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By John N. Ludden, Maurice Rive, Hillar Pintson

"Quelques soixante-dix-sept plutons présents dans la Sous-Province de Pontiac et dans la partie centrale de la Sous-Province de I’Abitibi ont fait I ’objet d’une reconnaissance systématique. Ils ont été regroupes en huit suites plutoniques majeures et trois suites mineures à partir de critères géologiques et petro logiques. Parmi les suites majeures, quatre représentent I' activité intrusive la plus ancienne dans la région. L’une d' entre e/les est représentée par deux complexes anorthosito-gabbroi' ques lites et les trois autres comprennent les orthogneiss dioritiques a leucotonalitiques et les intrusions dons la composition varie de diurétique et granodioritique à leucotonalitique. Leur mise en place peut être pretectonique a syn ou tarditectonique; certains plutons sont synvolcaniques. Quelques data/ions U! Pb effectuées à propos de ces roches donnent des âges s' étalant entre 2 718 et 2 694 MA. Les données géochimiques indiquent la présence des deux lignées magmatiques, tholemique et calcoalcaline bien qu’il n'y ait aucune évidence de relations entre elles dans I' espace et dans le temps. Ces suites magmatiques différentes peuvent provenir soit d’une croute tholemique impliquée dans un processus de subduction soit directement du manteau.Les trois autres suites majeures comprenant des monzodiorites, des granodiorites et des monzonites ainsi que les deux suites mineures comprenant des syenites correspondent à un évènement intrusif plus jeunesse déroulant entre2 694 et2 680 MA. Ces roches sont syn, tarti a post tectoniques et sont enrichies en alcalins, Ba, Sr et terres rares legeres par rapport aux quatre suites précédentes. Leurs caractères chimiques prop res suggèrent qu' e/les proviennent d' une source différente par rapport à celle precedemment citee.La derniere suite plutonique majeure correspond a un monzogranite leucocrate, riche en pegmatite, également syn a tard tectonique, dont I' age n' est pas connu avec précision. ll représente le seul granite ""vrai"" de la région et dérive d’une anatexie soit des meta sédiments soit des granodiorites-tonalites plus anciennes. La troisième suite plutonique mineure correspond a quatre stocks de granodiorite porphyrique qui n’ont pas été étudiés en détail.ABSTRACTSevenly-sevenplutons have been identified in the east-centra/part of the Abitibi Subprovince and adjacent Pontiac Subprovince. These have been subdivided, on the basis of geological and petrological criteria, into eight major and three minor plutonic suite. Four of the major suite, which represent the oldest intrusive activity in the area, range in composition from dioritic-leucotonalitic orthogneisses to diorite-granodiorite/leucotonalite and include two layered anorthosite- gabbro complexes. Their time of emplacement ranges from pretectonic to syn-late-tectonic and some plutons are synvolcanic. U-Pb zircon ages for these rocks range from 2 718 to 2 694 Ma. Geochemical data indicate the presence of both calc-alkaline and tholeiitic magma series for these rocks although there is no evidence time and space relationships between the two. The different magma series also suggest the derivation of these rocks from two sources, either from subduced tholeiitic crust or directly from the mantle. Three major monzodiorite-granodiorite, monzonite, and two minor syenite suites comprise a younger inlrusive event ranging from 2 694 to 2 680 Ma in age. These rocks are syn-, late- to post-tectonica and, compared to the above four plutonic suites, are enriched in alkalis, Ba, Sr and light Rare Earth Elements.Their distinctive geochemistry suggests that these rocks were derived from a different source region than for the older plutonic suites. The remaining major plutonic suite consists of leucocratic, pegmatite-rich, monzogranite-granodiorite. These rocks are also syn- to late-tectonic but their ages are not known with precision. They are the only ""true"" granites in the area and were derived by the partial melting of either older"

