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By J. T. McCartney

"INTRODUCTION The surface areas of the finest fractions of a pulverized material are disproportionately larger than their weights. For instance, Pesrott and Kinney 3/ showed that, in a sample of minus 200-mesh coal, particles that are about 2 microns in diameter represent 15 percent of the entire surface area but only 1.5 percent of the total weight. Because the sur- face area is the dominating factor in the behavior of finely divided materials in many practical processes, the role of the finest particles is of great importance. The oxidation and combustion of pulverized coal, both in the dry form and in suspension in oils, and the hydrogenation to fluid hydrocarbons of mixtures of pulverized coal and heavy oil are reactions in which the surface area of the coal particles has considerable influence. This investigation of the size distribution of fine coal particles was conducted with the hope that such processes would thereby be better understood. The results should also be of value in the study of the crushing and fracture of coal."

Sep 1, 1945

By Alfred Weiss

Over the past 25 years hard-rock mining companies have developed a number of profitable computer applications which appear applicable to operations in the coal industry. The evolution of these applications are described and the most profitable discussed. The basic nature of these systems is that they must cut across organizational boundaries. While technological advances contributed significantly to the successful implementation of computers within mining, the human aspects related to organization, management and control of systems projects remain as key to future success in coal as they were and still are in hard-rock mining.

Jan 1, 1983

By D. Mills, G. B. Craig

ZIRCONIUM has been float-zone-refined in an electron-beam furnace and the redistribution of oxygen, iron, and tungsten has been measured. The iodide zirconium used in the present experiments initially contained both oxygen and iron in the range 100 to 200 ppm by weight, and tungsten in amounts less than 10 ppm. Float-zone refining of zirconium, using induction heating, has previously been attempted by Kneip and Betterton1 and Langeron.2 Kneip and Betterton were primarily interested in the removal of iron and nickel. They achieved some purification, with respect to both these elements, in material given up to six passes at 150 mm per hr under an argon atmosphere. Langeron reported purification for a large number of elements after four completed passes in a static vacuum system operating at pressures less than 10-6 mm of Hg and with rates of zone travel between 30 and 40 mm per hr. He did not report oxygen concentrations, but stated that there was inverse segregation of this element. westlake5 has also used a minimum of four zone passes to remove iron from zirconium. No rates or conditions were given. Belk6 has shown that tungsten contamination can occur during electron-beam melting. He reported an increase from 0.01 to 0.05 pct by weight tungsten in molybdenum after four complete zone passes. The vacuum system for the electron-beam unit used in the present investigation consisted of a single-stage rotary pump backing a liquid-air-trapped oil-diffusion pump. A pressure of less than 10-8 mm of Hg was obtained with Dow-Corning 705 fluid in the diffusion pump. In order to avoid contamination of the zirconium by evaporation from the tungsten filament, a special focusing cage4 was employed. Three rates of zone travel, 114, 38, and 4 mm per hr, were investigated, with the liquid zone moving from the bottom to the top of the bar. The bars used were 3 mm diam and the total melted length was 130 mm. Oxygen was analyzed by neutron-activation analysis using a neutron flux of 10' neutrons per sq cm per sec to form the isotope N16 by the 016 (n,p) N16 reaction. The standard deviation is quoted for each oxygen determination. The iron and tungsten analyses were performed spectrographically, and the precision is estimated to be ±6 pct. Analyses for tungsten were all below the detectable limit of 10 ppm, confirming the protection given by the focusing cage. No significant redistribution of oxygen was found at the two higher rates of zone travel. The redistribution of oxygen and iron obtained after five passes at a rate of zone travel of 4 mm per hr (1.1 x 10-4 cm per sec) is recorded in Tables I and 11. Burris, Stockman, and Dillon3 have estimated the distribution of solutes during multipass zone refining. Using their curves for an effective distribution coefficient of Keff = 1.5 and 2 for oxygen and Keff = 0.3 for iron, the expected concentrations were estimated for the present material. These are shown in Tables I and 11, along with the experimentally measured values. The calculated concentrations are based on a molten-zone length of 10 pct of the total melted length, whereas in the present experiments the molten zone was approximately 5 pct of the total melted length. The effect of zone length on solute redistribution is most pronounced after a large number of zone passes. Comparison with Pfann's published data8 for solute redistribution for various Keff's and zone lengths indicates only small differences at low numbers of completed zone passes. It is evident that the expected distribution has not been realized in the case of iron. Scrapings of material deposited on the inner surfaces of the electron-focusing cage were found to be magnetic. It is, therefore, concluded that redistribution of iron is masked by evaporation. Deposition of iron inside the focusing cage was observed at all rates of zone travel. The results of the investigation may be summarized as follows: 1) Segregation of oxygen is typical for a solute with a distribution coefficient, Keff > 1. 2) No redistribution of oxygen takes place at high rates of zone travel. 3) The distribution coefficient for oxygen lies between 1.5 and 2.0. 4) Purification with respect to iron occurs mainly by evaporation. 5) The focusing cage is effective in preventing tungsten contamination.

