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By John A. Allan

Introduction There are times when meditation on the past is worth while. Too often does it happen that in the busy routine there appears t9 be little time for reflection, and little good or benefit to be derived from what has already taken place, or what has become past achievement. Under conditions such as those that prevail at present, consideration is being given to many subjects that a few years ago were not looked upon as worthy of time or thought. The temporary lull in industrial development is permitting of a stock-taking investigation, a perusal of past activities, and a planning for future development with the return to normality. It is not proposed to include much new data in this address, but the endeavour will be made to survey, in resume, the sequence of events which led up to the birth of the mining industry in Canada, and to show how, as new discoveries were made, the centres of interest changed from time to time until mineral development extended across Canada from the Atlantic to the Pacific. It will appear, also, that external causes have accentuated mineral development at one time and retarded it at another. Early Records A, historical background to the mining industry extends even to an earlier date than the discovery by white men of that part of the continent of North America represented by Canada. It has been stated that the aborigines were still in the neolithic stage when the white man arrived. One metal only was known to the natives, and that was copper, obtained from possibly many parts of Canada, but particularly from the shores of lake Superior in Ontario, from the Coppermine river on the Arctic coast, and from die coastal regions of British Columbia.

Jan 1, 1933

By Michael Sheedy

Recoflo® ion exchange technology utilizes fine mesh resin beads, a fully packed resin bed, and counter-current regeneration. These unique features help to improve exchange kinetics, reduce regenerant consumption, and increase the concentration of strip solutions. Commercially, Recoflo technology has been extensively used in the following areas: the separation of strong mineral acids from dissolved metal salts, the purification, removal and recycle of dissolved metals in the surface finishing industries, and the production of high purity water. In the mining and metallurgical industries Recoflo ion exchange systems have been installed to treat a copper refinery bleed stream at Falconbridge's Kidd Creek plant and to treat a nickel and cobalt bearing ammonium sulfate effluent stream at another primary metal producer's facility. In the first application an APU® Recoflo system is used to separate the sulfuric acid at 200g/L from the dissolved copper and nickel sulfate salts at 80 g/L. The absorbed sulfuric acid is recovered from the resin by elution with water and is then returned to the refinery electrolyte circuit. In the second application a chelating ion exchange resin is used to remove nickel and cobalt at 0.01 - 3.0 g/L from process streams containing 120 - 240 g/L ammonium sulfate. This Recoflo system has been designed to reduce the nickel and cobalt levels to 0.001 - 0.002 g/L while recovering cobalt and nickel at concentrations up to 30 g/L and 15 g/L respectively. Case studies for both these metallurgical applications and other Recoflo processes are presented in this paper.

Jan 1, 1998

By Ralf M. Kleine

THE property of Consolidated 1 Discovery Yellowknife Mines Limited, (Figure I) is situated in the Northwest Territories, approximately 50 air miles north of the town of Yellowknife. The mine is reached by a shaft which extends from surface to a depth of 4,000 feet, with working levels established at 1 50-foot intervals. Stopping operations are carried on throughout a vertical range of 2,000 feet, with both shrinkage and cut and fill methods being used, depending on the ground conditions. Production started in 1950 and milling is done in a 1 65-ton per day cyanide plant. During ten months of the year, the property is serviced entirely by air, utilizing charter aircraft from Yellowknife. A 4,000-foot runway near the mine was constructed from mill tailings. This strip is adequate to receive Bristol freighter planes carrying heavy loads. Other servicing is done by Otter aircraft, equipped with skis or wheels for winter and with pontoons for summer operations.

Jan 1, 1962

By Michael Oakland

This paper will discuss the design analysis of sheet pile cofferdams for static and dynamic blast loads. Following construction of the new Willis Avenue Bridge across the East River between Brooklyn and Manhattan, in-river piers No. 9 and No. 10 from the former bridge were demolished, partially by explosive charges. The blast at Pier 10 was conducted first and though the demolition charge was relatively small, it gave confidence that the sheeting could be designed to resist the blast load. This paper primarily summarizes our analysis and performance of a sheet pile cofferdam at Pier 9 used to withstand the larger blast loads, contain the blast debris, and allow excavation of the pier below the existing river bed mudline. The program NLFlex was used to predict stresses and deformations of the cofferdams under dynamic blast loads, using simplified equations to estimate the underwater blast pressures. Specifically, the analysis focused on the stresses in the struts, waler beam, sheet pile interlocks and connection of the sheeting to the waler beam. Design included allowing plastic deformations and limited rupture of the sheet pile interlocks under the blast loading. Comparisons are made between stresses assessed by the dynamic finite element modeling and empirical relationships used within the industry. The performance of the system after the actual blast is discussed as well as details of the performance of welded vs. bolted connections within the system.

