Search Documents

By Judson H. Whitman

To evaluate intelligently and to market a source of rare earth raw material, it is necessary that the producer understand the requirements of the processor and the manner in which these requirements effect the value and salability of his product. This paper will be an attempt to aid in such an understanding. The majority of rare earth processors are primarily chemical companies, not mining or metallurgical companies, as the complexities of the processing procedures are' much more chemical in nature than metallurgical. The rare earths and the rare earth industry are normally divided into two groups - the ?light? or cerium group and the ?heavy? or yttrium group. They are so named because cerium and yttrium are the most common elements in 'heir respective groups and are so divided on the basis of mineralogical and chemical characteristics. The dividing line of the two groups is not rigidly fixed but usually is considered as being between samarium (atomic number 62) and europium (atomic number 63). Although the two groups are quite similar, processing procedures differ significantly, hence most processors tend to specialize in one group or the other. There is, however, a growing tendency toward participation in both groups.

Jan 1, 1960

By R. J. McNally

THERE are three primary plant nutrients—nitrogen, phosphorus, and potassium—expressed in any fertilizer compound as percent N, percent P 2 O 5, and percent K 2 O, in that order. This article will be concerned with the first two. The chief source of P 2 O 5 is phosphate rock. As found in the western states phosphate rock is essentially tricalcium phosphate-calcium fluoride (fluor-patite). As such, it is quite water insoluble.

Jan 1, 1957

By P Craig, A Crosky, H Ramandi, S Saydam, H Chen

Frequency of reports on premature failure of rock bolts and cable bolts have increased in past two decades. Such a failure threatens both the safety of underground mine workers and the economic viability of the operations. Herein, we report on analysis of rock bolts and cable bolts failed recently in three underground mines in Australia. Magnetic particle inspection (MPI) and scanning electron microscope (SEM) techniques were used to study the failed bolts. MPI showed a number of subcritical cracks on the surface of the bolts. The majority of the cracks in both cable bolts and rock bolts were initiated from the base of ribs (indentation) where the stress concentration was high. SEM examinations showed tearing topography surface (TTS) in all failed rock bolts and cable bolts. These indicated that the failure occurred through hydrogen assisted stress corrosion cracking (HISCC). The results of this study enhanced the understanding about the failure of rock bolts and cable bolts in underground mines. CITATION:Chen, H, Ramandi, H, Craig, P, Crosky, A and Saydam, S, 2018. Analysis of premature failure of rock bolts and cable bolts failed in underground coal mines, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 407–413 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By Michael Markels

The United States Environmental Protection Agency (EPA) is charged under the Federal Water Pollution Control Act Amendments of 1972 with establishing effluent limitations which must be achieved by point sources of discharge into the navigable water of the United States. Section 301 (b) of the Act requires the achievement by not later than July 1, 1977, of effluent limitations for point sources, other than publicly owned treatment works, which are based on the application of the best practicable control technology currently available as defined by the Administrator pursuant to Section 304(b) of the Act. Section 301(b) also requires the achievement by not later than July 1, 1983, of effluent limitations for point sources, other than publicly owned treatment works which are based on the application of the best available technology economically achievable which will result in reasonable further progress toward the national goal of eliminating the discharge of all pollutants, as determined in accordance with regulations issued by the Administrator pursuant to Section 304(b) to the Act. Section 306 of the Act requires the achievement by new sources of a Federal standard of performance providing for the control of the discharge of pollutants which reflects the greatest degree of effluent reduction which the Administrator determines to be achievable through the application of the best available demonstrated control technology, processes, operating methods, or other alternatives, including, where practicable, a standard permitting no discharge of pollutants.

