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By C. H. Mathewson

CONSIDERABLE progress has been made during the last few years in analyzing the action of plastic deformation in metallic crystals. This is due largely to the development of X-ray spectrographic methods for studying changes in the orientation of single crystals, or of conglomerates, as they occur during the process of plastic deformation, but partly to the widespread knowledge of suitable technique for preparing large (single or variously combined) crystals for direct crystallographic observation under stress or in various conditions of strain. These two methods of studying changes in the crystalline structure of metals may of course be used in conjunction with features of mutual support, but unfortunately the advantage of direct crystallographic observation is lost when we proceed to the study of severely cold-worked structures, owing to the occurrence of real or apparent crystalline discontinuities which become more and more complicated as the amount of plastic action increases. Furthermore, the X-ray methods do not appear to be adequate, at least in their present stage of development, to fix definitely the character of structural alteration in the parent crystal lattice by plastic deformation. The principal question at issue concerns the nature of the crystalline particles that remain after plastic deformation. These are generally known in our American metallurgical literature as crystalline fragments,' and they seem, indeed, to diffract as individuals causing the Hull pattern of a severely cold-worked metal to resemble the pattern of a fine powder,2 with certain features of preferred orientation among the particles deter- mined by the manner and intensity of cold working. We must freely concede that there are conceptions of lattice alteration, apart from that of simple fragmentation, which would account for an increasing number of lattice positions according to X-ray spectrographic observation as the degree of deformation increased.

Jan 1, 1927

By Charles G. Maier

"INTRODUCTION The use of thermodynamic calculations to answer practical problems in metallurgy, especially those that are relatively difficult to test experimentally, is rapidly becoming a conventional method of procedure. Nevertheless, these methods cannot he applied effectively until the fundamental thermodynamic constants used for them have become available either by direct experiment or by recalculation of data already existing in more or less undigested form.In an attempt to collect such data far the compounds of lead and the antimony group the incentive has been to make a preliminary survey that will disclose the gaps or questionable phases of available information and to collect data that may be used to answer certain rather practical problems presented by operating metallurgists.This report comprises three sections; the first gives the basis of selection of the constants which may now be given or estimated, and the later sections discuss the application of the figures obtained to two of the more interesting problems.The reader will discover that many of the quantities involve critical study of a number of more or less discordant observations. Although certain data could be rejected on the basis of thermodynamic comparisons, it must not be overlooked that many of the figures are the results of rational estimates rather than exact experiment. The use of thermodynamic methods to control and partly authenticate such estimates is one of its most valuable characteristics for the practising metallurgist or chemist, who cannot check by direct experiment each property of the materials which he converts to usable form.Nevertheless, while it is definitely possible in certain instances that the final figure selected for the heat or free energy of a process or substance may be in error by as much as a few hundred to a few thousand calories per formula weight, questionable figures are usually revealed by the thermodynamic calculations made. When quantities of such degree of accuracy are, and they often must be, used for estimating an unknown reaction, the result often gives no more than the order of magnitude of the desired quantities. Yet even in these extreme cases the answer is far more reliable and valuable than an unordered guess or a conclusion based on incorrect data."

Dec 1, 1934

By Michael J. Magyar

This report contains a cost estimate of the Bureau of Mines process for dewatering Alaskan placer effluent streams with polyethylene oxide (PEO). In this process effluent slurry is withdrawn from the placer plant pond system after a primary settling stage. A dilute PEO solution is injected into the slurry line to flocculate the fine, suspended solids. The flocculated solids are dewatered on a stationary screen. Clarified water is returned to the placer operation or discharged, while the 35 percent solids waste is pumped back into the mine cut. Cost estimates are presented for dewatering plants processing 1,000 gallons per minute of effluent slurry at three representative turbidity levels. Both the placer and the dewatering plants operate on the same 1-shift-per-day, 6-day-per-week schedule for the 100-day Alaskan operating season. Estimated fixed capital costs for these plants processing placer with effluent turbidities of 1,000, 3,000, and 5,000 nephelometric turbidity units (NTU) are approximately $29,000, $31,000, and $34,000, respectively, on a fourth quarter 1986 basis. Operating costs are estimated to be $0.34, $0.37, and $0.40 per thousand gallons of effluent slurry.

