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By A Guillen, J-P ChilFs

Most 3D geological modelling tools were designed for the needs of the oil industry or detailed mine planning and are not suited to the variety of situations encountered in other application domains. Moreover, the usual modelling tools are not able to quantify the uncertainty of the geometric models generated. The potential field method was designed to build 3D geological models from data available in geology and mineral exploration, namely the geological map and a digital terrain model (DTM), structural data, borehole data and interpretations of the geologist. This method considers a geological interface as a particular isosurface of a scalar field defined in the 3D space, called a potential field. The interpolation of that field, based on cokriging, provides surfaces that honour all the data. The 3D model and its parts are always consistent with the observations. New developments allow the covariance of the potential field to be identified from the structural data. This makes it possible to associate sensible cokriging standard deviations to the potential field estimates and to express the uncertainty of the geometric model. It also, for the first time, gives a statistically optimal, geologically sound way of interpolating geology, other than directly joining the dots as you do with CAD. Practical implementation issues for producing 3D geological models are presented: how to handle faults, how to honour borehole ends, how to take relationships between several interfaces into account, how to model thin beds over many kilometres, how to optimise lithological properties and how to integrate gravimetric and magnetic data. We describe all geology surfaces and volumes using implicit functions. These are then rendered onto the required sections, plans, etc. The estimation of orebody grades and tonnes, using an unbiased and optimal geostatistical technique, makes use of the stratigraphically bound 3D geology model. An application to the geological modelling of the Hamersley iron ore district, Australia, is briefly presented.

Jan 1, 2009

By J. R. Thoenen

The objective of this circular is threefold: First, to describe briefly the various modes of occurrence of sand and gravel. Second, to emphasize the need for adequate prospect¬ ing and exploration prior to the expenditure of funds for development and plant construction. Third, to describe various methods of prospecting and exploration and their application to the several modes of occurrence of sand and gravel. Sand and gravel may be found in nearly every county or township in the United States. Commercial deposits, however, are by no means so widespread. The introduction of concrete and the consequent impetus given to consumption of gravel and sand aggregates has seriously depleted deposits in some congested areas. Increasing re¬ strictions in the specification requirements for marketing sands and gravels have further narrowed the economic areas. On the other hand, the combination of increasing transportation costs and decreasing selling prices has forced the decentralization of gravel production. As a result smaller, intermittently operated, and widely scattered portable or semiportable unit plants have been encroaching on the territory formerly supplied from centrally located pits with large tr.atment plants. Generally speaking, the small portable plant can not produce any great variety of ma¬ terials to as exacting specifications nor as economically as the large permanent plant.

Dec 1, 1932

By B Y. Luan, Y Tian, W Zhou, X Lu, Q X. Cai

The unmanned driving technology in open pit coalmines is an important technology that relies on innovation to drive the development of the open pit coal mining industry in China’s transformation of growth drivers and industrial structure upgrading. It is an important path to solve the shortage of mine truck drivers in the future mining, an important way to improve the working environment of open pit mining personnel, and an important foundation for achieving flexible production capacity in open pit mining to cooperate with the coordinated development of new energy. The communication rules at intersections are key to ensuring the safety and efficiency of unmanned driving in open pit coalmines. This paper proposes a collaborative traffic strategy between unmanned trucks for the single bucket unmanned truck intermittent process system in open pit coalmines. Based on the gap theory, this paper analyses the conflict characteristics and establishes a coordinated traffic strategy for the common intersection and merging conflicts of unmanned truck trucks in open pit coalmines, A multi-agent system simulation platform was built to evaluate the coordinated traffic efficiency under different initial average gap sizes of vehicles, with intersection traffic density, vehicle speed, and gap changes as key indicators. The results show that under the simulation conditions of this article, when the initial average gap of vehicles reaches three (four) times or more of the safe distance, the coordinated traffic performance of intersection conflicts (merging conflicts) is better, and the traffic capacity of intersections is close to the traffic capacity without conflicts.

