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By David S. Young

All pigments and extenders or fillers whether organic or inorganic fall into the following broad general classes: I. Colored II.-White III. Black IV. Metallic A pigment- is any particulate matter that is essentially insoluble and chemically unaffected by the media into which it is dispersed. According to this very broad definition, colored pigments, white pigments, fillers, extenders, and functional pigments would all be included. The particulate size range would also be quite broad ranging from very fine colloidal particles (~0.01µ) to relatively coarse particles (~100.0µ). This broad definition is usually subdivided into more practical divisions which tend to relate the classification of the pigment to its primary function in the system in which it is used. Hence, the word extender implies that its major purpose may be to extend the system.

Jan 1, 1985

By John V. Beall

HEAVY-DENSITY separation processes, a commercial application of the sink-float test used in mineralogical laboratories for the separation of mineral particles by their difference in specific gravity, are the biggest development in mineral dressing since flotation, which was at about the same stage of development thirty years ago. The scope of their application has broadened and, though still in the development stage, they are being accepted in a constantly increasing number of commercial installations. This progress in mineral beneficiation is especially satisfying when we realize that our high-grade ore deposits are fast disappearing and a big factor in determining whether a hole in the ground is being sat upon by a liar or an honest citizen is how economically the ore dressers can concentrate comparatively low-grade ores. As early as the middle of the nineteenth century attempts were made to use aqueous salt solutions in a heavy-liquid separation for cleaning coal. But the original and recovery costs of these liquids were high and further, the fact that they were corrosive, unstable, and toxic added to the difficulty in using them.

Jan 1, 1948

By Emily Johnson, Catherine Johnson, Rachel Bauer, Paul Pitzel

Demolition projects involving explosives may incorporate cutting charges to sever columns in collaboration with kicker charges that “move” the columns out of alignment. Traditional kicker charges often involve the use of dynamite secured to the column above the cutting charge. Nitroglycerine, the main component of dynamite, causes medical problems and can be a hazard to workers on site. Dynamite can also cause fragmentation of the column and structures, resulting in potential injuries to people or leading to the possibility of cutoffs in neighboring charges. This study investigates the use of water-cased kicker charges to reduce the amount of dynamite in demolition. Water charges, traditional charges, and detonating cord charges were placed on hanging steel columns and analyzed for the fragmentation of the column and velocity of the column. A W 10 X 22 beam was hung in an underground limestone test area and allowed to swing freely acting as a severed column. Charges were attached to the bottom of the column with tape and initiated using electric detonators. Explosive charges of dynamite or detonating cord were placed in the center of a water container or directly on the column for use as the kicker charge. Tests were recorded with high-speed video and velocity was calculated using Phantom Camera Control software. Velocity and time were then used to calculate force, kinetic energy, impulse, and pressure exerted by the explosive on the column. The water charge transferred energy to the column over a larger area with no direct contact of explosive and the column. Water charges moved the column faster and with more power than traditional charges. After preliminary tests, water charges were also used as the primary kicker charges in a full-scale demolition project as a case study using 118 charges. The kicker charges successfully moved building members without creating fragmentation while using less dynamite than traditional kicker charges. Due to the success, multiple full-scale projects are being designed using water charges to show success and repeatability.

Feb 6, 2023

By Shimeni Baptista Ribeiro Daer, Patrícia Freitas Rodrigues, Edir Neves Teixeira, Naiara Vieira Le Sénéchal, Andersan dos Santos Paula, Francisco Manuel Braz Fernandes

Este trabalho visou em compreender as características microestruturais de uma liga de NiTi rica em Ni deformada a quente por meio do processo de forjamento rotativo, que foram submetidas ao processo com temperaturas distintas de pré-aquecimento (800 e 950 ºC) sem e com tratamento térmico de recozimento prévio (950 ºC por 2 horas) para homogeneização do lingote. Por meio dos aspectos da evolução microestrutural verificados com auxílio das técnicas de Microscopia Óptica, Microscopia Eletrônica de Varredura e difração de Raios X pôde-se observar que a adoção do recozimento prévio para homogeneização e incremento da temperatura de pré-aquecimento as etapas de forjamento rotativo a quente, conduziu a resultados mais satisfatório ao processamento termomecânico a ser aplicado nesta liga, a fim de seguir para as etapas de deformação a frio.

