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By William R. Webster

At the Florida meeting of the Institute, in March, 1895, I presented a Note on a Proposed Scheme for the Study of the Physics of Cast-Iron,1 giving an outline which, for convenience of reference, I here repeat. Suggested Lines for DiScuSsion and IvestiGation. I.—Correspondence between chemical composition and melting-point, fluidity, shrinkage, fracture, chill, micro-structure, and other physical properties. II.—Influence of: 1. Cupola-mixture, use of steel and other scrap, oxidized or clean material, 2. Manner of melting, flux, etc., 3. Casting-temperature, A. Fracture. 4. Manner of handling melted metal and B. Micro-structure. method of casting, C. Physical properties. 5. Size and form of casting, D. Shrinkage. 6 Kind of mold, green sand (under dif- on E. Chill. ferent conditions of ramming, amount F. Residual strew of moisture, and skin-dried), dry sand, G. Condition and quan- loam, and chills, tity of carbon and 7. Rate and mode of cooling castings, other elements. 8. Manner and temperature of heating for annealing, 9. Additions of nickel or aluminum, III. —-Segregation as affected by : 1. Composition ; 2. Casting-temperature; 3. Rate of cooling ; 4. Size and shape of casting. IV. —Blow-holes, their volume and position as affected by: 1. Composition; 2. Casting-temperature; 3. Casting-pressure ; 4. Rate of cooling; 5. Size and ehape of casting ; 6. Special additions. It was hoped that a discussion might thus be elicited, similar in interest and value to the discussion of the physics of steel, which had been so widely and gratefully welcomed by students and practitioners in that department. That this hope was not

Jan 1, 1905

By R. M. Zimmerman

INTRODUCTION Tuff is being considered as a possible geologic median for the underground storage of commercial high level radioactive wastes by the Department of Energy (DOE). DOE has the responsibility for developing or improving the technology fir safely and permanently isolating these wastes. DOE programs must satisfy requirements established by the Nuclear Regulatory Commission (NRC) for the licensing and regulating of these storage facilities (NRC 1981). Pertinent draft NRC requirements are: 1) releases of radioactivity to the environment must be within prescribed limits and 2) emplaced canisters containing wastes must be retrievable up to 50 years following emplacement. High level radioactive wastes produce heat in storage and it is essential that the thermal/mechanical/hydrological response of the host rock will not significantly degrade either the structural performance o£ the repository or the ability of the natural or engineered barriers to retard radionuclide migration. The Nevada Nuclear Waste Storage Investigations (NNWSI) was established by DOE to evaluate the suitability of disposing of high level nuclear wastes on or near the Nevada Test Site (NTS) (NNWSI 1980). NNWSI has focused exploration and site evaluation on the tuffs of Yucca Mountain. Field testing is essential to support site characterization and repository design efforts. Preliminary studies have been conducted indicating that tuffs in G-tunnel on the NIS contain welded and nonwelded tuffs that have similar properties to those in Yucca Mountain. Thus, field testing can be accelerated. This paper discusses the issues supporting the planned field experiments in G-tunnel. Issues not related to rock mechanics are not included.

Jan 1, 1982

By Gregory Dybalski

The purpose of this paper is to illustrate the forecast capability of the econometric model of the cobalt industry1/ as utilized by the Federal Preparedness Agency. Forecasts from this model are illustrated from the premise that the leading producer continues production of cobalt. An alternate forecast is presented where the model structure is altered to reflect the condition where the leading producer leaves the market. All estimations and forecasts presented here are shown for illustrative purposes. The cobalt industry is highly concentrated; one company, owned by the Zaire government, accounts for approximately three-fifths of world production. The cobalt supply outside of Zaire is determined by the level of activity of copper or nickel markets, as cobalt is mined as a by-product of copper or nickel. The demand for cobalt reflects a diversified usage pattern; cobalt is used mainly in heat and corrosion-resistant materials, high- strength materials and permanent magnets. According to 1974 U.S. consumption data superalloys accounted for 22%, magnetic alloys 18%, cutting and wear-resistant materials 13%, and catalyst 7%. Foreign consumption is probably similar in terms of usage categories, but the relative order of the categories is in variance.2/ The Cobalt Model The cobalt model's object is to explain consumption, supply and price movements by utilizing statistically estimated equations. Central to the econometric model is the role of Zaire as the profit-maximizing "dominant firm". Zaire sets the price that is most profitable for itself. The price of cobalt depends on industrial demand, production of other firms, and net exogenous purchases, such as government

