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By A. U. Seybolt

As is well known, many questions affecting the properties and uses of a metal cannot be answered without careful consideration of the state of purity realized in the various operations of preparation, refining, or special treatment that have brought the product to its final state. The occurrence of an impurity in minute quantity offers no guarantee that its effect will be inconsiderable because dissolved substances often modify the properties of a metal quite out of proportion to their concentration. In such cases the determination of solid solubility must be accepted as a problem of considerable difficulty, requiring the use of especially purified materials and methods not ordinarily used in the metallurgical laboratory. This aspect of the equilibrium between metals and their oxides is especially important and a search for fundamental data reveals little except .conflicting opinion even concerning the systems of common occurrence and interest. Rhines and Mathewson1 in 1934 studied the solubility of oxygen in solid copper by annealing to equilibrium in air and gave reasons for the failure of other methods, notably the ordinary procedure of heat-treatment followed by microscopic examination, to yield reliable results. In this paper, a similar study has been made of the solubility of oxygen in cobalt. The simple theory of this method is outlined below.

Jan 1, 1935

By A. Torkian

Process water from production of concentrates in Meydook copper sulfide mine is transferred to the 8.3 million m3 tailings dam and a water retention pond after initial thickening. Elevated concentrations of heavy metals, sulfate, and TDS and decrease in pH as well as seepage into the aquifers have been the concern of the regulatory agencies since the start of activities. In this paper the results of a 6-month monitoring program from 4 wells are presented. The wells were located approximately 1.5 km from downstream of tailing dam (0.4 km from water retention pond) as well as upstream background well (2.28 km from water retention pond and 1.27 km from tailings dam). The objective was to study possible effect of accumulated tailings on the groundwater resources. Water levels in sampled wells were on average between 20 and 40 m. Results showed high levels of lead (5 ppb), copper (0.17-0.46 ppm) and selenium (73.1- 29.1 ppb). High levels of selenium and lead were partly due to natural geological settings of the area with high levels present in unaffected soils in the vicinity including water wells of villages upstream of mining operations. High copper levels were attributed to both mining operations as well as deposition from particulate air deposition onto the soil and transport to ground water by rain.

Aug 1, 2013

By Wenjun Duan, Zongliang Zuo, Qingbo Yu, Qin Qin, Junxiang Liu

Moving bed has been widely used in the field of heat and mass transfer and reaction between solid particles and gas. In order to enhance the heat exchange coefficient, there will be tube banks inserted in the moving bed. In the process of drying ammoniates particles or heat recovery from high-temperature particles with moving bed, the particles flow behavior around the tube banks is significant. In this paper, the particles flow behavior around the tube banks is investigated, and all the results can provide guidance for the design and operation of a moving bed.

Jan 1, 2016

By J. Tremolada

El presente trabajo señala las bases y resultados que favorecen la recuperación del oro cuando se incrementa la concentración de oxigeno disuelto en la solución lixiviante. En ese sentido, el oxígeno es el agente que incrementa la disolución del oro, y el cianuro, su medio de transporte. Asimismo, aumentar la cantidad de oxigeno disuelto en la solución cianurada de riego mediante el uso de venturis (dispositivos que aspira aire del medio ambiente) logra soluciones cianuradas con concentraciones de oxígeno más altas, de forma se lograría una mejora en el proceso de la extracción del oro.

Sep 14, 2009

By Robert A. Irvine

Traditionally, cost effective gains in the capacity of material handling systems were a result of increases in equipment size. In general, the use of maximum capacity components in a system optimizes the production "costs per ton." The trend-"Bigger is Better" will continue in material handling equipment. Since it is rare for plant operators to lament an over abundance of screening capacity, one can safely predict that vibrating screens will follow this trend. Large Vibrating Screens - The Challenge Large vibrating screens represent a unique challenge for Manufacturers, Plant Designers, and Plant Operators. The inherent mode of operation for vibrating screens is self-destructive. More often than Manufacturers admit, Designers plan for, or Operators staff for, a vibrating screen succeeds and self-destructs. This is a problem. It can magnify with larger vibrating screens.

