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By A. E. Dyment

In formulating an explosive for any specific set of conditions, various factors must be taken into consideration. Is it to be subjected to water or moisture? .If so, it must be designed to have an inherent ability to resist water. Is it to be used in confined spaces underground, where ventilation is limited? If it is, it must possess qualities enabling it to form, upon explosion, the minimum quantity of noxious gases, such as carbon monoxide or oxides of nitrogen. Is it for use where low temperatures may possibly prevail? If so, it must be capable of resisting such temperatures without freezing. Is it for use where dust or inflammable gases may be present? If it is, then it must be so formulated as to produce, upon detonation, a flame of the lowest possible temperature and the shortest possible duration, in order to lessen the chance of ignition of such gas or dust. This is actually the essential property of a permitted explosive, and it is undoubtedly the most important characteristic of an explosive which is to be used in gassy or closed-light mines. This being the quality that distinguishes permitted explosives from other types, it is interesting to investigate the ways and means by which the low-flame-temperature characteristic is obtained . Generally speaking, such explosives are so designed as to contain comparatively small quantities of nitroglycerin and relatively large quantities of the strength-producing salt, ammonium nitrate. This ingredient does not develop as high a temperature upon explosion as does nitroglycerin, so its presence, in large measure, in place of nitroglycerin results in an explosive which has an inherent low-flame-temperature characteristic, as opposed to one which is .made up largely of nitroglycerin, which would ordinarily be in the high-flame-temperature class. Additions are also made of flame-quenching salts such as sodium chloride, ammonium chloride, and up to a certain limiting percentage of sodium nitrate. These salts, with the exception of the last, do not ordinarily take an active part in the explosive reaction, being present primarily to absorb heat liberated by the reacting ingredients.

Jan 1, 1947

This paper examines the feasibility of combining network modeling and computational fluid dynamics for modeling of underground mine ventilation systems. Both simulation methods have specific advantages and disadvantages for analysis of mine systems. Network modeling is widely utilized by many operations and allows for assessment of current systems and simulation for planning purposes. Alternatively, CFD has been utilized only marginally by operations and is typically a research tool, requiring considerable computational power, complex models, and careful analysis and calibration of results. Network modeling allows for a holistic approach to the ventilation system, giving quantity, velocity and pressure in every branch, but CFD modeling can resolve the flow regime in 2-D or 3-D, which is idea when examination of an area on a more detailed basis is useful, such as dust and gas control. Integration of the two can allow for more flexible systems analysis. The feasibility of integration, along with application to limited underground mine data are examined.

Feb 23, 2014

By A. Lackner

Using the CFD software package FIRE, the smelting process inside a cyclone reactor is modelled. The fluid flow is calculated 3 dim., using different turbulence models. The effects of design parameters (length and diameter of the cyclone, concentrate feeding tangentially or from the top,..) and operating conditions are investigated. Single particle traces illustrate how to increase particle retention time before the particles reach the liquid film flowing down the cyclone wall. Moreover a two phase flow approach is developed, based on the "Discrete Droplet Model". The position, velocity, diameter and temperature of each reacting particle is described. The results show the advantages of top concentrate feeding, large height/width ratio of the tuyeres and increasing number of tangentially gas inlets.

Jan 1, 1995

By D. H. H. Quon

Results of a study conducted to determine the properties of iron ore pellets made from Mount Wright and Carol Lake ore concentrate fines with partial and full substitution of bentonite by several organic binders are presented. Carboxy methyl celluloses 7H and 6TL, hydroxy ethyl cellulose (natrosol) and modified guar gum all produce pellets of acceptable wet, green and dry strength. However, when fully substituted, an inorganic binder such as calcium carbonate is required for satisfactory strength development after induration. Mixing the Carol Lake ore with Mount Wright ore in a 50-50 ratio also achieves the same result. The failure of the Carol Lake ore in the pelletization process is attributed to the low hematite content of the ore. The results are very similar to those from the extrusion studies reported earlier (8).