Nov 14, 2019

By AIME AIME

DATA in this report enable comparisons to be made within the bituminous coal industry and comparison as well with copper and steel in respect to capacity and overdevelopment. The conclusions reached from the data will tend to correct numerous current misconceptions. The data have been prepared by various members of the Coal and Coke Committee of the A.I.M.E., from the most authentic sources avail¬able, and cover the period 1913-1924 wherever possible. CAPACITY AND OVERDEVELOPMENT Table 1 shows statistics for the industry, mainly from the U. S. Geological Survey sources, but partly from the U. S. Coal Commission reports. The mine capacity with equipment and labor as of given date is calculated for each state by obtaining the total man days worked as reported by the operators, and dividing this figure into the total production, getting the production per man day; this figure times the number of men employed times 308 (a theoretical full working year) equals estimated full-time capacity. Two major objections are made to this method-one that the total number of men employed is used instead of the number actually working, and the other that the number of days used only deducts Sundays and five holidays. Covering the first, the same number of men is used in estimating capacity as is used in actual production, and this condition exists at all times. Regarding the second, the opinion is general among coal men that 280 days is as great a figure as should be used, as it is practically impossible to keep any mine working full time at the same daily rate as when it is working part time. The capacity, as estimated on this basis, is much more nearly the true capacity, although even with present railroad efficiency this amount of coal could not be moved.

Jan 1, 1926

By William H. Waggaman

CURTAILMENT of the mineral industry as a whole undoubtedly will follow world peace, but the output of certain minerals should pursue a course well above the average on any curve of probable output projected beyond the trends exhibited through 1939. Without speculating on industrial conditions in the pending recomversion period, demand for fluorspar should be greater than before the war because of these factors, introduced by or resulting directly from military necessity: (1) Discovery and development of new deposits. (2) Improved technology in benefication. (3) New and expanded uses for fluorspar and its derivatives. The steel industry has been and continues to be the greatest consumer of fluorspar, and it wag largely to meet the wartime needs for steel that the domestic fluorspar industry has been expanded so greatly. Not only were the search for and development of new deposits of this mineral considered esstinal but the marginal nature of some of the,c- domestic deposits made it necessary to improve mineral dressinc and processing techniques to utilize them

Jan 1, 1945

By Leandro Miranda Nascimento

A maior parte da produção mundial de aço passa pela conversão de minério de ferro em grandes altos-fornos, tendo o coque como uma das matérias-primas. Por um lado, boas propriedades mecânicas a quente do coque, como o CSR e CRI, são necessárias para que o consumo de coque seja o mínimo, pois é também, junto com os óxidos de ferro, um dos maiores componentes dos custos variáveis do ferro gusa. As misturas dos vários tipos de carvões minerais utilizados exigem a participação de uma fração Hard, a mais cara e com maior poder de coqueificação, e de uma fração Soft, mais barata e inerte. Logo, quanto maior for a participação do Hard mais caro será a mistura a ser coqueificada. Uma maneira de aumentar a fração de Soft na mistura de carvões, reduzindo o custo da mistura, e ainda assim obter um coque com boa qualidade é aumentar a densidade a granel da mistura. Para isso alguns métodos já são empregados com sucesso, como o Stamp Charging e a Briquetagem Parcial. Este artigo apresenta um novo método, que consiste na densificação da mistura de carvões dentro do forno via dispositivos de vibração. Foram realizadas simulações físicas a frio e em escala reduzida para avaliar o potencial de aumento de densidade a granel da técnica. Os resultados mostram um ganho de aumento de 30% da densidade a granel da mistura.