By T. Wajima

"A novel carbonaceous adsorbent for recovery of nickel from nickel plating waste solution was prepared from rice straw using sulfur impregnation. The rice straws were cut to 1 cm pieces, and then immersed in 0.01 - 3 M K2S solution to prepare sulfur-immersed materials. The immersed-materials were heated at 100-700 ºC in nitrogen gas to produce the sulfur-impregnated carbonaceous adsorbent by pyrolysis. The contents of carbon and sulfur in the adsorbent and abilities of adsorbent to recovery nickel from aqueous solution were examined. The contents of carbon and sulfur in sulfur-immersed materials are almost same as those in raw material. In pyrolysis, with increasing the heating temperature to 200 ºC, the contents of carbon and sulfur are almost constant, and then above 300 ºC those increase. The recovery for nickel using raw material, sulfur-immersed material and the product pyrolyzed at 100 - 200 ºC are almost same, and with increasing the heating temperature to 400 ºC, that of the product increases, and above 500 ºC that of the product decreases. In immerse step, with increasing K2S concentration, the carbon content of the product at 400 ºC gradually decreases, the sulfur content of the product increases, and the recovery for nickel using the product gradually increases and then above 1 M K2S decrease. The product prepared from material immersed in 1 M K2S solution at 400 ºC indicates a maximum recovery for nickel ion. The product can adsorb nickel ion in nickel plating waste solution coexisting with phosphate ion, and adsorbed nickel ion in the product was deposited as nickel metal after heating at 1000 ºC under N2 atmosphere.INTRODUCTIONRice is the second world’s largest cereal crop after wheat, but produces large amount of straw residues, of about 330 million metric tonnes. Rice is a widely grown crop in Asia, and rice straw is produced as a by-product of rice production. In most parts of rice fields, open-field burning of rice straw is commonly practiced in the region when there is limited time to prepare a field for the next crop. However, open-field burning of crop residues is an uncontrolled combustion process during which air pollutants are emitted into atmosphere. These air pollutants have significant toxicological properties and are potential carcinogens (Gadede et al., 2009). Although wildfires are prohibited in cultivation fields of most countries, farmers usually keep on burning their crop by-products. Biomass burning is an important source of aerosol particles which may affect local and regional air quality (Gao et al., 2011), and also contribute to global climate changes."

Jan 1, 2016

By Roberto Silva de Andrade

O inchamento é um grande problema durante a redução de pelotas de minério de ferro. Várias mudanças podem ser feitas nas pelotas para minimizá-lo. Conforme o sínter utilizado se torna cada vez mais básico, pelotas mais ácidas são desejadas. A adição de MgO, assim como a modificação da basicidade binárias das pelotas pela adição de CaO são soluções que têm sido apontadas. Dessa forma, este trabalho estudou os efeitos do MgO a da modificação da basicidade binária nas seguintes propriedades de pelotas: compressão a frio, porosidade e índice de inchamento. Foram preparadas pelotas com até 5% de MgO e com basicidades entre 0,67 e 1,5. O aumento do teor de MgO causou aumento de porosidade e queda de resistência. A basicidade diminuiu a porosidade e causou aumento de resistência nas pelotas de basicidade 1,0. Tanto o aumento de basicidade quanto a adição de MgO diminuíram o inchamento.

Oct 30, 2017

Traditionally, the predominant drilling method in open pit mining has been large hole rotary drilling using cumbersome, inflexible equipment offering merely limited scope for improvements in pit design and overall costs. By contrast, the recent development of comparatively light high-pressure down-the-hole hammer crawlers has paved the way for new ideas and trends. High penetration rates coupled with superior mobility and fast set-ups contributing to substantial productivity gains have resulted in a renascence for this drilling method in open pits. The ability to cover a wide range of hole diameters and angles gives designers unique drill pattern possibilities especially when establishing steep and stable pit slopes. As pre-split holes, buffer holes and production holes all can be drilled by using the same equipment, there are, there are obvious advantages in production scheduling as well as in materials handling and service. This paper presents some case stories, which will demonstrate the benefits and improvements that the introduction of new drilling methods and equipment has brought to open pit mining operations.