Sep 1, 2024

By H. H. Law

Large amounts of waste material in the form of flue dust are generated in the operation of copper smelter furnaces. As a result of increasingly stringent disposal, it has become important to develop methods for treating such metallurgical wastes to extract metals and convert them into salable products. A two-step closed-loop hydrometallurgical process, has been developed: (1) extraction with sulfuric acid removes about 90% of zinc and decreases the dust volume by 50%; (2) extraction with hydrochloric acid dissolves the lead and further decrease the dust volume by 75%. A process scheme for generating salable products is proposed.

Jan 1, 1992

By D. E. Cameron

"INTRODUCTION Grade control requirements for base and precious metal projects are an important input to both conceptual and feasibility mine plans. It’s the author’s experience that grade control input is insufficient at these critical stages. The few exceptions are a stimulus for this paper. A significant portion of CRC’s practice has involved assisting operations to solve grade control issues which were finally recognized as contributing to negative production variances. Even in operations perceived to be successful, deficiencies in grade control are often masked by measures taken by an operation to compensate a deficiency in one area with outperformance in another. The advantages in having a realistic and adequate grade control plan developed at an early project stage by a geologist(s) with considerable operations experience are manifold. It’s important for the geologist to prepare clear inputs into the mine plan backed by detailed supporting information in usable, flexible formats. When the decision is made to advance a project, the exploration team passes its model to a mine planner. The team doesn’t usually provide a detailed grade control plan with the block model, thus the planner tends to treat grade control as an activity to be rolled into a broader operating category. The consequences of highly compartmentalized mine planning can be severe in the long run. Once a plan is tabled, and especially once production begins, it is very difficult to improve grade control outside the fixed parameters of the operation. Major fixes tend to be costly in terms of time and dollars. Implementing needed changes to the grade control practices and culture in an established mine can present almost insurmountable difficulties. Hypothetical examples of grade control planning are presented to illustrate the author’s points. The diagrams are conceptual and schematic; any resemblance to actual deposits is coincidental. BEYOND 50¢/TON In more than a few cases, grade control cost is buried in a subcategory of mining cost with little more consideration than a plugged number. It is possible to do a word search in 43-101 Technical Reports on advanced projects and without finding reference to “ore control” or “grade control”. The idea is to reach the orebody by the shortest and least expensive means, achieving production and investor payback at the earliest possible occasion. This entails a low stripping ratio pit or a decline ramp with sills on ore to prepare the first stopes. The processes to achieve the target production, one of which is grade control, will fit into this framework. After all, there is a block model and the planner can see the grade and tons in each block. The exploration geologist whose responsibility was to bring a large percentage of the deposit into mineral resource owns the model and has released it to planning. Now comes the planning stage. Mine geologists haven’t been hired yet and they will be phased in with production. What could go wrong? Larger companies may have the geologists with operating depth who will be inserted into the mine planning discussions, but it’s not a given. Junior companies must often delegate the conceptual and detailed planning tasks to consultant groups. Is a senior-level grade control review part of the scope of work for the mine planning? If a good grade control plan is in place before the mine geology team is staffed, a key element of success is assured."

Jan 1, 2018

By William I. Weisman

Natural sodium sulfate is obtained from both brines and solid deposits. The brines almost always contain other salts with sodium chloride predominating. They may be obtained from surface occurrences, such as Great Salt Lake or from shallow subterranean deposits. Althought many sodium sulfate minerals are known to exist, only three are of commercial significance. These are thenardite, the anhydrous salt; mirabilite, the decahydrate; and glauberite, the double salt of sodium and calcium sulfate. The reader is referred to Weisman (1983) for details on mineralogy and geology of sodium sulfate minerals. Sodium sulfate deposits, either in the form of brine or solid minerals, are found in many parts of the world. Natural sources, by far, provide the primary supply of commercial grades in Canada, Mexico, Spain, and probably in the U.S.S.R., Chile, Argentina, and Turkey. In the United States, production of natural material and synthetic (including by-product) are about equal in volume and have been for many years.

Jan 1, 1984

By Dan Preston, Shane Yanagisawa, Robert Marshall, Don Deere

Geotechnical Baseline Reports often estimate the number of cobbles that will be encountered in terms of volume or weight. These estimates are practically impossible to verify in the field. ClaroVia Holdings in conjunction with Frontier Kemper Constructors Inc. developed Digital Geologist 2.0 to classify and count cobbles discharged from an EPB TBM at the RSC7 project in Burbank, CA. The system worked by using two stereoscopic laser sensors with a global shutter to scan and count cobbles at 12 frames per second. Results of the effort are revealed along with lessons learned and paths for improvement.

