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By J Shillabeer

Paste backfill has been adopted by many underground mines in North America and a growing number elsewhere. Paste offers a number of advantages. This paper suggests wider applications of paste technology to surface tailings disposal and water management. Advantages include improved overall stability, potentially easier permitting, smaller water inventory and earlier reclamation. It may be feasible to use the same plant to prepare backfill and to dispose of surplus tailings. Example cost models are given to illustrate potential applications.

Jan 1, 1998

By Sahendra Ram, Arnn Kr Singh, Dheeraj Kumar, Rajendra Singh

"Inherent existence of different rooms (openings) along the extraction line in a depillaring panel provides an easy path for the goaf to encroach the working area. Each of these openings in a mechanized depillaring (MD) operation along the extraction line is supported by the roof bolt-based breaker line support (RBBLS) to restrict the goaf encroachment. Different field studies by Council for Scientific and Industrial Research - Central Institute of Mining and Fuel Research (CSIR-CIMFR) found that the RBBLS works effectively during the depillaring under the shadow of stable surrounding ribs/fenders only. It is observed that, generally, these natural supports experience high value of induced stresses after a large amount of void creation inside the goaf. The induced stress creates spalling/loosening of the sides of the natural supports. Field studies also found that the positions of the RBBLS at the goaf edge need to be adjusted according to the depth of this spalling/ loosening. However, a systematic study in field for the correct positioning of the breaker line as per the spalling/loosening under different site conditions is difficult. Therefore, on the basis of the data and guidance provided by these field investigations, a detailed parametric investigation was conducted in the laboratory on simulated models for an effective design of RBBLS in a MD panel. FLAC3D is used for the simulation of the depillaring, and the available empirical formulations for Indian coalfields are used for subsequent calibration. An analysis of stress redistribution for different stages of the MD in simulated models showed the significance of the nature of overlying strata/induced stress for the RBBLS design. Discussing some results of field studies, this paper presents results of the laboratory investigations for an effective design of the RBBLS.INTRODUCTIONContinuous Miner (CM)-based mechanized depillaring (MD) is an important issue for Indian coalfields, where huge amounts of coal are locked up in standing pillars (Dixit and Mishra, 2010). Considerable variations in site conditions of these developed pillars bring a number of technical challenges into consideration during their final extraction. One of these challenges is goaf encroachment/overriding during caving of the competent roof strata. Goaf encroachment/overriding can effectively be controlled, mainly, by suitable design of natural supports (rib/snook/fender). However, there is a requirement of applied supports against the immediate roof as a considerable portion of this roof is exposed due to the presence of different openings along the line of extraction. These applied supports act as a fulcrum at the goaf edge between the working area and the goaf to facilitate the break out of the hanging roof inside the goaf. This is called breaker line support. An effective breaker line support is important for the efficiency of a depillaring operation. Generally, MD adopts roof bolt-based breaker line support (RBBLS) at the goaf edge (Singh, et al., 2014). For the first time in India, roof bolts were applied at the goaf edge as RBBLS in a CM-based MD (Leeming, 2003). In the beginning, three rows of roof bolts were installed as primary and secondary breaker lines support. On the basis of the observations of instrumented bolts, only two rows of roof bolts were used as secondary RBBLS (Ram, et al., 2014). Now, most of the MD operations in India are using only two rows of bolts as RBBLS (Table 1). However, the strata mechanics studies at different MD operations showed interesting characteristics resulting from this support (Ram, et al., 2015)."

Jan 1, 2016

By Hernando Labarthe

El presente trabajo señala los posibles soluciones a problemas encontrados en el diseño de una planta de beneficio en nuestro país. Para ello, es necesario considerar cuáles son los factores que ocasionarían esta dificultad como el costo de producción, economía de espacio, almacenamiento de minerales, etc.y en el que tanto la ingeniosidad y experiencia del diseñador son relevantes, para que el mejor diseño del proyecto no altere la economía del proyecto en sí mismo.

