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By I. Peerawattuk

Growing demand for Li-based battery technologies is leading to an unprecedented growth in the lithium industry. Although innovation in battery technologies has pushed lithium into the spotlight, lithium was not always known for its application in batteries. The primary use of lithium—prior to the introduction of commercial lithium-ion batteries in the early 2000s—was in the ceramics, glass, grease, and the medical industry. Before being converted into usable forms, lithium products must be upgraded from the raw material. Processes for recovering lithium may involve: thermal treatment, water leaching, solar evaporation, ion exchange, carbonation, and electrodialysis. Presented, is a historical review of lithium applications and the different techniques of converting lithium-rich minerals and brines into usable products with additional discussion on future lithium extraction processes.

By Roy J. M. van Lier

In industrial aqueous solutions, germanium generally occurs in trace amounts amid high concentrations of other metals, such as zinc, copper and iron. Separation of germanium from these metals as well as its isolation from gallium and indium pose a real challenge to the hydrometallurgist. After a brief discussion of the aqueous chemistry of germanium, this paper reviews the flowsheet of the Apex Mine in Utah. The Apex property was the only mine in the world to be operated primarily for production of gallium and germanium, but apparently closed due to great operating difficulties. Several process variants proposed for the treatment of the Apex ore, including bioleaching methods, are addressed. Following a more general description of the behavior of germanium in hydrometallurgical zinc processing streams, available technology for its recovery from aqueous solutions is summarized. Precipitation, solvent extraction, ion exchange, electrowinning, ion flotation and liquid-membrane separation are all outlined in terms of the aqueous chemistry of germanium. Finally, the production of high purity germanium dioxide and metal is briefly discussed

Jan 1, 1995

By R. W. Bruce, K. W. Downes

"IntroductionSULPHUR production in Canada from all sources for the year 1953 amounted to about 375,000 tons. Except for 16,000 tons of elemental sulphur derived from natural gas, this production was in the form of by-product pyrites, liquid sulphur dioxide, and sulphuric acid. In the same year, Canadian industry imported 359,000 tons of elemental sulphur from the United States. The cost, including transportation charges, to Canadian consuming plants ranged from $35.00 to $45.00 per long ton, depending upon location.Although most of the sulphur consumed is used in the oxidized form it is often most convenient to buy sulphur in the elemental form, and convert it to sulphur dioxide or sulphuric acid in situ as required. This is because elemental sulphur is easily shipped and stored, weighs only half as much as an equivalent quantity of sulphur dioxide and one-third as much as the corresponding quantity of sulphuric acid, and is readily converted to these forms in a sulphur burner. A process, therefore, which could economically recover elemental sulphur from sulphide ores would be most attractive.Since the turn of the century, notable improvements have been made in extractive metallurgy, but until recently only limited attention has been paid to the possibilities of elemental sulphur recovery. This has been due to the plentiful supplies of cheaply mined Frasch sulphur which have been available on the world markets."

