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By Neusa Alonso-Falleiros, Aristeu Braz da Veiga, Marcelo B. Mourão, Adriano Pescarmona, Antonio Alberto Froes Schettino, Cyro Takano, Carlos A. S. Giraldo

"The Caron process of nickel extraction from lateritic ores produces a fair amount of an inert residue, the so-called “black sludge”, that is disposed in a dam according to the required environmental regulations. On the other hand, it represents an opportunity to resource recovery. This work presents the characterization of the residue, discusses some possible ways to recover the valuables, and presents experimental results of pyrometallurgical runs aimed at recover nickel as an iron-nickel alloy. It has been shown that the residue contains large amounts of silicon, iron, aluminum and magnesium, in the form of oxides and silicates, and small quantities of nickel, cooper and cobalt, besides several other elements. It has also been shown that gravimetric or magnetic concentration methods do not present promising results. On the other hand, it is possible to obtain iron-nickel alloys by high-temperature carbothermic reduction of the “black sludge”.IntroductionThe Caron process consists of a combined pyro-hydrometallurgical process to extract nickel from high iron limonitic lateritic ores, recovering also the cobalt present in the ore. The main steps are the reduction roasting of the ore, aiming at a selective reduction of nickel and cobalt to the metallic state, avoiding as much as possible iron reduction, followed by leaching with ammonium carbonate solution and the recovery of metal from the pregnant liquor [1,2]. As a result, significant amount of tailings are generated, that are disposed in appropriate dams. This residue, called “black sludge”, contains significant proportion of silica and iron, and also small amounts of nickel, cobalt, cooper and some other elements. Due to diminishing deposits of nickel ore, high metal prices and a significant amount of “black sludge “ available after several years of operation of the plant, Votorantim Metais, who operates a facility in Brazil that uses the Caron process, decided to explore the possibility of recover nickel from the residue. This paper presents the characterization of the residue, and the results of experimental work aiming recovery of nickel from it."

Jan 1, 2008

By R. D. Currie

Many coal companies have a system for checking men into and out of the mine , and generally such systems appear to be perfectly sound and adequate . However , when the real test comes at the time of a mine disaster , too often the system is found to have failed , and hours and sometimes days pass before it is known how many men are in the mine and who they are . Most of the systems in use , when properly maintained , are adequate for the routine work of the mine , and some of them may prove adequate at the time of a mine disaster . All systems , however , depend upon proper supervision and strict adherence to the system .

Jun 1, 1930

By J. Aravena, S. Gajardo, M. Ayala, P. Salinas

Both, Teck Carmen de Andacollo (Teck CDA) and Orica, work hard in the implementation of new technologies available in the explosives industry and drilling and blasting techniques, with the objective of sustainable development of their operations, regeneration, and protection of the environment, also considering the welfare and relationship with the surrounding communities. The open-pit Carmen de Andacollo mine is located adjacent to the town of Andacollo. Therefore, both companies together have developed the implementation of different techniques and technologies to mitigate the impacts of mining operations in the community, considering an important part of this challenge to minimize the impact of their perception of blasting by reducing the level of vibrations and sound pressure (airblast), in addition to the control of dust and smoke, strengthening sustainable production in harmony with communities. The technologies and techniques that have been implemented are the installation of airblast and vibration monitoring stations stands out, whose database has records since 2011. Using the vibration database, different models were developed to predict the vibration level of blasting in its design phase, achieving a difference of 4.1% between the estimated and measured values in the last year. Two techniques stand out to minimize the ejection of material, "Hydraulic Dome" and "Dual layer blasting", the first consists of water irrigation on the surface to be blasted and the second is an unconventional blasting technique, which was awarded in 2015 for its results in the environment. Also pre-splitting engineering has been modified in a positive evolution, where through different configurations, the airblast has been reduced by 15% compared with records from 2011 to 2022. Finally, due to the impact of operational restrictions, such as days available to blast, number of holes, and powder factors, the wireless initiation technology was implemented, which allowed reducing the limitations in the loading, generating an improvement in terms of blasted materials over conventional systems. Understanding the restrictions and challenges in terms of impact on communities, the correct implementation of all these techniques is important, and in conjunction with collaborative work, it has been shown and validated that producing in a sustainable and sustainable manner is possible.