Jun 20, 1954

By Nadir Ansari, Brian W. Wilson, Marina S. W. Li

"A hybrid Deep Mixing (DM) shoring system was recently constructed for a high-rise development in downtown Vancouver, British Columbia, Canada for the temporary support of a five-level basement excavation. The site is bounded by an existing bridge off-ramp structure along its longest side and by city streets on the other two sides, which formed a truncated triangle in plan. A conventional secant pile wall was installed along the longest side, about 380 ft (116 m) in length, of the site. Hybrid shoring walls (HSW) 1 and 2 were installed along two shorter sides with each being 235 to 246 ft (72 to 75 m) long. HSW 3 completed the excavation support system along the shortest side with a length of about 55 ft (17 m). Cutter soil mixing (CSM) was proposed by the excavation and shoring design-build team in lieu of conventional secant piling. CSM was the preferred method to construct the infill panels between soldier piles because of the speed at which the shoring system could be constructed in the variable fill, peat, wood waste and overburden. Design ConsiderationsTo minimize the impact on buried utilities along the outside perimeter of the excavation, the temporary shoring was designed to limit the lateral displacements to less than 0.8 in (20 mm). Factors taken into consideration for shoring design included the lateral earth pressures from the fill and native soils, groundwater pressures, temporary construction loads (e.g., crane or heavy plant/equipment), and permanent structural requirements. The subsurface conditions at this site typically consisted of fill (cohesive and granular), overlying peat and/or wood waste, overlying clayey silt to sandy silt, overlying weathered to dense to very dense clayey silt till to sandy silt till with silt layers. Localized, perched groundwater was observed within the fill, peat, wood waste and sandy silt layers above the dense till."

Jan 1, 2017

By Walter I. Nelson

THE geology of the Copper Mountain mine has been ably described by Dr. Victor Dolmage in Memoir 171 of the Geological Survey. Reference is invited to that paper for a more extended description of the geology of the ore deposits than will be given here. The important orebodies of the mine occur in fragmencal volcanic rocks, parallel with and adjacent to the gabbro of the Copper Mountain stock. In the mine area, the contact strikes N.45°W. and dips either vertical or steeply co the southwest. For a distance of 500 feet or more from the contact, the fragmental rocks have been intensely metamorphosed both dynamically and hydrothermally. The dynamic effects are reflected in the foliation and fracturing parallel with the contact, which occurs throughout the mine, and the volcanic rocks within this foliated zone are, in places, highly schistose. Superimposed upon thi.s structure is a system of fine, straight, parallel frac-tures that strike nearly normal to the foliation (and contact) and dip between 65° and 75° to the north; it is with this last-described fracture system that the ore minerals are structurally associated. The fractures are mineralized with bornite and, to a considerably less extent, with chalcopyrite and some pyrite. A notable characteristic is the extreme fineness of the fractures; even in high-grade ore they are rarely larger than pencil lines. The tenor of the ore, therefore, varies directly with the fracture spacing. Replacemcnr of the host-rock between two or more fractures, varying in degree from finely disseminated sulphides to masses of nearly solid bornite up to 18 inches wide and 2 to 3 feet long, is not uncommon in the higher-grade portions of the orebodies. Two structural types of orebody are recognized in local nomenclature: the 'contact' orebodies, so-called because they occur along the contact; and 'outlying' orebodics, which are enclosed in the volcanics. The former arc tabular or lenticular bodies elongated along the strike and dip of the contact. The 'outlying' orebodies are coniform, chimney-like masses roughly elliptical in plan; with depth, their roots plunge at steep angles toward the contact. All of the orebodies are cut by a number of light-coloured granophyre and felsite porphyry dykes. These dykes-the so-called 'mine' dykes -enter the mine area from the north, curve gently southeasterly across the orebodies, and then cross the contact into the gabbro at the south end of the mine. All the dykes dip vertical to steeply east.