Jan 1, 1955

By Daniel Lachapelle, Nuri Hmidi, Turgut Yalcin

"Simulation can serve as a convenient tool in studying the behaviour and performance of grinding circuits by facilitating the evaluation of various scenarios and identification of optimum operating conditions. This technique was applied to the St Andrew Goldfields Ltd.’s Stock Mine Mill which is a 1300 tpd gold milling facility, offering custom milling services as well as processing the Company’s own ores. Lack of adequate instrumentation in the mill poses a challenge in attaining optimum performance especially with changing ore types and characteristics. The grinding process is monitored essentially by manual measurement and adjustment of pulp densities at various streams. A simulation program was designed to assist in the effective implementation of this mode of grinding control. Product sizes from both the primary and secondary grinding circuits were correlated empirically to relevant process variables using a database formed from the results of past sampling campaigns. The simulator was created in Microsoft Excel whose data analysis and optimization tools coupled with its Visual Basic Programming capabilities were found to provide an excellent environment for the development of a cost-effective, efficient and user-friendly simulation program.INTRODUCTIONGrinding is often a very costly unit process in milling operations, mainly due to the excessive energy consumption associated with it. For example, for a Canadian copper-zinc flotation mill, grinding was listed as being the most costly item taking up 30.4% of the total milling expenses, followed by the flotation cost at 2 1 .O% (Kidd Creek Mines Ltd., 1982). A survey on 45 copper flotation mills around the world showed the average grinding cost to be 34.5% of the total milling cost (Weiss, 1985).Overgrinding aggravates the cost issue, while insufficient grinding either causes loss of valuable minerals to tails or results in low-grade concentrates. Therefore, it is essential that grinding circuits be carefully controlled and monitored. To this end, a great deal of effort has been devoted over the years to the modelling and simulation of grinding systems in order to assist in the efficient running of these processes."

Jan 1, 2001

By R. M. Taylor

Lime addition to acid mine drainage (AMD) leads to precipitation, predominantly of metal hydroxides and calcium sulfate, and is the benchmark for remediation by precipitation. Geo2 Limited of Melbourne, Australia has developed and patented a novel alternative precipitation scheme based on the formation of mixed valency, M(I1)-M(III), hydroxide sulfate salts. When the composition of AMD is appropriate, the Green Precipitate Process provides a useful and more effective alternative to conventional liming. The characteristics and utility of the Green Precipitate Process are described in terms of the underlying chemistry, and a case study where the Green Precipitate process outperforms conventional liming. A mobile pilot pipe reactor rig which was built by Geo2 to demonstrate the process, and used successfully in both Australia and the United States, is described.

Jan 1, 1998

By K. C. Dean

This report is the first of a series concerned with processes for producing magnesium. These reports will evaluate metallothermic, carbothermic , and electrolytic production methods, and will furnish a cost basis for comparing the processes. Areas deemed most promising for future research will be delineated for each procedure. This report presents briefly the history of the metallothermic process, and describes the operations of the Defense Plant Corp. (DPC) plants that employed the process. A hypothetical plant designed to produce 12,000 tons of magnesium per year, using ferrosilicon as a reductant, is described, and raw materials, energy, and major equipment requirements are estimated. Several process modifications are suggested for future research.

Jan 1, 1965

By Ingunn Opland, Silje M. Tinderholt

Drill and blast project in Norway’s capital. The contract consists of 7 rock caverns (350–950 m2), 9.2 km tunnels, and four shafts. With 110 blue-collar and 31 white-collar, the project produces an average of 16–21,000 m3 hard rock per week, with a total of 19 tunnel faces. Weekly, nine grouting rounds for water control, 800 m3 shotcrete, and 1,200 bolts are required, and 60 trucks leave the site pr. day. Challenges include blasting in densely populated areas, planning and coordination to maintain high production, obtaining a CEEQUAL certification of very good, and transporting rock on Oslo’s main highway.

Jun 13, 2023

By Alessandro Navarra, Joël P. T. Kapusta

"The converting cost modeling software introduced by Ng et al. in 2005 [1] has been extended to consider the reprocessing of reverts and copper scrap. The original model evaluated the operational costs of a Peirce-Smith converter; algebraic relationships had been implemented with arrays (to represent matrices, vectors and scalar ratios). The new software brings flexibility to the underlying thermochemical balances, by using linked-lists instead of arrays. It is now possible to consider the blending of several feeds, including reverts and scrap.The software computes the length of the converting cycle from the Fe and S content of the charge together with the blowing rate; the times required for other operations (charging, skimming and idle time) are also accounted for. The costs of consumables such as flux, fuel, oxygen or compressed air are all evaluated. Downtime, labor, and materials for converter lining repairs are also considered. The software is easily extended to examine the costs of alternative operating strategies or injection technologies such as sonic single pipe injection and sonic shrouded injection. The potential cost benefits of alternative operating procedures and technologies are discussed through example calculations."