Jan 1, 1967

Vanadium, molybdenum, and a titanium-10 percent vanadium alloy were evaluated for their susceptibility to stress corrosion cracking in a number of corrodents. Tests were conducted utilizing conventional U-bend techniques with subsequent evaluation in a pneumatic constant-load apparatus. Vanadium and molybdenum were generally resistant to stress corrosion cracking in the media studied. U-bend specimens of vanadium showed evidence of stress corrosion cracking in 6 li hydrochloric and 18 li sulfuric acids; however, tensile stress specimens exposed to these solutions did not exhibit stress cracking. Similar results were obtained when U-bend specimens of molybdenum were immersed in 10 percent formic acid. Titanium-10 percent vanadium alloy was susceptible to stress corrosion cracking in 10-percent (2.85 li) hydrochloric acid solution. Heat treating the alloy greatly reduced its corrosion rate and its susceptibility to stress cor-rosion cracking in this medium.

Jan 1, 1965

By W. H. W. Husband

Rock salt has been mined by the solution method for many years in many countries. Attempts have been made in the past in Canada and various other countries to produce potash by the' same method. However, only Kalium Chemicals Limited (1) has been successful, possibly because the conditions in Saskatchewan are the most favorable conditions to be found so far for the development of a solution mining method for potash. There are significant differences in solution mining of rock salt and solution mining of potash. First, rock salt deposits are relatively pure in respect to soluble minerals, whereas potash is never found in the pure state and contains Substantial amounts of other soluble minerals, particularly rock salt. In comparison to rock salt, much less potash is dissolved and brought to the surface for the same amount of water circulated through the orebody. The amount of water to be evaporated per unit weight of product is a major difference. Much greater amounts of water must be evaporated when producing potash and the treatment of the brine is more complicated because other dissolved salts have to be separated. Secondly, the rock salt deposits, particularly the domes, are much thicker. Bed thickness is of prime importance because it determines the yield of a well and consequently the economics of the process. Furthermore, as rock salt provides a strong roof structure, larger cavities can be developed and this prolongs the life of the rock salt well.

Jan 1, 1971

By Alan A. Campoli

The U.S. Bureau of Mines conducted research to characterize longwall gob loading under bump-prone geologic conditions. Bureau-designed stress meters were installed in the floor rock beneath two longwall panels and coal pillars in the gate road between them. Gob and gate road pillar stress was monitored continuously by a state-of-the-art data acquisition system. The timing of the final destruction of the abutment pillar's load-bearing core was optimal, since the pillar is located between two gob areas and no longer of significant importance for ground control. Maximum stress was observed immediately in front of the longwall face, and this pressure quickly dropped as the face moved past the instruments. The center of the longwall panels regained significant overburden load, while the instruments located less than 100 ft from the edge of the panel showed little or no increase in pressure due to gob reloading.