Jan 1, 1941

By Sevket Acar, Tim Acton

"Zarafshan/Newmont is a 50/25/25 joint venture between Newmont Gold and the State Committee for Geology and Mineral Resources, and Navoi Mining and Metallurgical Combinat, two entities of the Republic of Uzbekistan. The Zarafshan/Newmont joint venture consists of a heap leaching operation which will process 220 million metric tonnes of existing low-grade oxide ore stockpiles (averaging 0.036 oz Au/t) from the Muruntau mine. Net recovery over the 17-year life of the project is expected to be 4.8 million ounces of gold.The plant construction started in October 1993 and operations commenced on May 25, 1995. The crushing plant consists of four stages of crushing and screening to produce a 95% passing 3.35 mm product, followed by heap leaching and gold recovery by the Merrill-Crowe process. The dore metal is refined at the Muruntau refinery. All gold produced by the joint venture is sold on the world market. IntroductionThe Muruntau mine and nearby town of Zarafshan are located in the center of the Kyzylkum desert, 250 miles west of Tashkent, capital of Uzbekistan. Following a mining conference in Moscow in 1990, a Newmont geologist was among the first team of westerners to visit the Muruntau Mine, the second largest gold producer in the former Soviet Union. At Muruntau, they found 220 million tonnes of low grade gold ore that had been stockpiled during the previous 25 years. In February, 1992, six months after Uzbekistan's independence, Newmont signed a 50/50 joint venture agreement with the Uzbek government to use heap leach technology to process the ore. The feasibility study was completed in November of 1992. Plant construction started in October, 1993 and operations commenced on May 25, 1995.Newmont Metallurgical Services performed metallurgical studies to obtain heap leach process design criteria parameters. The initial metallurgical study on 20 grab samples is the subject of this paper."

Jan 1, 1997

By I R. F MacCulloch, K Jones

Pintail Systems, Inc, a Colorado USA based company has developed and commercially applied bioremediation processes for biological detoxification of cyanide compounds in mine waste. Site-specific microorganisms are isolated from spent ore, tailings or process solutions and augmented in the laboratory for cyanide oxidation, denitrification and metal biomineralisation. Biological processes typically treat complex contaminants (cyanide compounds, soluble metals and nitrates) in a fraction of the time of conventional remediation processes. Cyanide is used in microbial metabolic processes as a carbon or a nitrogen source. Biological detoxification processes applied at the end of mine life can end long-term liability and perpetual monitoring and containment. Case studies from commercial application and demonstration programs for the US Environmental Protection Agency will be presented in this paper.

Jan 1, 2004

By A Tawadrous, B Wheeler, D S. Preece, S A. Silling

The two key results of rock blasting are fragmentation and movement of geomaterials. Movement/flow of the blasted rock is often referred to as heave. Moving rock with explosives rather than mechanical equipment can improve mining efficiency. Such is the case with coalmine cast blasting. Controlling and directing rock movement through explosive deck delay timing can greatly improve ore recovery by segregating ore and waste. In both cases, understanding, predicting and controlling heave is an important element of successful blasting.Computer programs for predicting 2D blasting-induced heave have been used in mining for decades, helping to drive the innovation of new and more efficient mining methods, ie cast blasting. The past few years have seen the advent of 3D distinct element modelling of blast-induced heave. This is an important advancement because most blasting situations are three-dimensional in nature, especially when controlling the direction and intensity of rock movement through explosive deck delay timing.This paper documents the first full-scale blasting simulations in 3D with distinct element models that include hundreds of blastholes and in excess of a million particles, made possible with parallel processing. Surface mineral blasting is the focus of this study which treats the effect of blasthole delay timing on ore recovery. Ore waste and dilution resulting from typical row-on-row delay timing will be demonstrated. Also demonstrated will be the ore recovery possible with delay timing designs that significantly enhance ore/waste segregation. This type of high fidelity modelling and the use of electronic detonators makes possible the sculpting of rock blasting muck into separate piles of ore and waste.CITATION:Preece, D S, Tawadrous, A, Silling, S A and Wheeler, B, 2015. Modelling full-scale blast heave with three-dimensional distinct elements and parallel processing, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 127–136 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Smuts. E. M.