Jan 1, 1977

By Shadia J. Ikhmayies

"Cadmium sulfide thin films were prepared on glass substrates by the spray pyrolysis technique at a substrate temperature of 490°C. Some of the films were etched by HC1 in distilled water, others were heat treated in nitrogen atmosphere, and another set of films was first etched by HC1 and then annealed. Room temperature impedance spectroscopy measurements on the films were performed using coplanar geometry in the dark and in room light in the frequency range 20 Hz to 1 MHz. The experimental data were represented by complex plane diagrams and showed one well-defined semicircle in the high frequency region. Hence the equivalent circuit that models the CdS: In thin films was found to be a single RC circuit, which indicates the bulk conduction through the grains. The influence of treatments on the electrical properties was investigated.IntroductionCadmium sulfide (CdS) is a brilliant II—VI semiconductor material with a direct band gap of 2.42 eV at room temperature. It has many outstanding physical and chemical properties, which have promising applications in multiple technical fields including photochemical catalysis, gas sensor, detectors for laser and infrared, solar cells, nonlinear optical materials, various luminescence devices, optoelectronic devices and so on [1]. There are different methods to prepare undoped and doped CdS films, such as rf sputtering [2] chemical bath deposition (CBD) [3], pulsed laser deposition (PLD) [4], and spray pyrolysis (SP) [5-11]. Of these methods, spray pyrolysis represents the less expensive option, and can produce large area high-quality low cost thin films [12]."

Jan 1, 2012

By Frank Fahrenwald

INTRODUCTORY A COMPLETE list of the elements as given for 1915 includes 18 that melt above 1,700° C. There does not exist one complete thermal equilibrium diagram for any pair of these 18 elements. Several of these elements have been combined, in relatively small proportions, with metals of lower melting point: e.g., tungsten, molybdenum, and vanadium, in steels, or with nickel and cobalt; but of this refractory group, platinum is the only one that has been extensively studied in this connection. When one considers that, with few exceptions, the industries have made use of alloys to the exclusion of pure .metals, it is reasonable to expect that alloys of this refractory group will invade fields in which the pure metals have found little application. The past neglect of this class of metals has, no doubt, been partly due to the rarity of some of them, for even though alloys of very valuable properties should be developed, their cost, unless in exceptional applications, would be prohibitive. There is also a well-founded reluctance to undertake research involving very high temperatures which, in the case of most of these elements, must be accompanied by an inert atmosphere as well. This combination of high temperatures* and control of atmosphere within the heating chamber of any furnace of present design is a difficult problem. It is the purpose of this paper to give results,1 of an investigation of one binary series of this group, in which methods were employed that avoided the usual difficulties accompanying high-temperature alloy investigation.

Jan 6, 1916

By John W. Tieman

Coal is a term applied to vegetable matter (trees, grasses, etc.) which was subjected to heat and pressure through geologic ages. This resulted in a change in both the physical and chemical properties. Because its chemical composition is variable, geologists classify coal as a heterogeneous mineral rather than a homogeneous mineral. Peat represents the initial, unconsolidated stage in the development of coal. This coalification continues with time and the application of temperature and pressure to lignite, subbituminous, bituminous, and anthracite toward the theoretical graphite end member. PHYSICAL PROPERTIES OF COAL The physical properties are concerned with the characteristics of coal in its natural state, or prior to its end use as a fuel. For example, the hardness and grindability of coal determine the maintenance cost for coal mining, handling, and pulverizing equipment; the specific gravity of coal and its associated minerals determines the coal preparation technique used in a cleaning plant as well as the capacity of coal bins, boats and size of cargo, and other coal storage facilities. The physical properties are, of course, dependent on the chemical constituents of coal, and all properties are interrelated. Specific Gravity The specific gravity (sp gr) of a solid is the ratio of the weight of a cubic foot of the solid to the weight of a cubic foot of water. The specific gravity of pure coal has been reported to range between 1.23 to 1.72 and increases with the change in rank from lignite to anthracite. This means that it is 1.23 to 1.72 times heavier than water.