Jan 1, 2010

By Ole Rud Bendixen

Topsoe has developed a Wet gas Sulphuric Acid (WSA) process which effectively recovers SO2 in off-gases from non-ferrous smelters and roosters. The product is concentrated sulphuric acid of typically more than 96 wt% irrespective of SO, concentration in off-gas. The process does not generate any waste products or waste water and does not use any absorbents or other chemicals. In the process, up to 99.3% of the SO2 is converted catalytically into SO3, which reacts with water in the gas, hereby forming gaseous sulphuric acid. The acid is condensed in a WSA condenser of proprietary design. Excellent heat economy and practically no sensitivity to the water balance mean that no extra sulphur burning is required at any S02 concentration, The process is especially well suited for treating off-gases where the SO2 content is lower than approx. 5-6%, and it is a good alternative to a complete renovation of a smelter. However, also off-gas from flash smelter may be treated. The process has found good use in both molybdenum and lead roosters. An example from a molybdenum roaster in Chile shows that 97-98wt% acid is produced from a 2.3 % S02 gas. This plant is situated in the outskirts of Santiago and represented a major local source of SO2. The plan was started in May 1993.

Jan 1, 1996

By B. C. Craft, Murray F. Hawkins, John R. Rayne

A reservoir mechanism of sulfur recovery by the Frasch process is presented. Improving the economic, of recovery appears to be largely a well, rather than a reservoir problem. A most important factor is the limitation of the lateral extraction of .sulfur about the wells due to the almost vertical .flow of the injected hot water. Model studies are described which confirin the mechanism of sulfur recovery by presently used methods. Studies on a five-spot system indicate improved econo171ics regarding recovery, recovery rate, therinal efficiency, and well spacing. INTRODUCTION Sulfur mining by the Frasch process is one of the most important methods of sulfur production. Developed by Herman Frasch in 1894, it enjoyed a rapid growth and presently supplies 40 per cent of the world's sulfur and about 80 per cent of the U. S. sulfur." The Frasch process of mining the underground native sulfur deposits involves melting the sulfur in place by introducing super-heated water into the sulfur bearing formations, and producing the sulfur as a liquid. Many problems are encountered in mining these native sulfur deposits, and sulfur production depends chiefly upon the nature of the sulfur deposit and the underground thermal efficiency of the heat transfer system. THE RECOVERY MECHANISM Sulfur is typically found in salt dome cap rock as crystal aggregates occurring within the cavities, seams, and pores of limestone and gypsum formations.' Sulfur-bearing limestone is typically cavernous, vugular, and fractured. Porosity averages about 20 per cent and sulfur saturation averages approximately 25 per cent by weight.1,15 Vhe sulfur bearing formations are very heterogeneous in nature and physical characteristics vary widely within small distances. Total cap rock thickness may vary from 50 to more than 1,000 ft, and net productive thicknesses from a few feet to a few hundred feet. In most cases the upper portion of the limestone formation is barren of sulfur, varying from 5 to 200 ft in thickness.1,15,33 The immediately overlying sediments and the underlying dense anhydrite formation provide permeability barriers to the flow of water from the cap rock section.'" Sulfur wells are drilled with conventional oilfield drilling rigs. Fig. 1 illustrates the casing program of a completed sulfur well. The cap rock sections are drilled with core bits and continuous core logs are recorded. After coring, the cap rock section is underreamed to a diameter of 9 7/8 in. The bottom of the 8-in. casing is welded closed and rests on the bottom of the drill hole, which extends through the cap rock to a few feet above the bottom of the sulfur-bearing formation. The 8-in. pipe contains 5 ft of 3/4-in. perforations on 6-in. centers and 15 ft of 1-in. perforations on 1-ft centers. The 20-ft perforated section is set opposite the lower 20 ft of the sulfur-bearing formation. The 4-in. sulfur pipe is set inside the 8-in. water line on a seat ring at the top of the 5-ft section of 3/4-in. perforations. The mining water, heated to about 330°F under a pressure of 250 psi, is forced down the annulus between the 8-in. and 441-1. pipes and through the 1-in. perforations to the sulfur-bearing formation. Compressed air, at 400 psi pressure, is supplied through a 1-in. air line near the bottom of the well to provide air-lift of the liquid