Jan 1, 1990

By P. H. G., Durville

ANY metal which contains even a small percentage of aluminum possesses certain peculiarities of appearance and properties which are exhibited both when the metal is melted and after it solidifies. Pure aluminum, or an alloy containing a small proportion of aluminum, can be melted without flux-except for a layer of charcoal-because a film of aluminum oxide and metal forms at the surface of melted aluminum. Although very thin, this film is air-proof, and it prevents the metal underneath from oxidizing. This oxidized film does not move easily on account of its toughness and high surface tension. One very important point in connection with this process of still casting has not been strongly enough stressed, namely, that the same kind of surface film with the same peculiarities forms over the surface of all melted alloys that contain even a small proportion of aluminum. Experienced foundrymen know how desirable it is to cast aluminum under its "skin" or under the surface of the film which tends to remain still. In the case of red copper, when in fusion, the surface shows pure copper only. This' is due to the fact that liquid copper constantly absorbs the copper oxide which forms on the surface. By closely examining melting copper the oxide can be seen dissolving in the bath, and going into solution just as pulverized sugar dissolves in water. When copper is cast in the open, either in wire bars or cakes, the surface of metal exposed to the air is covered by a film of black oxide that cannot be absorbed by the metal.

Jan 1, 1927

By D. L. Passmore

The development of microcomputer software that provides an analysis of pit-specific accident and production data for the mining industry is seen as a vital component in a total loss-control system. The Mine Injury Reporting System (MIRS) allows users to access accident and production data prepared by the Health and Safety Technology Center of the Mine Safety and Health Administration of the United States Department of Labor for any particular state and to generate a simple, yet informative, report.

Jan 1, 1988

By Junji Shibata

It is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. In this paper, some examples of the application of solvent extraction to the treatment of wastes are introduced. The treatment of solid wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse water, etching solution and pickling solution are accomplished using solvent extraction technique.

Jan 1, 1996

By G. Macfarlane

"In 1985, a crushing plant, located in the feed preparation area of Kidd Creek's copper smelter, was modified. The plant, which originally had treated only copper-bearing materials for the smeller, at a rate of 10 tonnes per hour, was expanded to 40 tonnes per hour capacity and modified to treat silica ores to meet the smelter’s flux requirement and also gold ores from the company's Hoyle Pond property. In the storage area adjacent to the crushing plant a 300 tonne per day gold mill was constructed.This paper outlines the construction and first year of operation of the crushing plant and gold mill with emphasis placed on the capital and operating advantages to be gained by utilizing an existing metallurgical infrastructure.IntroductionThe Kidd Creek Mines Ltd. copper-zinc-silver orebody is located 24 km north of Timmins, in Northern Ontario . Mining of this massive sulphide de posit commenced in 1966 and, in the ensuing years, a concentrator and zinc plant were constructed at the metallurgical complex, approximately 17 km by rail from the mine site . At this same site, in 1981, a copper smelter and refinery were commissioned. The smelter which utilizes the Mitsubishi smelting process for the continuous production of blister copper from copper concentrate, has been comprehensively described in previous papers.At the time of the smelter construction, a small (10 tonnes per hour) crushing plant was installed in the smelter's feed preparation area. This plant was used to treat the copper-bearing revert material produced by the smelter, and, apart from periods when slags and matte were produced through furnace drainage at the end of each operating campaign, it was generally under-utilized. This fact, together with the requirement to devise a more cost effective method of providing silica flux for the smelting operation, was the basic rationale for modifying and expanding and crushing plan t. At the same time, development at Kidd's Hoyle Pond orebody had progressed to such a stage that a gold mill of 300 tonnes per day was warranted."

Jan 1, 1988

By Paloma Lazaro, Moe Momayez

Interactions between human beings and their work environment require the body to regulate its temperature by balancing heat production and loss. Comfortable environmental conditions are crucial for keeping workers safe and healthy and to maintain a suitable level of productivity. However, achieving a proper core body temperature may become challenging under different conditions, especially in high heat-generating workplaces such as hot underground mines. Because hot underground mines have the potential to expose workers to heat stress, compliance with standardized and regulated indices and criteria is distinctly required. The objective of this paper is to provide an overview of the current research on heat stress and strain in hot underground mines, collected from published and specialized literature. General definitions, statistics of heat-related accidents in mining, overview of the indices, standards, and recommendations for heat stress are provided herein.