Jan 1, 2003

By Anthony (Sam) J. S. Spearing

Backfilling using coal waste is not a novel means for waste disposal throughout the world; yet, backfilling using a high density (paste) backfill is relatively new, except in Germany and Poland. One of the main benefits of a high density backfill, as opposed to a low density (slurry) backfill, is that, if placed at a low permeability and low moisture content, the risk of water table contamination can be relatively low. In addition, if paste backfill can be placed cost effectively, environmental benefits are huge because the surface impoundment footprint can be greatly reduced or even eliminated. This is especially true in room-and-pillar applications. In its current state, backfilling is considerably more costly than surface disposal. This is mainly because paste, as opposed to slurry, significantly increases backfill placement costs; however, this could be offset by increasing the achievable extraction rate. Overall, such a system could potentially improve the public?s image of coal mining in the US for a myriad of reasons. This paper discusses a proposed backfill system for a typical room-and-pillar coal mine in the Illinois Basin of the US and clearly shows the technical advantages, although costs are still higher with fill. The cost differential will likely reduce over time, in favor of the backfill option, as costs of traditional surface disposal increase, due mainly to ever-restrictive disposal regulations.

Jan 1, 2013

By David E. Siskind

The Bureau of Mines recorded particle accelerations in the mine roof produced by three types of explosives in the Pilot Knob Pellet Co. mine, Pilot Knob, Mo. Examined were the effectiveness of cube root, square root, and two-thirds power scaling in grouping the underground blast vibration data, and the effects of mine geometry, rock type, explosive type, and charge size on blast vibration levels. A propagation law for this mine was determined. The scaling factor of the square root of the charge weight was developed from previous Bureau studies of vibrations from quarry blasts, and in under-ground blasting both square root and cube root scaling were found applicable for scaling particle vibration data. The vibrations from the Pilot Knob blasts were best grouped by a square-root scaling factor. The empirical propagation equation AW1/2 = 76,250 (R/W1/2)-2.61 where A is the peak acceleration in g's, W is the charge weight in pounds, and R is the distance from the blast in feet, may be used to describe vibration amplitudes from charges fired with zero delay caps or with a single cap at Pilot Knob. Statistically significant differences were found in the vibration levels generated by the different explosives. The Power Primer (75-percent weight-strength ammonia gelatin dynamite) produced levels of vibration of 1.7 to 2.4 times those of AN-FO and slurry explosives; the latter two are approximately equal.

Jan 1, 1973

By Chas. F. Jackson

During the current business depression the Bureau of Mines has received many inquiries concerning placer mining, the prospects for men of small means to make wages by small-scale placer operations, the locations of placer deposits in the United States, methods of working placers on a small scale, and allied subjects. It has therefore seemed desirable to prepare a circular covering, in nontechnical language, the principal questions which have boon referred to the Bureau of Mines for answer. There are a number of bureau publications dealing with placer mining, most of which are now out of print, but which may be consulted in the larger libraries. Other articles on placer mining nave appeared from time to time in the technical press and several good textbooks have been written on the subject. A partial bibliography of this literature appears at the end of this paper. A recent pamphlet published by the Idaho Bureau of Mines and Geology to assist the prospector and inexperienced small operator has received wide and favorable attention and is recommended as a useful reference. In the present paper no attempt will be made to cover the subject of placer mining in a comprehensive manner, but discussion will be confined to elementary questions of particular interest to persons of limited experience.

Jan 1, 1932

By Marie-Pierre Bourdouxhe-Barnich

Since 1997, in partnership with the Laboratoire Central des Ponts et Chaussées in Strasbourg, ProfilARBED has been carrying out a vast study to qualify the improvements jetting can make to vibratory driving of steel sheet piles, and to understand its effect on the surrounding ground and on the sheet piles themselves. The process basically involves discharging a fluid (mostly water, sometimes in association with air) at controlled pressure and/or flow rate near the toe of the sheet pile being driven. The steel jetting pipes are attached to the sheet pile and are connected to the pumps by hoses. The jet of fluid loosens the soil, thus reducing the resistance at the toe of the sheet pile. Depending on ground conditions, the fluid that flows along the pile can reduce skin friction. Four soil types were involved in our experiments. Each site was instrumented: the driving parameters and the geotechnical characteristics of the soil before and after vibratory driving and jetting-assisted driving were recorded. Each test provided its own particular information which contributes to overall thinking on the matter and is of help to project managers who are often confronted with rapid driving to the final depth.