Jan 1, 1957

By John L. White

The vibro driver/extractor is a machine that grips to a pile and vibrates it up and down. When the vibrating pile is lowered into the ground, all soil around the pile begins to vibrate. A vibrating pile breaks the friction between the pile and the soil, thus allowing it to penetrate the ground. A vibro is usually operated by hoisting it into the air with a crane and then placing it onto the pile. The vibro has hydraulic gripping jaws that are controlled from the ground. Once the operator has successfully lowered the vibro onto the pile, the jaws are closed and locked onto the pile and operations can begin. Please see the drawing below: [ ]

Jan 1, 1990

By A. H. Lang

"IntroductionMUCH PROSPECTING, exploration, and development work was done for uranium in Canada in 1952, chiefly in northern Saskatchewan and in the Great Bear Lake region of the northwest Territories. The outstanding feature of the year was the great amount of work done in preparing for production at the Ace mine of Eldorado Mining and Refining, Limited, in the Goldfields region . of Saskatchewan. Many private companies and prospectors were also active in this region. Most of the other parts of Canada where uranium has been found received less attention than during the last few years, partly because so much interest was taken in the Goldfields region.In presenting this short summary of the year's activities now, the writer is handicapped because the season is not yet over; some discoveries have probably not yet been announced, and there has not yet been time to digest the numerous reports that have been sent in by companies and prospectors. In any case it would be impossible to give details for most of the discoveries and properties, because that would require a long report, and because that information is classed as confidential until released by the discoverers and companies concerned. It is only possible, therefore, to give a few generalizations, a brief out-line of the activities in northern Saskatchewan, even briefer ,accounts of the work in other parts of the country, and a few details that property owners have informed the writer he may publish or that have already been published by the owners."

Jan 1, 1953

By S. Abe

An extensive study has been carried out to determine the true cause of floating slimes precipitation which sometimes occurs and badly affects the quality of copper cathodes. Soluhilities of floating slime compounds systematically measured for the ternary system As-Sb-Ri added solely or in combination with conventional copper electrolyte (63°C) and bench scale electrorefining experiments done by varying electrolyte composition, have shown conclusively that the level of Sb(V) ions plays a substantial role in the precipitation mechanism. It was, therefore, speculated that controlling the level of the less soluble S b ( V ) ions below a certain critical level should result in a complete elimination of the undesirable precipitation. This can be easily achieved, for instance, by the addition of a reducing agent such as SO2 gas and the simultaneous employment of a certain type of cheating agent that effectively removes excessive Sb and Bi from the contaminated electrolyte. Long-term pilot testing conducted in line with the above speculation has confirmed the SO2/chelating resin scheme to be industrially very attractive and feasible.

Jan 1, 1987

By Mao Chen, Baojun Zhao, Xiangfeng Cheng, Zhixiang Cui, Leonel Contreras, Anh Nguyen

Smelting is an important process in copper production to produce matte and slag.The slag,containing about 1–12% Cu can be further processed to recover the copper contaminated, but recycle of the slag concentrate reduces overall productivity and efficiency of the operation. The best solution is to minimize the copper loss to the slag. The entrained matte droplets in copper smelting slag may originate from a few sources. The present study aims to investigate possible copper matte loss mechanisms by visualization of room temperature experiments and high-temperature examination. It is believed that the gas bubbles from the matte phase disperse the matte droplets into the slag causing entrained matte in slag. Analyses of quenched slags from industrial operation and laboratory experiments confirmed that matte droplets in the slag are extensively associated with the gas bubbles. Water model is used to simulate the procedure and the bubble behaviors at the liquid-liquid interface are observed experimentally with a high-speed camera.