Oct 6, 2020

By S Mitra, T Singh, D O’Dea, T Honeyands

Permeability and air flow rate in the bed during iron ore sintering is crucial to controlling the sinter quality and productivity of a sinter plant due to its influence on the flame front speed. In the present work, the permeability of the bed during sintering was analysed by means of measured pressure drop and temperature at multiple points in the bed during sintering. Three different zones were categorised, ie humidified (green) bed, region of maximum resistance (high temperature zone) based on temperature, and sintered bed. Previous work has shown that the maximum pressure drop during sintering was due to several concurrent physico-chemical processes including dehumidification, calcination of fluxes, dehydroxylation of goethite, combustion of coke and melting of granules (>1200°C). To quantify the effect of the different process, sintering experiments were conducted in a milli-pot (diameter 53 mm, height 400 mm) with pressure and temperature measured at same location in bed. The milli-pot was fitted with four equidistant (80 mm apart) taps. Overall, five sections in the milli-pot were analysed for pressure drop at different times during sintering. It was found that in region of maximum resistance, coke combustion and flux calcination were highest contributors with ~35 per cent of the pressure drop when compared to other processes like de-humidification and goethite dehydroxylation which contributed to ~20 per cent and 25 per cent each respectively. The pressure drop contribution of the coke combustion region increased with increasing coke addition rate.

Nov 8, 2021

By L. G. Stolarczyk

In-mine Continuous Wave (CH) Radio Imaging method (RIM) instrumentation has the capability of measuring EM wave propagation constants in layered formations. The RIM method is based upon the fact that seams of coal, trona, potash, quartzite, gilsonite and oil bearing sands form natural waveguides for low loss transmission of electromagnetic (EM) waves. The waveguide forms whenever the seam is bounded by more conducting claystone, mudstone, shale or in the case of oil/gas traps, by a floor of saline water. Disturbances caused by faults, shear zones, paleochannels, sills and dikes significantly alter the propagation constant. The analytical values of the EM wave propagation constants depend on the physical and electrical parameters of the seam. The values are presented in this paper in a graphical form to assist in the interpretation of RIM tomographic images. This paper compares in-mine geologic mapping obtained during mining to tomographic images of the geologic disturbance zones in a Central Utah coal mine.

Jan 1, 1989

By John M. Warde, Raymond M. Richardson

What to do with atomic wastes is one of the major problems of the atomic age. Unlike other waste materials, these cannot be burned, evaporated, or filtered, and the transfer of radioactive material from one physical or chemical state to another is not a complete answer, because only time diminishes radioactivity. Rate of decay of radioactive materials varies from a few seconds to several thousand years and cannot be altered by known economic methods. At present the Atomic Energy Commission and its contractors are coping with the situation adequately. Intensification of private development of atomic power could, however, pose problems in the nation's nuclear energy program.

Jan 5, 1955

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

By V. V. Lvov, L. S. Chitalov

"The purpose of the research is intensification of physico-mechanical ore properties determination for ball grinding processes in comminution circuits. The research presents comparative studies aimed at intensification of Bond Ball Mill Work Index (BWi) determination, such as testing technique of Ahmadi and Shahsavari, Berry and Bruse, Gharehgheshlagh, Horst and Bassarear, Kapur, Magdalinovich. The subject of the research is a test procedure of apatite-nepheline, copper-nickel, gold-sulfide and iron ores for the Bond ball mill index. The Bond Ball Mill Work Index for the material firstly was determined by standard Bond test methodology. Two the most promising testing techniques - Ahmadi and Kapur testing techniques - were modified. For the Ahmadi technique it was proposed to pay attention to the circulating load, which should be stabilized on the value of 250% as fast as possible. Two methods were put forward to quicker stabilize the circulating load. For the Kapur technique it was proposed to use empirical coefficients, which is determined especially for the apatite-nepheline, copper-nickel, gold-sulfide and ores. The modified Ahmadi and Kapur techniques require no more than two cycles of ball grinding to determine BWi (while normally 6-8 cycles are required) and less than 5 kg of initial feed. The suggested modified Ahmadi and Kapur techniques allow to intensify the physico-mechanical ore properties determination for ball grinding processes and BWi test costs considerably, which makes them useful for mass sampling and monitoring strength properties of ores entering a concentrating mill. INTRODUCTION When designing concentrating mills, the choice of the technological scheme for ore pretreatment, particularly the type, quantity and size of the main process environment, the determination of optimal grinding conditions and the calculation of equipment load are carried out by preliminary studies of grinding in semi-industrial or laboratory-scale plants. Semi-industrial tests on full-scale plants provide the most reliable information for calculating specific loads for equipment. However, this requires a significant amount of ore samples, a high labor costs and the pilot plants. Thence the most researchers performed grinding tests with small laboratory equipment using small ore samples."