Jan 1, 2002

By Henrique Silva Furtado

Concerning production of low phosphorus steel critical grades at ArcelorMittal Tubarão site, bottom blowing system plays a very important role. For those systems with independently controlled tuyeres, some non-uniform bottom blowing patterns seem to be promising in improving metal-slag mixing; however, based on computational fluid dynamics (CFD) results of ArcelorMittal Tubarão’s post oxygen bottom blowing, this may not be generalized. Also, from industrial trials it became clear that higher the bottom blowing flow rate, the closer were the end point P to the equilibrium. Despite this result an analysis of the apparent mass transfer coefficient has shown a week correlation with the classical power stir correlation suggesting a more complex kinetic limiting step for phosphorus removal.

Jul 30, 2018

By N. Henderson, J. Weyer, J. F. Brune

"The mining industry worldwide is currently facing a significant restructuring process. In most underground mines, widespread mechanization of the mining processes increases production while reducing staff numbers. At the same time, mining depths as well as the lateral spread of the mine workings are increasing. This ever-changing mining environment requires sophisticated solutions for the design and operation of underground mines. In fact, a reduced number of mining engineers is taking responsibility for everincreasing mine operations. This applies not only to the excavation of the minerals, but also to all other aspects of the mining operation, including health and safety, disaster management, and mine rescue organization.Most mining engineering graduates entering the industry lack experience in mine emergency management. Young engineer trainees must learn mine emergency management and rescue work in addition to their normal training experience on the job. Often, and unfortunately, emergency and rescue training at different mining companies is not carried out to the highest level and standard and with the best possible training outcomes. The tasks and challenges a young engineer faces while being trained in a new position do not leave much room for additional training in mine rescue and emergency management. At the same time, experienced, ’old hands’ are retiring and cannot easily be replaced due to limited graduation numbers.Strategies are being developed at mining universities worldwide to train mining engineering students in handling mine emergency situations and to provide hands-on experience for managing potential accident and disaster scenarios underground. Two of these strategies, from the USA and from Central Europe, are presented in this paper. These specific strategies have to be seen under special consideration of the local and regional boundary conditions, but might serve as case studies for mining schools and universities in other countries."

Jan 1, 2014

By David B. Burrows, Francis R. Conley

INTRODUCTION A prerequisite to the evaluation and management of oil properties is accurate information derived from the analysis of core samples; but reliable data, such as porosity and permeability, can result only if all oil and water have been removed from the core samples analyzed. The most common method of core cleaning used to date has been Soxhlet extraction—a somewhat static technique, which depends upon the slow diffusion of hot solvent through the core sample. Soxhlet extraction performs satisfactorily only with highly permeable samples and at best requires long cleaning periods. The centrifuge method was developed in 1951 by Continental Oil Co. to overcome the inefficiencies inherent in the Soxhlet method. The new method is basically an operation in which hot solvents are caused to flow through the samples under the influence of centrifugal force. The centrifuge unit has proved so successful that samples which formerly required days for partial extraction can now be completely cleaned in approximately one hour. The original idea was conceived in 1950 by Elmer S. Messer, whose early experiments consisted of flowing solvent over sandstone samples suspended in a revolving basket and driven by a vertically mounted vacuum cleaner motor. Results were so outstanding that more permanent units were constructed. A modified model using this basic design was recently built by Core Laboratories, Inc., and is now used regularly in their operations. DESIGN Fig. 1 shows a photograph of the two extractors routinely used to clean small core plugs in the Production Research Div. of Continental Oil Co.'s Ponca City laboratories. For illustrative purposes, the basket from one of the units has been removed, and because both extrac- tors are of identical design only one is described in the following discussion. Each extractor unit consists of a centrifuge and a solvent still. The core basket of the centrifuge is made of mild cold rolled steel 7 1/2 in. in diameter and 1 1/8 in. deep. The basket holds 18 1-in. samples (cubical or cylindrical) and is attached directly to a cone fitted to the shaft of the motor. Both the outer rim and the hollow hub of the basket contain perforations for the passage of solvent and extract. The solvent is delivered to the perforations by means of a copper tube inserted into the hollow hub. The motor is a vertical tool post grinder motor; (115 v, 5.6 amp, 0-60 cycles, AC-DC, rated at 1/3 hp). It has a rated speed of 10,000 rpm under full load and 15,000 rpm with no load. Variation of speed is obtained by the use of a variable transformer. The solvent still was constructed from one end of a stainless steel oxygen bottle by inserting a heating element, sight glass, and piping as shown on the schematic diagram, Fig. 2. The heater used was a three-position, 1,000 w, 115-v, immersion type. Intermittent flow of solvent to the centrifuge is obtained by means of a siphon bottle inserted between the condenser and the centrifuge.