Jan 1, 1989

By Rogério Felício dos Santos

Nitriding of metallic materials using electric discharges generated during electric discharge machining (EDM) is a recently developed technique. The aim of this paper was to correlate mechanical properties of a nitrided layer produced in AISI 4140 steel by EDM nitriding with the type and amount of nitrides. A conventional die-sinking EDM equipment and electrolytic copper electrodes were used to generate the electric discharges. The electrolyte was a solution of urea in deionized water. Knoop microhardness profiles assessed the variation of hardness along the nitrided layer, whereas the elastic modulus of this layer was measured using nanoindentation tests. Optical microscopy and X-ray diffraction (XRD) were used to characterize the nitrided surface. The results showed the formation of a nitrided layer containing iron nitrides with average thickness of around 25 µm. The amount of nitrides reduced from the surface towards the centre and these results correlated well with microhardness profiles obtained.

Jul 31, 2018

By John Loop, W. A. Gibbins, Donald D. Hogarth

"Introduction Background The Frobisher voyages of 1577 and 1578 were organized by the Cathay Company for the express purpose of finding and mining gold ore. Since publication of the Baffm expedition of Charles Francis Hallill, the location of Kodlunarn or Countess of Warwick Island, the headquarters of Frobisher's third (1578) voyage, and focal point of the largest Arctic voyage of all time, has been known to the world. Through Hall we also know the location of the Countess of Warwick Mine on Kodlunarn Island. However, the exact locations of the other mines are not known. Of the ""ore"" we know little. Pieces of the original ""black stone"", once as large as ""a half-penny loaf' have now disappeared altogether. Specimens collected at random from the repository of shipments in England and from loose rock on Kodlunarn Island were termed, respectively, ""hornblende pyroxenite"" and ""amphibolite"" and from a locale about 200 yards from Kodlunarn as (hornblende) ""pyroxenite""121. However, it is uncertain whether these specimens are representative of Kodlunarn or of the other mines, although Blackadar131 notes that, in the northern trench of Kodlunarn, biotite gneiss contains lenses and bands of amphibolite. The ""gold"" itself is even less well defined. It has long been accepted that gold was virtually absent in Frobisher's ore. The ""gold"" has been termed pyrite, biotite and both biotite and pyrite together. Even t h e word "" marquesset"" , which appears and reappears in contemporary descriptions, is nebulous and is defined as ""a stone participating in the nature of some metal, yet in so small quantity, that the metal cannot be melted from it"" (0.E.D., definition of 1616)."

Jan 1, 1999

By Larry H. Heflin

The Washington Metropolitan Area Transit Authority's Wheaton Station and tunnel design was completed and offered for bid in the Spring of 1983. The format was unique to the Authority: a four part, four fiscal year contract developed in response to funding limitations with construction divided into four stages allowing the maximum amount of work to be done each year for the funds available. The bid was based on the entire contract, but was orginally awarded for only the first year's work. Each year's work had a maximum funding limitation thus safe guarding the Authority from a grossly unbalanced bid. The Authority's estimate for this work was $83,871,524. The low bid came in at 61% of this for a total low bid of $51,512,058. The low bidder was ILBAU America Corporation whose home offices are in Austria. Following receipt of the bids (and resolution of objections cited by other bidders who felt that the job could not be done for the $51 Million dollar figure), a Notice-To-Proceed was given on October 5, 1983. The construction contract allows a Value Engineering Change Proposal, called a VECP which is initiated and developed by the contractor to change the drawings, specifications or other requirements of the contract. Among other things the VECP should decrease the contract price while maintaining the service life, reliability, ease of maintenance, and standardized features and appearance and not require an unacceptable extension of the contract time. A VECP must estimate the amount of the net savings

Jan 1, 1985

"An unparalleled growth in the Canadian coal industry in 1970 coincided with increasing awareness by Canadians of their environment and their geography with its accompanying transportation factors. R and D on coal moved with greater emphasis toward solving problems in these areas as well as continuing with strong interest in coal preparation, carbonization, combustion, ""weathering'', spontaneous ignition, storage, exploration and geology. Long-range ""basic"" research was not forgotten in that work continued on coal-based carbons, coal chemistry and agrobiological uses for coal. This paper reviews the status of these many areas of coal research at the beginning of the seventies and takes note of some of the more significant legislation and projects brought to the author's attention. No attempt is made to itemize or to describe in detail all the worthwhile projects, many of which are reported elsewhere."