Jan 1, 2018

By Junli Xu, Xianwei Hu, Kaiyu Xie, Liangxing Li, Zhongning Shi, Zhaowen Wang, Bingliang Gao, Aimin Liu

Al-Ti master alloys were prepared by aluminothermic reduction between the dissolved titanium dioxide and aluminum in cryolite melts at 960oC. The kinetic analysis by differential scanning calorimetry indicated that the apparent activation energy of the reaction of reducing titanium dioxide by aluminium is 22.3 kJ/mol, and the reaction order is 0.5. The products were analyzed by means of X-ray diffraction, X-ray fluorescence, scanning electron microscopy and energy dispersive spectrometer. Results from X-ray diffraction showed that the phase compositions of produced alloys are Al and Al3Ti. In addition, Al-Ti master alloys containing 2-6 mass% Ti were formed at different reduction time of 2-5h in aluminothermic reduction experiment.

Jan 1, 2015

The mill area of PT Freeport Indonesia is located in a valley surrounded by steep natural slope, characterised by extreme topography with mountains rising to above 4500 m within 100 km from the seashore. The valleys are deeply embedded into the mountainous terrain and bordered by steep natural slopes. Vertical or overhanging lime walls are interrupted by steep vegetated screen sections containing accumulated loose material from weathering processes and ancient rock falls and/or debris flows/avalanches. The climate can be best described as alpine subtropical with an accumulated rainfall of more than 5000 mm per year. Occasional snowfalls and superficial freezing above 4000 m elevation leads to heavy weathering of the superficial rock layers and along open joints and fractures. The mill area is a crucial and strategic infrastructure for the entire mining operation which is best characterised as a high density industrial area with facilities including water tanks, power generators, crusher, and concentrating facilities including office buildings and workshops as well as access tracks to the underground mining blocks. Considering the local topography, the restricted space conditions and the number of technical installations, the facilities are likely to be affected and highly vulnerable to rock fall from the surrounding slopes. In order to minimise the rock fall hazard three rock fence barriers area were constructed at the mill area. The 7.5 rock fence barriers were designed with the maximum capacity of 5000 kJ. These are the largest capacity of rock fall barriers ever constructed in Indonesia. The total length of the barriers for the three locations was 126 m. The biggest challenge of this project was the construction of the barrier at West Gulley, which was constructed at 300 m above ground level. For this site, construction access was undertaken using helicopter. This presentation discusses the design of the mitigation structures as well as the construction approach and stages of the barriers. Please note: This paper is abstract only.