Jan 1, 1983

By Hyun Kyu Shin, Byeong Deok Lee, Young Eun Lee

The reduction of Mn oxides at pre-smelting steps is an integral part of smelting processes for Mn alloys, and an understanding of its reaction mechanism is expected to contribute to the improvement of processing efficiency for Mn alloys smelting. The phase diagram shows that five Mn carbides are operative in the Mn-C system. Although they are expected to participate in the reduction of Mn oxides, no specific information is available yet to clarify their roles in presmelting carbothermic reaction of Mn oxides. Experiments with composite pellets prepared with Mn oxides and graphite powders show that Mn3O4 is reduced initially to MnO at about 1130oC and, subsequently, to Mn7C3 carbide as temperature increases further. At 1331oC, Mn7C3 carbide dissociates to Mn alloy and carbon. The degree of reducing reaction increases with increasing carbon balance in composite pellets and increasing temperatures.

Jan 1, 2014

By Terry D. Vandell

The purposes of this presentation are: (1) to discuss the actual as well as potential incidents that have caused and that could cause groundwater contamination at uranium in situ leach mining sites and (2) to discuss remedial actions and solutions that have been or that could be implemented in the future to stop or prevent serious groundwater contamination from in situ leach mining in Wyoming?s Powder River Basin. Open pit, underground, and existing and proposed in situ leach uranium mine sites in the Powder River Basin are shown in Figure 1. In situ leach mining or solution mining for extracting minerals in liquid form is a relatively new addition to the list of conventional mining methods currently used to extract uranium in Wyoming's Powder River Basin. Basically, the in situ leach mining method involves: (1) the injection of a leach solution lixiviant (an acidic or basic oxidizing solution) into a uranium-bearing ore body, via injection wells, to complex the contained uranium, (2) mobilization of the uranium complex from the host material via creation of a soluble complex salt, and (3) surface recovery of the solution bearing the uranium complex via production wells. Uranium is then separated from the leach solution by conventional milling unit operations (ion exchange).

Jan 1, 1981

By Geoffrey A. Brooks, M Akbar Rhamdhani, Md Saiful Islam

A novel electrically-enhanced metal purification using slag has been developed. This was achieved by applying DC potential between liquid metal and slag phases. The concept was demonstrated through small-scale experiments at temperatures of 1500-1600oC for the removal of boron from Si-B melt using CaO-SiO2-16wt%Al2O3. Silicon (containing B) and slag were reacted in an alumina crucible in a resistance tube furnace. A circuit was produced by immersing graphite rods into the silicon bath and the slag layer. Electrical potential differences of up to 3.5 V were applied during the reactions. The reaction rates, the opencircuit voltages and short-circuit currents (in the case when the potential was applied) were then measured and determined for various slag to silicon ratio. It has been shown from this study that both the apparent rate and the boron partition ratio were increased by a factor of approximately 1.6.

Jan 1, 2014

By D. L. Langhans

Platinum-group metal (PGM) converter matte from the Stillwater Complex, MT, was subjected to chemical and biological leaching in an effort to upgrade the matte by decreasing the Cu and Ni content. Copper and NL extractions were optimized in a two-stage chemical leach. Atmospheric pressure sulfuric acid leaching removed over 90 pct of the Ni and Fe in the first stage, while 95 to 98 pct of the Cu was removed is the second stage using an acidified cupric chloride leach. This two-stage leach, followed by an elemental sulfur removal step, decreased the weight of the matte by 90 pct. The combined Cu and Ni content was reduced from 65 pct to less than 20 pct, while the PGM content was increased from less than 2 pct to 26 pct. Biological oxidation using Thiobacillus ferrooxidans also proved to be an effective method for removing Cu and Ni. Over 90 pct of the sulfide was oxidized and 99 pct of the Cu and Ni were solubilized, leading to a 60 pct reduction of sample mass during the 17 week bio-oxidation of the Stillwater converter matte. The final residue, after removal of jarosite that accumulated during bio-oxidation, contained less than 3 pct combined Cu and Ni and 6 pct MM.