Jan 1, 1971

Jan 1, 1994

By Alvin Schallis

The. problem of supplying enough magnesia for the American war effort has become highly important. Before hostilities began, only about two-thirds of our, require vents came from domestic sources; now they must supply almost all the magnesia we need. A further burden is placed upon our own supply by the fact that more and more magnesia is being required, not alone to pace the war tempo of general industrial activity, but also to replace chrome ore in refractories and to make magnesium metal. The domestic magnesite and brucite industry is equipping itself to satisfy much of this greater demand for magnesia, but the remainder must be obtained elsewhere. The principal sources of magnesia are magnesite, brucite, dolomite or high-magnesium limestone, natural brines, sea water, salt-works bitterns, magnesium silicates, and magnesium salts. Although dolomite is tae subject of this paper, it should be considered in perspective with all these highly competitive sources of magnesia.

Jan 1, 1943

By C. M. Diaz

The chemistry of the main unit processes in nickel extractive pyrometallurgy is reviewed. Key re1a ions between smelter feed composition and process selection are discussed, with particular reference to operating conditions, energy requirements and products. The paper a1 so includes a brief discussion of current nickel smelters, based on the results of a recent survey carried out by TMS.

Jan 1, 1988

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grind-ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4 issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor; if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1965

By W J. Rankin, D R. Swinbourne

There are large tonnages of low-grade manganese ores in India fromwhich it is uneconomic to produce ferroalloys by conventionalsubmerged arc furnace smelting. A possible way to utilise these ores is to smelt them with carbon to produce pig iron and a manganese-rich slag, then to metallothermically reduce the molten slag to silicomanganese. Thermodynamic modelling of the metallothermic reduction stage using aluminium, silicon or aluminium-silicon alloy as the reductant at 1450¦C showed that an acceptable grade of silicomanganese could be produced. Manganese recoveries were predicted to be about 80 per cent. Heat balances indicated that silicothermic reduction may not produce enough heat to maintain reaction temperature. Small-scale laboratory experiments showed that the manganese grade of the alloys, and the manganese recoveries, were close to those predicted, but those for silicon were muchlower. Aluminothermic reduction produced the highest grade manganesealloy. The slag-metal equilibrium involving manganese, silicon and their oxides was investigated and it was found that equilibrium was not attained in any of the experiments, due probably to the very low rate of reactions involving silicon. This could be used to advantage in practice to achieve higher manganese levels in the alloys.

Jan 1, 1998

By Galen H. Clevenger

THE real and permanent advances which take place in any industry are for the most part slow evolutions which frequently develop and grow almost imperceptibly from clay to clay. A meritorious idea may and generally does require long and patient development and commercial application under a variety of conditions and in a number of localities before it emerges as standard and generally accepted practice. There must be not only technical perfection but also economic advantage. Thus a cross-section taken at any particular time of an industry may reveal little that is distinctly new and yet there may have been considerable progress. During the past year there has been little that is new in milling and yet there has been real progress; some problems have been solved and some of what we may term the newer developments have become more firmly, established.