Jan 1, 2009

By R. T. Jones

"SynopsisScientific progress relies on the publication of ideas and experimental results that can be replicated, tested, and improved over time. The first printed book on metallurgy to have been published in Europe is considered to be De la Pirotechnia, written in Italian by Vannoccio Biringuccio, and published in Venice in 1540. Together with De Re Metallica, written by Georgius Agricola and published in Latin in 1556, this can be considered to mark the start of scientific and technical literature in this field. Scientific publishing of journal papers has been in existence for 350 years, since the world's oldest and longest-running scientific journal, the Philosophical Transactions of the Royal Society, was first published in London in 1665.The nature of scientific societies has changed significantly since the early days when regular meetings were held to discuss science and conduct experiments, and the reading of scientific papers took place, and publication of papers was undertaken to record the proceedings of meetings, often including rather robust debate. In today’s world, there is a plethora of publications, and it is close to impossible for anyone to keep up with the vast flow of information. International conferences with hundreds of presentations have taken the place of the local meetings that used to discuss a single paper or experiment. In this frenetic environment, it is essential that researchers are able to trust the material they read.The system of peer review is used to maintain standards and to improve the quality of papers. This vital system is, however, significantly flawed. There is little incentive for reviewers to invest sufficient time in picking up all errors in publications, and any ineptitude on their part is usually protected by anonymity. It has reached the point where some reviewers have mistakenly permitted the publication of hoax papers deliberately presented with a complicated scientific facade. In light of such astounding inadequacies, perhaps a more open review process would be an improvement. Electronic publishing allows errata to be linked to the original papers.There is an increasing trend towards open access for papers in scientific journals and conference proceedings, which helps to reach as wide an audience as possible. This also supports the statement in the Universal Declaration of Human Rights, which says ‘everyone has the right freely to … share in scientific advancement and its benefits’."

Jan 1, 2015

By R. N. Orava

TO the author's knowledge, only one satisfactory high-resolution technique for etch-pitting dislocations in Cu-Zn alloys has been published.' In that account, pits in 70/30 brass single crystals were produced by etching electrolytic ally in a 30 pct orthophosphoric acid bath. Thereafter, observations were made from surface replicas by electron microscopy. The method of pitting and observation permitted the high resolution necessary for the distinction of individual dislocations in arrays of pile-ups. However, no comment was offered concerning the possibility of obtaining pits which are amenable to optical resolution. Moreover, for adequate results, the electrolytic pitting process is invariably preceded by a polishing stage which could obscure the surface features of interest. Consequently, it would be desirable to be able to delineate, by solely chemical means, dislocations which could be detected by both optical and electron metallo-graphic techniques. This was achieved by the simple expedient of modifying two etchants reported by young2 to reveal dislocations on the (100) planes of pure copper. Single crystals of 70/30 a brass, described previously,3 were sectioned to provide a surface parallel to a set of {100) planes, mechanically polished, and subsequently electropolished at 2.4 v in a solution comprised of 2 parts H3PO4, 4 parts ethanol, and 3 parts water. The inclusion of ethanol tended to inhibit nonuniform surface attack. Etch-pitting was effected by a 2 to 3 sec immersion in a 70 pct aqueous solution of HNO3. The samples were then washed in a fast-flowing stream of water, and rinsed further in distilled water, and ethanol, before drying. It is important to note that this reagent should be either used immediately after mixing, or, if allowed to cool, reheated to about 35°C prior to use. No pitting was obtained at room temperature. Typical results are shown in Fig. 1 where (a) is an optical view of the pitted surface and (b) is an electron micrograph of a silicon monoxide replica shadowed with tungsten oxide. The former is characteristic of a somewhat longer etching time (-6 to 8 sec) which varied with bath temperature. Similar pits accrued from a 1/10 aqueous dilution of another of Young's solutions2—2 M FeC1,6H20 and 7.8 M HBr.