Jan 1, 1993

By Andy L. Shaffer

A novel liquid settlement system (LSS) was installed in advance of mining at a western United States (U.S.) longwall mine to measure total roof sag from the time of cutting to days after mining during gate road development. The system was used to compare differences in roof sag between conventional place-change mining using a Joy continuous miner and a Fletcher roof bolter and mining using a miner-bolter. The LSS was installed with an intrinsically safe, miniature data acquisition system (MIDAS) to record roof response at four locations in the same gate road. The system utilized pressure transducers to measure roof sag by the principle of falling head (fluid pressure) in fluid-filletubes installed in the immediate roof. Details of the LSS design, installation, data collection, post-processing, and future applications are discussed.

Jan 1, 2014

By Shek N. Lau, Nicola Samman

"Enclosed gear cases on board heavy mining equipment have traditionally been lubricated with regular heavy duty gear oils. However, equipment manufacturers, have recommended the use of an ISO-1000 gear oil for this application to ensure adequate lubricant film strength, especially at the higher end of the working temperature range. The majority of these ISO-1000 gear oils are based either on residual/asphaltic oil or synthetics, primarily higher viscosity polyalphaolefins. Although the performance of these lubricants has been satisfactory, they suffered other shortcomings that equipment users have lived with over the years.The major requirement at the user’s mine was to provide lubrication for the shovel Hoist gear case. Within such a gear case design, the gears and the roller bearings, that have different lubrication requirements, are lubricated with the same lubricant. Several lubricants were used, light gear oils as well as the recommended ISO-1000 heavy gear oils. On the one hand, the lighter oils performed adequately for the lubrication of the bearings that formed part of the enclosed gear system. These lighter oils did not perform as well for the lubrication of the gears due to their lower viscosities, resulting in shorter gear servicelives.On the other hand, the ISO-1000 gear oils performed well for the lubrication of the gears, but were too viscous to creep into the bearing elements to lubricate them adequately, especially during the cold northern Canadian winters. This resulted in catastrophic bearing failures and secondary damages to the gears.The challenge, then, was to formulate a lubricant which met the 1000 cSt at 40°C viscosity requirement as stipulated by the equipment manufacturer, while satisfactorily lubricating the bearings at the full working temperature range. This was achieved by the development of a semi-fluid grease lubricant, which has proven in field trials to give adequate performance in this application for the lubrication of both the bearings and gears down to -40°C.This product met the equipment manufacturer’s performance criteria and resolved, to a large extent, leakage of the lubricant through seals experienced with the use of conventional and synthetic gear oils.Although the main performance criteria of the fluid was its capability to lubricate the “Hoist” gear case, it was also used during the field trial in other gear cases on board the shovel to test its full capabilities.This unusual alternative lubricant was field tested and evaluated for more than two years. Based on this assessment, the product was reformulated to improve its fluidity, slumpability and the settling of debris/wear metals to the bottom of the gear cases. This reformulated softer grade, a semi-fluid grease, has been performing satisfactorily for more than eight months and is still undergoing longer term assessment."