Mar 1, 2017

By V. Gangrade, J. Addis, S. Vanderslice

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are conducting research to improve the ventilation of large-opening underground stone mines. The mine ventilation in these mines are characterized by: (1) challenges related to keeping airflow velocities high enough to effectively remove or dilute airborne contaminants, (2) low pressure losses needed to move large air volumes of air, and (3) costly stoppings needed to direct ventilation airflows. Each of two field studies was dedicated to specific focus areas. The first focus area was the characterization of underground mine ventilation airflow. The primary means of airflow control in stone mines is through the use of freestanding booster fans. The primary goal of this study was to identify the effectiveness of various fan types and optimize their placement. Both traverse and grid-based airflow readings were taken at various distances from the fans, ranging from 70 ft to 425 ft away from the fan. The air readings were taken using a vane-anemometer and a handheld hotwire anemometer. The data was used to develop precise computational fluid dynamics models. The second focus area was to determine diesel particulate matter (DPM) concentrations in the mine. For large-opening underground stone mines, controlling DPM exposures dictates the design of the ventilation system. Therefore, researchers carried out the DPM sampling campaign to identify potential areas of concern within the mine. The samples collected during the campaign were analyzed using NIOSH Method 5040. The sampling was done using the Mine Safety and Health Administration’s (MSHA) compliance sampling methodology.

Feb 1, 2023

By C. F. Kaiser

The Broken Hill proprietary company Limited grate kiln pellet plant (1) located at Whyalla in South Australia commenced production on May 13, 1968. During commissioning, about 25,000 long tons of fluxed pellets were produced. Plant performance was satisfactory and acceptable under the plant guarantee. For production reasons, it was necessary to curtail the fluxed pellet run and revert to the production of acid pellets. In 1970, some 250,000 long tons of fluxed pellets were produced under varying operating conditions to determine the requirements for optimum quality pellets at acceptable production rates. In excess of 180,000 long tons of these fluxed pellets were exported to Japan. Problems experienced in production of the fluxed pellets are detailed, and the quality of the fluxed pellets compared to that of normal acid pellets produced at Whyalla. Brief Plant Details Run of mine ore treated was predominantly soft and friable and contained an average of 66 per cent Fe, 1.7 per cent Si02 and 1.8 per cent Al203. The main iron mineral in the ore was hematite with some martite also present. Plant feed was ground dry in ball mills 11 ft in diameter by 29 ft long to a Blaine surface area of 1600 sq.cm/g and the ground ore was wetted in a pug mill. Balling was carried out in balling drums 10 ft in diameter by 32 ft long. Induration equipment included an eighteen windbox grate 12 ft 2 in. wide by 164 ft 1 in. long, a rotary kiln 18 ft 6 in. diameter by 118 ft 8 in. long and an annular cooler 50 ft mean diameter by 7 it wide.

Jan 1, 1972

By Nasser Madani, SULTAN ABULKHAIR

The abstract of the paper discusses the challenge of quantifying iron content in a coal deposit in Kazakhstan. The iron dataset is limited, coming from only three drill holes and some stope samples, while a large amount of geological information is available from legacy drill hole data. The paper proposes a workflow using multiple-point geostatistics to model geological domains and two-point geostatistics to model iron content within these domains. The results show that the direct sampling (DeeSse) algorithm effectively reproduces the complex seam layers, and sequential Gaussian simulation models the iron within each domain.

Mar 30, 2022

By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

By T. M. Garland

A nomographical approach is proposed as a fast, easy-to-use, and reason- ably accurate method for estimating expected discounted cash flow (DCF) rate of return and payout time for onshore development drilling and oil production. All costs pertaining to drilling, completing, and equipping development wells, annual expenses of operation, maintenance, and taxes incurred in producing properties, and crude oil prices were considered in developing the nomographs. This report briefly outlines the origin, derivation, and use of the nomographs.

