements. At the onset of the 2012 rainy season, movement was identified on the slope monitoring system and cracks developed on the slope. After a minor failure on the crusher slope an assessment of the slope stability was conducted and a slope management plan recommended, which included deployment of real-time monitoring. An evaluation of the conditions leading to instability was conducted and the likely causes for the failure identified. A full evaluation of the slope monitoring, rainfall, and mining conditions was undertaken and movement triggers were determined. This paper describes the events leading to the development of the failure and the evaluation of the monitoring data to determine a management plan for the failure that allowed for minimal shutdowns of the primary crusher.

Jan 1, 2014

By Michael Kelly

Inertial navigation technology has, for the first time, allowed the position of a longwall shearer to be mapped in three dimensions. Following the success of the technology in highwall mining and successful trials on a longwall face, the Australian Coal Association Research Program (ACARP) commissioned a three year "Landmark" project that aimed to advance longwall automation to the level of "on-face observation" by the end of 2004. This project has been completed with the following successful technical outcomes: Automatic face alignment was achieved, using an inertial navigation-based sensor on the shearer, to accurately measure face geometry and feedback signals used to move OEM (Original Equipment Manufacturer) roof supports. Operational on-line measurement of creep with creep information incorporated into face alignment corrections. Inertial Navigation System (INS)-based enhanced horizon control was bench-tested. Operational broadband communications system to shearer using wireless Ethernet on a commercial-product basis. Acquisition of located coal-face features for use in thermal infrared-based horizon control. Automated Longwall Information System (LIS) developed which integrates information from multiple systems and sensors and provides high quality visualisation and control interfaces. Automatic roadway and face convergence monitoring tools successfully tested. Condition monitoring tools developed and demonstrated for improved face reliability. This paper summarises the outcomes of the project and describes the work being undertaken for the 2 year Landmark Extension project approved in April 2005. Consistent with the conference theme, the paper focuses on the ground control aspects of the project.

Jan 1, 2005

By H. Mitri

A new monitoring device called SAFEBOLT (Stress And Force Evaluator in BOLTs) has been recently developed at McGill University. The device is essentially an alternative to the load cell, it permits the monitoring of bolt axial load in the field. The SAFEBOLT system consists of a portable readout unit, a connecting cable and the SAFEBOLT device, which is installed in the bolt head. The new device can be installed on any industry standard rockbolt or rebar. The device is completely encapsulated in the bolt head, which makes it resistant to corrosion, rugged, and free of any electric wires. Pilot tests at two underground Quebec mines were carried out and helped improve the initial design of the device head.

Jan 1, 2002

By Clyde E. Williams

[As a results of work conducted during the past three years, the Northwest Experiment Station of the Bureau of Mines, in cooperation with the University of Washington at Seattle, Washington, has developed a process for the production of sponge iron. Commercial operation of this process in a 3 to 4-ton scale has been so satisfactory that its use on a large scale (20 to 100 tons per day) can be safely considered. Description of Process. The process consists in passing a mixture of iron ore and coal through a rotating kiln heated at one end to a temperature sufficient to convert iron oxide to metallic iron, discharging, cooling, and separating the sponge iron from the residual coke and silicious material on a magnetic separator. Both the coal and the ore should be crushed to peso as 6-meth scream, tans producing particles finer then 1/12 of an inch. Seventy-five parts of coal or other carbonaceous material arc charged with every 100 parts of ore), This large amount of coal is required in order to supply sufficient carbon to maintain a strongly reducing atmosphere in the charge, but may be reduced to about 65 parts per 100 parts of ore by recovering and using tae carbon that remains in the discharge product. Large-scale operation and refinements in furnace design should lower this ratio to perhaps 56 or 60 parts of coal to 100 parts of ore.]

Jan 1, 1924

By M. Görnerup, M. Hayashi, S. Seetharaman, C. -Å Däcker

The mould flux plays a crucial role in the continuous casting operation of steel due to its multi-functional assignment as lubricator and heat flux controller. In reality, the commercial fluxes can fall short of the expectations of the operator. In such cases, the performance of the mould flux reduces production throughput in the casting machine. This paper presents the results of a study of two different commercial mould fluxes in continuous casting of steels. The results of online sampling during casting, as well as off-line measurements in the laboratory, are presented. Mould flux powder and slag samples from the caster have been characterized with respect to melting behaviour, interfacial tension and thermal diffusivity, using various measuring techniques. An experimental technique has been developed in order to simulate the melting behaviour of a flux in the mould, which has been found to be useful for qualitative studies. A cross-sectional view of different powders reveals that up to four different material layers may exist in the bed: a loosely packed powder layer, sintered layer, semi-solid layer and liquid slag layer. It is found that the melting rate of the mould flux is dependent on the liquid slag layer thickness. Thus, in a continuous casting operation the melting rate is likely to be non-uniform with position in mould due to the difference in liquid slag layer thickness. Mould slag composition is found to be influenced by the starting powder for as long as 30 min, representing a large part of the first heat casting time. Observations of gas formation indicate that interfacial reactions between the steel and slag take place. Keywords: continuous sacting, mould flux, mould slag, properties