Jan 1, 1996

By K McSweeney, A Marton

This paper discusses the development of a strategy for ensuring long-term geotechnical stability of final pit walls at AngloGold AustraliaÆs Sunrise Dam Gold Mine. The strategy makes use of improved blasting techniques, changes to the mining sequence and other geotechnical techniques. Only the blasting techniques will be discussed in this paper. These were developed from numerous trials over a period of several months from May 2003 through to November 2003. The focus was to reduce crest loss damage and thereby improve final wall integrity, maintain designed safe berm widths, and ensure long-term stability. Crest loss mechanisms are now understood and are explained in this paper. The preferred solution is outlined; which is a combination of improved blasting and changes in the mining sequence to cater for pre-existing ground conditions. These ground conditions include dynamic hyper saline water with sometimes intersecting steeply dipping discrete structures. Project requirements were defined as mitigating or eliminating crest loss using 127 mm diameter pre-splitting and targeting minimal production blasting vibration levels against the walls. Blast results were measured by post blast visual inspections and video. Blast design input utilised the predictive algorithms built into simulation software when attempting to minimise vibration levels against the walls. Protection of the already fired pre-split line is now achieved using small charges against the wall and timing sequences which form a mask for the later firing main charges. The pre-split spacing is now modified to suit the geology. There eight blast domains identified around the perimeter of the pit, each having varying joint orientation. In addition, blasting the bench adjacent to the berm crest has particular considerations not required by the middle and lower benches. The preferred solution was to purposefully translate this damaged top section of the pre-split bench into a planned subsequent dig zone. The design of this top æweightÆ is a direct response to the nature of the crest loss mechanism.

Jan 1, 2004

By Robert Small, Amshu Chappa, Ihab Allam

The Biosolids Digester Facilities Project (BDFP) is located in southeast San Francisco. The jobsite is bounded by active Caltrain and Union Pacific Railroad tracks on the west side and the existing Southeast Treatment Plant (SEP) on the north, south and east sides. The existing SEP was constructed in the 1950s and portions of the facility have reached their operational life. The $2 billion BDFP will replace and relocate the outdated existing solids treatment facilities with more reliable, efficient and modern technologies and facilities. In addition, the nearby Bayview and Hunters Point neighborhoods will benefit from the improved odor control. MWH/Webcor, a joint venture, as the construction manager general con- tractor (CMGC) for the project. As part of an alternate delivery method set forth in the prime contract, the CMGC was permitted to propose the use of a core trade subcontractor partner for the SFPUC's approval to provide precon- struction services. The CMGC identified three major scopes (electrical, mechanical and foundation) where a core trade partner would be able to assist

Jan 1, 2023

By W. Carter, P. Chaubal, K. Spaleck, M. Schoeman, J. Bobek, W. Seegers

Keywords: Pyrometallurgy, steel, hearth, blast furnace The Mittal Steel Company operates about 36 blast furnaces on four continents. Furnaces range from 1100 m3 to 4800 m3 inner volume. The focus of the group is to push for increasing productivity and increasing campaign life. This has been especially challenging, as many of these furnaces were not equipped for long campaigns during their prior rebuilds. Monitoring and operating practices have to be modified to match the new philosophy. Mid-campaign hearth repair strategies and hearth design philosophies have had to be reconsidered. The paper describes experiences with the current hearth designs and measures taken for hearth life extension. Additionally, the philosophy of recent hearth re-designs is discussed.

Jan 1, 2006

The propensity of coal spontaneous combustion can be evaluated using various laboratory testing methods such as R70 adiabatic tests, thermal gravimetric analyzer (TGA) and critical self-heating temperature (CSHT) methods. Each of the methods has its unique characteristics and index for classifying the propensity of self-ignition of coals. Accountable relationships among the propensity indices of different methods should be established. Using the newly established R and TGA testing setups in our ventilation laboratory, samples from US coal mines have been collected and tested. 70 The TGA is a relatively new quantitative method. A test can be conducted in a relatively short time. The temperature and weight of the sample can be measured with high precision and then used to determine the activation energy of the coal which is a good indicator for potential of self-heating. Under a specific experimental design, the TGA technique could perform the proximate analysis for determining coal quality parameters (e.g., moisture, volatile matter, fixed carbon and ash content). These parameters can be used in an empirical equation for assessing the potential of coal self-ignition. The trend of activation energies determined using TGA techniques and adiabatic tests are reasonably consistent with each other. As a case study, a comparative analysis of these two methods for determining activation energy was made on coal samples collected from Indiana. The kinetics of the spontaneous combustion mechanism has been explained. If the functional groups of a coal are easier to be activated with a small amount of activation energy at a relatively low temperature, the coal will has a higher potential of self-heating. With the kinetic and coal quality parameters determined by the TGA setup, it has been found that the coal with low potential of self-ignition has low self-heating rate, high activation energy and high minimum self-heating temperature.