Jan 1, 1987

By Wallace W. Key

Mineral raw materials produced in California, other States, and foreign countries were purchased for consumption in quantities valued at over $60 million at 800 of the 1,200 chemical plants operating in California in 1960, according to questionnaires completed by company officials. These and other data received from mineral consumers, producers, dealers, and Government agencies formed the basis for this the first of a series of reports designed to present the intricate features and relationships controlling mineral raw material supply and demand in California industries. The results of this study indicated certain changes in use patterns of minerals in chemica 1 manufacturing; a shift in requirements from metals to nonmeta ls, from inorganics to organics, from natura 1 to synthet ic materia ls , and from distant to local sources of supply.

Jan 1, 1965

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

By A Penney, M J. Pascoe, R M. Stephenson

The empirical McCracken and Stacey stability and risk assessment method has been in use for more than 20 years to assess geotechnical stability issues for raise bored shafts. The methodology has been applied with various levels of success. Increasingly, trends in mining and civil tunnelling have been towards larger diameter, single pass, raise bored shafts to rapidly provide means of ventilation, material movement (ore passes), or emergency egress. Identifying and assessing potentially problematic zones before raise boring commences can allow for appropriate risk-based decisions on construction, or to investigate alternative solutions. The implementation of a proactive solution to raising through an identified weak zone is preferred to the application of an engineered solution to an area subjected to substantial instability or failure. Methods for investigating potentially problematic areas are discussed in this paper based on AMC’s benchmarking data. Proactive investigation programmes resulting from these investigations are also discussed. Previous publications discussing the benchmarking data have concentrated on Australian case studies. Increased efforts and recent updates have been made to expand the database to include international case studies. This has provided further refinement of lower bound ‘raise bore rock quality index’ (QR) values, and various rock mass parameters for stability assessments. CITATION:Penney, A, Stephenson, R M and Pascoe, M J, 2018. Raise bore stability and risk assessment empirical database update, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 434–445 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By I. Iwasaki

Platinum group elements (PGE) are often found in arsenide and sulfarsenide minerals as inclusions in copper-nickel bearing gabbroic rocks. Major losses of platinum in flotation have been attributed to the poor recoveries of the arsenic minerals. Flotation characteristics of a synthetic nickel arsenide and arsenopyrite were studied through rest potential and oxidation rate determinations, surface analyses, and micro-and batch-flotation tests. The use of nitrogen during grinding and flotation together with copper activation improved the PGE recoveries from Duluth Complex ores. The flotation behaviors of the sulfarsenide minerals are still unresolved. The role that electrochemical interactions play among arsenides, sulfarsenides, sulfides and grinding media on their f10atabilities is discussed.

