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By J. A. Woolf, E. S. Leaver

The presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent. of cyanide-soluble copper and the effect of zinc in the cyanide solution. Part I.—Copper in Cyanidation The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent. of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust. Solubility of Copper Minerals in Cyanide Solution In order to determine the solubility of copper minerals, including metallic copper, under the usual conditions for cyanidation, experiments were conducted with synthetic ores. Each ore sample was prepared by mixing the particular pure copper mineral with barren sea sand. Both the mineral and sand were ground to pass 100 mesh before they were thoroughly mixed. The percentage of copper in each head sample was determined by direct assay, excepting the metallic copper sample, which was computed on weights before mixing. Table 1 gives the results. Azurite, bornite, chalcocite, cuprite, malachite and finely divided metallic copper are readily and completely soluble under the usual conditions for cyanidation. Enargite and tetrahedrite are sufficiently soluble to cause an excessive loss of cyanide, and they also cause fouling of solutions with arsenic and antimony. Precious-metal ores containing small percentages of chalcopyrite or chrysocolla may give satisfactory returns with the usual cyanidation.

Jan 1, 1930

US 4,134,618-Method for restoring an underground reservoir subsequent to the solution mining of an ore body of uranium, copper, nickel, vanadium, molybdenum, silver, rhenium, or selenium. Clean water a cycled through the mined area, via the injection and production wells used during mining, at a flow rate sufficient to entrain residual dissolved solids. The solids are separated at the surface and disposed of, e g., in a deep disposal well, while clarified water is recycled C A. Kossack, assigned to Atlantic Richfield Co. Jan 16, 1979 4 pp. (299-5) Filed. 12-29-77 (865,646) US 4,155,982-In situ leaching of a subterranean uranium ore deposit The ore is leached with a dilute aqueous solution of ammonium bicarbonate containing a small amount of hydrogen peroxide in order first to convert tetravalent uranium in the ore to the hexavalent state and second to dissolve the hexavalent uranium preferentially to the other metals or elements commonly occurring In such ore The uranium- enriched leach liquor IS brought to the surface, and the uranium recovered by means of adsorption on a particulate ion exchange resin, elution with an acid, and treatment with ammonia to precipitate relatively pure ammonium diuranate. G G. Hunkin, T P. Fife, and J R Stano, assigned to Wyoming Mineral Corp. May 22, 1979. 13 pp (423-7). Filed: 10- 9-74 (51 3,445). Same: Canadian 1,027,849, dated Mar. 14, 1978. US 4,157,847-In the mining of sulfur by the Frasch process hot water accumulating above subterranean sulfur from previous mining operations is recycled downward to contact and heat additional solid subterranean sulfur. Advantageously, pressurized and superheated drive water from above ground is commingled with the underground water to raise its temperature before it is recycled downward R. L Williams, R L Latiolais, J. L Gabriel, and R. L Bouis, assigned to Freeport Minerals Co June 12, 1979. 13 pp (299- 6) Filed 7-28-77 (81 9,879). US 4,158,76%1n this method for determining the uranium content of a solution obtained in the solution mining of an underground uranium ore deposit, the intensity of gamma radiation from the Th-234 daughter of U-238 emitted by the solution is determined as it impinges on a scintillator after being passed successively through filter foils of a ytterbium- tin alloy, a lutecium-tin alloy, and a hafnium-zirconium alloy This scintillation is evaluated as a measure of the uranium content To assure that the uranium-thorium conversion has reached a stable state, the measurement should be made about three months after the uranium solution has been produced R C Smith, assigned to Westinghouse Electric Corp. June 19, 1979 11 pp. (250-255). Filed. 10-20-77 (843,770).