Jan 1, 2012

By Les A. Beckett

The Bureau of Mines has developed MULSIM/BM, an improved computer program using the boundary-element approach for geomechanical analysis of mine plans in single or multiple coal seams. This Information Circular presents the improved features of the MULSIN/BM program. The four major improvements are the following: (1) Ability to specify up to 26 material property sets. (2) A new material model capability for gob and inserted materials such as packwalls or cribs. (3) Ability to model a large area with a grid of undivided blocks and to subdivide only a specified fine-mesh portion of these blocks into elements. (4) Specification of extraction ratios for the undivided blocks. In addition, an interactive graphics mesh generator program was written to accompany MULSIM/BM. A complete user's guide and program listings are included within the appendixes. The MULSIM/BM and mesh generator programs are available on tape from the National Technical Information Service.3

Jan 1, 1988

By A. Qaredaqi, M. Mohammadi

Wet High Intensity Magnetic Separators, for short, WHIMS are used for recovery of Iron ores with low magnetic susceptibility. A Jones patent WHIMS with "grooved plates" matrix is being used in Dry Tailing processing line in Hematite Recovery Plant at Golgohar mining & Industrial Co. for recovery of Hematite. In this kind of separators Matrices are used for increasing the Magnetic field intensity and providing high magnetic field gradient. The laboratory WHIMS in Golgohar Iron Ore and Steel research Institute is capable to provide a background magnetic field strength up to 0.85 Tesla and in presence of ‚expanded metal? matrix, magnetic field intensity could increase up to 0.9 Tesla. More than 50% of feed particles in this separator were finer than 36 micron and recovery of these particles needs more magnetic field intensity. Hence, ‚Grooved Plates? matrices with Js= 2 Tesla and 3.8 mm gap were constructed. Measurements indicated that magnetic field intensity around the matrix will increase to 1.25 Tesla. Graph of Magnetic field intensity around the matrix to background magnetic field intensity was plotted and a model with Rsquare= 0.9 was offered. In addition, magnetic field gradient and magnetic force were calculated. In WHIMS with feed top size of 150 micron, the main effective forces on separation process are the magnetic force and the hydrodynamic drag force. With assuming that the particles are smooth and spherical and the flow is laminar, Recovery of fine magnetic particles is problematic in this separator because of drag force. Considering these facts and mentioned model, finest particles that are recoverable in different magnetic field intensities were calculated. Computations illustrated that with magnetic field intensity more than 0.8 Tesla, particles as fine as 4 micron are theoretically separable but it should be noted that in practice a larger attractable particle size would be expected.

Jan 1, 2014

By R. T. C. Rasmussen

"INTRODUCTION The primary purpose of the Bureau of Mines electrolytic manganese pilot plant at Boulder City, Nev., is to improve the Bureau-invented electrowinning process and to determine the applicability of the process to the extensive domestic low-grade manganese ores with a view to making the United States dependent upon foreign sources of manganese. 3/4/ Incidental to accomplishing this purpose, the pilot plant has produced a substantive quantity of electrorytic manganese since the start of operations late in 1941; present cabacity about 1 ton a day of manganese metal. A second important purpose of the pilot plant is the supplying of electrolytic manganese for full-scale tests in cooperation with industrial users of manganese.The Rustless Iron& Steel Corp., Baltimore, Md., was the first steel company to cooperate with the Bureau of Mines in large-scale testing of electrolytic manganese. Arrangements were made with C. E. Tuttle, then president of the corporation, whereby the Bureau would supply electrolytic manganese to make a sufficient number of full-scale stainless-steel heats to demonstrate thoroughly its merits as a replacement for low-carbon ferro-manganese in the corporation's stainless-steel practice. The corporation's purpose in the investigation was to determine the possible advantages of electrolytic manganese resulting from its almost complete lack of phosphorus and caroon that might offset its then considerably higher cost per unit of manganese than low-carbon ferromanganese. The data presented herein are based upon reports of A. L. Field, technical director, and L. Weitzenkern, research engineer of Rustless Iron & Steel Corp.; they are supplemented by observation of the author who visited the plant during the tests."