Jan 1, 2024

By William A. Apel

Several different strains of bacteria have been shown capable of reducing hexavalent chromium, Cr(VI), to Cr(III), a less toxic, .. more readily recoverable form of Cr. This paper examined the Cr(VI) reduction efficacies of 3 different Cr(VI) reducing bacteria: Pseudomonas f1uorescens LB300., Pseudomonas aeruginosa PAOI, and Pseudomonas aeruginosa PAOI (pCROI) It was demonstrated that all three bacterial stratns reduced Cr(VI) primarily during their exponential growth phases while using glucose as their carbon and energy source. Significant differences in the three organisms' Cr(Vl) reduction capabilities depending on initial Cr(VI) concentrations were also demonstrated. P. aeruginosa PAOI showed superior Cr(VI) reducing capabilities over the. entire range of Cr(VI) concentrations tested while the Cr(VI) reduction capabilities of the other two strains were increasingly inhibited as Cr(VI) concentrations increased.

Jan 1, 1991

By Jun Deng, Daohong Wu, Zhicheng Cao, Jingkun Tang, Luxing Feng, Xun Xue

The effect of reducing temperature, H2/CO mole ratio, and reduction gas flow rate on the metallization rate of oxide pellets were investigated at laboratory scale, with ludwigite iron concentrate used as raw materials. The reducing temperature varied from 850 to 950 °C, the H2/CO mole ratio changed from 1.5 to 4.5, the range of reduction gas flow rate was from 2 to 5 L/min. The results indicate that the metallization degree of pellets increase with increase of the temperature, H2/CO mole ratio, and gas flow rate. However, after temperature rises to 850 °C, metallization degree increases slowly. The effect of H2/CO on the metallization degree is not very obviously with the ratio of H2/CO increasing from 1.5 to 4.5. When the gas flow rate was increased from 2 to 3 L/min, the metallization degree increased greatly from 72.2 to 92.1%. In the flow range from 3 to 5 L/min, the metallization degree was increased slowly. The results obtained could be useful for comprehensive utilization of ludwigite iron concentrate by gas-based direct reduction method.

Mar 1, 2017

By Wilbert McBride

Two Alco 3 ½ -ton motor trucks were used by Young Bros. while operating at the Mammoth Collins mine at Shultz, Ariz. One was equipped with an oil tank holding 1,075 gal. and was used for the transportation of "tops." The, other was fitted with a stake body and used to carry machinery, wood, rails, pipe and all classes of miscellaneous supplies. The bodies were made of oak with maple flooring and were attached to the frame of the chassis by U-bolts, to avoid drilling the main members of the frame. Most of the hauling was done from Tucson, a distance of 47;2 miles. During the first. 3 months, part of the road was in very bad condition and the tire cost was excessive. After this part was repaired the road was in fair condition, but never good. There were no excessive grades or bad sand, but wagon ruts, too narrow for the truck wheels and of a different gage, caused heavy tire loss; while chuck holes, sharp curves and stones, both imbedded and loose, were objectionable features. During wet weather the trucks could not get sufficient traction to climb some of the hills and were likely to stick in the mud in certain places, so that no attempt was made to run them unless they were on the road when the rain started. This lost time amounted to about 5 per cent. of the total, but, whenever possible, it was utilized in making minor repairs. The price of gasoline, was from 17 to 21 c. per gal. Rubber tires were used throughout. Drivers were paid $4.50 to $5 per shift, and a return trip to Tucson was counted as two shifts even when made in one day. Drivers were provided with a room in Tucson and were paid for all time lost due to causes beyond their control. Trucks were loaded one way only.

Jan 7, 1916

By Kirk A. Mcintosh

Augered, cast-in-place (ACIP) piles have been utilized in the United States for a wide range of projects since the 1950's. Due to the cast-in-place nature of the installation method (and lack of a driving criteria); however, ACIP piles have not been readily accepted by some practicing geotechnical and structural engineers. Since ACIP piles were initially developed, the installation equipment and techniques have been improved and refined and the number of experienced contractors has significantly increased. Over the past 10 to 15 years, the pile type has experienced significant growth in the United States (particularly in Florida) because engineers have become more knowledgeable and comfortable with its use. The Miami area, in particular, has experienced considerable growth in the utilization of ACIP piles primarily due to their usage on the $1 billion Miami Metrorail System project in the early 1980s. The economic advantages over other deep foundation types, coupled with some unique installation advantages, have shown that ACIP piles can be a viable foundation alternative on many projects. Even though ACIP piles have gained respect in the private sector, the pile type has generally not been readily accepted by government transportation agencies. The reluctance to readily accept this foundation type stems primarily from the quality assurance aspect of cast-in-place pile construction. Additionally, there has not been much research activity on this foundation type, technical papers, formal associations (other than the DFI), or a concerted effort to standardize the industry. This paper serves to discuss the state of practice for ACIP pile installation in the state of Florida.