Jun 13, 2023

By Dezhong Kong, Jaichen Wang, Shengli Yang

"The stability control of longwall coal face is the key technology of large-cutting-height mining method. Therefore, a systematic study of the factors that affect coal face stability and its control technology is required in the development of large-cutting-height mining method in China. After the practical field observation and years of study, it was found that the more than 95% of failure in coal face are shear failure. The shear failure analysis model of coal face has been established, that can perform systematic study among factors such as mining height, coal mass strength, roof load, support resistance, and face flipper protecting plate horizontal force. Meanwhile, sensitivity analysis of factors influencing coal face stability showed that improving support capacity, cohesion of coal mass and decreasing roof load of coal face are the key to improve coal face stability. Numerical simulation of the factors affecting coal face stability has been performed using UDEC software and the results are consistent with the theoretical analysis. The coal face reinforcement technology of largecutting- height mining method using the grouting combined with coir rope is presented. Laboratory tests have been carried out to verify its reinforcement effect and practical application has been implemented in several coal mines with good results. It has now become the main technology to reduce longwall coal face failure of large-cutting-height mining method.INTRODUCTIONLarge-cutting-height mining method of more than 3.5m mining height, is one of the main methods for thick-seam mining in China. Currently, the largest mining height is 7.3m and the support capacity is 1,800mt. Shendong and Jincheng mining area have the best use of large-cutting-height mining technology (Wang, 2009). Generally, the mining height ranges from 6.5m to 7m and the support capacity ranges from 1,000mt to 2,000mt, annual output of the panel is between 10 and 12 million tons and the highest are 15 million tons. The main goal of large-cutting-height mining technology is to achieve high yield and high efficiency by increasing the advancing speed of longwall face (Yuan, 2011- 2012). However, in certain geologic conditions, rib spalling and roof falls in the unsupported area often occur. Because of the large tonnage of large-cutting-height mining equipment, once the rib spalling and roof falls cause the equipment to be out of alignment, the face advancing speed could be affected seriously that in turn affects the output (Yang, 2012). Therefore, studying the failure mechanism and control technique of coal face in large-cuttingheight mining method is of great significance."

Jan 1, 2015

By EDGAR K. SOPER, Clarence A. Wright, DOUGLAS C. LIVINGSTON, Thomas Varley

In 1917 the Federal Bureau of Mines and the University of Idaho arranged to cooperate in an investigation looking to the improvement of mining and milling methods in the mining districts of the State of Idaho, with an especial view to the wider development of the minerul deposits and greater efficiency in the treatment of the lowgrade ores of the State. This work has been made possible lnrgely through the generosity and active assistance of the mine operators, especially certain companies in the Coeur d'Alene region. As the first step in the work under the cooperative agreement it wa.s decided to gather all data possible on the various mining districts throughout the State, both active and abandoned, in order to ascertain their potential possibilities, especial attention being paid to methods of metallurgical treatment and to the solution of the many metallurgical problems in order to effect a greater commercinl saving. With this plan in view, field work was begun in the latter part of May, 1917, and was continued during the summer. E. K. Soper, formerly professor of mining, University of Idaho, and now dean of the mining department of Oregon Agricultural • College, Corvallis, Oreg., visited the mining districts in central and southwestern Idaho and also some of those in the northern part of the St.ate. D. C. Livingston, professor of geology at the University of Idaho, Moscow, Idaho, also visited some of the mining districts in central Idaho during the summer; in addition, much valuable information he had gathered on former trips to many other districts is included in this report. Credit is also due Mr. Livingston for the maps covering the State, as well as the bibliography nt the end of each chapter. Thomas Varley, superintendent of the Seattle mining experiment station of the Bureau of Mines, spent a short time in the field, principally in the mining districts in central and . northern Idaho, and made a brief visit to the southwestern districts with Mr Soper. The field work of Mr. C. A. Wright, metallurgical engineer of the Bureau of Mines, in direct charge of the cooperative work, was chiefly in the Coeur d'Alene region. Mr. Wright visited nearly all of the mining districts in the region and devoted most of his time to studying the milling methods. The results of the investigation are set 1iorth in this bulletin. The bulletin aims to give the l9Calities of the various mining districts, and the nature of the present operations and those that have been carried on in the past. The geology is discussed only in a general way, the descriptions being intended more especially to bring out the types of ore deposits and the character of the ores, a knowledge of which is essential in determining the proper treatment of the ores. The writers do not wish to imply that all districts mentioned in this bulletin were visited during the summer of 1917, for a great deal of the material has been gathered from other reports, especially from publications of the United States Geological Survey. However, it is hoped that this report will be of help to those who are interested in mining in the State of Idaho. The plan is to continue the field work and subsequently publish the results of the investigations in much more detail, with greater emphasis given the metallurgical treatment of the ores and the problems involved.