Jan 1, 1975

By S. Usui

In a previous article1 the methyl stretching vibrations for a series of xanthates and amines were reported, and the frequency of the methyl stretching vibrations in a homologous series of the alkyl compounds were shown to decrease exponentially with chain length and approach a limiting value corresponding to that of saturated hydrocarbon beyond six or seven carbons. These observations were explained quantitatively by the theory of Goto and Takenaka2 who proposed an equation relating the frequency shifts to the inductive effect of polar groups. As a result, the alkyl groups in the shorter chain heteropolar compounds were interpreted as becoming somewhat polar, and a good correlation was observed between the CH3-stretching frequencies and such surface chemistry parameters as contact angle, surface tension lowering, solubility, and critical micelle concentration" The substitution of fluorine atoms, the most electronegative of all atoms, for the hydrogen atoms in alkyl groups was expected to reverse the direction of the inductive effect within a heteropolar molecule, and its effect on the C-F stretching frequency shifts and on some surface chemical properties became of interest. In a recent study the C-F stretching frequencies of a series of normal perfluorocarboxylic acids and a few 1,1' -dihydroperfluoro alcohols were determined as a function of chain length and the results were compared with the corresponding hydrocarbon analogs. Furthermore, the nature of the induced polarity in the hydrocarbon and fluorocarbon groups was investigated through surface potential measurements at the interfaces of air-aqueous solutions of normal butyl alcohol and of l,l'-dihydroperfluorobutyl alcohol and through differential capacity and electrocapillary measurements at the interfaces of mercury-aqueous solutions containing the above two alcohols. Experimental Normal perfluorocarboxylic acids and 1,1' -dihydroperfluoro alcohols were provided through the courtesy of the 3M Company, St. Paul, Minnesota. Normal butyl alcohol was purchased from Distillation Product Industries, Rochester, New York. A Perkin-Elmer Model 621 infrared spectrophotometer was used to investigate the spectra in the frequency region of 1200 to 1270 cm-l with frequency scale

Jan 1, 1971

By William K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/ AgC1 reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrodes to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 2010

By Jr. D'Angelo, Michael M. Blendy, Shawn Downey

"A grouted helical pile was used to support new buildings in the reconstruction of a large residential development. Foundation options were complicated by urban fill underlain with variable alluvial soil. A driven timber pile and grade beam system was recommended to support the new buildings. Other foundation options are also discussed. The grouted helical pile was quoted as an alternate and ultimately won the bid based on the economics and performance of the system. Data from 8 load tests was used to develop an empirical site specific relationship for determining pile capacity based on both installing torque and installation depth. Design to incorporate tolerance on installed pile location is presented. With the three phases completed, 554 residential dwelling units supported by 3645 grouted helical piles had been constructed covering 18 city blocks on the 44 acre site. IntroductionThe Philadelphia Housing Authority reconstructed the Tasker Homes housing complex located in southern Philadelphia, Pennsylvania, adjacent to the Schuylkill Expressway in the Grays Ferry area. Keating Building Corp. and Pennoni Associates were the general contractor and the structural engineer respectively. The original Tasker Homes development was constructed from 1940 to 1941 and consisted of 44 acres of primarily two and three-story residential brick buildings. These buildings were supported by a timber pile foundation system. The structural condition of the buildings supported on the timber piles was generally good in comparison to areas outside the buildings. These areas had settled possibly up to 2-feet in places due to the heterogeneous nature of the urban fill."

Jan 1, 2005

By M. Meratian

The in-situ methods have been developed in production of aluminum matrix composites. A commonly adopted in-situ method involves reaction between a metal oxide and aluminum to produce alumina particles or whisker reinforcements. Aluminum-alumina particle composite was fabricated by in-situ method where alumina particles were produced from reduction of copper and silicon oxides by melting and casting aluminum. Aluminum matrix composites reinforced by Copper and Silicon alloying elements and alumina particles have been obtained. The size and shape of alumina particles were studied by scanning electron microscopy (SEM). The size of alumina obtained from mixture of SiO2 and CuO was bigger than the alumina particles obtained from CuO.

Jan 1, 2007

By C. Cano

One of the main concerns within the mining industry is to minimize the impact of tailing facilities to the environment and nearby communities. Since the implementation of the first thickened tailings disposal (TTD) methodology at Kidd Creek in 1964, the thickened tailing disposal has been growing alternative disposal technology to mitigate the environmental impacts. Technical investigations on the TTD technology have been studied in detail to counteract the increasing shortage of water resources. One of the benefits observed with TTD is its resistance to potential earthquakes, particularly in zones with high seismic activity (Los Andes). TTD technology optimizes the maximum possible density for the material and generates a negative internal pore pressure in the material due to the surface and sub-surface water evaporation. This internal pore pressure should be enough to resist the pores pressure to which tailings are subject due to an earthquake action. The objective of this study is to verify the Shrinking Limit (SL) of thickened tailings during initial deposition and in the long term and the ability of tailings deposited by TTD would resist liquefaction. Fresh tailings coming from a flotation process of a copper plant concentrator were used. The samples put under cyclical three-dimensional tests associated with maximum credible earthquake magnitude range of 7.0 8.0 to develop a curve for the safety factor v/s depth for dry densities related to the maximum density obtained at the SL. At a dry density of 1.65 t/m3 liquefaction did not occur at any depth. At 90 % of dry density of 1.51 t/m3, liquefaction did not occur at earthquake magnitudes of 7.0 or 7.5 nor at any depth but liquefaction occurred at magnitude 8.0 between 0 m and 14.5 m; below 14.5 m, liquefaction does not occur.