Jan 1, 1957

By Liyuan Chai, Qin Liu, Bing Peng, Jia Wang, Qiang Zhang

"Electrolytic Manganese Residue (EMR) was used as the main material to prepare cementing material activator for the utilization of the residue from electrolytic manganese dioxide (EMD) or electrolytic metallic manganese (EMM) production. The effects of chemical activation, thermal activation and mechanical activation on retarding activity and excitation activity of EMR were investigated according to the setting time and activity index of EMR-slag cementing material. The results showed that the EMR exhibited good activating performance after being ball-milled for 18 min and then treated for 1-2 hours at temperature range of 350-450 ?. The optimal properties of cementing material activator were achieved at the weight percent ratio 30 : 3 : 5 of EMR/Ca(OH)2/cement clinker.IntroductionMany hazardous industrial solid wastes such as blast furnace slag, fly ash, steelmaking slag, chromic slag and electrolytic manganese residue [1] are generated n China and their amounts increases every year. The accumulation of the solid wastes during past years is very huge and they could be hardly recycled effectively as a sustainable resource. 2.35 billion tons of industrial solid wastes have been produced up to now [2]. It is estimated that they would exceed 3.3 billion tons by the end of 2015 [3]. On the other hand, the quick development of Chinese infrastructural construction needs more cementing materials. The production of traditional building materials consumes lots of natural resource such as clay and limestone and discharges at least 1 ton CO2 and other pollutants per ton clinker [4]. Therefore, it is necessary to develop new types of cementing materials instead of clinker [5,6]."

Jan 1, 2012

By P. T. Bissert, T. J. Lutz, J. A. Yonkey, G. T. Homce

"Underground refuge alternatives require an air source to supply breathable air to the occupants. This requires pressure relief valves to prevent unsafe pressures from building up within the refuge alternative. The U.S. Mine Safety and Health Administration (MSHA) mandates that pressure relief valves prevent pressure from exceeding 1.25 kPa (0.18 psi), or as specified by the manufacturer, above mine atmospheric pressure when a fan or compressor is used for the air supply. The U.S. National Institute for Occupational Safety and Health (NIOSH) tested a variety of pressure relief valves using an instrumented test fixture consisting of data acquisition equipment, a centrifugal blower, ductwork and various sensors to determine if the subject pressure relief valves meet the MSHA requirement. Relief pressures and flow characteristics, including opening pressure and flow rate, were measured for five different pressure relief valves under a variety of conditions. The subject pressure relief valves included two off-theshelf modified check valves, two check valves used in MSHA-approved built-in-place refuge alternatives, and a commercially available valve that was designed for a steel refuge alternative and is currently being used in some built-in-place refuge alternatives. The test results showed relief pressures ranging from 0.20 to 1.53 kPa (0.03 to 0.22 psi) and flow rates up to 19.3 m3/ min (683 scfm). As tested, some of the pressure relief valves did not meet the 1.25 kPa (0.18 psi) relief specification.IntroductionThe Mine Improvement and New Emergency Response Act of 2006 (MINER Act) was enacted in the United States in the wake of three mine explosions/fires that claimed 19 lives that year. Intended to help improve underground coal mine accident preparedness, the MINER Act includes provisions that target mine safety issues in areas such as emergency response planning, adoption of new technology, training and education, and mine safety standards enforcement (U.S. Mine Safety and Health Administration, MSHA, 2006). Section 13 of the MINER Act specifically directed the U.S. National Institute for Occupational Safety and Health (NIOSH) to provide for research into the effectiveness and viability of refuge alternatives for underground coal mines. This mandate culminated in the 2009 adoption of changes to Title 30 of the Code of Federal Regulations (30 CFR) mining health and safety regulations, requiring underground coal mines to provide mine emergency refuge alternatives and associated components, to provide a life-sustaining environment for persons trapped underground. Such refuge alternatives can be either self-contained mobile units or built-inplace facilities. The regulatory changes also include provisions establishing requirements for MSHA approval of refuge alternatives and their components, and among these provisions are numerous criteria for providing a safe breathable atmosphere under positive pressure within the refuge alternatives. One specific criterion for maintaining a safe refuge alternative atmosphere requires the inclusion of an air pressure relief valve that will activate at a maximum of 1.25 kPa (0.18 psi), or at a pressure above mine atmospheric pressure, in the refuge alternative, as specified by the manufacturer when the breathable air is supplied by a fan or compressor (MSHA, 2008)."