Jan 1, 1997

By Vernon Helm, John S. Ball, Welton J. Wenger, William E. Haines

"INTRODUCTION Although the presence of sulfur causes many petroleum’s to be classified as ""low-grade"" because of the difficulties encountered in manufacturing products to meet rigid specifications, the petroleum industry is finding it necessary to use such crude oils to satisfy present needs. As the demand for petroleum products increases, and available reserves diminish, this utilization of high-sulfur crude oils will be accentuated. Programs designed to supplement the supplies of fuel available from petroleum by the manufacture of synthetic fuel from natural gas, shale oil, and coal are in progress. Such fuels, especially shale oil and, less so, oil from the hydrogenation of coal, also contain sulfur compounds which must be effectively removed. Thus, the need for fundamental research on the sulfur compounds that may be expected in petroleum and allied products is becoming greater as the industry is forced to call upon all available resources to meet the demand for petroleum products. In recognition of this need, the Bureau of Mines has inaugurated a long-range program assigned to furnish fundamental data concerning the presence, characteristics, and effects of sulfur compounds in petroleum and its products."

Dec 1, 1946

By C. H. Stockwell

"The Precambrian rocks of southeastern Manitoba contain a great variety of mineral deposits, including gold, chromium, copper, nickel, lithium, tin, beryllium, tungsten, and molybdenum. Although considerable interest has been shown from time to time in each of these types of deposit, production to date has been almost entirely in gold. This has had a value of about $26,000,000 and has been derived chiefly from the San Antonio mine, with lesser amounts from the Central Manitoba, Gunnar, Beresford Lake, Ogama-Rockland, Diana, and other properties.Most of the deposits lie within volcanic and sedimentary rocks or within basic intrusions cutting these rocks. These favourable rocks occur in several areas, which have been given local names and are separated from one another by large bodies of granite (Fig. 1).In general, the several areas are characterized by different types of mineralization. Thus, the Rice Lake-Beresford Lake area contains numerous gold deposits and has yielded almost all the gold production to date; the Maskwa River, Euclid Lake, and Oiseau River areas are, on the whole, characterized by deposits of chromium, copper, nickel, lithium, tin, and beryllium; and in the West Hawk Lake area there are deposits of gold, tungsten, molybdenum, and lithium.As might be expected in a district containing such a variety of mineral deposits, the structural conditions controlling their deposition also vary greatly. It is, accordingly, convenient to discuss the structural geology and mineral deposits of each of the more important areas separately."

Jan 1, 1954

By Morris B. J

Soil air samples taken from the top one metre of the soil profile, were measured for C02 and 02 using portable field analysers at a number of sites of known sulphide mineralisation in South Australia. Carbon dioxide anomalies were detected over actively oxidising sulphides during autumn and winter following recent rainfall. Anomalies were not detected where no oxidation was occurring, where seasonal conditions had been very dry, or where the sulphur content of the ore was low (

Jan 1, 1993

By M. D. Carver

The purpose of this investigation was to determine the effects of variations in content (near the residual level) of the impurities aluminum, nitrogen, manganese, and copper on the corrosion rate in pressurized hot water and in pressurized steam of zircaloy-3, a zirconium-base alloy of 0.25 percent tin and 0.25 percent iron. Thirty-five 10-pound ingots were cast with the appropriate additions of impurity elements, and these were converted to wrought sheets. These specimens were then tested both in water and in steam. The analysis of the resulting data showed that in environments of either pressurized hot water or superheated steam, corrosion rates increased with increasing content of aluminum, nitrogen, or manganese, but were not affected by variations of copper. The effects of aluminum and nitrogen were found to be greater than the effect of manganese. INTRODUCTION At the request of the Atomic Energy Commission (AEC) in August 1956, the Federal Bureau of Mines, in cooperation with Bettis Plant of Westinghouse Electric Corp., began investigating the effects of certain impurity elements on the corrosion rates of zircaloy-3 in pressurized hot water and in pressurized steam. It was necessary to know these effects in order to set control limits on residual impurity levels in zirnaloy-3, intended for heat transfer service in the nuclear reactor of the pressurized water type. A factorial expert it was designed by Westinghouse statisticians. The Atomic Energy Commission provided raw zirconium sponge purchased from Wah Chang Corp. The Bureau's laboratory at Albany, Oreg., made material of different combinations of impurity levels and subjected the material to corrosion tests. This report will describe the work done at the Bureau laboratory and will show, quantitatively the effects of different residual levels of aluminum or nitrogen, or manganese or copper on corrosion rates.