This paper describes a methodology used to develop a numerical model for the study of particulate suspension rheology. Initially, Computational Fluid Dynamics (CFD) models of different rheometer geometries were tested with both a Newtonian fluid (water), and a non-Newtonian Herschel-Bulkley slurry. Rheograms were reproduced from these models and compared to experimental values. Once a single-phase model had been validated, a coupled model combining CFD and the Discrete Element Method (DEM) was created. Two open source software packages were chosen. CFD is implemented using Open FOAM®, and DEM using LIGGGHTS. These two different codes were coupled via another program called CFDEM. This coupled model is currently capable of modeling spherical particles in a suspending liquid. DLVO forces have been included in some models to account for inter-particle forces due to the surface charge on the particles. The coupled model is currently being validated. Preliminary results show good qualitative behavior of the model. Keywords: rheology, cfd, dem, suspensions, modeling

Sep 1, 2012

By D. W. Alexander

Researchers from the U.S. Office of Mine Safety and Health Research (OMSHR) of the U.S. National Institute for Occupational Safety and Health (NIOSH) completed field trials during coal mine rescue contests using simulated gas detectors in place of placards. The gas monitor simulator (GMS) devices replaced static, paper placards to deliver gas concentration data. Eleven teams were observed during the field contest, which was approved by the Mine Safety and Health Administration (MSHA). GMS devices were given to three team members (the captain and both gasmen). Observation of teams revealed that team members changed behavior by acknowledging and sharing information more often while using the GMS. As a result of this research, it has been demonstrated that under the existing contest format, the newly developed GMS device may be used with no adverse impact on team contest performance. Furthermore, when GMS technology advantages are used, contest realism is improved. In the future, competency assessment may be incorporated.

Jan 1, 2012

By Olivia Perkins, Shawn Sismondi, Adrian St. John, Vicky Potts

"INTRODUCTION An inherent aspect of any tunnelling project is ground risk: how it is identified, quantified and managed throughout the various stages of a project. Early identification of these risks, such as adverse ground conditions or potential obstructions is crucial; however specific identification of all risks will inevitably be limited by the extent of the desk study, ground investigation and accuracy of as-built information available, particularly in a densely populated urban environment such as London with a long and varied history of development. It is therefore crucial to have suitable plans and procedures in place for dealing with potential ground risk scenarios if they occur during construction work to ensure the safety of the workforce and to protect nearby critical assets. A number of experiences of potential ground risk were encountered during the Sprayed Concrete Lining (SCL) works on Crossrail contract C300/410 which was constructed by a joint venture of BAM Ferrovial Kier (BFK). The C300/410 works, undertaken in the heart of London, comprised of over 2.5km of SCL tunnels for Bond Street and Tottenham Court Road Stations and the Fisher Street crossover, as well as two 6.2km TBM tunnel drives between Royal Oak and Farringdon. BFK appointed Donaldson Associates as their SCL designers for the works; together they were responsible for excavation stability up to the point of ring closure. Despite the majority of SCL tunnelling works at Bond Street and Tottenham Court Road being through the favourable medium of London clay, there remained areas of local geotechnical challenges. Some of these were expected from the outset, some became apparent as works progressed from records of other nearby excavation works, and some were only encountered during tunnel excavation. Being located in the centre of London meant that there always remained a possibility of meeting some form of obstruction from previous structures. However, identification of all potential issues prior to the commencement of the works was challenging and proved to not be entirely possible. Through a series of case studies, this paper documents incidents where obstructions or adverse ground conditions arose. These scenarios all had the potential to cause safety risks, impact the tunnel design and/or construction methods and ultimately add time and cost to the works. The paper discusses how these challenges were overcome which utilised in part, a progressive risk reduction cycle, feeding back knowledge gained at all stages of construction into the approach for undertaking the works. It also examines what could be done in future to further reduce the ground risk through early identification, communication, education and appropriate contingency measures."