Jan 3, 2018

By Nik Sokol, Mike Jaeger, Leo C. Weiman-Benitez

Silicon Valley Clean Water signed a progressive-design-build (PDB) contract with Barnard Bessac Joint Venture (BBJV) to design and construct the Gravity Pipeline tunnel in Redwood City, CA. Owner and Design-Builder teamed with designer Arup to provide a final product: 3.3 miles of 182 in. O.D. precast concrete segmentally lined tunnel with 10 ft. and 11 ft. I.D. Fiberglass Reinforced Polymer Mortar (FRPM) carrier pipe, complete with two FRPM Drop Structures. BBJV and Arup collaborated with SVCW to evaluate alternative design concepts, negotiate an agreeable price and reduce contingencies through a transparent estimating process, and deliver the project ahead of schedule.

Jun 13, 2023

By C. H. McGuirk

Computerized Preventive Maintenance is important in maintaining consistent and efficient operation in any industry utilizing sophisticated and expensive equipment on a continuous basis. At today's large bulk materials handling facilities, the problems of continuous operation of complex machines with their thousands of components exposed to abrasion, dirt, dust and the elements, are intensified and multiplied. Effective preventive maintenance can increase profits. Yet, the number of tasks to be performed is so staggering that it is beyond error-free human capacity. The computer must be an essential ele¬ment in any efficient and economical preventive maintenance system. Computerized preventive maintenance techniques have been successfully used in many fields, usually involving highly skilled and specialized personnel working under favorable and controlled conditions. Now, The Pittsburgh & Conneaut Dock Company has developed and is applying a computerized preventive maintenance system that is applicable to the bulk materials handling industry. The "system" has taken many years of intensive effort to develop and has been time-tested and proven during the past years on equipment handling materials with rugged physical characteristics and corrosive and abrasive qualities, under some of the most adverse weather conditions on the Great Lakes.

Jan 1, 1976

By A Fern, A Hawkes, o, W Smith, K Mee

Serious Injury and Fatality (SIF) prevention remains a priority focus within high-risk industries sector. A major mining operation sought to strengthen their approach to the management of high-risk activities through an in-depth review of all historical incidents that had serious injury or fatality potential (SIFp) events (sometimes known as hi-potential events). The analysis found that the organisation invested a disproportionate level of resources, time and effort on low consequence incidents with a high proportion of SIFp incidents going under the radar. It was found that 76 per cent of SIFp incidents were rated in moderate or lower risk categories and conversely, almost half of those incidents with a ‘serious risk’ rating had little or no potential for a serious outcome. As a result of this project, the operation engaged in a renewed focus on critical risk management and enhanced its operating cadence in critical risk for the workforce. This included bow tie analysis, an update to critical risk standards and increased workforce engagement in the use of critical control verifications in the field. Data analytics with lead and lag indicators continue to provide senior leadership team and risk owners with an understanding of exposure for SIFp and control effectiveness. The audience will take away learnings from a real-world case study that provides data-driven insights of the human, local and organisational factors contributing to incidents with SIF potential. In addition, participants will understand the steps taken to categorise and analyse this incident data and the initiatives currently being implemented by the organisation as a result.

Apr 16, 2024

By I. M. Ahmed, R. S. Hassan, M. I. Aly

Extraction and separation of La, Sm and Dy ions from acidic sulfate-phosphate solutions was investigated using a cation exchange extractant, bis(2,4,4-trimethylpentyl) phosphinic acid, CYANEX 272, in kerosene. The influence of shaking time, equilibrium pH, extractant, sulfate and phosphate ion concentrations, diluent type and temperature was studied. The extraction was found to be pH-dependent, and increasing the phosphate ion concentration inhibited the extraction which was found to be endothermic. The stoichiometry of the extracted metal species was found to be MOH.H2OHSO4H2A.A2. Aliphatic diluents were found to enhance the extraction compared to aromatic diluents. The results showed that there was a separation mode between the metal ions when varying the hydrogen ion and sulfate ion concentrations, under the used experimental conditions. The investigated process was used for the recovery of La, Sm and Dy from the acid solution resulting from the leaching of low-grade monazite.