Jan 1, 1968

By D. C. Seidel

The role of surface charge in soluble salt flotation, which was developed in Part 1, is extended to relate the theory to the specific phenomena of KCI- NaCl separations. Temperature-collector solubility relationships, metal ion activation, and particle size effects are discussed.

Jan 1, 1967

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012

By J. Y. Kim

Lead ions originating from galena during processing of complex sulphide ores migrate to "cover" the surface of sphalerite and iron sulphide mineral particles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead-activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide particles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.

Jan 1, 1995

By E. Chiyangwa, L. Schoeman

The commercially successful electrowinning and refining of metals typically requires the optimization of the electrolyte composition and operating parameters to produce high quality compact electroplated metal. The prediction of the effect of the electrolyte composition on the structure and morphology of the plated metal remains a challenge. Initial work on the use of polarization measurements to predict and control plating behaviour in electrowinning plants involved potentiodynamic polarization but proved unsatisfactory as accurate and repeatable predictions could not be achieved. The aim of the present work was to develop a reliable galvanodynamic technique specifically applicable to the plating of zinc from sulfate electrolytes with which plant operation may be controlled and optimized. Initial results indicated that plating and nucleation potentials could be measured accurately and repeatably and that the relationship between the two could be used as a predictive tool for the effect of electrolyte composition on the quality of zinc electrodeposits.

Jan 1, 2014

By F. Fournier Dit Chabert, F. Tancret, J. François Castagné, R. Le Gall

During the repair of turbine blades by a laser cladding process, it is observed that interdendritic cracking occurs in the heat affected zone (HAZ). Auger electron spectroscopy, performed on sample broken at high temperature, reveals interfacial sulfur segregation, which is known to be one of the main causes of microcraking in the HAZ during welding processes. Moreover, thermal gradients generated by the process are responsible for important thermomechanical stresses. In the present work, the finite element code Comsol Multiphysics is used to simulate the laser cladding process in order to determine both the thermal field and, using an elastoplastic law, the stress field inside the component. The originality is that the temperature history calculated in the thermomechanical model is extracted then injected in a segregation model in order to calculate the local segregation behavior. This model can be eventually used to predict the risk of cracking as a function of process parameters and alloy chemistry.

Jan 1, 2006

By Michel Fillon

Hydrostatic assistance is a commonly used method to improve limited load carrying ability of tilting-pad thrust bearings during transient states of operation of the vertical shaft hydro-generators. Despite of special hydraulic equipment (as pumps, valves etc.), it also requires manufacturing of special recesses/pockets at the pad sliding surfaces, into which oil is injected under high pressure. It allows to lift the rotor before start-up of the machine and form a hydrostatic film between the pads and the collar. There is a quite wide variety of geometry of recesses (shape, depth, size) met in practical large bearing applications. The presence of a hydrostatic pocket (usually located in the sliding surface above the pivot area, where thin film, high oil pressure and temperature are observed) affects bearing performance under hydrodynamic operation. In theoretical researches, there is an almost common practice not to include hydrostatic recess in THD or TEHD analysis. This is probably due to the problems with obtaining solution for oil film geometry with pocket, with pocket depths order of magnitude larger than gap thickness. In this paper, an attempt was taken to study the effect of the lifting pocket on THD performance of a large tilting-pad thrust bearing of ltaipu power plant. Bearing performance was evaluated including recess shape for several cases of its depth. The results show, that hydrostatic recess changes calculated bearing properties quite significantly, especially in the vicinity of the pocket.