Jan 1, 1930

By N. H. Grace

"IntroductionDURING the past half century, the economy of Western Canada was largely centred on agriculture. However, the impact of World War II has led to an acceleration in the development of a variety of natural resources so that, today, Western Canada is experiencing great industrial development. Consequently, the availability •of low-cost energy assumes prime importance. In the final analysis, industrial growth and expansion are intimately linked to the energy resources.Coal ReservesHas Western Canada adequate coal reserves to meet the present accelerating demand for power in the days that lie ahead? This question must be answered before detailed consideration can be given to the probable patterns •by which various energy sources in Western Canada may be expected to meet the expanding demand. Figure 1 indicates the extent and distribution of the Canadian coal reserves, the data having been prepared by Dr. B. R. MacKay for the Royal Commission on Coal in 1946 (1). The amount of readily recoverable coal is listed as one-half the quantities shown on the chart. It is interesting-to note that upwards of 90 per cent •of the Canadian coal reserves .are located in the three most westerly Canadian provinces. It has been estimated that the coal reserves, at the present rate of mining, would be adequate for about 3,000 years. Consequently, it may be concluded that the coal •reserves in Western Canada •are indeed adequate to meet tremendous energy demands for many centuries. When the oil and natural gas have been exhausted, the great coal reserves will still be available."

Jan 1, 1953

By D. C. Buffum, L. D. Jaffee

QUANTITATIVE measurements of the temper brittleness of steel are made by comparing the difference between embrittled and unembrittled specimens in the temperature of transition from ductile to brittle fracture. Since hardness affects the transition temperature, a study of the combined effects of hardness and temper brittleness appeared desirable. In this investigation a commercial SAE 3140 steel, which has been reported on previously in temper brittleness studies,* was used. Blanks from this steel were austenitized for 1 hr at 900°C and water quenched. The blanks were then divided into six groups and further heat treated as follows: Group 1—tempered at 675°C for 4 hr and water quenched; Groups 2, 3, 4, and 5—tempered at 675", 650°, 625', and 600 °C respectively for 1 hr and water quenched; and Group 6—tempered at 500°C for y2 hr and water quenched. Each of these groups was divided into two parts; one part was tested without further heat treatment, and the other was embrittled for 48 hr at 500°C and water quenched. Tempering treatments between 500" and 600°C were avoided because of the rapid embrittlement occurring in that range for this steel. The heat-treated blanks were machined into standard V-notched Charpy bars. Each group was tested over a range of temperatures on a 217 ft-lb Charpy machine. The energies necessary to fracture the bars and the percentage fibrous fracture of each bar were recorded. The transition temperatures were obtained from a plot of the percentage fibrous fracture as a function of testing temperature. They were taken as the lowest point on these curves at which the fracture was 100 pct fibrous. The transition temperatures for both embrittled and unembrittled specimens are presented in Fig. 1 as function of the hardness. It will be noticed in this figure that the point for the unembrittled condition at 21 Rockwell C is out of line. These specimens were tempered for 4 hr at 675 °C and this point indicated that under isothermal conditions at this temperature, as is well known, embrittlement may develop fast enough to more than offset the effects of softening. From this data, it was concluded that the difference between transition temperatures for the embrittled and unembrittled conditions at any given hardness, within the range of Rockwell C 24 % to 32lh, is constant. It is also concluded that, within the hardness range studied, the transition temperatures for embrittled and unembrittled specimens rise in a parallel fashion with an increase in hardness. The authors wish to acknowledge the assistance of Frank Carr in this work.

Jan 1, 1952

Al2O3,-WC Composite powder for cutting tools was synthesized by self-propagating high-temperature synthesis using A1 powder as a reducing agent. WC, W2C and Al2O3 were concurrently formed in WO3Al-C system. It was found that the complete reaction was achieved with excessive addition of carbon and appropriate processing parameters such as degree of dilution, particle size of aluminum, compaction pressures of green pellets and carbon source. The final product which was leached by 50% HN03+HF diluted solution was consisted of Al2O3-55wt% WC having 2-3um of mean particle size.