Jan 1, 2007

By Saieb Haddad, Henry Pate

"Building retaining walls in an urban area is becoming more difficult due to right-of-way restraints. Using standard concrete cantilever walls requires a construction easement behind the walls for installation, which for the most part is unavailable. To install these types of walls in a limited right-of-way requires extensive temporary walls to minimize the construction easement. Top-down construction walls utilizingtie-back anchors for support require either the purchase of the right-of-way or underground easements in the area of the anchors.These problems faced the Department on Interstate 75 widening in Knoxville, TN in an area of a large cut. A multi-story Insurance Building and a large commercial Retail Center were located at the top of the cut. To prevent any impact on the buildings, the walls had to be placed within a limited area. The option of buying the properties was prohibitively expensive. Due to the height of the two walls and the variability of the underling rock line, contiguous caisson pile cantilever walls were contemplated as the only wall type that would be appropriate. The cost of the two walls was estimated to be very close or even higher than the cost of purchasing the two buildings. The Department believed that there must be a better way to deal with the problem. A vertically tied-down pile frame wall constructed from the top-down with a concrete facing was developed. This allowed the construction of the walls to be restricted to the available limited area and provided substantial savings for the State.INTRODUCTIONThe widening of I-40/75 has been a major transportation project in the Knoxville area which is being constructed by the Tennessee Department of Transportation. The project includes 18 Retaining Walls and 13 Bridges.Two of the 18 Retaining Walls, refer to Figure 1, are to support two valuable properties, one being an insurance company housed in a multi-story office building and the other a suburban shopping center which were appraised at $13.0 million and $5.0 million respectively. Due to the 31 ft. (9.5m) maximum height of each of the two Retaining Walls and the limited Right-of- Way of 15.0 feet (4.6m), a contiguous caisson pile cantilever wall was proposed for each of the two retaining wall sites with an estimated cost of $12.0 million each. The contiguous pile cantilever Wall is comprised of a line of caisson piles socketed into underlying competent bedrock. The design required that 4 ft. (1219mm) dia. piles be installed at 6 ft. (1.83m) centers, socketed into rock in order to provide lateral stability and restrict lateral wall movement to acceptable limits. The line of caissons would be fronted with a cast-in-place concrete face wall"

Jan 1, 2007

By P. Cowx, L. Els, P. Smith, R. Nordhagen

"Tapping operations at ferroalloy smelters generate a significant amount of fume. Effective capture of fumes is required to meet the obligations of environmental, as well as occupational, legislation.A study was completed on an existing fume extraction system at a ferromanganese furnace tapping area. The area under consideration included the tap-hole, launder, and ladle area. The study consisted of site test work as well as computational fluid dynamics (CFD) modelling to identify and evaluate solutions.Site test work and observations during furnace operation provided a baseline of system performance as well as input parameters for CFD modelling. Gas flow rates and energy contents from each extraction area were measured. Photographs and video footage were taken to evaluate areas of fume leakage.The CFD study was firstly validated against site observations to ensure the accuracy of input parameters. Thereafter several modification concepts were modelled and suitable combinations were investigated to ensure robust solutions. The following concepts were considered:•,Air curtains•,Ladle hood aspect ratio and position•,Increase of ladle extraction volume•,Extension of the length of the tapping garage structureThe paper presents the results of a performance test on a working ferromanganese tapping area fume extraction system and the results of CFD modelling as compared to site test results. Upgrade options are evaluated and an integrated robust upgrade of the system described."

Jan 1, 2014

By Bin Du

In recent years, concurrent product design and process is gaining popularity and will become a norm of the industry of the future. Forging has been a critical manufacturing process for production of components with superior tensile strength, toughness and grain flow. This paper describes an expen system which is being developed for forging die design and forging process analysis in concurrent engineering environment. Rules and guidelines pertaining to forgeability are formulated and incorporated into the knowledge-base in building the system. The system is built using an object-oriented paradigm. The object-oriented approach and hierarchical rule structure paradigm are briefly discussed. Finite element analysis packages (ALPID-2D) were incorporated into the program to give the simulation result of the forging process. The system can automatically produce a competent design and recommend a set of processing parameters for a given product. The designer can modify the design according to the result of the simulation.

Jan 1, 1992

By D. Malhotra

Climax byproduct-plant tailing assayed 0.019 percent WO3. Pilot-plant and laboratory tests were performed to investigate the possibility of recovering additional tungsten values from the byproduct-plant tailing. The paper discusses the methodology used in the study and the results of this investigation.