Jul 31, 2018

By C A. Myburgh, S Craig, K Deb

In focusing on open pit mine scheduling, one of the biggest areas that a mining engineer can add value is in the area of cut-off grade optimisation. It is not atypical to add up to an extra 20 per cent in value by bringing forward higher-grade ore and deferring costs into the future.There are many techniques available to maximise net present value (NPV) when applied to open pit mine scheduling. That in itself raises the question of why so many of these techniques exist. The short answer is that none of these techniques are robust. Every time the problem changes, the algorithms also have to change.Instead of trying to make a problem fit the constraints of an existing technique, there is much to be said for usefully hybridising different approaches. This paper describes an innovative approach where evolutionary algorithms are combined with both local search and linear programming. The goal is maximising NPV through optimisation of cut-off grade policy and extraction sequence for an open pit mine. The cut-off/cut-over grade policy produced caters for multiple processing streams and stockpiles.Finally we demonstrate the quality of the algorithm by comparing some results with a well-known mathematical solution.CITATION:Myburgh, C A, Deb, K and Craig, S, 2014. Applying modern heuristics to maximising net present value through cut-off grade optimisation, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 155–164 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By W. M. Myers

Certain minerals possess inherent color and other properties that make them suitable for the pigmentation of paints, mortar, plaster, concrete, face brick, and other materials. Their production is one of the most ancient of mineral industries and their use by primitive man is well known. These natural pigments have some economic factors in their favor, particularly wide geographic distribution, low cost of production, ease of preparation, chemical stability, and permanence in use so that they continue to form the basis of a small but useful industry. When used in paints such pigments act as a filler and supply body and opacity in addition to color. Natural mineral pigments are prepared for the market by the comparatively simple operations of washing, grinding, blending, and calcining. Any one, or all of these processes may be applied to a single pigment. The development of synthetic pigments and the use of by- product materials have introduced competition with the products of nature and are having a growing influence on the economic position of the mined minerals.

Jan 1, 1949

By J. M. Rapkoch

In late October 1996, an acid plant at a major U.S. copper smelter was faced with unexpected and rapidly increasing pressure drop across the gas cooling tower in the acid plant, indicating a build-up on the packing. This threatened to halt operations if not resolved. Earlier that month, a smaller vessel in the acid plant was found to be completely plugged with lead sulfate. It was feared that a similar fate awaited the gas cooling tower unless the scale build-up was stopped. Although lead sulfate is present in most copper smelter acid plants, this accumulation was unusually severe. An investigation was launched to find the source of the lead, determine how lead is transported to the gas cooling tower, recommend operating practices to prevent such severe scaling, and seek ways to recycle the lead value in the scale covered polypropylene packing. Late in the investigation it was learned that the lead originated from an improperly executed recycling program.

Jan 1, 2000

By William M. Thornton

[Owing to the comparatively high freezing point of nitroglycerin (14, 15, 16, 17, 18, 23, 37, 38)3/ - 1.9° C. and 13.0° C. for the labile and stabile modifications, respectively, as determined by Hibbert (16) - manufacturers of dynamites have incorporated into the liquid portion of these composite explosives various substances capable of participating in an explosion, to depress the above-mentioned freezing point. Aromatic nitro-compounds, chiefly nitrobenzenes, nitrotoluenes, and nitronaphthalenes, have been used to a considerable extent (11), but such nitrosubstitution products have not proved altogether satisfactory, as has been shown clearly by Naoúm. (14). Consequently there has been a strong tendency in recent years to replace them with one or more of several nitric esters, among which the following (29, 35) have been prominent: Dinitrochlorhydrin (monochlorhydrin dinitrate); nitrosugars, for example, sucrose octanitrate (19); tetranitrodiglycerin (diglycerin tetranitrate); nitroglycol (ethyleneglycol dinitrate); and diethyleneglycol dinitrate (13, 46, 47). Of these, nitroglycol (33, 4l, 45, 48, 49, 65) is outstanding in importance. As the Bureau of fines is naturally interested in the analytical chemistry of the "explosive oils," it seemed desirable to bring together in this report the widely scattered experimental work covering the problem of differentiation that has appeared in various chemical and physicochemical publications.]

Jan 1, 1941