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By Pedro Henrique Teshima Shioga

Quando processos de engenharia de superfícies multifuncionais que combinam fases de propósito orientadas são aplicados a substratos moles, uma combinação de alta resistência ao desgaste, suporte de alta carga e baixos coeficientes de atrito podem ser obtidos. Neste estudo, os efeitos de diferentes camadas nitretadas no comportamento tribológico de revestimento Diamond-Like-Carbon (DLC) depositado sobre aço SAE 1040 são investigados. A nitretação foi conduzida sob diferentes temperaturas e misturas de gases para criar três camadas de nitretos distintas: duas camadas de compostos com predominância de fases e e ?’ e uma camada de difusão. Todas as superfícies foram então revestidas com DLC, depositado via Plasma-Enhanced-Chemical-Vapour-Deposition (PACVD). As fases de nitreto foram analisadas utilizando difração de raios-X e a topografia da superfície foi analisada por interferometria de luz branca e microscopia eletrônica de varredura. O comportamento tribológico foi investigado utilizando esfera e plano com movimento alternado com carregamento incremental até a falha do filme DLC. Os testes tribológicos indicaram que o melhor desempenho foi alcançado por uma específica combinação de dureza, rugosidade superficial e tipo de nitreto. A melhor capacidade de mancalização entre o revestimento DLC e o substrato mole foi alcançada quando a camada de nitretos constitui-se apenas de uma camada de difusão.

Aug 16, 2017

By Gislan William Guimarães

Neste trabalho avaliou-se o efeito de diferentes ciclos térmicos na microestrutura e propriedades mecânicas de um aço Dual Phase revestido por imersão a quente, da classe de resistência de 800 MPa, a partir de simulações em escala piloto no equipamento HDPS (Hot Dip Process Simulator), ensaios dilatométricos, tração à temperatura ambiente e flangeamento. Nas simulações de recozimento contínuo foram experimentadas duas temperaturas de encharque no recozimento intercrítico (740°C e 780°C) e três temperaturas de patamar isotérmico no resfriamento rápido (610°C, 560°C e 510°C). A caracterização microestrutural evidenciou que a temperatura de encharque de 740°C não foi suficiente para dissolução completa dos carbonetos formados na laminação a quente, resultando em frações reduzidas de segundo constituinte. Com isso, o limite de resistência mínimo de 800 MPa não foi alcançado. Além disso, os resultados de ductilidade e flangeamento se mostraram aquém dos obtidos nas simulações com encharque a 780°C. Nas simulações com temperatura de encharque a 780°C e isotérmicas de 510°C e 560°C no resfriamento rápido foi atendido o limite de resistência mínimo, com capacidade de expansão de furo ligeiramente superior à obtida nas simulações com encharque a 740°C.

Aug 16, 2017

By Thais Cristina Lemes dos Santos

Neste trabalho será apresentado estudo sobre nanotubos de dióxido de titânio (TiO2) sintetizados pela técnica de anodização com variação do potencial entre 10 V e 50 V durante tempo fixo de 1 h. Além disso, para obter a estrutura cristalina deseja as amostras passaram por um tratamento térmico que foi realizado a 400 °C por 3 h a uma taxa de aquecimento de 10 °C/min. As amostras foram caracterizadas pelas técnicas de microscopia eletrônica de varredura com emissão de campo (MEVFEG), difração de raios X (DRX), espectrofotometria no ultravioleta visível (UV-VÍS) e de espectroscopia de impedância eletroquímica (EIE). Observou-se que o potencial de anodização exerce influência obre a morfologia dos nanotubos e sobre a absorção de luz e, consequentemente, sobre o desempenho fotoeletroquímico das amostras. O melhor desempenho foi obtido a partir da amostra anodizada a 30 V, este resultado está relacionado com a sua ótima absorção de luz e a sua baixa resistência ao transporte de carga interfacial obtido por EIE.