Jan 1, 2016

By Andrew Lewis, Amarit Nitaramorn, Alexander Garcia, Peter Altounyan

"Indonesia is a major coal producer, the vast majority being sourced from opencast operations. Underground production to date has been constrained by unfavorable ground conditions and limited local experience. However, an underground trial in East Kalimantan has now shown that it is possible to successfully extract coal and mine safely, despite the technical challenges.A trial drift mine has been worked to a current maximum depth of 160 m (525 ft) in a dipping coal seam. The 3 m (10 ft) thick coal seam is overlain by very weak mudstone and sandstones. The mudstone forming the immediate seam roof strata proved a particular challenge given its adverse reaction to water and overall friability.Rock bolts were used as roadway support, the system being carefully selected to optimize effectiveness. An innovative method of partial extraction was trialed, which demonstrated the potential for productive mining despite the ground conditions. Roof falls have occurred within the working area, and roadways demonstrate reasonable stability over time.Throughout the course of the trial, strata behavior monitoring has been an important aspect, and a comprehensive ground control monitoring system is in place. This has enhanced the ability to increase the level of support where required and to react to deteriorating conditions. In addition, monitoring information has allowed a quantitative assessment to be made of the technical feasibility of future full-scale mining.INTRODUCTIONWith current production at over 200 million tons, much of this destined for overseas markets, Indonesia is the second largest exporter of coal (Ritschel and Schiffer, 2007). The majority of the coal is sourced from the Kalimantan coalfields. Mining is predominately opencast, yet in recent years there have been attempts made to introduce underground operations. This move would permit continued access to good quality seams that are beyond the reach of viable opencast mining."

Jan 1, 2010

By M. J. Reasor, J. M. Antonini, L. Wu, K. Van Dyke, Z. Ye

The inhalation of silica has been shown to produce a dramatic inflammatory and toxic response within the lungs of humans and· laboratory animals. Currently, no effective treatment exists for workers who may have been exposed to the inhalation of silica. The objective of this study was to develop an animal model in which we could evaluate the effect that anti-inflammatory steroids have on the acute silica-induced pulmonary inflammatory response. Male Fischer 344 rats were pretreated with either dexamethasone (2 mg/kg) or saline vehicle (i.p.) on days 1, 3, and 5. On day 6, the animals from the two groups were then intratracheally instilled with either silica (20 mg/0.5 ml saline vehicle) or saline vehicle (0.5 ml). Twenty-four hours after the instillations in the non-steroid group, significant increases occurred in total protein, total number of cells, neutrophils, and lymphocytes recovered from the lungs of animals treated with silica compared to saline controls. Silica also caused dramatic increases in the luminol-dependent chemiluminescence (LDCL) of lung tissue and bronchoalveolar lavage (BAL) cells. The LDCL reaction was markedly decreased by either superoxide dismutase (SOD) or N-nitro-L-arginine methyl ester hydrochloride (L-NAME). SOD is involved in the enzymatic breakdown of superoxide anion, while L-NAME, a nitric oxide (NO) synthase inhibitor, prevents the formation of NO. When the superoxide anion and NO react, they form the highly oxidizing substance peroxynitrite. This study then implicates peroxynitrite as an agent which may be involved in the silica-induced oxidant lung injury. When the animals were pretreated with the steroid dexamethasone, there was a complete protection against the biochemical, cellular, and chemiluminescent indices of damage caused by silica. The mechanism in which the steroid protects the lung from damage may be due to the ability of dexamethasone to block the induction of NO synthase. With further study in animals, the anti-inflammatory steroids may be useful in the treatment of silicainduced lung injury.