Jan 1, 1985

By Ricardo Montero

At this time, over 300 tons of Au are used in electronic equipment each year with other precious and strategic metals such as Ag, Pt, Pd, Cu, Nb, Ta, etc. After the use-phase, the electronic devices become electronic waste (e-waste); consequently it is important to consider e-waste as a secondary supply for recovery of these metals. One of the most important components is the printed circuit boards (PCBs) because the amount of their precious metals is ten times higher than rich precious metals bearing ore. This paper presents the recovery of Au, Ag, Cu and Nb from PCBs of discarded computers using leaching column technique. The amount of these metals in used PCBs was: 613 g/ton of Au, 1515 g/ton of Ag, 36 g/ton of Nb and 23.4 % of Cu. The PCBs were crushed with a hammer mill until reaching a particle size between 3.33 mm to 0.43 mm. Then, it was leached with sodium cyanide solution in a glass column using the following conditions: sodium cyanide concentration 4 g/L, flux 20 L/kg PCBs day, pH between 10.5 to 11 and leaching time 15 days. Every day, after leaching, the pregnant solutions passed through a column with activated carbon to complete the closed loop system. The following recoveries were obtained: 46.6% of Au, 51.3% of Ag, 47.2% of Nb and 62.3 % of Cu. The products obtained are: a) loaded carbon that contains the desired metals and b) processed PCBs with precious metal contents. A preliminary technical-economic study shows the feasibility to create a small-scale PCBs recycling plant. The initial investment is on the order of US$ 155 639, considering the recovered metals from loaded carbon. The internal rate of return for 10 years period (IRR) and net present value (NPV) estimated are 27% and US$ 105 926 respectively. Keywords: printed circuit boards, recovery, precious metals, niobium, leaching column

Sep 1, 2012

By C. H. Perbix

[On Pier D in the Port of Long Beach, California, the Port of Long Beach has built a new bulk cement distribution terminal. The facility is operated by Pacific Coast Cement Corporation, who designed the complex and leased it from the Port of Long Beach on a 40-year lease. At one bulk cement is unloaded from vessels carrying from 12,000 to 30,000 t. The unloading is performed with pig speed mechanical unloading equipment and delivered into a concrete silo complex with, a capacity of 50,000 t. From the silos, bulls cement is loaded into trucks for delivery. The facility was completed in September 1981.]

Jan 1, 1983

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei. These ores require mineral processing to remove the sub-strate/nuclei rock before smelting. This paper reviews experimental results of previous investigations. Observations and analysis of 10 samples from different localities were carried out and it was found that the liberation ratio of crushed product was high even at coarse size fraction, 0.5mm to 4mm. Experimental and calculated results in the smelting stage confirmed that the separation product satisfies the standards of the subsequent smelting process if the substrate/nuclei rock is removed from the 0.5mm to 4mm fraction with high separation efficiency. There was a density difference between the substrate/nuclei rock and the ferromanganese component. Thus the coarse sized sample was treated with gravity separation; air table separation was used as a dry method and jig separation as a wet method and high grade values with high recoveries were obtained by both kinds of gravity separation.

Jan 1, 2014

By M Gabbitus, B Young, T Lukins, M Slater

This paper details the implementation of a new type of grade control system at the Black Star open cut mine in Mount Isa, Queensland. It explores the site requirements for grade control, what as previously in place and what the site required moving forward. It also details some of the features of the system installed and why it was chosen over other grade control systems available. Black Star open cut mine has been in operation since late 2004, and was developed to extract the surface extents of the Ag-Pb-Zn mineralisation previously mined in the Isa Lead Mine. Black Star is currently mining seven distinct orebodies in and around active void hazard zones and hence, its grade control requirements are very detailed and complex. The implementation of a new system to manage the model update and block out processes was, therefore, of critical importance to the site and required a detailed understanding of the requirements of the entire mining team from drilling through to geology, survey and production. Having previously run the grade control process using site specific æblack boxÆ scripts and macros, Black Star needed to implement a more open, auditable and flexible system, which allowed the geologists to control the process and make strategic changes as the situation demanded. MineSightÆs Axis Grade Control, with its flexible, generic framework for managing the process, met these demands. Being an out of the box solution that requires minimal setup and training was also a key factor in the decision to use it.CITATION:Lukins, T, Slater, M, Gabbitus, M and Young, B, 2012. The introduction of axis at Black Star Open Cut, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 71-74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By Boris CARO VARGAS, Bernard Theron