Jan 1, 1980

By John W. Taber

The Bohemia mining district is a small but intensely mineralized area in western Oregon . For its size , it has made a substantial although somewhat sporadic production of gold throughout a long period of years . The veins also contain lead, zinc , and copper, but in the past these metals have not been recovered in important amounts . In reviewing the progress of mining activity in the district , an effort has been made to gather under one cover all available information on former operations , including methods of mining , production, and geology pertinent to the ore deposits , problems encountered, and other factual data that may affect future mining in the district . A special effort has been made to assemble as many maps of former workings as possible in order that these may be preserved and readily available to assist in future exploration. The data presented herein are based on brief reconnaissance examinations made during several weeks spent in the field in September 1946. These are supplemented by information obtained from various individuals actively or formerly connected with operations in the district . Only the principal properties and several of the more outstanding prospects were actually examined. Many of the older workings were inaccessible.

Aug 1, 1949

By Rob Farnfield

In the UK all new developments, including mines, quarries, tunnels, etc., are subject to a system of planning control. If the use of explosives is anticipated then such developments will attract a number of so-called ‘planning conditions’ relating to the blasting operation. This paper will outline a ‘typical’ set of conditions and how operators ‘plan to comply’. British Standards relating to both human and structural response are also reviewed and contrasted to the typical planning conditions previously outlined.

Jan 1, 2005

By A. Davis, K. Nelson, C. Webb

Abandoned mines in parts of the Black Hills of South Dakota have the potential for acid rock drainage. For this work, ten sites were examined on Black Hills National Forest land or on private land whose drainage could affect Forest Service land. Water samples from all the sites had pH values less than 6. Results of analyses from water samples and rock samples showed a correlation between metals content and pH. Acid-base accounting was used to determine acid drainage potential of the sites. One site (King of the West Mine) had a high potential for acid generation; fortunately, little or no surface runoff leaves the mine site. Six sites appeared to have moderate potential, including the Minnesota Ridge Mine, which currently is being remediated. Three of the sites had low acid drainage potential.

Jan 1, 2004

By Shaohua Ju, Huang Chang-yuan, Lu Shuaidan, Peng Jin-hui, Wu Guoqin, Yaqian Wei, Zhang Li-bo

"The contrastive studies of microwave and conventional roasting copper residue from zinc hydrometallurgical was carried. The experimental results showed that the microwave roasting has the higher dechlorination rate in the same condition such as temperature, heat preservation time and atmosphere. When the samples with 100 mesh grain size, the Cl content turned from 14.27% to 1.33% and the dechlorination rate achieved over 90% at 400°C with 2h microwave roasting. And in the same conditions, the materials' dechlorination rate after conventional roasting just reached around 78%. The phase changes of the roasting process was investigated with X-ray diffraction analysis.IntroductionCl element can be accumulated gradually in the solution of Zinc hydrometallurgical system. When Cl content in electrolysis solution comes up to 100 mg/L, the stability of electrodeposits process would be severely affected [ 1]. It would not only accelerate the consumption of cathode and anode plate, elevate the power consumption, but also cause serious corrosion of device, increase production costs and lower the quality of electrolytic zinc [2]. Thus, C1- contained in the solution should be removed before electrodeposits."

Jan 1, 2013

By Kubik K

Recent significant advances in the Global Positioning System (GPS) have contributed to making real-time kinematic/dynamic process for decimetre to centimetre-level positioning more reliable and ready for the production-use. As a result of research and development efforts in this area, a robust real-time kinematic (RTK) GPS positioning prototype system has been established at QUT for both scientific and engineering purposes. This system is finding applications in a wide range of automobile robots or automatic guidance vehicle systems. This paper first summarises the theoretical basis necessary for centimetre real-time kinematic positioning, then gives a brief description for the real-time dynamic GPS system developed at QUT. The paper summarises the results of a designed vehicle tracking test. The results demonstrated that the differences between RTK filtering solutions and OTF solutions are in the order of magnitude of about 20 centimetres and the accuracy of OTF solutions are in the levels of two centimetres. This confirms that the RTK system delivers three-dimensional position with decimetre-to-centimetre accuracy. This particular RTK processing system is robust and reliable, although the system is referred to as a prototype and will be further developed.