Aug 17, 2017

By Paulo Sérgio Moreira

O tamanho de grão austenítico prévio é determinante na área de tratamentos térmicos dos aços, pois este parâmetro influencia sua microestrutura e propriedades. Para que o tamanho de grão possa ser medido, é necessário que antes se aplique métodos de contraste para sua revelação. A literatura relata, entre métodos desenvolvidos, dificuldades em se conseguir bons resultados em função deles serem susceptíveis a variações de composição química e histórico de processamento dos aços. Neste contexto, esse trabalho propôs métodos para a revelação dos contornos de grãos austeníticos prévios dos aços ABNT4340 e ABNT1030. Foram utilizadas duas técnicas: ataque químico e ataque térmico. Para a técnica de ataque químico, utilizou-se um reativo a base de ácido pícrico. Já na técnica de ataque térmico, as amostras foram austenitizadas de forma a promover uma oxidação controlada. Os resultados obtidos mostram o sucesso das técnicas, com destaque para o ataque térmico que se mostrou mais efetivo para o objetivo proposto. Foi possível mostrar que no ataque químico, o ajuste da concentração de HCl em função da composição química do aço é o ponto de maior importância, ao passo que no ataque térmico, a segregação química e a temperabilidade dos aços são relevantes para o sucesso da técnica.

Aug 17, 2017

By Aichun Dou

Au-Sb alloy sample in which the total amount of Cu and Ni is below 25% (wt. %). In practice, Cu and Ni were difficult to be dissolved in sulphuric acid solution by oxidative leaching under the atmospheric pressure conditions, because of the lower concentration of Cu and Ni in the sample. In this paper, pressure oxidation leaching in sulphuric acid system (POLS) followed by hydrochloric acid leaching (HAL) was employed to remove impurities in the Au-Sb alloy. The effects of variables in POLS on leaching ratios of different metals were investigated in detail. Under the optimal conditions: the concentration of H2SO4 is 1.5 mol/L, liquid-solid ratio is 7:1, the amount of oxidizer is 1.2 times of the theoretical amount, leaching time is 4h and leaching temperature is 427K, the leaching ratios of copper and nickel reached up to 99%, antimony, lead and silver were not dissolved in dilute sulphuric acid solution. The residue from POLS was then treated with hydrochloric acid solution in fixed conditions, the leaching ratio of antimony reached over 92%, the grade of gold in the ultima residue was enriched up to 66%.

Jan 1, 2016

By F. G. Cottrell

(New York Meeting, February, 1912.) ABOUT a year and a half ago, at the San Francisco meeting of the American Chemical Society, in connection with the excursions to local smelting-works, I had occasion to show some lantern-slides illustrating the recent commercial development of electrical methods for precipitating the suspended matter from smelter-smoke, the underlying phenomena of which were clearly brought to the attention of the technical public by Sir Oliver Lodge as long ago as 1884. In the Journal of industrial and Engineering Chemistry, August, 1911, most of these views were reproduced, together with an account of the work from its beginning up to July, 1911. To-day I wish particularly to show you some of the further developments of the work since that time; but in order to make these clear they will be prefaced by a brief abstract of the article above referred to. The removal of suspended particles, front gases, by the aid of electric discharges is by no means a new idea. As early as 1824 we' find it suggested by Hohlfeld 1 as a means of suppressing ordinary smoke, and again a quarter of a, century later by Guitard.2 These suggestions, which do not seem to have stimulated any practical study of the question, were soon entirely forgotten, and only brought to light again by Sir Oliver Lodge,3 many years after he himself had independently rediscovered the same phenomena and brought them to public attention 4 in a lecture before the Liverpool Section of the So-

Jul 1, 1912

By M. A. Mekicha, M. B. de Rooij, C. Pelletier, D. T. A. Matthews

One of the main factors that reduce strip cleanliness are iron fines, which are formed due to the abrasive interactions of the roll surface and the strip in the roll bite during cold rolling. They can cause a problem in fouling of the cold rolling mill as well as downstream processes. It has been repeatedly observed that chrome plating the work roll improves strip cleanliness. In the present work, scratch tests and reciprocating sliding tests were carried out under lubricated conditions to explore the influence of chrome plating on iron fines formation. Scratch tests were conducted to study the influence of chrome plating on iron fines formation at single asperity scale due to its intrinsic property. Reciprocating sliding tests were performed to study the influence of chrome plating a rough surface on iron fines formation, taking into account the initial roughness. The scratches made using chrome plated pins showed lower friction, generated less iron fines and exhibited lower material transfer. Reciprocating sliding tests done using the uncoated pins showed galling at different sliding distances depending on the roughness of the pin. On the contrary, reciprocating sliding tests with the chrome plated pins exhibited no galling irrespective of the roughness.