Jan 1, 1988

By Saverio Agresti, Giuseppe Lunardi, Donato Basta, Roberto Trapasso

"At a distance of 10 years from the first application of the Nazzano Method, the widening under traffic of a tube of an existing motorway tunnel was realized near Ancona, along the A14 Motorway in Italy. This paper describes the works for the enlargement with conventional method of the second tube, very close to that already widened under traffic.This enlargement was realized very fast, taking into account the advantages of some interesting technological improvements of the Final Design proved in the first tube.INTRODUCTION TO THE WIDENING OF EXISTING MOTORWAY TUNNELSThe widening of a twin-bore motorway tunnel usually considers the double option of creating a third bore as an alternative or closure to traffic of one of the two bores with the resulting reduction in the level of service for users.On the contrary, the extension in situ of a road, motorway, railway or underground tunnel in the presence of traffic, made possible by an inspired idea of Prof. Pietro Lunardi, enables the level of service of the infrastructure to be maintained without the need to resort to alternative routes to create new permanent or temporary bores, not always feasible because of the lack of the necessary space.This construction technique, known as the ‘Nazzano Method’, is part of the technologies refined and offered by the ADECO-RS approach to tunnel design and construction (Lunardi P., 2008) which is increasingly used in the world, leading to the industrialisation of tunnelling (meaning respect for the times and costs set out during detailed design) both in conventional and mechanised (through TBM) excavations.The first true experimentation of the ‘Nazzano Method’ was carried out between 2004 and 2007 to enlarge the two-bore ‘Nazzano’ tunnel (Italy, Milan-Rome A1 motorway) in the presence of traffic, widening it to house from two to four lanes in each direction (Lunardi P. et al., 2007). Following the success achieved in this first application, the Nazzano Method was strengthened considering all the possible suggestions arising from the previous experience and then taken up to enlarge the north bore of the ‘Montedomini’ two-bore tunnel (Italy, Bologna-Taranto A14 motorway), in situ and the presence of traffic."

Jan 1, 2016

By H Arvidson, Rondinelli Sousa, Nic Pollock, Cesar Carrasco, Boz Elloy

Global public mineral reporting codes have driven strong governance of public disclosures of minerals information. Recently, we have seen an increase in disclosure of information related to Environmental, Social and Governance (ESG) issues, and governance of ESG information in mining companies has arguably reached a similar level of governance and diligence afforded mineral reporting. We define Resource Governance as the conjunction of environmental, social and minerals governance. A modern systems approach to Resource Governance, which combines mineral and ESG information, would provide not only reporting and governance capability, but also has the potential to sense/respond, predict, and manage ESG risks.

Feb 1, 2024

By G. F. Zhang

Yunnan mineral is a kind of containing Ta-Nb rare earth deposit, the most potential economic valuable element in it is Sc, and raw mineral has 17.0 g/t Sc. Take the character of Sc into account, the key problem in producing scandium chloride molten salt by adaptive technology is how to man-ufacturer anhydrous scandium chloride molten salt. During the course above, the key problem is that preventing Scandium chloride from being hy-drolyzed into ScOCl. The ScOCl content of molten salt not only affect purifying scandium but al-so do harm to the production of Mg-Al alloy. In order to restrain the creation of ScOCl, add ammo-nium chloride into molten salt. As long as ScOCl is created, it would be chloridized. Thus, during the course of dehydrating anhydrous chloride molten salt this method prevents scandium from hydrolyzing. Accordingly, the key phase of this producing course is eliminate ammonium chloride and the surplus crystal water, and the most crucial of it is restrain scandium chloride from being hydrolyzed into ScOCl. This research analyzed the theory that ammonium chloride is trend to be hydrolyzed into ammo-nium chloride, and propose the research scheme of restraining this process from creating ScOCl. The new process of restraining the generating of ScOCl and dehydration for crystal water rare earth chloride is adopted: Inert gas temperature increases rapidly to a certain degree to eliminate ammonium chloride and crystal water. The experimental research were done such as : the temperature of eliminating ammonium chloride and crystal water, amount of ammonium chloride, time, temperature growth speed, influence of inert gas flow toward to scandium percent hydrolysis, whereby, we conclude the optimal process condition in this period: Temperature: 400°C, proportion of oxidized scandium and ammonium chloride is 1:1.5(Proportion of oxidized scandium and additional salt is 1:5.4), time is 120minute, temperature growth speed is 10?/min inert gas flow is 5L/min.