Dec 1, 1995

By T. J. Otto, C. Musingwini

"The objective of any mining company is to sustainably maximize the net present value (NPV) throughout the life-of-mine (LOM). The expected NPV over the LOM is calculated based on a mine plan, yet the actual value realized by the mining company depends greatly on the level of intertemporal execution against the mine plan. Consequently, a major key performance indicator (KPI) that is often overlooked in open pit mining, due to a greater focus on temporal KPIs, is the degree of spatial compliance to the mine plan. Such focus sometimes leads to short-term actions being detrimental to long-term plans. In this paper we describe the development and implementation of a spatial mine-to-plan compliance reconciliation approach for an open pit mine. Application to a case study open pit iron ore mine in South Africa indicated a significant improvement in the spatial mine-to-plan compliance, from 69% to 94% over a three-year period from 2014 to 2016. These results indicate that implementation of the proposed spatial mine-to-plan compliance reconciliation approach can contribute positively to improving the level of spatial execution and assists in improving the alignment between short-term, medium-term, and LOM plans.IntroductionThe objective of any mining company is to maximize the net present value (NPV) throughout the life of mine (LOM). However, this objective needs to be fulfilled in a sustainable manner that considers the needs of various stakeholders, including employees, shareholders, and local communities where the mines operate. The expected NPV is calculated using a mine plan as a basis. Mine planning broadly involves identifying a strategy to exploit the mineral resource in a way that maximizes value at an acceptable level of risk throughout the LOM (Tholana and Neingo, 2016).The mine planning process is a well-recognized component in the mining value chain of an open pit mine. Figure 1 reflects the relative position of mine planning within a typical open-pit mining value chain from the mineral resource to the market"

Mar 1, 2019

By James G. Ulinski, Sebastian Lobo-Guerrero, Vishal B. Patel

"Recently modified design equations used in the transportation industry to calculate side friction and end bearing capacity for drilled shafts are now providing more realistic estimations of capacities than did previous methods. Using multiple case studies and test results from various projects, a more realistic design approach was formulated by the Federal Highway Administration (FHWA), which resulted in greater values of ultimate capacity for side friction and end bearing and in a more efficient design overall.In 2010, the FHWA published GEC-10 – Drilled Shafts: Construction Procedures and LRFD Design Methods, which illustrates a different method of calculating side friction and end bearing resistance and results in greater values for design. In 2014, the Association of State Highway and Transportation Officials (AASHTO) adopted the method put forth by FHWA, which was included in its LRFD Bridge Design th Specifications, 7 Edition. The Pennsylvania Department of Transportation (PennDOT) recently adopted and incorporated the similar methodology as AASHTO for calculating side friction and end bearing for drilled shafts in rock, and these changes are reflected in the 2015 edition of the PennDOT Design Manual, Part 4 (DM-4). This article discusses the past and current design methodology along with a project case study with results from Osterberg Cell (O-cell) load testing, which presents a comparison between the design resistances of ultimate side friction and end bearing and the measured capacities at failure.The Old and the NewEditions of the AASHTO LRFD Bridge Design Manual from 2012 and earlier estimated ultimate side resistance, qs, in rock using the following equation (modified from Horvath and Kenney, 1979):qs=0.65aEpa(qu/pa)0.5 < 7.8pa(f ’c/pa)0.5 where: qu is the uniaxial compressive strength of the rock in ksf; pa is the atmospheric pressure in ksf; aE is the reduction factor to account for jointing in rock; and f ’c is the compressive strength of the concrete in ksi. For intact rock, previous versions of the AASHTO manual required that the ultimate end bearing resistance, qp, was calculated using the following equation: qp=2.5qu."