Jan 1, 1981

Discussion of the paper of J. V. EMMONS, presented at the Pittsburgh meeting, October, 1914. and printed in Bulletin No. 93, September, 1914, pp. 2233 to 2248. ALBERT SAUVEUR, Cambridge, Mass.-Mr. Emmons is to be congratulated for having placed before us in so forcible and satisfactory a manner a question of much importance-that of the surface decarbonization of steel. Of course, both manufacturers and consumers have known for many years that during the heat treatment of high-carbon steel, surface deca.rbonization is always likely to occur to a greater or less degree, but the subject does not seem to have been investigated with the method and thoroughness it deserves. I am in substantial agreement with Mr. Emmons's conclusions, and I have but little to add to what he has so well said. His statement that carbon dioxide is just as effective an oxidizing agent as pure oxygen is likely to cause surprise and some will wonder whether his investigation has been carried far enough to warrant so unexpected a conclusion. The reaction C + 0 = CO, expressing the oxidation of carbon by pure oxygen, is decidedly exothermic, whereas the reaction C + C02 = 2C0, expressing the oxidation of carbon by carbon dioxide, is endothermic. Decarburization by pure oxygen, therefore, should take place much more readily than by carbon dioxide. One cannot help regretting that the author does not mention' the best way of preventing in a practical manner surface decarbonization while treating tool steel and other high-carbon steels.

Jan 4, 1915

By C Li

Removal of gangue minerals from ilmenite concentrates can beaccomplished by relatively low temperature roasting in controlled gasatmospheres to selectively enhance the magnetic separationcharacteristics of the ilmenite. At roasting temperatures below 800¦C the magnetising reactions are often not consistent with phase equilibria considerations. Metastable phases can nucleate and control the roasting products. In weathered ilmenites the phase assemblages and microstructures in the altered ilmenite grains can influence the roasting reactions. In this paper we give an overview of the phase chemistry of chemically weathered ilmenites and of metastable phases formed by low temperature roasting. We also report the results of roast experiments conducted in a neutral gas atmosphere. Major increases in magnetic properties after short roasting times at low temperatures were obtained for a range of ilmenite concentrates. For example heating a secondary ilmenite concentrate from Western Australia for 15 minutes in nitrogen at 600¦C gave an increase in the three kilogauss magnetic fraction from three to 92 wt per cent. The solid state phase changes accompanying the inert atmosphereroasts were characterised by combining elemental analyses withquantitative phase analyses of the ilmenite concentrates and their roast products. It was found that the phase reaction that is principally responsible for the increase in the magnetic properties of weathered ilmenites involves a transformation of disordered ferrous-containing pseudorutile to an ordered ilmenite-hematite solid solution containing typically ten to 35 mole per cent of the hematite component. Examples are given of the application of the inert atmosphere roast to effect separations of ilmenite from gangue minerals.

Jan 1, 2001

By V. Bojarevics, K. Pericleous

"A number of different methods have been developed for noncontact electromagnetic treatment of liquid metal and to investigate the melting/solidification processes. Applying AC magnetic field in terrestrial conditions, along with the buoyancy and thermo-capillary forces, results in turbulent flow. The use of a homogenous DC magnetic field allows damping both of the turbulence and the large scale flow at different rates leading to surprising results at some stages. The dynamic interaction of the turbulent flow with the oscillating interface needs to be accounted if it is required to levitate liquid metal of up to few kilograms without the contact to container walls. At the high values of magnetic field some oscillation modes are damped quickly, while others are modified with a considerable shift of the oscillating droplet frequencies and the damping constants from the non-magnetic case. Numerical models are used to investigate behavior of liquid metal suspended in high DC magnetic fields providing microgravity-like conditions with laminar viscosity and heat transfer to the surroundings.IntroductionSince the early Electro Magnetic (EM) levitation experiments [1] in AC magnetic field it became apparent that the levitated liquid metal is prone to oscillation and instability. The EM and electrostatic levitation experiments with liquid metal droplets show difficulties related to confinement stability and a need for complex correction functions to establish a correlation between the measurements and the droplet material properties [2,3]. Intense internal fluid flow is visually observed, apparently being in the turbulent regime for earthbound conditions."

Jan 1, 2012

By C Gunther

The term metamorphism as commonly used means any change in a rock in either form or composition, from whatever cause. By metasomatism, according to Lindgren, is meant a metamorphism that involves a change in the chemical composition of a rock by the addition or subtraction of substance. Certain types of metamorphism are due to the action of mineralizing solutions, and are closely connected with ore deposition; they form, therefore, valuable guides in the exploration for ore-deposits. Other types of metamorphism are due to regional processes, and are not connected with ore deposition. By dynamo-regional metamorphism is meant a primary alteration of rocks over large areas under conditions of pressure, flow- age, and heat. This process produces schists and gneisses from either sediments or igneous rocks. It is thought that there is little migration of minerals or of elements in dynamo-regional metamorphism, and that the changes are due chiefly to recrysallization and rearrangement of original minerals in bands with their major axes oriented normal to the direction of greatest pressure. Under these conditions limestones are commonly altered to marble, and sandstones to quartzite, basic igneous rocks to greenstone or serpentine, while rocks of normal or acid com- position commonly yield the usual types of schist or gneiss. Dynamo-regional metamorphism, extending over large areas, has no connection with mineralizing processes, and is, therefore, no guide to ore deposits; while this process has certain features, such as characteristic mineral associations, in common with contact metamorphism, the results of the two processes may usually be distinguished without difficulty.