Jan 1, 1961

By M. A. Bartkoski

Today?s surviving companies are being pushed to a heightened level of excellence due to market changes. Therefore, new business strategies must be explored. This paper offers a sequenced plan to retool, empower, and organize the entire team for a common goal. Integrity Process is an operating system that is very comprehensive and is integrated in every part of the business. It relies on a detailed prevention concept intertwined with accountability that produces individual efficiencies and team effectiveness. Integrity Process focuses on the importance between working from commitment motives versus compliance fears. The results are balanced in priority and truly yield a win-win for the owners, management, workforce, and the community. Integrity Process can and is being used in any industry that is challenged to optimize the relationship between people and process.

Feb 23, 2014

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Jacob T. Wainwright

This stove has been designed to meet the requirements of a fur nave that must be operated with either a reducing or a neutral flame ; and more particularly to make feasible the operating of re duction-furnaces with the cheaper grades of gas-fuel, which has heretofore been impracticable. In general, cheap gas-fuels result from incomplete combustion, and, being suited for further combustion, answer very well for heat ing purposes; and high temperatures may be attained with them, when they are used in conjunction with regenerative stoves. But, in operating a reduction-furnace, a high temperature is not the only requirement. It is also necessary that the fuel shall not be cansumed beyond a certain degree, in order to insure a re ducing flame for the reduction-process ; consequently, it becomes necessary to dispense with combustion as much as possible previous to the use of the fuel-gases in the reduction-furnace. Moreover, these gases must be preheated to a high degree, in order that a sufficient temperature may be maintained in the furnace; and, since this preheating cannot be accomplished by a previous, partial combustion of the gases themselves, it follows that the stoves for pre heating these gases should be heated to as high degree as it is pos sible to attain with an inferior fuel. This result can best be accom plished by complete combustion of the heating gases, and is further facilitated by preheating all of the air and gas used for this com plete combustion. It is more particularly desirable to preheat the air, since the combustible gases used may generally be obtained directly from the furnace, or gas-producer. The reducing gases, escaping from a gas-fuel reduction-furnace, are capable of considerable further dilution with air to secure com plete combustion, and consequently may be utilized for heating the stove to a high temperature, provided the air be sufficiently preheated.

Jan 1, 1889

By Lingzhi Yang, Feng Chen, Yufeng Guo, Tao Jiang, Zeqiang Xie

Zinc ferrite (ZnFe2O4), one of the major forms of zinc in Electric Arc Furnace (EAF) dust and zinc leaching residue, is very difficult to chemically dissolve in either acidic or alkaline solutions. In spite of the zinc resources in the Electric Arc Furnace (EAF) dust and zinc leaching residue are abundant, there is no mature utilization technology. This situation not only causes the waste of resources, but also produces the harm to the environment. In the paper, the basic principle of this process has been established by revealing the phase equilibria in the CaO–Fe2O3–ZnO system, where Ca2Fe2O5 can be in equilibrium with ZnO rather than ZnFe2O4 at higher CaO region. It has also been demonstrated that the formed ZnO can be solved by ammonia-leaching and Ca2Fe2O5 keep in solid residue, which can be used as a flux for steel refining.

Mar 1, 2017

By Shihan Zhang, Qingguo Xue, Jingsong Wang, Yaxing Du, Guang Wang

The rotary hearth furnace iron nugget process is in line with China’s energy and resource condition. It has the advantages of short reaction time and high quality iron nugget. The fundamental study on the novel ironmaking process is meaningful. Based on CaO-SiO2-Al2O3-FeO quaternary slag system, the effects of slag basicity and Al2O3 content on the melting of slag were studied. Using the iron concentrate as raw material, the effects of different slag basicity and Al2O3 content on the reduction and melting separation behaviors of carbon composite pellets, such as the starting temperature of melting separation and the morphology of melting separation were studied. Then, the relationship between the properties of slag and melting separation quality was established, which could provide standard for the selection of iron ore for the rotary hearth furnace iron nugget process.