Jan 1, 1999

By Carl F. Cline, Richard R. Vandervoort, Willis L. Barmore

THE objective of this investigation was to determine the high-temperature plastic deformation behavior of stoichiometric uranium mononitride as a function of stress and temperature. Interest in the properties of this material stems from its potential use in high-temperature nuclear reactor systems. The creep of other refractory compounds containing uranium (e.g., U02, UC) has been studied by various investigators.1"4 Fassler et al.4 have studied the creep of UN in vacuum from 1100° to 1350°C at stresses of 6000 and 8000 psi. In the present work, the creep of stoichiometric UN was investigated from 1500° to 1800°C at stresses from 2000 to 5000 psi in a partial pressure of 200 mm of nitrogen. The specimens were prepared by hot isostatic pressing of UN powder into cylinders of $ in. diam by about 1 in. high. After pressing, the specimens were heat-treated in nitrogen at 1900°C for 50 hr. The densities of individual specimens were determined by the water displacement method. All specimens were theoretically dense, based on a value of 14.32 g per cu cm.5 Principal metallic impurities in ppm by weight were: Ca, 50; Cu, 5; Fe, 30; Mg, 5; Ni, 10; and Si, 20. Oxygen content was 400 ± 50 pprn and carbon content was 100 i25 ppm. The nitrogen content was 5.56 ±0.05 wt pct. The average grain size for five specimens, as determined by the intercept method, was 0.14 i 0.01 mm. One specimen had a grain size of 2.0 mm. This large grain size is an anomaly, since all specimens had the same chemical and thermal histories. Specimens of 1/4 in. diam by 1/2 in. high were creep-tested in compression in a clam shell furnace heated by W-25 pct Re sheet elements. Temperature was measured to ilODC by an optical pyrometer which had been calibrated by a standard source. The distance between fiducial marks on the specimen was measured before placement into the furnace. The furnace chamber was evacuated to 10-5 Torr and back-filled to 200 mm N2. After heating rapidly to temperature, the load was applied and controlled to ±2 pct by an Instron testing machine. Upon initial loading, the specimen was deformed until a constant crosshead rate was obtained, then quenched to room temperature, remeasured, and replaced in the furnace. Upon subsequent reloading at temperature, the crosshead rate was constant for the selected condition indicating steady-state creep.

Jan 1, 1969

By Takahiro Miki

Soldering material widely used is Sn-Pb alloy, which have low melting point and excellent electrical, strength properties and wettability. However, Pb is one of the toxic elements, which is undesirable due to environmental and safety reasons, thus Pb-free alternative alloy is preferred for new soldering materiaL Sn-Ag and Sn-Zn based alloys have been viewed as very promising candidates, among many potential substitutes. Addition of third element to these alloys will decrease melting point of the alloys. Hence, Sn-Ag-In and Sn-Zn-Mg alloys are expected to be suitable for replacing Sn-Pb solder alloy. In order to dcsign new Pb-free soldering materials, it is crucial to understand precise thermodynamic properties and phase diagrams of alloy systems. In the present work, ion current ratios of Ag to In and Mg to Zn were measured for Sn-Ag-In and Sn-Zn-Mg alloys by mass spectrometry, respectively. Also, the authors reviewed the thermodynamic properties of terminal binary alloys determined by other researchers and evaluated a thermodynamic functions to express the excess Gibbs free energy of each binary alloy. Thermodynamic functions to express the excess Gibbs free energy of liquid Sn-Ag-In and Sn-Zn-Mg ternary alloys were determined, utilizing the assessed Gibbs free energy of terminal binary alloys with the measured ion current ratios using mass speetrometer.

Jan 1, 2003

By Guilherme Vieira Braga Lemos

Uma superliga a base de Níquel, popularmente conhecida como Inconel 625®, foi estudada no presente trabalho. A Soldagem por Fricção e Mistura Mecânica (SFMM) aplicada a liga 625 foi realizada com velocidades de rotação da ferramenta entre 1200 a 200 rpm e velocidade de soldagem entre 1 e 1,5mm/s. O aporte térmico foi calculado como função dos parâmetros de soldagem empregados. Adicionalmente, análises metalográficas e de microdureza foram realizadas na seção transversal das juntas soldadas. A aplicação da soldagem no estado sólido foi efetiva e resultou em maiores valores de microdureza todas as juntas soldadas. Por outro lado, um aumento na velocidade de rotação causou um aumento do aporte térmico.

Aug 17, 2017