Jan 1, 1997

By R. H. Walton

"In recent years the recovery of copper from low grade oxide ores has received widespread attention. The cost of treating such ores using conventional technology, such as milling and flotation, is frequently prohibitively high and copper recovery is generally low. The introduction of heap leaching, solvent extraction (SX) and electrowinning (EW) has resulted in high recoveries, good copper cathode quality and low production costs. This technology has now been successfully applied on a worldwide basis.This paper reviews the various process and design options and gives approximate capital and operating costs for a 1.0% copper ore.INTRODUCTIONAs a result of the low copper prices that prevailed for much of the last two decades, aggressive attempts were made by the industry to cut operating costs. Under such circumstances heap leaching, solvent extraction and electrowinning, to recover low cost copper from oxide ores, has received particular attention and ultimately widespread acceptance.Low grade copper ore (typically containing less than 1.0% Cu), which could not be economically treated by other methods, is placed on heaps and leached with dilute solutions of sulphuric acid. The copper rich, pregnant solution, drains from the heap into a collecting pond and is pumped to a solvent extraction plant where it is purified and upgraded. The resulting solution, termed the pregnant electrolyte, passes to the electrowinning section where the copper is recovered as high grade cathodes and sulphuric acid is regenerated, (Figure 1).This paper specifically describes the processing of copper oxides. Other copper minerals such as chalcocite and chrysocolla are also leached by dilute solutions of sulphuric acid. In practice the oxide minerals are frequently associated to varying degrees with less easily leached sulphides, such as chalcopyrite. In some cases, once the oxidized capping of the ore body is removed, the oxides are totally replaced by more refractory sulphides. Under these circumstances the leaching recovery is significantly reduced. However the principles described here for solvent extraction and electrowinning are also applicable to solutions received from heaps containing sulphide minerals, which are leached more slowly and involve bacterially induced reactions."

Jan 1, 1990

By D. G. Willard

The U.S. Department of Interior, Bureau of Mines has evaluated the potential resource and annual availability of cobalt from 27 deposits or districts in 11 market-economy countries. More than 95 pct of primary cobalt production from market-economy countries, mainly byproduct output from copper and nickel operations, was analyzed. Approximately 1,200,000 mt of cobalt is potentially recoverable at the demonstrated resource level. Very large additional resources exist, especially in laterite deposits, but are at the inferred level. The producing operations evaluated in this study are expected to produce about 19,000 mt of cobalt in 1989, significantly less than the available capacity of about 31,000 mt. More than 14,000 mt per year of cobalt is produced from copper-cobalt deposits in Zaire and Zambia, of which 11,000 mt can be produced at a copper price of $O.60jlb or less with a O-pct discounted cash-flow rate of return (DCFROR). Approximately 4,400 mt of cobalt is produced annually from nickel-cobalt deposits in six countries, of which about 1,800 mt (in Canada and Brazil) could be produced at a nickel price of $1.50jlb or less at a D-pct DCFROR. Approximately 200 mt per year of cobalt is produced from a cobalt mine in Morocco. Most of the evaluated nonproducing operations and prospects that could potentially produce cobalt as a principal product or byproduct would require a total cost (including a 15 pct-DCFROR) significantly exceeding January, 1989 market prices of the principal commodities. Principal-commodity dependence, transportation routes, cobalt toxicity, and other issues that could affect the availability of cobalt are addressed herein.