Jan 1, 2014

By Descarreaux. Jean

"The Abitibi volcanic belt was sampled along a cross section extending from Matagami to a point east of Rouyn. A few samples were also collected in Louvicourt township, Quebec. The major elements were determined for 344 samples, and rock names were defined using normative minerals. The analytical data were studied by means of variation diagrams. The Abitibi volcanic belt is characterized by rocks belonging to both the tholeiitic and calc-alkaline magmatic series, but they show some differences as compared to some typical reference series, particularly those from Japan. Basalt is the predominant rock type and accounts for 44 per cent of the sampled outcrops. The volcanic rocks are relatively poor in K2O and TiO2. Regionally, the volcanogenic copper-zinc mineralization is associated with the calc-alkaline volcanic sequences. Locally, within such sequences, some types of abnormal deviations from the averages are recognized only in association with the copper-zinc mineralization. The anomalies are ascribed to hydrothermal alteration consisting of the introduction of MgO and removal of N a20; enrichment in K20 is also observed where zinc mineralization predominates. Examples of such anomalous zones show that, in places, this alteration phenomenon can be quite extensive. Petrochemical characteristics can be used as geochemical ore guides in exploration programs."

Jan 1, 1973

By M. A. Bartkoski

Today?s surviving companies are being pushed to a heightened level of excellence due to market changes. Therefore, new business strategies must be explored. This paper offers a sequenced plan to retool, empower, and organize the entire team for a common goal. Integrity Process is an operating system that is very comprehensive and is integrated in every part of the business. It relies on a detailed prevention concept intertwined with accountability that produces individual efficiencies and team effectiveness. Integrity Process focuses on the importance between working from commitment motives versus compliance fears. The results are balanced in priority and truly yield a win-win for the owners, management, workforce, and the community. Integrity Process can and is being used in any industry that is challenged to optimize the relationship between people and process.

Feb 23, 2014

By U König, N Norberg

Traditionally, quality control of iron sinter has relied on time-consuming wet chemistry. However, the mineralogical composition that defines the physical properties, such as strength or reducibility, is not monitored.X-ray diffraction (XRD) analysis in combination with Rietveld quantification and statistical data evaluation using partial least squares regression (PLSR) has been successfully trialled to determine the mineralogical composition and process parameters such as the FeO (Fe2+) content and basicity of iron sinter within an analysis time of less than eight minutes per sample. The results were compared with wet chemistry data.PLSR does not require pure phases, crystal structures or complex modelling of peak shapes. The analysis is therefore easy to set up and ideal if only one property needs to be analysed. PLSR results show an accuracy for the FeO content of ±0.3 per cent for the samples analysed in this case study.Both the PLSR and Rietveld methods take the full XRD pattern into account and can be simultaneously applied on the same measurement. PLSR was found to be the more robust method if only FeO and basicity results are required. The Rietveld method helps to predict other parameters, such as the compression strength of the sinter, by monitoring all existing phases (eg larnite C2S or silico-ferrite of calcium and aluminium phases).CITATION:König, U and Norberg, N, 2015. Iron sinter process control using x-ray diffraction, in Proceedings Iron Ore 2015, pp 53–60 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By K. V. Godfrey

With the increasing need to exercise better control over mill circuits has come a requirement to develop rapid, accurate means of measuring circuit parameters. One of the most important parameters is the assay of the material in the circuit (or about to be introduced to the circuit). To date, most on-stream analysis has been performed using X-ray fluorescence equipment. Neutron activation offers an alternative method in certain circumstances, and one which has several interesting advantages. Recognizing the need for a simple, safe neutron activation unit suitable for on-stream analysis in the mineral industries, Atomic Energy of Canada Limited has designed, built and tested the SHERLOCK system. One prototype (SHERLOCK I) is located in Ottawa and is now used primarily in research. A second prototype (SHERLOCK III) is located in Vancouver at the laboratories of B.C. Research. This unit is being used for some development research and for evaluating the unit in specific applications. Most of the work completed to date has been aimed at proving the technique and in developing some of the parameters needed to design systems for a milling plant. Funding for the work has been through research grants and through sponsor¬ship by interested companies.