Jan 1, 1932

Economic Significance of High-grade Concentrates BY PAUL M TYLER AND CARLE R HAYWARD (Min & Met, Dec, 563 4000 words) Generally pyro¬mctallurgical methods yield a higher recovery but cost more per ton of ore treated Milling methods are inherently cheaper for the reason that they do not involve dissipa¬tion of heat energy in slag formation, ctc It is vaguely realized that the smelter man could do a better job if he were supplied with purer raw materials but hard¬headed mill men have been offered little inducement to do a really good job of cleaning concentrates To do this may involve some sacrifice in percentage yield and in mill capacity and unless there is a compensating saving in freight and smelter charges, it simply is not good business to go beyond a certain point in the way of making clean concentrate Opportunities exist for eliminating one or more steps in the expensive series of processes for recovering various metals, or at least reducing the volume of materials that has to be handled at the most costly steps The beneficiation of nonmetallic minerals likewise affords numerous examples of over-all economies obtainable through more refined methods of mechanical improvement All this leads to the conclusion that perfecting selective processes for isolating pure minerals (e g, galena) virtually free from other sulfides as well as gangue may be productive of industrial economies Conversely, cheapening smelting methods may invade the field of mechanical improvement of ores but, as Kiphng said, that is another story

Jan 1, 1937

By Robin N. Adair

The Halfmile Lake stratiform volcanogenic massive-sulfide deposit consists of pyrrhotiterich breccia-matrix sulfides and pyrite-pyrrhotite-rich layered sulfides that form a laterally continuous sheet stratigraphically underlain by an extensive pyrrhotite-chalcopyrite-quartz stringer zone. Mineralization is hosted by a sequence of felsic pyroclastics and volcanic-derived, fine-grained metasediments. The proportion of volcanic to sedimentary rocks indicates increasing vent proximity from southwest to northeast across the deposit area. Fine- to medium-grained felsic pyroclastics and roughly equal amounts of fine-grained metasediments comprise the stratigraphic footwall to the mineralization. Quartz-feldspar porphyritic bodies cut this sequence and may have provided the heat source for exhalite activity. Felsic tuffs, locally crystal-rich, and lesser amounts of metasedimentary rocks make up the immediate stratigraphic hanging wall. This sequence is stratigraphically overlain and locally interfmgered with mafic volcanics that contain substantial proportions of felsic fragments. Deposition of sulfides post-dated the beginning of felsic volcanism, which places the deposit in the middle of the Lower Tetagouche Group. Compositions of the volcanic rocks range from basalt to rhyolite and exhibit sub-alkaline affinities. Strongly overprinted whole-rock, trace-element, and REE geochemical signatures resulting from mineralizing hydrothermal activity confirm the genetic relationship between the stringer zone and the mineralized sheet. Large-scale D1 folding has overturned the entire sequence. D1 thrust faults and related sheath-like folds have profoundly affected sulfide distribution. D2 is manifested by a penetrative S2 foliation, and D3 is represented by large-scale open folds.

Jan 1, 1992

By Laurentiu Nastac

"This paper describes the development and validation of a comprehensive multiscale modeling approach capable of predicting at the mesoscopic scale level the ingot solidification structure and solidification-related defects commonly occurring during the vacuum arc remelting (VAR) process. The approach consists of a coupling between a fully transient macroscopic code and a mesoscopic solidification structure code. The predictions from the multiscale model, including grain morphology and size, primary and secondary dendrite arm spacings, Laves and NbC phases, tendency for freckling and columnar-to-equiaxed transition, were validated against experimental measurements for a 20-inch diameter VAR alloy 718 ingots. The validated model was then used to investigate the effects of melting rate and ingot diameter on the solidification structure of VAR processed 718 ingots.IntroductionThe objective of this work was to develop a fully transient multiscale modeling approach to get an insight into the effect of processing parameters on the cast micro- and macro-structure during VAR processing. The developed model assists in achieving better control of the ingot solidification structure and to determine trends in the macrosegregation in these ingots. Another objective of this work was to analyze the transient effects of production rate and ingot size on the resultant ingot microstructures. This objective was met by first understanding the effects of the full range of processing parameters typically used in the VAR process. Processing parameters such as power input and heat extraction rate significantly influence the ingot liquid pool size and shape as well as the ingot structure, which in turn will greatly impacts the final ingot quality."