Jan 1, 1991

By H. F. Fuls

The quality of Pregnant Leach Solution (PLS) at Skorpion Zinc is of utmost importance for efficient operation of the Solvent Extraction (SX) Plant. Suspended solids in the PLS forms CRUD in the settlers, resulting in reduced zinc transfer capacity and increased impurity carry over to Electrowinning. The Ishigaki Fibre-Wakishimizu filter (fibre media rapid filtration equipment) has been identified as polishing filter that potentially could remove solids from the PLS of Skorpion Zinc. A pilot unit with 20m³/h capacity was tested on site over a period of 9 months under plant operating conditions in the refinery. The FW filter produces a clear filtrate, acceptable for the Solvent Extraction. Turbidity is improved by 72%. Gravimetric analysis indicates a 47% removal of solids. However, the gravimetric method is biased by a co-precipitation of saturated salts during the analysis. Filter media is blinded by the Skorpion Zinc PLS solution, as result of suspended solids and process chemistry. The media could not be regenerated to acceptable conditions. Further testwork to investigate the impact of process solution chemistry modification on blinding is undertaken. Based on the outcome of this investigation a final decision on the FW filter can be taken.

Jan 1, 2008

By J. J. Mulligan, F. F. Colcord, E. F. Kern

The electrolytic separation of silver and gold has been practiced by the refineries in the United States for a good many years, and probably because of frequent visiting between officials of plants and the consequent exchange of views, operations in the various silver and gold refineries are very similar. We find, for instance, they practically all use electrolytes of approximately the same composition, which, no doubt, is more the result of experience than of studies of electrolytes. At the new electrolytic parting plant of the U. S. S. Lead Refinery, Inc., East Chicago, Ind., considerable attention has been given to the composition of electrolytes, especially to their conductivity and their effect on the character of the silver deposit. We are not aware that anything has been recently published on this subject and are, therefore, presenting such data as we have with the idea that, although it will not be wholly new, it may stimulate interest in the subject. Effect of Copper Content on Conductivity The first work was to determine the specific conductivity of silver nitrate and copper nitrate solutions. Concentrated solutions of silver nitrate and copper nitrate were prepared by dissolving analyzed chemically-pure salts in distilled water, and determining the silver and copper in each. Definite amounts of the concentrated solutions were taken, mixed and diluted to a definite volume. The silver and the copper were determined in each of these solutions and the conductivity was then determined. The plotted results are shown in Figs. 1 and 2. The effect of increasing quantities of silver and copper is readily seen. A comparison of the two sets of curves shows conclusively the benefit of holding the copper content of the electrolyte above 5C g. per liter, as its effect is to increase greatly the conductivity in an approximate propor-

Jan 1, 1926

By D. Hanekom

Over the past couple of years, Anglo Platinum has made extensive use of technology within the core disciplines (geology, evaluation, survey, and planning) that collectively form part of mineral resource management (MRM). While these technologies were primarily developed to enable geology, evaluation, survey, and planning to carry out their daily tasks, with the main objective of supporting the mine?s production effort, they have also enhanced the disciplines? ability to produce the required outputs within the annual business planning cycle. Anglo Platinum has developed a very comprehensive business planning process, and these technologies play a vital role in enabling both the quality and quantity of inputs into the process, and also the value-add of the final product. This prompted a question regarding the practical application of the CADSMine software. If we changed our thinking in how we applied the software, would it be possible to further improve on the time taken to deliver a business plan? In changing the current planning approach, would we be able to further simplify the process? Is there a way to reduce the data generated in order to enhance the time taken to do reporting, as the CADSMine software is totally network dependent? Less data should equal faster reporting. This paper focuses on the practical application of the CADSMine software, and demonstrates the value-add to the business planning process that can be gained if the mine design methodology is changed from individual panels to bigger blocks representing a raise line.

Jan 1, 2012

By Tristan Worsey

This work was performed during the summer of 2008 during the junior year of a BS in Mining Engineering. It was observed that the mine was having a problem with back break during the blasting of development drifts. The unwanted back break was causing the mine extra costs in ventilation, ore dilution, ground support, back fill, explosives and man-hours. The blasting practices were observed for four weeks and the problems and their solutions were defined. In this paper the reasons and causes of the problem are explained with the proposed solutions to eliminate back break.