Aug 17, 2017

By Hiury Voltz

Diversos são os defeitos que ocorrem durante o lingotamento contínuo dos aços. Um tipo de defeito de forma recorrente encontrado no lingotamento contínuo de jato aberto da ArcelorMittal Cariacica é a romboidade. O foco deste trabalho foi avaliar a influência da velocidade da água de refrigeração do molde, da velocidade de lingotamento, da lubrificação, do superheat e da conicidade na ocorrência de romboidade em aços de médio teor de carbono. Por meio da técnica de planejamento de experimentos, testes foram realizados para melhor compreender os efeitos de cada um dos fatores listados. Após análise estatística feita no MINITAB® versão 16.0, os resultados mostraram que a melhor condição, ou seja, as menores romboidades, foram encontradas reduzindo-se o superheat e aumentando-se a velocidade da água de refrigeração do molde, a velocidade de lingotamento e a taxa de lubrificação. O uso de moldes com menor número de corridas foi também outro fator que favoreceu a redução deste tipo de defeito.

Aug 16, 2017

E. K. Landis, Philadelphia, Pa. (communication to the Secretary) : Mr. Firmstone's paper is of great interest; but he has unfortunately otnitted to state the most important point, viz., the percentage of sulphur in the two materials he compares; and this omission vitiates the conclusions which he draws. Comparing by grade, instead of silicon-contents (as in his Table III.), the iron made using limestone with that made using dolomite, we find for gray-forge the average of four analyses under limestone to be, Si, 0.644; S, 0.089 ; while one analysis under dolomite gives Si, 0.508 ; S, 0.070. For No. 2 iron, the limestone flux gives, as an average of 19 analyses, Si, 1.107; S, 0.051; while the average of 4 analyses made with dolomite flux gives Si, 0.630; S, 0.056. It will be observed, that no No. 1 pig is given under limestone, while 14 analyses appear under dolomite, averaging Si, 0.950 ; S, 0.028. As nothing is said about changed conditions, it is Fair to presume that the ore and fuel, as well as the blast-temperature (which is stated to have been uniform at about 750' F.) remained practically the same; and since the sulphur in the two fluxes is not given, it is impossible to know whether the lower sulphur for equal silicon-contents is due to the use of dolomite or to other conditions. The use of dolomite would produce a more fusible cinder, and the furnace would be hotter than when using limestone; therefore, we might expect to see a grayer iron. The amount of So. 1 iron made with dolomite seems to confirm this supposition; and, under these conditions, we might expect more of the sulphur to be volatilized, and to pass off in the gases. The easier fusibility of the cinder would also permit more rapid driving; and this should reduce the amount of silicon and sulphur in the iron, as the amount of reduced metalloids in the pig is directly proportional to the length of time it remains in the reducing-zone.

Jan 1, 1895

The lignites of Otago and Southland offer a potentially viable future feedstock for electricity production and possible conversion to petrochemicals or liquid fuels. The deposits, when combined, represent New ZealandÆs largest energy inventory; equivalent to about 74 000 petajoules û or approximately 35 times current natural gas reserves. Too often dismissed as irrelevant to New ZealandÆs energy future because of adverse perceptions of the value of low rank coals, the strategic value of this resource is in fact huge.   Investigations of the lignites extend back over more than 50 years (LFTB various, CRL Energy Ltd). Whilst it is not the intention of this paper to review this work, these investigations have confirmed the suitability of the resource as a feedstock for thermochemical conversion. Current estimates of South Island lignite mining costs are NZ$1.0 - 3.0/GJ (Natusch 2005), making these resources amongst the most competitively-priced energy sources available world-wide.   This value, however, will only be captured if we as a country begin to envisage a world-scale, long-life, integrated and multi-faceted development sized to supply world markets for chemicals or fuels. Recent CAE studies (Hooper and Riddolls, 2005) have emphasised the vital importance of ensuring that any exploitation of this resource maximises their value to New Zealand. The question that thus must be applied is how might large-scale utilisation of the resource fit with New ZealandÆs primary energy supply, and its potential for the export of high-value commodities.   From the broader perspective of New ZealandÆs total energy supply equation we need to examine other supply options beyond just the generation of electricity. We face in this country a situation wherein almost all our liquid fuels feedstock has to be imported with projections for an increasing dependence on imported oil. In addition NZ has a natural gas reserves-to-production ratio of less than ten years, and dwindling supply from local production. Without further natural gas discoveries, New Zealand has only a window of approximately five years before we will need to commit to imported LNG or some other thermal fuels option.   In other words, New Zealand is facing an uncertain future unless we can restore energy inventories to cover an adequate strategic reserve capacity as well as enable long-term investment in alternative sources. Within this context the South Island lignite resources are thus deserving of more attention. The extent of the resource is well known, its suitability for conversion reasonably assessed, and its magnitude such that there is little doubt that lignite conversion could adequately meet NZÆs future energy needs for many years out.   This paper reviews coal gasification technology, its application to lignite and the possibilities for future development of the lignite resources. It is argued that the strategic imperative for this country is to secure the lignite resources as a primary energy source for this country well into the latter half of this century.