Mar 1, 2018

By Pinar Eksert, Hakan Akcin

Investigations show that injuries and fatalities in mining workplaces in developing countries are increasing. In Turkey, the number of workers killed in occupational accidents in the Zonguldak Hard Coal production region per 100,000 tons of coal production is 2.83 in the private sector and 2.03 in the public sector. For this reason, it is important to conduct risk analyses in terms of occupational health and safety and to implement measures quickly. Risks are evaluated with reactive and proactive approaches. Because hazards and events are often unpredictable in high-risk areas such as coal mining, it is not practical or meaningful to plan proactively in advance for every possible situation underground, especially psychosocial risks. However, it is important to develop protective strategies and measures for unexpected events or to take a reactive approach to prevent future incidents or accidents and to identify psychosocial risks. Therefore, reactive risk assessments based on the tactics and strategies of criminology can be conducted and spatiotemporal geographic information system (GIS) techniques can be utilized, enabling managers in mining workplaces to correct assessments.

Oct 1, 2024

By F. R. McDonald

The proton NMR spectra of 32 pyridines in two solvents, carbon tetrachloride and benzene-d6, are presented. The chemical-shift and differential-shift values are correlated with the substitutent position and with the solvent media. The ring protons and the protons on alkyl substituents are tabulated. The paramagnetic shift of the protons adjacent to the nitrogen is discussed, and a proposed structure for the pyridine-benzene complex that is consistent with the observed anomalous paramagnetic shift is presented. The utility of the data in the identification of pyridine compounds found in shale-oil naphtha is demonstrated.

Jan 1, 1971

By Enver Alan

This Research & Development (R&D) study was conducted in the field of applied blasting engineering in Ethiopia, within the AKH Railway Project, which was built in Girena, within the boundaries of the province of Mersa, in the Basalt Quarry at km 346, Ashangi Formation, occured in Eocene geological time in the aphanitic trachibasalt. Under the scope of the study, which has been performed to determine the effects of the artificial discontinuities at different depths and the effects of artificial discontinuities through structural damage risk, three test areas, at the same location and same formation, were considered. Six numbers of artificial discontinuities, each 10 m (32, 81 ft) transverse, were created by using pre-splitting and drilling-blasting technology. The number of sequential artificial discontinuities on each test area is two and they have the same length. The length of artificial discontinuities are; 6,80 m (22,31 ft) at the first test area, 13,60 m (44,62 ft) at the second test area and 17,00 m (55,77 ft) at the third test area respectively. The distance between sequential artificial discontinuities is 8 m (26,25ft) on each test area. Thirty-one shots were executed in order to produce vibration (10 shots on the first test area, 11 shots on the second area, 10 shots on the third test area). One hundred and twenty-three seismic recordings were obtained during the execution of the shots by using 4 seismographs. The closest distance between the shot points and the nearest measuring station is 5,30 m (17,39 ft). During the shots, the rock was cracked and there was no fragmentation and/or fly rock. At the first test area, measured PPV values are between 25,40-127,00 mm/s (1-5 inch/s) before the first artificial discontinuity and less than 50,80 mm/s (2 inch/s) after the second artificial discontinuity. At the second test area, measured PPV values are between 76,20-177,80 mm/s (3-7 inch/s) before the first artificial discontinuity and less than 76,20 mm/s (3 inch/s) after the second artificial discontinuity. At the third test area, measured PPV values are between 50,80-279,40 mm/s (2-11 inch/s) before the first artificial discontinuity and less than 50,80 mm/s (2 inch/s) after the second artificial discontinuity. Peak reduction rates in Peak Particle Velocity (PPV) values determined by measuring as follows: In the first test area 95,77% (106,00 mm/s to 4,48 mm/s) (4,17 in/s to 0,18 in/s), in the second test area 79,77% (176,00 mm/s to 35,60 mm/s) (6,93 in/s to 1,40 in/s), in the third test area 95,85% (from 205,00 mm/s to 8,55 mm/s) (from 8,07 in/s to 0,34 in/s). The arithmetic mean of the differences of PPV values (decrease rate) is 82,66% in the first test area, 69,37% in the second test area, and 92,03% in the third test area. The highest sound value is 138,50 dB and is defined as “noise”. When the measured parameter values are examined it was determined on the USBM norm graphs that these vibrations carry a risk of structural damage in the region before the first artificial discontinuity. While passing through artificial discontinuities the vibrations progress by losing energy and the vibrations passing through two artificial discontinuities do not carry structural damage risk under current conditions.

By J. H. Zietsman

It has previously been observed that industrial high-titania slags display a compositional invariance, remaining close to stoichio-metric M3O5. The present study focuses on this invariance and the phenomena which may cause it. The invariance was studied using thermochemical calculations and a mechanism is proposed for the observed behaviour. The mechanism suggests that a combination of thermochemical equilibrium and transient slag solidification and melting results in the observed compositional invariance. The proposed mechanism provides new insights and prompts questions about other mechanisms in the smelting process.

Jan 1, 2004