Jan 1, 1919

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By S. M. Copley, M. Yankova, E. Y. Yankov, J. A. Todd

"Nanophased coupled growth structures, with spacings of -10 nm, have been observed in banded microstructures produced by laser melting hypoeutectic Ag-Cu alloys. These coupled growth structures comprised a Cu-rich phase of width - 1 nm and a Ag-rich phase of width - 9 nm. In this paper, microstructural observations of nanophased coupled growth structures in hypo eutectic AgCu alloys are presented. Laser beam velocities for the transition from banded to microsegregation free microstructures are modelled and compared with experimental values. Models are presented to show that, at a critical undercooling, initial growth of a Ag-rich, metastable, extended solid solution is rapid but slows to a halt as copper is partitioned into the liquid at the solid/liquid interface. Following nucleation, the coupled growth structure then grows until the partitioned copper is consumed, at which point growth of the Ag-rich solid solution is again accelerated. This cycle then repeats resulting in banded microstructures comprised of 750 nm of the Ag-rich extended, metastable solid solution, followed by 250 nm of the coupled growth structure.1. Structural Studies of Laser Melted and Resolidified TrailsPresented here are observations of laser melted and resolidified trails in Ag-Cu alloys obtained at beam velocities ranging from 0.7 to 34 cm S·I. When the laser beam is scanned along the surface (positive x-direction) with a velocity Vb a melt pool with the shape given in Fig. 1a moves with the beam. The isotherms move with the velocity, Vi,. = Vb cos.p. Calculations employing the thermal analysis of Kou, Hsu and Mehrabian [1] for the beam velocities of this investigation and for the thermal properties of AgCu alloys, indicated that, .p, the angle between the isotherm velocity and beam velocity should be small at the surface where microstructural studies were made. This prediction was supported by observations of trail cross-sections. Based on these observations, and the calculations which include latent heat effects, the isotherm velocity for observations near the surface in our investigation was taken to be 27 cm S-I."

Jan 1, 1994

By T. G. Joseph, A. Chamanara

ABSTRACT: The chicken and egg scenario — where adverse truck motions cause ground deterioration and poor ground profiles cause adverse truck motions — is a downward deterioration spiral dominating our industry. If we remove one action, the reaction stops. A simple truck to excavator load data analysis and wireless communication system is outlined, which will provide visual assistance to the excavator operator in achieving improved load placement and balance in a truck body. This will reduce subsequent hauler duty cycle adverse motions and g levels that contribute to structural fatigue, higher tkph, reduced tire life, and ongoing maintenance of haul roads.

Jan 1, 2012

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018

By Ali Behrad Vakylabad, Esmaeel Darezereshki, Babak Koohestani

As a by-product of the steelmaking industry rich in iron and zinc, electric arc furnace dust (EAFD) landfill disposal is restricted in many countries due to the metal lixiviation risks. Several approaches have been examined to recycle or reuse EAFD. Hydrometallurgical methods mainly include the preparation of pregnant acid leached solution (PLS) using inorganic acids followed by selective metal recovery using different methods. We herein proposed a hydrometallurgical process initiated by acid leaching and finalized by thermal treatment to produce nano-ZnO from EAFD. At the condition of this study, only 67% of zinc was leached by sulfuric acid from EAFD into PLS while 98% of surplus leached iron was removed through precipitation by sodium hydroxide. Additional purification of iron removed PLS was accomplished using di-2 ethylhexyl phosphoric acid to extract Zn+2. The addition of ammonium hydroxide to purified PLS provided (Zn(OH)2)3(ZnSO4)(H2O)5 as the final precursor for nano-ZnO that ultimately transformed to nano-ZnO (60 ± 6 nm particle size) at 850 °C. The achieved results were scrutinized through various tests and analyses including TEM, XRD, SEM, EDS, FTIR, and TGA.