Jan 1, 2005

Crandallite and millisite in Christmas Island 'B' and 'C' phosphate ores are rapidly decomposed by sodium hydroxide solutions at about 80QC. As these phosphates generally contain less than 1% silica, an alkaline extraction process can be designed, in which up to 95% of the sodium hydroxide used, may be recycled. The insoluble residue consists of an impure, highly reactive apatite, which in pot trials, has given good responses as a direct application fertiliser; alternatively this residue can be underacidulated to give a granular product with fertiliser potential. The hot leaching solution contains up to 95% of the alumina and approx- imately half of the phosphate from the original ore. Simple crystallising techniques have been developed on a laboratory-scale to use this leaching solution for producing smelter-grade alumina and detergent-quality trisodium phosphate. As the demand for detergents is limited, an investigation was made of the reaction between trisodium phosphate and slaked lime, derived from a high-grade New Zealand limestone occurring near Oamaru. The product is calcium phosphate, containing up to 40% P205, and less than 0.2% each of iron, aluminium and fluorine, and it should be a useful raw material for phosphoric acid manufacture. A preliminary economic evaluation of the whole process looks promising, And warrants further investigations, including pilot-plant work.

Jan 1, 1971

By C. E. More

Some observations on 'ancient' mining at Phalaborwa C. E. MORE. B.A. (Pretoria) (Visitor) A brief account is given of historical references to the Phalaborwa area, the first being to the mountain of copper and iron sought by Francois de Cuiper in 1725. These are followed by a description of several finds in the area, which are related to finds described in the literature and to Bantu tradition on the subject. Phalaborwa is one of the earliest known mining sites in the Republic of South Africa, Loolekop having been a mining centre, as shown by carbon-14 dating, since 770 A.D.

Jan 1, 1974

By S Mitra, T Singh, D O’Dea, T Honeyands

Permeability and air flow rate in the bed during iron ore sintering is crucial to controlling the sinter quality and productivity of a sinter plant due to its influence on the flame front speed. In the present work, the permeability of the bed during sintering was analysed by means of measured pressure drop and temperature at multiple points in the bed during sintering. Three different zones were categorised, ie humidified (green) bed, region of maximum resistance (high temperature zone) based on temperature, and sintered bed. Previous work has shown that the maximum pressure drop during sintering was due to several concurrent physico-chemical processes including dehumidification, calcination of fluxes, dehydroxylation of goethite, combustion of coke and melting of granules (>1200°C). To quantify the effect of the different process, sintering experiments were conducted in a milli-pot (diameter 53 mm, height 400 mm) with pressure and temperature measured at same location in bed. The milli-pot was fitted with four equidistant (80 mm apart) taps. Overall, five sections in the milli-pot were analysed for pressure drop at different times during sintering. It was found that in region of maximum resistance, coke combustion and flux calcination were highest contributors with ~35 per cent of the pressure drop when compared to other processes like de-humidification and goethite dehydroxylation which contributed to ~20 per cent and 25 per cent each respectively. The pressure drop contribution of the coke combustion region increased with increasing coke addition rate.