Jan 1, 2010

By Jr. Hazen

Relationships that may exist between assays and sample interval lengths when using unequal sample intervals in mine sampling have been investigated as part of the larger research problem of adapting statistical methods to the analysis of weighted average grades. The theoretical relationship between the amount of difference in the weighted and unweighted average grade of ore and the size of the correlation coefficient between assay value and sample interval length was found to be linear. Numerous examples of actual field sample and assay data, which have been obtained by using unequal sample intervals, are documented, and the differences between weighted and unweighted average grades of ore and the correlation coefficients between assays and sample interval lengths have been computed and plotted on graphs. Differences between these actual field data and the expected theoretical linear relationship are examined. It is hypothesized that the use of unequal sample intervals in mine sampling is, in fact, stratified sampling in a statistical context. The sampler establishes stratification by selecting unequal sample intervals on the basis of differences in lithology, changes in rock type, characteristics of mineralization, or differences in metal content. Statistically} methods currently used in mine sampling, involving unequal sample intervals, fail to consider differences in the inherent variances in grade of ore within the various strata established by using unequal sample intervals. Consequently the strata are sampled with different precision. This difference in precision of sampling between strata may account for much of the deviation between the plotted points representing actual field sampling data and the theoretical linear relationship between the amount of the difference between weighted and unweighted average grade of ore and the size of correlation coefficient between assays and sample interval lengths.

Jan 1, 1966

By J. He

The separation performance of a raw coal sample from South Africa based on the dense gas-solid fluidized bed beneficiation technique was investigated. Analysis showed that the raw coal sample distributes mainly in the -50+6 mm size range with the -1.6 g/cm3 density fraction accounting for 78.20% of the cumulative mass distribution. A flow sheet of the sequential coal beneficiation technique was introduced. The experimental and simulation results of the hydromechanical and density distribution stability indicate that the dense gas-solid fluidized bed could provide a stable separation environment with uniform density fluctuations under suitable operating conditions. With the application of this technique on the raw coal sample, the separation results show that three products, consisting of 73.25% clean coal with an ash content of 9.59%, 11.31% middlings, and 15.44% gangue were effectively separated at two different densities of 1.82 g/cm3 and 1.57 g/cm3. This study provides an effective flow sheet for achieving the high-efficiency separation performance on raw coal from arid areas. Keywords dense gas-solid fluidized bed, dry coal beneficiation, density distribution, separation efficiency.

Jul 1, 2013

THE object of this paper is to review certain features in connection with the mining of narrow lodes, say up to 20 ft. or so wide. The types of ore-body to which it is intended to refer are those which occur. chiefly as fissure or shear-Iodes-that is, those lodes which are to be found in belts of country which have been subjected to dynamic stresses, resulting in the formation of cracks and fissures, into some of which has been concentrated sufficient metal-bearing material to form ores. Very frequently one of the walls of such a lode is found to be a fault, or plane of differential movement.The first point which comes up for consideration is the shaft and its position. From the information afforded by the prospecting which has been done on a lode relative to the dip, nature of country, &c., the position of the main hauling shaft can be determined. For purposes of general utility the hangingwall is generally chosen, if a vertical shaft, though, on account of freedom from creeps, the foot-wall would be safer. Vertical shafts are preferable to underlie shafts in many ways; but wherethe lode maintains a flat dip the cost of cross-cutting at the various levels becomes very heavy'. This difficulty may to some extent be modified· by sinking a vertical shaft in the hanging-wall...