Oct 1, 1945

By Innocent John Arinze, Chidubem Okwudiri Emedo

This contribution presents the first multi-scale geophysical investigation conducted in the Abakaliki and Obubra mining districts (AOMD), southeastern Nigeria, for the exploration of shallowly emplaced (< 50 m) massive sulfide and barite mineral deposits. Raw airborne magnetic data covering the AOMD was acquired and subjected to diverse enhancement routines to facilitate the identification of areas of subtle magnetic anomalies for subsequent ground truthing. The mineralization is mainly made up of galena, sphalerite, and barite. The contrasting physical properties between these minerals and their host rocks make resistivity, induced polarization (IP), spontaneous potential (SP), and magnetic methods ideal to study and delineate the mineralization and possibly locate the ore bodies. Wenner DC resistivity and IP data acquired along the same parallel traverses are inverted using Res2dinv to produce 2D tomography models of resistivity and chargeability. The resistivity and IP models were successful in delineating zones of sulfide and barite mineralization. The ground SP data collected along the same traverses as the resistivity and IP data were interpreted as line graphs. The 1D SP models show a number of central negative anomalies that could be related to sulfide mineralization. These anomalies show fair-to-good spatial continuity and are in close agreement with the result obtained in the resistivity and chargeability model. This study suggests the presence of exploitable mineral deposits in the AOMD and demonstrates the superior interpretative ability of combined geophysical methods over a single geophysical approach.

Oct 20, 2020

By Douglas D. Donald

The New Jersey Zinc Co. successfully holed through a 2 1/2-mile haulage tunnel connecting its new Ivanhoe shaft with the Van Mater Shaft at Austinville, Va. This 8x 10-ft cross-section tunnel was driven from both ends and met at a point approximately a mile from one shaft and a mile and a half from the other. In order to make certain that the faces met accurately on line and grade it was necessary to refine conventional mine surveying practices. The mines that are serviced by these shafts are located in the southwestern part of Virginia approximately midway between Roanoke and Bristol at the west foot of the Blue Ridge. While the presence of lead-zinc sulfide ores has been known in this area for more than 200 years, it was in 1902 that New Jersey Zinc Co. acquired the Austinville property, which has been in constant operation since that time. About ten years ago the company undertook an extensive diamond drilling program at Ivanhoe several miles to the southwest. This program was successful in locating sufficient ore to justify the purchase of a number of the properties in this area and plans were made to develop the new orebodies. The discovery of this ore as well as substantial addi- tional reserves at Austinville resulted in a decision by the company to increase its daily milling capacity to 3000 tons, of which about 1000 tons would be supplied from the Ivanhoe mine. After careful consideration of all possible methods of transporting this volume of ore from Ivanhoe to the mill, it became evident that diesel locomotive haulage through a 2½-mile tunnel between the two mines would best suit prevailing conditions. Since the lowest operating level, known as the 1100 level, of each mine would be at approximately the same elevation, it was obvious that such a tunnel should be driven on this level. Not only would this tunnel facilitate feeding Ivanhoe ore into the underground crusher and skip loading installation at Austinville, but it would also open up a known orebody 5000 ft southwest of the Van Mater shaft. In addition it would provide a valuable diamond drilling base from which a large and a potentially favorable but untested block of ground might be explored. In order to hasten the completion of the tunnel, it was felt that it should be driven from both ends. ENGINEERING CONTROL PROCEDURES It was vital that the tunnel junction be made accurately on line and grade; thus it was felt that engineering control of an unusually high degree of reliability was required to prevent an accumulation

Jan 1, 1959