Nov 8, 2021

By O A. Aladejebi, S Mitra, T Singh, D O’Dea, S, T Honey

Granulation of the iron ore blend and the additives is the foremost step in the agglomeration of iron ore fines to achieve a permeable bed during sintering, which is crucial for sinter productivity. This study investigated the granulation of four types of blends to determine the impact of granulation on bed permeability. The blends were granulated in a rotating drum at various moisture contents and their JPU permeability was measured at each moisture content in a permeability pot (diameter 95 mm and height 500 mm) at various flow rates. Several independent experiments were carried out to investigate the changes in permeability when mixtures of different particle size range (-1 mm and +1 mm) were introduced into a packed bed with a larger particle size range (-6.3 mm to +4.0 mm). The results revealed that the addition of particles in the -1 mm size range had a more pronounced negative impact on permeability compared to particles in the +1 mm size range. This can be attributed to the relatively higher energy losses (mainly inertial) associated with the presence of -1 mm particles in the mixture. The findings were used to quantify the granulation process based on the -1 mm particle size fraction in the granulated mix and their utilisation (denoted by UI-1 mm). For achieving optimal permeability in a specific blend, it was found that a UI-1 mm (utility index of -1 mm particle size) ranging from 0.82 to 0.92 was required. However, exceeding a UI-1 mm value of 0.95 resulted in weaker granules prone to deformation and led to decreased bed permeability. The study also showed that the UI-1 mm was highly dependent on the water addition per kg of -1 mm in dry feed and suggested adding ~80 to 110 mL of water per kg of -1 mm in dry feed to attain the best possible permeability. Additionally, the research proposed a mechanism involving the melting of granules at high temperatures and highlighted the influence of -1 mm particles on bed permeability during the sintering process.

Sep 18, 2023

By Fernando Generoso Neiva Ferreira

Os aços alto carbono baixa liga são amplamente utilizados, principalmente em componentes que necessitam de elevada resistência mecânica, manutenção de forma e resistência à abrasão. São largamente aplicados em lâminas de corte, molas, peças de segurança, implementos agrícolas, utensílios, serras em geral, entre outros. Neste trabalho, estudam-se, em escala industrial, os parâmetros de processo, as características críticas para o desenvolvimento e as propriedades mecânicas e metalúrgicas de um aço alto carbono baixa liga especialmente desenhado para a produção de correntes de motosserra. Utilizando ensaios de tração, dureza, microscopia óptica (MO) e eletrônica de varredura (MEV), avalia-se a evolução das características mecânicas e metalúrgicas do aço estudado.

Oct 30, 2017

By F. K. Crundwell

The rate of dissolution of sulphide minerals is frequently interpreted in terms of the passivating behaviour of a layer of material on the surface. This interpretation has driven research to identify and possibly remove this layer from the surface, and thus yield higher rates of dissolution. The identification of such layers has proved difficult, with different researchers claiming different compositions for possible layers. An alternative framework has been pursued by the author and co-workers, who have argued that the rate of dissolution is governed by the electronic structure of the minerals which give rise to their semiconducting properties. Researchers sceptical of this approach have argued that semiconducting properties are only important in highly pure substances. In this paper, we review the electronic and semiconducting properties and discuss how they impact dissolution behaviour. These properties affect their colour and dissolution properties even though the minerals are not high purity substances. Keywords: Dissolution, leaching, passivation, semiconductor, chalcopyrite

Jan 1, 2020

By Milena Kellen Oliveira Mendes

O entendimento mais aprofundado dos parâmetros que afetam a temperabilidade dos aços carbono permitiu atingir propriedades antes alcançadas apenas por aços microligados. Assim, este trabalho teve como objetivo avaliar o efeito dos teores de C e Mn, assim como da temperatura de austenitização sobre a temperabilidade de aços baixo carbono, possíveis candidatos para aplicação na fabricação de vergalhões de grau 50. Três aços com composições químicas diferentes foram submetidos a ensaios de temperabilidade Jominy, considerando temperaturas de austenitização de 850ºC, 920ºC e 1050ºC. Curvas de dureza em função da distância Jominy foram construídas e análises microestruturais por microscopia óptica foram realizadas em toda a extensão dos corpos de prova. Os resultados obtidos mostraram que tanto o C quanto o Mn aumentam a temperabilidade dos aços. O Mn, por ser um elemento de liga estabilizador da austenita, dificulta a nucleação e crescimento de constituintes difusionais. O C mostrou ter maior influência sobre a temperabilidade, pois além de também ser um elemento gamagêneo, é responsável pelo cisalhamento da rede da austenita que resulta na formação da martensita. A temperatura de austenitização influenciou a temperabilidade dos aços estudados, porém seus efeitos devem ser estudados com maior profundidade.