Mar 10, 2021

By C. Dorfling, M. Tadie, S. Grobbelaar

The physicochemical properties of the complex electrolytes used in direct copper electrowinning are an important consideration for the development of a high-fidelity model of the process. Direct electrowinning electrolytes typically contain a high background of metallic impurities. The effect of metallic ions on the properties and accompanying change in the limiting-current density for copper reduction have been the subject of several studies. Although various empirical correlations have been published for describing the physicochemical properties of electrowinning electrolytes, the correlations are only applicable to a limited range of conditions and cannot be extrapolated without further validation. Consequently, in this paper we validated existing physicochemical property correlations for the full range of operating conditions applicable to direct copper electrowinning and developed a new correlation for predicting the associated limitingcurrent density for copper deposition. Following, we evaluated the benefit of using the validated correlations as a component of a dynamic electrowinning model.

Jan 1, 2023

By R. D. Williams

Several hydrometallurgical leach processes have been recently proposed for the recovery of copper from copper concentrates. These include the Cymet Process of Cypress Metallurgical Processes Corporation, the Arbiter Process of the Anaconda Company, and the Treadwell Process of Treadwell Engineering company(1). These processes and similar processes for recovery of other minerals, have several phenomenological similarities which make their quantitative description difficult at best. These include (a) the presence of more than one phase, (b) non-uniform mineralization of the feed concentrate, (c) surface and diffusional effects, and (d) a particle size distribution which varies with time. Semi-theoretical, rather than purely empirical, treatment of such processes in their developmental stages will result in a better understanding of the physico-chemical mechanisms in effect. This, in turn, will allow reliable process designs to be made on reasonable time scales for reasonable development costs. Once a production unit is built, such an approach will provide straightforward methods for process control and optimization. A research and development effort to determine criteria and procedures for semi- theoretically characterizing such mineral leach recovery processes has been initiated in a joint venture by the Arizona Bureau of Mines and the College of Mines at the University of Arizona. This group has as its task the mathematical characterization of hydrometallurgical leach recovery processes using semi- theoretical mechanisms for the underlying phenomena. The resulting models are experimentally verified and parameterized on the laboratory scale in such a way that they can be utilized with similarity criteria to provide reliable scaleup to production designs. This discussion will be centered around the elements of such an approach and how they fit together.

Jan 1, 1975

By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, in spite of the low-grade nature of the ore, has become one of the largest production-scale and most profitable non-ferrous metal mines in China. The successful application of hydrometallurgy as well as proper engineering design are the key factors for large-scale development of the Zijinshan gold-copper mine. In this contribution, the practical experience acquired in the development of the Zijinshan gold and copper mines is summarized. This covers most aspects of the production process including mining, beneficiation, ore stacking, heap (bio)leaching, carbon-in-leach, solvent extraction, electrowinning, wastewater and tailing treatments. The authors believe that this practical experience will not only help to promote the development of hydrometallurgy, but can also serve as a model for other gold and/or copper plants around the world.

Jun 3, 2020

A variety of algorithms and methods are being used by the mining industry today to map mineral resource for reserve estimation. The traditional methods including Polygonal, Sectional and Inverse Distance methods are relatively easy to understand and implement. They have served industry well for several decades and should continue to do so for the large bulk mineable deposits with very regular geometries with relatively small variation in grade.

Jan 1, 1992

By Hillary W. Clair

An equation is derived for the rate of reaction of a sphere of metal oxide in a restricted enclosure through which a reducing gas is flowing . The equation takes into consideration the reaction rate coefficient , transport through the gas and through the porous shell of reduced oxide , the rate of gas flow , and the volume of the enclosure . The equation serves as a model for predicting the course of reduction of a particle of metal oxide in a shaft furnace .

Jan 1, 1964