Jan 1, 2004

By A. J. Williams, T. N. Croft, M. Cross

"The computational modelling of extrusion and forging processes is now well established. In this work a novel approach is described which utilises finite volume methods on unstructured meshes. This technique can be used to solve simultaneously for fluid flow, heat transfer and non-linear solid mechanics and their interactions. The approach involves the solution of free surface non-Newtonian fluid flow equations in an Eulerian context to track the behaviour of the workpiece and its extrusion/forging, and the solution of the solid mechanics equations in the Lagrangian context to predict the deformation/stress behaviour of the die. Some preliminary examples of this approach will be discussed.IntroductionThe computational modelling of extrusion and forging processes is now well established. Within the last 20 years the finite element method has become the most commonly used technique to simulate metal forming processes [1]-[4]. The Lagrangian and Eulerian type of formulation have been the two major approaches to this problem.Lagrangian methods are efficient and suitable for handling non-linear problems in which small strains prevail, boundary conditions do not change with the course of deformation, and where mesh distortion is not a critical factor in the analysis. Unfortunately, the above points are essential to any accurate metal forming analysis. The problems of mesh distortion and element entanglement pose a serious drawback on the use of such methods. Some automatic remeshing techniques have been developed for Lagrangian finite element analyses of metal forming problems [5]-[7]. However, these methods are not robust and efficient enough to remedy the mesh distortion problems in general. An alternative is to update the mesh manually but this is not always possible, and even when it is feasible it involves major interaction by the user. In addition, remeshing is usually applied to the whole domain which is not necessary and increases CPU time. The complexities associated with remeshing also affect the ability to parallelise the code."

Jan 1, 2001

By Jean-François Boulanger

The production of rare earth elements from ore usually consists of three steps; the separation of a concentrate of REE bearing minerals; the cracking of the REE minerals to liberate the REE into an aqueous solution and separation of REE into individual elements. This paper describes the results of laboratory tests conducted on a carbonate-rich REE ore containing bastnaesite and monazite. The tests cover the whole processing sequence of beneficiation, preparation of the REE solution using a caustic leach followed by acid leach to break monazite and bastnaesite and liberate REE into an aqueous solution and the partial separation of the REE using solvent extraction. Details on the product quality and process performances (recovery and impurities removal) are given for each studied step. The paper also discusses the economic advantage of separating the REE rather than producing a mixed REO product to be sold to a refinery for REE separation. A mini-pilot plant version of the process is currently planned.

By Joseph M. Singer

Ignition of hybrid coal dust - methane - air mixtures by hot- turbulent - pulsedgas jets was investigated . The turbulent jets were generated by explosions in a primary chamber of stoichiometric mixtures of methane , oxygen , and nitrogen . The hot - gas ignition apparatus provided an adjunct means of testing , on a small scale , the type of ignition that exists in large - scale galleries or in coal mines . = coal particle The temperature Ignition variables were channel diameter , channel length , size , fuel concentration , and temperature of the hot - gas jet . of the hot jet was varied by changing the oxygen indices ( OI ) of the primary explosion mixtures . Coal dust having approximately 37 percent volatile matter was used . 02 O2ટ + N₂ The hybrid coal dust - methane - air mixtures required higher jet temperatures ( higher oxygen indices ) for ignition than the single fuel component methane - air mixtures . Methane in air concentrations less than the lower flammable limit of methane could be ignited in the presence of coal dust if the jet temperatures were increased . A specific explosion transmission ( ignitability ) curve existed for each coal dust concentration . The total fuel concentrations at the lower limit of each ignition curve was always close to or greater than stoichiometric , indicating that not all the coal dust was involved in the ignition .

Jan 1, 1964

By J. C. Agarwal

Do large-scale projects in mining and smelting start up and achieve expected capacity on schedule? In most cases not. Regardless of worldwide location, company know-how, or financial backing, unforeseen delays occur. A comprehensive CRA study for the World Bank shows that delays are the rule, not the exception, in most mining and smelting projects. When delays are not factored into analysis and planning, financial projections are, literally, not to be believed. Returns on investment will seldom achieve their targeted level because of startup delays. This paper reviews the results of our analysis of startup of new mines, mills, and smelters; provides a detailed discussion of why delays occur in the smelters and refineries; presents the cash flow implications of startup delays; and discusses preventive measures that should be taken to avoid financial shortfalls,

Jan 1, 1983