Aug 16, 2017

By Camila Barbosa Albani

Foram estudados os tipos de projeções, suas características e medidas de controle, a partir do acompanhamento de corridas na ArcelorMittal Tubarão, inclusive com amostragem e análises dos resíduos de projeção. Utilizando-se termodinâmica computacional estimou-se a viscosidade da projeção, que se mostrou muito heterogênea. Projeções ocorreram em uma faixa extensa de Si do gusa, inclusive em valores abaixo de 0,30%, com maior frequência entre 0,30% e 0,40%. As adições de minério de ferro tiveram forte influência na ocorrência de projeções possivelmente devido ao efeito conjugado de redução da permeabilidade e geração de gás. Um modelo conceitual das causas principais das projeções foi proposto e validado com observações de ocorrência de projeções tardias no sopro. Foi também proposto que as ações de controle de projeções deveriam ser ajustadas de forma a priorizar o controle da taxa de descarburação e o aumento da permeabilidade da emulsão.

Oct 30, 2017

By Scott Turner

I have been asked to speak briefly about recent progress in the mining industry of the United States, and to touch on the general advancement of en- gineering science as applied to mining. By recent, I shall mean within the past 20 or 30 years. Such a period includes a great many of the changes which are of particular interest to the present generation of engineers, and the undergraduates of today will hardly turn back farther than the beginning of the present century in their study of develop- ment of methods and processes. Also, my own professional life spans this period, and I have seen or have been aware of most of these developments as they were taking place. In my review of developments, for the sake of simplicity and clarity, I shall deal separately with improvements in metal mining, coal mining, mechanical and electrical machinery for mines, metallurgy, petroleum engineering, and safety practices. Under each of these headings I have set down what appear to me to be the outstanding changes brought about during the past 2 or 3 decades. Other points will occur to other engineers; I do not represent that the following re- view is complete; it is only intended to be suggestive. In general, improvements in mining and metallurgical practices have come gradually, the charges being effected little by little, simultaneously in widely scattered places, and through the experience and inventive genius of many men. These changes have has small beginnings, and are generally the cumulative result of many steady and unsensational progressions, which still continue. What we today might be inclined to consider the culmination of a series of betterments in mining is, of course, but an instantaneous phase of developments which will continue in the future at even a more rapid pace than they have in the past. We are looking at but a flesh of a moving picture, with an endless reel to come after we finally leave the theatre. Behind all the changes in the mineral industry, the driving force has been the increasing demand of an expanding population for more metals and minerals with which to advance civilization. More people, with an increasing per capita consumption, together with the exhaustion of the richer but smaller, and more

Oct 1, 1930

By Bin Zhu, Mingmei Zhu, Hong Zhou, Xiaofei Dou, Bin Xie, Yu Wang, Tiancheng Lin

In this study, the formation of 2CaO·SiO2 and 3CaO·P2O5 solid solution (nC2S-C3P) in hot metal dephosphorization process is discussed. The variations of CaO and SiO2 mass, both in nC2S-C3P solid solution phase and liquid slag phase with increasing P2O5 mass in CaO-SiO2-FetO-P2O5 slags were calculated using Factsage software. CaO-SiO2-FeOt-P2O5 slag containing up to 18 % P2O5 was melted at 1823 K then cooled to 1673 K. The contents of CaO and SiO2 both in the solid solution phase and liquid slag phase of quenched samples were observed and analyzed by SEM/EDS. Both the calculated and experimental results show that the contents of CaO and SiO2 in the solid solution phase decreased, just opposite in the liquid slag phase, with increasing P2O5 content in the slags. Formation mechanism of nC2S-C3P solid solution in the slags was derived based on the ionic structure theory of molten slag. The SiO4 4- in the nC2S-C3P solid solution can be replaced by PO4 3- in the liquid phase resulting in the increasing of free Ca2+ and SiO4 4- in liquid phase.