Oct 1, 2019

By M Zhu, G Tranell, N Simkhada, K Jakovljevic, M Wallin

Silicon is a vital element in many products today, such as electronic components, solar devices, high-quality alloys, and many others. The growing global demand highlights the need for the development of sustainable production methods to meet this demand as an alternative to the current carbothermic reduction, submerged arc furnace (SAF) based process. An alternative to this is the aluminothermic reduction of quartz in a CaO-SiO2 slag, which not only reduces direct carbon dioxide emissions but also promotes the utilisation of secondary raw materials such as quartz fines, aluminium dross and scrap as well as secondary alumina (SA) from dross recycling. In the current study, the effects of SA and CaF2 additions to slag on the resulting metal composition and metal yield were explored. Results were compared with thermodynamic simulations using FactSage™ 8.1. Experimental results show that, in agreement with thermodynamic simulations, the silicon content of the alloy is increased, while the Ca is decreased for starting slags where CaO-SiO2 is partly replaced by CaF2. Similarly, the addition of SA to the initial slag results in an alloy with a higher silicon content.

Jun 19, 2024

By O. Porterfield, M. O’Kane, M. Endersby

BHP Iron Ore initiated research programs in January 1995 to develop long-term plans for decommissioning waste rock material at its Mt. Whaleback operation. More than 2 Gt (2.2 billion st) of waste rock were deposited during the past 30 years. Ultimately, a total of 4 Gt (4.4 billion st) will be deposited in waste rock dumps constructed near the open pit. The Mt. Whaleback operation is located in a semiarid climate adjacent to Newman, Western Australia. The primary research program includes the development of technology for the long-term performance of the waste rock dumps with respect to vegetation, slope stability, surface runoff, erosion and water infiltration. This paper focuses on the design and implementation of a cover system to prevent water infiltration to the underlying waste rock. Data obtained from a laboratory program and from soil-atmosphere modeling was used to design horizontal field test plots. The construction of the horizontal surface field test plots is discussed together with the field instruments installed to monitor performance. The cover system is designed to maximize infiltration during wet periods for subsequent evapotranspiration while minimizing surface runoff. The result is a near-zero net infiltration to the underlying waste material. An important feature of the design is the use of run-of-mine waste material as the cover material. Monitoring is in progress and will continue for at least two annual wet/dry cycles. The optimum cover system should minimize the net infiltration of water to the underlying waste rock while maintaining physical and ecological integrity for long-term performance.

Jan 1, 2000

By Ken A. Phillips

Like the Arizona jeans commercial says: Arizona's not just a state, its a state of mines. Nearly 300 mines operate in Arizona making it the largest nonfuel mining state in the nation. Although copper is king in Arizona's mineral complex, nonmetallic minerals play important roles both regionally and nationally. Throughout Arizona's mineral resource development history industrial minerals have dominated over the metals for most, but not recent years. The State's metal mining industry which makes Arizona the number one mining state in the United States is a relatively young phenomenon. Arizona was an important industrial mineral producer long before her metal mining industry got started. Salt, phosphates, silicates, and oxides as food additives, tanning chemicals, gemstones, components of aboriginal ordnance, pigments, and construction materials are among the minerals produced long before copper, gold, silver, and the other metals became important. Around 92 % of Arizona's mineral industry is made up of nonfuel minerals, 86 % of that is accounted for by copper. Another 4 % is taken up by copper byproducts of molybdenum, silver, and gold. The remaining 10% of the production is occupied by non-fuel, non-metallic minerals. Arizona's 1994 industrial mineral production of nearly $380 million ranks us among the top 25 in the nation and higher than the total mineral production of at least 15 states.