Jan 1, 2012

By J du Plessis, W Marx

The FutureMine Collaborative Research Initiative has been successfully completed after three years of activity. The main objective of this initiative was to provide applications of research previously undertaken in the DeepMine initiative in terms of realistic solutions to problems facing gold mining operations as they reach for depths beyond 3500 m below surface. The FutureMine initiative was subdivided into four broad streams of technological expertise: rock engineering and seismicity; mining engineering and orebody management; software and communications and ventilation, cooling and refrigeration. This paper presents a summary of research output in this last area of expertise. Broadly, research in mine ventilation, cooling and refrigeration was directed in areas related to the recirculation of air, cyclical use of ventilation and cooling systems, air scrubbing technology, optimisation of chilled water reticulation, obtaining direct cooling at the workface, improving underground refrigeration systems through dry air-cooling and water heat rejection systems and a number of software simulation programs to be used in specific applications and as a tool assisting real-time monitoring of underground environmental conditions.This paper describes in broad terms the outcomes from this section of the research program and proposes ways in which some of these technologies may be combined synergistically in novel systems aimed at maintaining acceptable environmental conditions while reducing the impact on the profitability of operations.

Jan 1, 2005

By Paul C. Miclea, Robert E. Murphy

The behavior of fire and airflows in a confined tunnel differ significantly from more familiar fire situations outside, due to the buoyant effect which tends to create a layer of hot smoke and gases flowing away from the fire near the crown of the tunnel, while air supporting combustion moves toward the fire beneath the smoke layer. A subway emergency ventilation system is designed to force air to flow through the tunnel, shifting the balance of heated air in the direction of the forced flow and avoiding the "back-layering" of hot gases and fumes. This paper presents a computer program, called the "Subway Environment Simulation" (SES), which can be used to predict airflows created by the emergency ventilation system. It utilizes the latest state-of-the-art analytical treatment of fires in enclosed spaces, including observations from mine fires and gas explosions. The program allows designers to reduce construction cost by identifying unnecessary ventilation shafts and by verifying fan capacities. In addition, the program allows the designers and operators to determine safe evacuation routes, in case of a train fire, by predicting the occurrence of back-layering. It can be used to determine when the ventilation system can control the direction of smoke movement to provide a clear and safe path for evacuating people and facilitate fire fighting operations.

Jan 1, 1989

By J. Manchisi

Laboratory investigations were conducted to establish the feasibility of bioleaching a mixed copper oxide/sulphide rougher concentrate from Nchanga Mine on the Zambian Copperbelt. The objective was to determine the kinetics and extent of copper extraction for this material. Batch experiments were conducted under different solution conditions in stirred tank bioreactors. The progress of (bio)leaching was monitored through measurements of soluble ferrous and ferric iron, copper, pH, and redox potentials, while bacterial activity was monitored online through 02 and C02 gas utilization rates. About 20 per cent copper was solubilized within 2 hours in all cases of non-oxidative (abiotic), oxidative (abiotic), and bioleaching experiments. This was attributed to the dissolution of mainly copper oxides. Subsequently, bioleaching experiments resulted in an overall copper extraction of 93 per cent, with up to 8 g.L-1 copper after six leaching days, compared to 58 per cent copper extraction in the abiotic oxidative acid leaching experiments. However, there was little effect of time (i.e. poor dissolution kinetics) on copper recovery for abiotic non-oxidative acid leaching of the material. Hence, the rate of sulphide leaching increased due to the activity of bacteria. Thus, the material is potentially bioleachable under mesophilic conditions. However, more exhaustive test work needs to be conducted to establish the effect of bioleaching variables and heat requirement.