Jan 1, 1971

By S. Sakurai

"Gravitational force is an external body force acting on underground structures. It should be noted that gravitational force cannot be replaced with the surface traction vector (Cauchy stress) which is an internal force. This fact should be properly taken into account in a numerical analysis of underground structures, particularly for structures such as vertical shafts, tunnels, and caverns constructed at great depths. It is obvious that the gravitational force must be conserved at all times.In conventional numerical analyses, the initial state of stress of the ground medium is firstly calculated under the gravitational field. This means that the gravitational force is replaced with stress (surface traction vector), and after that only the initial stress is considered in the calculation of the stresses and displacements of the structure. It should be noted that the initial stress is Cauchy stress consisting of a surface traction vector, while the gravitational force is a body force acting on the mass of the materials. This computational approach may be acceptable for elastic problems because the principle of superposition is valid for elastic materials. However, this approach becomes questionable for elasto-plastic materials because there is no guarantee that the principle of superposition is valid for them.Furthermore, another problem exists in elasto-plastic analyses: The stress state in a plastic zone must satisfy a yielding criterion such as that of Mohr-Coulomb. In order to make the stress state satisfy the criterion, an excess stress beyond the yielding criterion should be transferred to an elastic zone existing outside of the plastic zone. This seems to always be possible, because an elastic zone always exists, no matter how large of a plastic zone appears. In some cases, however, the excess stress cannot be transferred to the elastic zone because the gravitational force must be conserved. Therefore, it is obvious that the magnitude of stress around underground structures may become large and surpass the yielding criterion at great depths where a large gravitational force exists.In this paper, it is demonstrated that in a conventional elasto-plastic numerical analysis of a vertical shaft at a great depth, all the stress components around the shaft become very small, even though a large gravitational force exists. This strange result may be due to the fact that the gravitational force is not properly taken into consideration in the numerical analysis."

Jan 1, 2015

By Reichmuth, Donald R.

Most brittle solids are relatively weak in tension and this weakness can be very significant in determining their performance in structures and excavations. Consequently, accurate knowledge of the tensile strength of brittle materials has long been recognized as important. In the past, measurements of the tensile strength of materials such as concrete, ceramics, and particularly rock have been hindered by problems encountered in fabricating test specimens and in accurately loading them. These difficulties have resulted in a scarcity of published tensile strength data. This can be readily seen in tabulations such as Wuerker's "Annotated Tables of Strength and Elastic Properties of Rocks.

Jan 1, 1968

By A Bird

Gravity gold circuits have an important part in reducing operating costs and maximising recovery in modern gold plants where coarse gold is present in the ore body. The design and selection of equipment has a vital part in the overall effectiveness of the gravity gold circuit. There are a number of associated factors that need to be taken into consideration when selecting the most suitable equipment for gravity gold circuits including occupational health and safety, security and labour requirements. This paper is a case study that outlines the validation behind the design, selection of equipment and subsequent benefits of the recent upgrade of the gravity circuit at the Marvel Loch gold mine with the main component to the upgrade being the installation of a Consep Acacia Reactor. Since the upgrade there has been a significant increase in gravity recovery, which has reduced the amount of gold reporting to the leaching circuit therefore reducing reagent consumption and overall operating costs. There has been an increase in overall gold recovery and therefore increased gold production. The benefits to occupational health and safety include the removal of toxic gases being released in the gold room during the previous practice of gold concentrate calcination and the removal of the arsenic and nickel from the gold doré, which poses a risk during refining. Manual handling and security has improved as there is no physical contact with gold concentrates during the automated process using the Acacia reactor. The total time for gold room personnel working in the gold room has also reduced from around six hours per day to less than one hour per day.With the continuing development of low grade gold deposits, there will be an increase in demand for low capital, high recovery gravity gold circuits that can significantly increase overall production while reducing operating costs.

Aug 8, 2011

By M Scoble, E Rubio

The re-engineering of manufacturing production systems has demonstrated the benefits from using production information for optimising processes. This paper explores the techniques and issues in the acquisition and analysis of mine production data for tactical decision making in production control. The use of information and operations management tools is presented in the context of block caving studies, with particular focus on the relationship between secondary breaking and LHD production performance.