Jan 1, 1996

By Michael A. Eamon

Magma Copper Company has operated its San Manuel SX-EW Plant facilities since 1986. The original plant facilities have a design capacity of 25,000 tons per year of electrowon copper cathode produced by processing pregnant leach solutions from an open pit/heap leach operation. In 1988, the plant was expanded to 50,000 tons per year to incorporate processing leach solutions from an insitu leaching operation. This paper presents a general overview of plant practices with particular emphasis on process innovations developed and implemented by Magma during construction and operation.

Jan 1, 1991

By Rachel L. Bauer, Catherine E. Johnson

Explosive demolition involves first, the use of cutting charges to sever a column and second, kicker charges to move it out of alignment. Dynamite is the traditional explosive used in kicker charges as it is inexpensive, easy to initiate, and has a consistent track record of use. Dynamite, however, has health concerns in handling, fragmentation concerns from direct contact on the beam, and availability concerns due to being manufactured at only one location in the continental United States. Recently, water-cased kicker charges have been used in industry, and research has shown that a reduced dynamite mass is possible due to the added confinement, for energetic performance, and the incompressible fluid, which aids in the transfer of explosive energy into beam movement. This research will compare two different explosives, an emulsion (DYNO AP), and binary (HELIX), to dynamite for use in kicker charges, both with and without water-casing. Emulsion is commonly used in rock blasting to create a large push or throw due to its high gas volume production which could translate to kicker charge movement. HELIX is a binary explosive commonly used by the military in breaching charges with water backing. Experimental tests placed kicker charges at the base of a hanging steel column, modifying the ballistic mortar test used to determine explosive power. The study shows that water-casing effectively reduces air overpressure and enhances explosive performance. Among the tested explosives, HELIX showed the most substantial improvements with a 1.8 dB reduction in air overpressure and a 3.2 m/s (10.5 ft/s) increase in column velocity when water-cased. Dynamite and emulsion also benefited from water casing, with decreases in air overpressure (1.1 and 0.7 dB respectively) and increases in column velocity (1.1 and 0.7 m/s (3.6 and 2.3 ft/s) respectively). This research also shows that emulsion is a viable replacement for dynamite in demolition projects, performing similarly in both traditional use and water-cased charges.

Jan 21, 2025

By Lorena Cristina Amorim Moura

As coquerias enfrentam um grande problema que é a oxidação do carvão. Este fenômeno as afeta diretamente, pois deterioram as propriedades coqueificante do material, impactando na síntese do coque metalúrgico. Portanto, gerando perda de valor econômico, uma vez que as propriedades coqueificantes são fatores que determinam a atratividade e o custo do carvão. Sendo assim, torna-se necessário o uso de medidas para retardar o efeito da oxidação, garantindo a menor perda possível, desde a extração do carvão mineral da mina, até o carregamento nos fornos de coqueificação. Neste estudo em particular, definiu-se uma equação para previsão do decaimento de fluidez, que é a principal propriedade afetada pela oxidação, e matéria volátil de carvões em pilhas a céu aberto. Foi também desenvolvido o estudo do efeito da aspersão de uma camada polimérica para minimizar os decaimentos de fluidez e matéria volátil.