"In early 2014, Nicholson Construction Company was awarded, together with its tunneling sister company Bessac, the Norris Cut Miami Tunnel Project. The 2.5-meters diameter segmental lined tunnel, 1600-meters long, is aimed to replace the existing 54” force main connecting the Waste Water Treatment Plant (WTP) on Virginia Key to Fisher Island. To overcome project challenges such as the highly permeable limestone of the Fort Thomson Karstic Formation (one of the most permeable formation in the World), the project team has developed State of the Art solutions: The TBM was launched with pipe-jacking technique for the first 70-meters and then converted to segment erection mode. It allows substantial schedule savings and drastically reduces the size of the circular launching shaft. The TBM, jointly designed and manufactured by Bessac and Herrenknecht, can convert from slurry to EPB mode within a few minutes. The cutters can be replaced by wet divers thanks to an innovative application in the TBM industry. PRESENTATION OF THE PROJECT The aim of this project is to replace the existing 54-inch force main pipeline which transmitted all sewage collected from Miami Beach, Surfside, Bal Harbour, Bay Harbor, North Bay Village and Fisher Island to the Central District Wastewater Treatment Plant (CDWWTP) to Fisher Island. The existing pipeline consisted of pre-stressed concrete cylinder pipe which is in poor condition in a number of locations and could be subject to sudden failure. An adjacent portion of this existing force main under the Government Cut (North Fisher Island) has already been replaced as part of a previous design-build contract and involved the installation of a 60-inch diameter fiberglass-reinforced mortar pipe installed inside a micro-tunneled casing."

Jan 1, 2016

By Dale Preece, Mike Stern, Steve Piercey, Ayman Tawadrous, GC Zhao

The McArthur River uranium mine in Saskatchewan, Canada is the world’s largest high-grade uranium mine. It has employed a freeze-wall system consisting of multiple freeze pipes to control the large quantities of water encountered during mining.

Jan 1, 2011

By Toshitaka Ota, Hisao Suzuki, Minoru Takahashi

"Perovskite-type lead zinc niobate (PZN) exhibits excellent electrical properties such as high dielectric constant, high electrostrictive coefficient and superior piezoelectricity. Therefore, PZN ceramics are very promising for high performance electronic devices. However, perovskite phase PZN is not stable under the ambient atmosphere. Accordingly, it is very difficult to prepare single-phase perovskite PZN ceramics. In this study, A-site cation of lead was partially substituted for barium to stabilize the perovskite phase of the PZN (Ba-doped PZN) powder. In addition, molecular design of an alkoxide precursor was controlled for a low-temperature processing. As a result, molecular design to suppress the lead-volatilization during calcination was preferred for a low-temperature processing. Processing temperature for a single-phase perovskite was depended on the amount of barium dopant. Doping of20 mole% of barium resulted in the single phase perovskite at 900 °C. The temperature for the single phase perovskite of Ba-doped PZN powder, which depended upon the amount of Ba-doping, was lower than that of the powder prepared by the atmosphere controlled conventional powder processing at least by 150 °C.IntroductionFerroelectric thin films and powders with perovskite structure are of renewed interest for micro-electronic applications, including ferroelectric random access memory (FRAM), dynamic random access memory (DRAM), and thin-layer capacitors integrated onto a silicon wafer [1-3]. In addition, recent advancement in micro-machine requires a high performance micro-actuator [4]. A perovskite type relaxor of Pb(Zn113 Nb213)03 is one of the promising materials for a high performance capacitor and microactuator because of their high permittivity and electrostrictive coefficient [5]. Therefore, this paper focuses on the low temperature processing of Ba-doped PZN powders.Chemical solution deposition (CSD) from molecular-designed alkoxide precursor solution is one of the most promising techniques for processing high-performance powders and thin films because it offers precise control of compositions on a molecular scale as well as a low processing temperature [6]. However, chemical solution deposition of perovskite type PZN powders and ceramics are very difficult because of the formation of stable pyrochlore phases. Therefore in the past, PZN powders and single crystal have been prepared by the hydrothermal method or flux method as well as the partial substitution method of a A-site cation [7-10]. In this study, a suitable molecular design for a preparation of perovskite type Ba-doped PZN powders with a chemical solution deposition process is investigated as well as the effect of A-site cation substitution. Chemical solution deposition from molecular-designed alkoxide precursor solution is expected to decrease the amount of a A-site substitution and/or a crystallization temperature for a single phase perovskite. This paper describes ""the relation between molecular-design and processing temperatures for a single-phase perovskite of Ba-doped PZN powders in comparison with the conventional oxides mixing method."

Jan 1, 2000