Jan 1, 2012

By Hashimoto H, Arai Y, Sikong L

For utilization of solid carbonaceous materials produced in processes of cracking heavy oil, such as petroleum pitch, as powder fuel, it is necessary to develop a process for fine grinding of these materials. It is known that grinding' additives are effective for fine grinding of cohesive and heat-sensitive materials such as petroleum pitch, therefore in this study, effective methods for fine grinding of petroleum pitch with some grinding additives were investigated. Experiments were carried out by using comminution kinetics based on mass balance. From the results of the investigation by using a batch ball mill, it was found that sodium stearate, calcium stearate and carbon black were effective additives for the improvement of grinding efficiency. Optimum concentration of the grinding additives was also found to give a required particle size of products. Concerning to the action mechanism of these additives, it is considered that the additives which adhired to, or were absorbed on the surface of petroleum pitch particles not only prevented cohesion of the particles but improved dispersion of the particles as well. From the results of the investigation by using a laboratory screen mill which is a representative built-in classifiered impact crusher, carbon black was found to be an effective additive for the improvement of grinding efficiency and mill performance. It is also considered that the improvement of classification efficiency by carbon black affected the mill performance.

Jan 1, 1987

By J. C. Mertz

ACCURATE knowledge of the solid solubilities of the elements that dissolve in the important base metals is needed for guidance in the preparation and heat-treatment of the alloys derived from these compo-nents. While there is still difference of opinion concerning the merits of the X-ray and microscopic methods of determining such solubilities, it is certainly true that the recent extensive use of X-ray diffraction to review the existing constitutional data has revealed many glaring inaccu-racies and has brought about a much improved knowledge of phase-boundary locations, which will inevitably come to include all of the important alloy systems. When the work is done with all necessary precautions it appears that in the majority of cases where the solubilities extend beyond a few tenths of a per cent the X-ray back-reflection technique is capable of furnishing the best of information in this field. For the most prolonged and thorough studies it is obviously advisable to combine the results of several methods, in particular, to obtain an agreement between X-ray and microscopic data. This paper reviews the work previously done on the solubilities of phosphorus, arsenic, antimony and bismuth in copper and, in considera-tion of the uncertainties thus made apparent, presents, new X-ray data obtained with the first three members of this group.

Jan 1, 1936

By Jitka Jandová

In this study, hydrometallurgical processing of waste ZnO flue dust arising during zinc removal from galvanized low-alloy steel sheets was investigated on a laboratory-scale to obtain electrolytic zinc. The flue dust was separated from flue gases, generated during heating waste galvanized steel sheets in an electric furnace under air atmosphere at temperatures of about 1000oC. The dust, comprising tetragonal ZnO and insignificant amounts of SiO2, was contaminated by Fe, Mn, Pb, Al, Mg, Pb, Cu and Ca. The dust was leached in 0.5 and 1.0M H2SO4 and/or in 20 and 30% NaOH at different temperatures and different liquid-to-solid ratios to determine the optimum conditions leading to the highest possible selectivity of leaching and efficiency of Zn extraction in minimum time. The subsequent electrowinning process was performed with refined zinc sulphate leach liquors and/or with untreated zinc caustic solutions. Zinc sulphate leach liquors were purified using a combination of a hydrolytic pH-controlled precipitation, cementation and carbon refining. Effects of operational variables on Zn electrowinning have been studied for both sulphate and caustic electrolytes. The conventional plate-plate electrowinning cell has been explored in this study. Comparison of results obtained for both zinc electrowinning from acid sulphate and alkaline solutions is presented contribution.

Jan 1, 2003

By H. O. Hofman

Lime-roasting is a term proposed by Ingalls' for the operation of forcing air under pressure through a mixture of galena and lime at the kindling-temperature with the object of oxidizing lead and sulphur and of fritting or fusing the charge. If finely-divided galena were treated in this manner without the addition of lime, the heat set free by the oxidation of part of the lead and the sulphur would be sufficiently great to fuse un-decomposed sulphide, and thus stop desulphurization. Besides the chemical action that the addition of lime, limestone or gypsum to the charge may have, the admixture has the physical effect that it keeps the particles of galena separated from one another and accessible to the oxidizing effect of the air. At present, three methods of lime-roasting are carried out on a working-scale,—the Huntington-Heberlein, the Carmichael-Bradford and the Savelsberg2 processes. In the last, which interests us here, an 8-ton charge is made up of galena, limestone and perhaps some siliceous or ferruginous flux; the whole is crushed to pass a screen with 3-mm. holes and moistened with 5 per cent. of water. It is fed gradually into a bowl-shaped converter, 6.56 ft. in diameter, supported by trunnions attached to a truck. On the bottom the converter has a grate with blast-inlet beneath. In starting, the truck with the converter

Jan 1, 1908