Oct 30, 2017

By Gabriel Filipe Barrelas Marques Gamito Cardos

O aço em estudo (SAE8620MOD) é um material utilizado na aplicação de estruturas de óleo e gás. Essa liga modificada é utilizada em estruturas off-shore para produção de amarras. Para garantir a qualidade do produto são realizadas uma série de ensaios, dentre eles propriedades mecânicas (RT, LE, Alongamento e redução de área) bem como resultados de dureza e impacto. O ensaio de impacto está relacionado diretamente com a microestrutura obtida durante o processo de solidificação do aço e com o tratamento térmico realizado. Microestruturas com alto grau de bandeamento podem comprometer a variabilidade dos resultados de impacto. A redução ou até mesmo a eliminação do bandeamento é um caso de amplo estudo, principalmente em aços com processo de lingotamento contínuo. Muitas soluções já foram propostas para a redução do bandeamento, o de agitação eletromagnética tem se mostrado bastante efetivo na redução dos níveis de bandeamento e segregação dos produtos lingotados. O ensaio consiste em avaliar a intensidade do campo eletromagnético (FEMS) para o comportamento do nível de bandeamento do material. Foi utilizada uma corrida para teste via lingotamento contínuo, onde a velocidade de lingotamento permaneceu constante e variou-se a corrente dos agitadores em três condições: tarugos com baixa agitação (FEMs com corrente baixa), tarugos com alta agitação (FEMS com corrente alta) e tarugos sem agitação (FEMS desligado). Com baixa agitação no FEMS conseguimos obter um nível de bandeamento menor se comparado com os outros resultados. Como consequência a variação dos valores de impacto apresentaram-se menores que as demais condições, devido a homogeneidade do material. Dessa forma podemos dizer que a redução do nível de bandeamento no material reduziu também a variação dos resultados de impacto, tornando o processo mais estável.

Oct 30, 2017

By Rudineli Demarque

Este artigo apresenta um estudo das características metalúrgicas, geométricas e microestruturais da soldagem TIG autógena aplicada em chapas de um aço AISI 304, o processo autógeno tipo cordão sobre chapa foi utilizado com a finalidade avaliar o comportamento deste aço quando submetido a ciclos térmicos distintos. A soldagem foi automatizada, na posição plana, e realizada com controle de velocidade com a finalidade de regular a energia adicionada ao material soldado. As variáveis de entrada foram a velocidade da tocha de soldagem TIG, e a corrente setada na máquina de solda. Foram avaliados os efeitos da variação da energia de soldagem sobre as características metalúrgicas do processo, sobre as características geométricas (penetração e largura) do cordão se solda, microestrutura, espaçamento dendrítico e microdureza da seção transversal da junta soldada. Os resultados indicaram uma forte influência sobre a geometria da junta soldadas, aumento de 28,5% na largura, 59,6% na profundidade e 44,6% na área, além de alterações microestruturais, aumento de 100% na quantidade de ferrita d, 12% na microdureza e 51,69% no espaçamento das dendritas no metal de solda, Além disso observaram-se ausência de defeitos nos passes isolados sobre as chapas.

Oct 30, 2017

By C Zschiesche, alam, A Abadias Llamas, A K

Lead has the ability to collect and carry valuable metals such as copper, bismuth, antimony, tin and precious metals for their downstream recovery. Therefore, lead metallurgy is key for the raw material supply that our society demands. Lead smelters, excluding lead-acid battery recyclers, tend to process more complex primary and secondary raw materials, which are mostly processed via the pyrometallurgy route. Accordingly, understanding the slag system of these metallurgical processes is key for the efficient industrial operation and recovery of minor elements. Glencore Nordenham is an integrated lead and zinc smelter in northern Germany with a production of 92 000 t of lead and 164 700 t of zinc in 2022. The lead production line processes complex leadbearing raw materials through the direct smelting process. Firstly, the feed mix is smelted in a Top Submerged Lance (TSL – Ausmelt®) furnace, where a lead bullion containing minor metals and a lead-rich slag are produced. Then, the lead-rich slag from the TSL is tapped (via launder) into a Side- Blown Furnace (SBF), where lead oxide is reduced to produce lead bullion (with minor elements) and discard slag. The lead bullion from both stages is refined to produce lead (>99.9 per cent) and recover the minor elements (Cu, Ag, Au, Sb, Te, Bi etc). This paper reflects the experience of operating the SBF after the first five years of operation and describes its ‘PbO-SiO2-FeOx-CaO-ZnO’ slag system. Firstly, the slag system, the furnace operating region and the potential solid phases present are discussed from a theoretical point of view. This theoretical study has been performed using FactSage™ 8.2 and the database developed by the Pyrosearch group at the University of Queensland, Australia (UQPY). Then, the FactSage™ simulations are compared with industrial slag measurements. Finally, some examples on how the slag knowledge gained at Glencore Nordenham can help the industrial operation of the SBF are discussed.

Jun 17, 2024