Jan 1, 2015

By Lóren Kelly de Paula Inácio, Witor Wolf, Renata de Oliveira Melo, Dagoberto Brandão Santos, Graziele Gianini Braga Maria, Nayara Aparecida Lopes Viana

Os aços inoxidáveis duplex combinam as propriedades mecânicas da ferrita com a resistência à corrosão da austenita. Quando submetido a tratamentos térmicos, pode haver precipitação de fases secundárias que prejudicam a resistência mecânica e à corrosão. O objetivo desse trabalho é avaliar a ocorrência de fases secundárias em um aço inoxidável duplex 2205 de grão ultrafino laminado a frio e submetido a temperaturas de recozimento de 600°C a 950°C por diferentes tempos (300-86400 s). Para identificação e quantificação das fases, foram utilizados microscopia eletrônica de varredura, difração de elétrons retroespalhados e difração de raios-x. As propriedades mecânicas foram avaliadas através de ensaios de tração e teste de microdureza Vickers. A presença de fase  e  foi observada junto ao carboneto de cromo, M23C6. A fase  foi confirmada apenas depois do tratamento à 800°C. De modo geral, o aumento do tempo de recozimento leva à uma maior precipitação das fases secundárias. À medida que a precipitação ocorreu, houve aumento da fração volumétrica de austenita e redução da fração de ferrita. Embora a resistência mecânica tenha aumentado, no geral, as propriedades mecânicas, como ductilidade, são prejudicadas pela precipitação.

Oct 5, 2019

By José Wilmar Calderón-Hernández

Os aços inoxidáveis supermartensíticos (AISM) foram projetados a partir dos aços inoxidáveis martensíticos de mais alto teor carbono, o seu desenvolvimento começou na década de 90. As características principais que os definem como supermartensíticos são: o baixo teor de carbono (C<0,03%) e adição de alguns elementos de liga, especialmente Ni e Mo, essas mudanças na composição química junto com os tratamentos térmicos adequados (têmpera e revenimento) fornecem excelentes propriedades mecânicas e resistência à corrosão melhorada, comparados com os aços inoxidáveis martensíticos UNS S41000 e S42000. Neste trabalho estudou-se o efeito da adição de Nb e da temperatura de revenimento (550°C, 575°C e 600°C) sobre a resistência à corrosão por pite e sobre o grau de sensitização através de dois AISM, um denominado SM2MoNb contendo 0,11% Nb e outro SM2Mo sem adição de Nb. Os resultados mostraram que o aço SM2MoNb apresentou, nas três temperaturas estudadas de revenimento, melhor resistência à corrosão por pite e menor grau de sensitização(GS), ou seja menor tendência à corrosão intergranular. Sabe-se que o Nb ajuda a diminuir o GS devido à inibição da precipitação de Cr23C6 por estabilização de carbono formando NbC em temperaturas mais altas, mas, na literatura especializada, não foram encontradas explicações quanto ao comportamento da corrosão por pite.

Aug 17, 2017

By Kunibert Hanusch

Copper in recycling material is accompanied by various groups of metals: 1) Metals which are much more negative than copper, such as Fe, Al, Si, P, Be They are mainly removed by fire refining during the recovery of copper and leave the process in form of slag. 2) Metals which are more positive than copper or difficult to separate by fire refining and which are partly reduced together with the copper. These metals are for example As,. Sb, Ni, Ag, Pb, Zn, Sn. They are enriched in intermediate products and recovered from these or remain for their major part in the fire-refined copper and can be separated by electrolytic refining and recovered from the electrolyte or anode slime. This report describes the process of Hüttenwerke Kayser AG in Germany and illustrates how considerable returns of material are partly required to separate or recover associated metals. They are finally removed in saleable products.

Jan 1, 1995

By A. Yudiarto, M. Z. Mubarok

At the present paper, synthesis of magnesia from ferronickel smelting slag is discussed. The first stage was extracting magnesium from the slag by leaching in HCl solution. Magnesium extraction of 97% was obtained from the slag leaching with HCl 8 molar, solid:liquid ratio 1:40 (g/ml) and temperature 80 °C after 24 h. Solution purification was performed by adjusting solution’s pH at 95 °C with addition of MgO powder. At pH range range of 3–4, co-dissolved iron was removed as akagenite (b-FeOOH) precipitate. Dissolved nickel precipitation was detected at pH range of 4–6, while dissolved Mg and Al started to precipitate in the forms of pyroaurite (Mg6Fe2CO3(OH)16∙4H2O) and hydrotalcite (Mg6Al2CO3(OH)16∙4H2O) at pH range of 8–9. High purity of brucite (Mg(OH)2) was obtained by Mg precipitation at pH range of 11–12, under stirring speed of 300 rpm and stirring time of 4 h. Calcination of brucite at temperature of 1000 °C completely converted brucite to periclase (MgO) powder after 240 min.

Mar 1, 2017