Jan 1, 2000

By R. M. Santmyers

Umber and sienna, like ocher, are naturally occurring mineral pig- ments composed largely of clay permeated with hydrated iron (ferric oxide), but they differ from ocher in that they also contain hydrated manganese oxide. The presence of manganese accounts for their browner color. In addition to silica and alumina (clay) and the coloring oxides of iron and manganese, these pigments often contain lime, barium, and other metallic salts as impurities. Sienna most nearly approaches ocher in chemical composition, and the chief distinction is its physical character. It grades into ocher with de- creasing iron content and into umber with increasing manganese content. Sienna is translucent rather than opaque and is more of a stain than a pigment; as the iron oxide content is rather high (often 60 to 80 per cent), the color is strong and rich and varies from pure brown to reddish brown. This pigment raw sienna, terra di Siena, and Italian earth. is known under several names: Burnt sienna is a pigment of an orange-brown tint made by cautionsly calcining raw sienna. It is divided into two grades; American, and Italian burnt sienna. American burnt sienna is a reddish-brown pigment containing from 25 to 60 per cent iron oxide (Fe2O3). One grade, found in Pennsylvania, analyses as high as 80 per cent and is mown as double strength sienna. Italian burnt sienna is a pigment generally containing more iron than the American product, averaging 60 to 75 per cent iron oxide.3 American pig- ments of the same iron content differ materially in shade, having a Havana- brown color, whereas the Italian is more of a maroon. Italian siennas when tinted with 20 per cent of white, show a bluish tint, whereas American siennas yield a brownish or yellowish hue. Raw umber, also known as Turkey umber, Levant umber, and terra ombra, is a greenish to yellowish brown siliceous and ferruginous earth, containing a considerable proportion of one or other of the higher oxides of manganese, Mng04 and MnO2." It is similar in many respects to raw sienna except that it is much coarser and contains more manganese oxide. All umbers contain over 5 per cent of manganese dioxide. Like sienna, umber is a permanent pigment, not being injured by light or by impure atmospheres. Burnt umber (velvet brown, chestnut brown, etc.), results from the calcination of raw umber. The color is much richer and warmer than that of the raw umber. The colors are equally permanent and can be used in conjunc- tion with all other durable pigments.

Sep 1, 1931

By Heinz W. Sternberg

A method for the electrochemical reduction of the benzene ring was developed and applied to the electrochemical reduction of coal. Successive electrochemical reductions of a vitrain from low-volatile bituminous coal in ethylenediamine saturated with lithium chloride resulted in the addition of 53 hydrogens per 100 carbon atoms. Ultimate analyses and pyridine solubility of the vitrain recovered after each reduction showed that hydrogen added at the beginning has a much greater effect on solubility than hydrogen added at a later stage. Surprisingly, the removal of sulfur from the vitrain takes place only after the more reactive aromatic rings are reduced. Nuclear magnetic resonance analysis and average molecular weight determination of the extracts of the reduced vitrain samples, representing about 18 percent of the vitrain, showed that these fractions had 95 percent of their hydrogen content on saturated carbon atoms and an average molecular weight of 800 to 900. A study of the effect of operating variables on current efficiency showed that current efficiency is highest with aluminum as cathode material and with lithium chloride as electrolyte. A substantial increase in current efficiency of difficulty reducible olefinic double bonds was achieved by adding a proton donor. This result is significant in connection with the electrochemical reduction of coal which proceeds from readily reducible aromatic double bonds to difficultly reducible isolated double bonds. It is proposed that reduction is achieved by electrolytically generated and subsequently solvated electrons and hence does not require prior adsorption of the substrate at the electrode surface. This offers a distinct advantage for electrolytic reduction of sparingly or insoluble substrates such as coal.

Jan 1, 1967