Jan 1, 2017

By Kenneth L. Nash

The control of solubility of waste actinide ions, by conversion to highly insoluble mineral phases has been demonstrated in the laboratory. Actinide metal ions are removed from neutral pH solutions by a combined ion exchange-decomposition-mineralization process based on the application of the naturally-occurring hydrolytically unstable.polyphosphate organic compound phytic acid.

Jan 1, 1999

By J. H. Kim

Since the Hardy Cross numerical algorithm was applied to the solution of mine ventilation networks, there have been numerous developments in ventilation network analysis procedures. The Newton-Raphson method, the linear theory method, and the second-order approximation method are three of the additional approaches that have been applied. The efficiency of a ventilation network analysis procedure depends not only on the method of solving the system of equations derived from ventilation networks, but also on the method of deriving the equations through selection of the meshes. This paper investigates the impacts of three mesh selection methods on the efficiencies of four ventilation network procedures. The minimum-resistance spanning tree method is the most popular procedure for selecting meshes. The shortest-path method was suggested by Epp and Fowler (1970) for improvement of the Newton-Raphson method. The minimum-resistance-path method is suggested here as the third method of selecting meshes. The effects of these three methods on the Hardy Cross method, the Newton-Raphson method, the linear theory method, and the second-order approximation method are analyzed in this paper. These network analysis methods have been summarized in the paper by Kim and Mutmansky (1991).

Jan 1, 1992

By S. B. Castor

Although production generally satisfies demand for rare earths, new markets may make undeveloped resources, particularly those rich in yttrium, more interesting. A Precambrian carbonalite orebody at Mountain Pass, California, has been the world&apos;s largest rare earth producer. Minor rare earth production comes from titanium placer mining in Florida and uranium mining in Canada. Prior to operations at Mountain Pass, North American production was mostly from placer deposits that constitute large, low-grade rare earth resources. Newly discovered North American rare metal resources in peralkaline igneous rocks are potential yttrium producers. Most of these resources are in a continent-wide belt of anorogenic magmatic rocks approximately coeval with mineralization at Mountain Pass. Other untapped rare each resources in North America are generally light rare earth-dominated and small or of low grade.

Jan 1, 1991

By R. A., Pallanch

THOUGH the flotation of gold ores has come into the lime- light largely in recent years, it is not a product of recent economic conditions but rather as old as flotation itself. It could hardly be other- wise, since gold, when in the right state of comminution and surface condition, is one of the more readily floated of minerals. In early practice it was not generally recognized that gold was floated as well; it was - thought that the gold was bound up with sulphide minerals that floated, but now we know that free gold must have been floated as well.

Jan 1, 1935

By R. Schuhmann

The thermodynamic data and calculations which underlie the design of the Q-S process for coppermaking are summarized. The efficient production of crude copper and slag of low copper content in a single con¬tinuous converter requires the establishment and control of gradients in oxygen activity and other physico-chemical variables throughout the reactor. These gradients are established by stagewise introduction of oxygen and solid feed materials to provide: (a) flash oxidation of sulfides above the bath, utilizing the great bulk of the oxygen, (b) conversion of high grade matte or white metal to crude copper by bottom blowing with restricted bath turbulence, (c) close approach to equilibrium staging of converting and deconverting reactions along the length of the slag layer, from a maximum oxygen activity near the metal discharge end to a minimum at the slag discharge end, and (d) completion of slag cleansing by deconverting. In terms of the Phase Rule, the Q-S process involves a system with a minimum of 5 components (Cu, Fe, S, O, and SiO2) and several liquid, solid, and gaseous phases. Accordingly, basic data from previously reported studies on simpler systems are utilized to prepare an equilibrium diagram for the 5-component system and to generate a quantitative thermodynamic model for the Q-S process. This model shows in particular the ranges of oxygen activities (measured by equivalent CO2/CO ratios) involved in the Q-S process and the relations of oxygen activity to temperature and other important physico-chemical variables of coppermaking.

Jan 1, 1976