Jan 1, 1973

By Ganesh Deepak K., Anjana R. K., Dr. Kumar Pitchumani N., Rajasekharam R. M. V. M. S. S.

The Phase 2 of Chennai Metro is being introduced in the city to ease the dependence on the existing transportation systems. Phase 2 is a combination of underground and elevated metro stretches comprising of three corridors. The current study focusses on the underground stretch of Corridor 3 which has a total of 29 underground stations. Construction of the underground cut and cover stations results in ground movements, which in turn impact the structures adjacent to the excavations. The greenfield ground settlement can be evaluated with the help of empirical approach or an approach requiring finite element modelling (FEM). The paper compares empirical and FEM approaches with regards to ground conditions in Chennai. Further, with the predicted ground settlements, building damage assessment is performed. The damage category of a building is defined based on the estimated tensile strains. This paper also compares the building damage assessment with empirical method and finite element modelling.

Nov 1, 2022

By Arash Khosravifar, Ali N. Ibrahim

"Large areas of Iraq are covered with collapsible soils namely gypsiferous soil which is often used as the foundation soil for structures. In particular, the Mosul Dam foundation is comprised of high contents of gypsiferous soils. Intrusion of water through the foundation soil dissolves gypsum which acts as the binding material between soil particles. This phenomenon results in the formation of collapsible soils which can cause serious damages to the dam structure. The failure of Mosul Dam, with a reservoir as large as 11 billion cubic meter of water, can be catastrophic. In the past, Mosul Dam Authorities have been remediating the soil foundation by injecting cement mortar. This method has been proved not economic; therefore, new, more efficient, methods are desperately needed.This research study focuses on finding practical methods to remediate collapsibility of gypsiferous soils by improving their geotechnical properties. This study presents remediation of collapsible gypsum-rich soil by grouting. Three types of stabilizer materials were used to make the grout; (1) sodium silicate (Na2 O3 Si) which is a well-known chemical soil stabilizer, (2) bentonite slurry, and (3) silicone oil. The purpose for using these stabilizer materials is to provide an impermeable layer (waterproofing coat) around the gypsiferous soil particles and to fill the voids that may occur in the soil as a result of gypsum dissolution when subjected to water.A series of double oedometer (collapse) tests and direct shear tests were carried out on gypsiferous soils before and after remediation by grouting. The results show that the soil compressibility decreases in the grout-treated gypsiferous soil by reducing volumetric strain. Consequently, the potential for collapsibility decreases too. It was also shown that grouting, increases the shear strength of the soil at confining stresses smaller than 250 kPa by increasing the cohesion combined with a slight reduction in the internal friction angle.INTRODUCTIONGrouting is one of the ground improvement techniques which is often used to improve the loose foundation soils. Bruce (2003) provides step-by-step procedures on using grouting techniques for sealing dams and other water reservoirs. Grouting can be classified as permeation grouting, compaction grouting or hydraulic fracturing. Permeation grouting is an effective way to send the grout into the ground without disturbing the soil structure, i.e. free flow of grout into the soil voids where grouting is accomplished by injection of a fluid-like material that is capable of forming a gel and binding the soil particles together. Grout materials may be solution grouts or suspension grouts. The permeation grouting technique is generally used to minimize ground permeability and to control ground water flow, but it can also be used to strengthen and harden the ground (Raman et al., 2012)."

Jan 1, 2017

By Jr. Wallace

This paper describes the importance of mine ventilation and air conditioning in the operation of a nuclear waste repository. It discusses the impact of ventilation on determining the number and size of shafts and access drifts to and within a repository horizon. The paper also describes the need to maintain separate ventilation systems for waste emplacement and construction operations. The requirement to have filtration capabilities for exhaust air from waste emplacement areas is discussed. Because radioactive high level waste will induce high temperatures in the emplacement drifts, the ability to cool an emplacement drift for re-entry requirements is important. The paper discusses strategies to cool an emplacement drift and the possibility of using continuous airflow to control temperatures in these drifts.

Jan 1, 1991