Jan 1, 1912

By E. V. Verhoef

The proposed EU directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment promotes the substitution of lead in consumer electronics to reduce emissions from lead in the end of life phase. In this paper, the consequences of substituting lead in solders is assessed using the Eco-lndicator-99 method for the examples. The base metal production system is considered as an interconnected network modeled dynamically in Simulink 4 and Matlab 6 (Mathworks Inc 2000), where the recovery and production of metal components of the assessed product partially overlap. This approach requires global modeling of metal production processes and mass balances and resulting allocation choices. It also reveals the susceptibility of LeA scores to different choices in the modeling and data availability and uncertainty. Besides the comparison between lead-free and lead-containing solders, other side effects are revealed. Lead is carrier material for the recycling and production of many co-elements in the interconnected production and recovery system. Substitution may have adverse effects such as temporary shortages of other connected metals that are often not considered in normal LeA assessments, thus leading to erroneous results. The suggested approach provides directions for including these external effects and for further assessment of the environmental effects of substituting lead. This paper shows that in order to assess the environmental aspects of metallurgy, dynamic modeling of the total system is required based on the fundamental thermodynamics in each metallurgical reactor, the basis of this dynamic model. With this the true environmental impact of metallurgy can be explained. In the case of lead free solder, it is shown that the mining of substitutes has a very much larger impact.

Jan 1, 2003

By E. V. Verhoej

The proposed EU directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment promotes the substitution of lead in consumer electronics to reduce emissions from lead in the end of life phase. In this paper, the consequences of substituting lead in solders is assessed using the Eco-Indicator-99 method for the examples. The base metal production system is considered as an interconnected network modeled dynamically in Simulink 4 and Matlab 6 (Mathworks Inc 2000), where the recovery and production of metal components of the assessed product partially overlap. This approach requires global modeling of metal production processes and mass balances and resulting allocation choices. It also reveals the susceptibility of LCA scores to different choices in the modeling and data availability and uncertainty. Besides the comparison between lead-free and lead-containing solders, other side effects are revealed. Lead is carrier material for the recycling and production of many co-elements in the interconnected production and recovery system. Substitution may have adverse effects such as temporary shortages of other connected metals that are often not considered in normal LCA assessments, thus leading to erroneous results. The suggested approach provides directions for including these extemal effects and for further assessment of the environmental effects of substituting lead. This paper shows that in order to assess the environmental aspects of metallurgy, dynamic modeling of the total system is required based on the fundamental thermodynamics in each metallurgical reactor, the basis of this dynamic model. With this the true environmental impact of metallurgy can be explained. In the case of lead free solder, it is shown that the mining of substitutes has a very much larger impact.

Jan 1, 2003

By R. J. Mirville

Flocculation is an important step in the treatment of coal preparation waste waters. The effects of polymer charge and molecular weight and solution pH and ionic strength on the adsorption and flocculation characteristics of a series of polymeric flocculants on some typical waste water constituents have been studied experimentally. The results indicate that the nature and extent of flocculation are strongly system-dependent. For the case of coal, both adsorption and flocculation behavior can be correlated with the polymer conformation in solution. For the mineral constituents, on the other hand, adsorption and flocculation depend also on the surface properties of the solid.

Jan 1, 1979

By H. Alzraiee

Traditional planning methods such as CPM and PERT have been useful tools to manage construction projects. However, the underlying model of these traditional methods often seems to fail to represent real projects as they tend to assume no interrelationship between project components. In reality, project components have complex dynamic feedback process that requires modeling of inherent uncertainty in the execution of these projects. Nevertheless, this dynamic nature and uncertainty have not been explicitly addressed by traditional planning methods. Project failure can be attributed to poor representation of the inner and outer aspects of operations that are responsible for project dynamics. Uncontrollable external forces are often cited but the real cause may be internal such as the feedback process among components of the project. An alternative perspective is offered in this paper through system dynamics (SD) that accounts for the feedback process and discrete event simulation (DES) for modeling the uncertainty. The proposed method utilizes SD method for modeling project dynamics and DES method coupled with CPM network for operational details and uncertainty, respectively. A case study that involves preparing engineering drawings in a design office is used to demonstrate the use of the developed method and to highlight its capabilities. Modeling the dynamic dimension is expected to enhance planning and scheduling of construction operations and to provide a better understanding of the impact of various internal and external factors on project schedule and productivity performance.

Aug 1, 2013