Nov 25, 2010

By S. Sumski, M. B. Panish, R. T. Lynch

The liquidus isotherms in the gallium-rich corner of the Ga-Al-P phase diagram have been determined from 1000" to 1200°C and at I100°C the corresponding solidus isotherm was obtained. A simple thermody-namic treatment which permits calculation of the solidus and liquidus isotherms is discussed. A technique which was previously used for the growth of GaxAl1-xAs was used for the preparation of solution epitaxial layers of GaxAl1-xP and ALP. An approximate value of 2.49 i 0.05 ev for the band gap of Alp at 300°K was obtained and the ternary phase data were used to estimate a value of 36 kcal per mole for the heat of formation 0f Alp at that temperature. The Gap-A1P crystalline solid solution is one in which there exists the possibility of obtaining crystals with selected energy gaps, within the limits imposed by the energy gaps of Gap and Alp. Such crystals are of considerable interest because of their potential value for optoelectronic and other solid-state devices. Furthermore, it has been amply demonstrated for GaAs and GaP,'-7 that device, or bulk materials grown from gallium solution generally have more efficient radiative recombination than materials prepared in other ways. This presumably due to the lower gallium vacancy concentration in such material.= Small crystals of GaXAl1-xP and A1P have been grown from solution,8-10 and A1P has been grown from the vapor," but neither have previously been grown by liquid epitaxy. In this paper we present the ternary liquidus-solidus phase diagram of the Ga-A1-P system in the region of primary interest for solution epitaxy, and discuss the thermodynamic implications of that phase diagram with particular reference to the liquidus and solidus isotherms in the gallium-rich corner of the GaxAl1-xP primary phase field and to the A1-P system. Several measurements of the absorption edge of GaxAl1-xP crystals have been made and the width of the forbidden gap of A1P has been estimated from these measurements. EXPERIMENTAL The differential thermal analysis technique used to determine the liquidus isotherms and the optical measurements used in this work are similar to those described previously12 for the Ga-Al-As system, ex- thermocouples in the thermopile for added sensitivity. The materials used were semiconductor grade Ga, Gap, and Al+ The composition and temperature range at which DTA studies could be done was quite restricted. The upper temperature was limited by the chrome l-alumel thermopile to about 1200°C, and the highest aluminum concentration to about 5 at. pct by low sensitivity caused by the reduced solubility of Gap with increasing aluminum concentration in the liquid. DTA studies were not possible at 1000°C and below because of the low sensitivity caused by low solubility of Gap in the Ga-A1-P system. The cooling rate for these studies was about 1°C per min. No heating studies were done because of limited sensitivity. Supercooling probably does occur, but our experience with other 111-V systems indicates that it is no greater than about 10 to 15.c. Solid solubilities were determined by analyzing epitaxial layers of GaxAl1-xP grown from the liquid, with an electron beam microprobe. The layers were grown on Gap seeds by a tipping technique in which the layer is grown over a short-temperature range (20" to 50°C) on the seed from a solution of known composition. The tipping technique reported by Nelsson1 for GaAs could not be used, particularly for solutions containing appreciable amounts of aluminum, because of the formation of an A1203 scum on the liquid surface. A system was therefore designed, which would effectively remove the oxides mechanically, so that uniform wetting and crystal growth could occur. This tipping technique has already been described in detail." The best control over the composition of the re-grown layer was obtained when the tipping was done at a temperature which corresponded to the temperature of first formation of solid for the solution being used. Generally, therefore, a solution was prepared by adding the amounts of Ga, Gap, and A1 required to yield a solution which would be completely liquid above the tipping temperature with solid precipitating below that temperature. For most of the work reported here, the 1100°C isotherm of the ternary was used. It was generally necessary to heat the solution to 50" to l00. C above the tipping temperature to dissolve all of the Gap in a reasonable length of time. The epitaxially grown layers were used both for optical transmission measurements to aid in the estimation of the way in which the absorption edge changed with aluminum concentration, and for the electron beam microprobe analyses to provide data for the determination of the solid solubility isotherm. RESULTS AND DISCUSSION Liquidus Isotherms in the Ga-A1-P Ternary Phase Diagram: Thermodynamic properties of the system. The only thermal effect studied in this work was that

Jan 1, 1970

By A. G. Pasamehmetoglu, N. Bolukbasi, O. Koncagul

A study has been undertaken to establish the relationships between the O&K wedge test cutting resistances and the geotechnical parameters of rock materials in the context of bucket-wheel excavator operation. Prediction equations were formed to estimate the cutting resistance from the geotechnical parameters by multiple regression analysis. The cone indentor index, uniaxial compressive strength and Shore hardness parameters have been found to be the most significant predictors

Sep 1, 1991

By Noel N. Moebs

Valley Camp No. 3 mine was the scene of an experimental shortwall introduced in 1973 in an attempt to improve the recovery from the Pittsburgh coalbed in the Ohio Valley area where adverse ground conditions have imposed partial extraction methods with only 40 to 55 percent recovery of the valuable resource. The Bureau of Mines, under a cooperative agreement with Valley Camp Coal Co., monitored ground pressures and caving in the shortwall section in an effort to determine whether the roof strata, notably the limestone main roof, will cave to the extent that roof pressures at the face are relieved and whether the powered roof supports can sustain the roof load. The Bureau's efforts included mapping of clay veins, instrumentation of chain pillars and shortwall panels with encapsulated pressure cells, recording hydraulic pressures in the legs of the shortwall chocks, and core drilling underground and from the :surface. The experimental shortwall was a qualified success. Recovery increased 5.4 percent compared with partial extraction. Pressures in chain pillars and the abutment zone were not excessive. Hydraulic pressures in the chock legs did not approach the yielding pressure. Apparently, the limestone strata caved and the roof pressure at the face was relieved.

Jan 1, 1976

By Alban J. Lynch, Khairun Azizi

Education and research have always followed production in the mineral industry. Almost all of the leading mineral education and research units in the world today are in developed countries which had strong mining industries created during the 19th and 20th centuries to meet the demands for minerals due to the Indus- trial Revolution. It is in those countries where the main advances in mining and metallurgical technologies have occurred. But it is in the developing countries, often with traditions which have not favoured engineering initiatives, that the mineral industry is growing. Legislative changes and high exploration expenditures in many of those countries are of such a nature that many mineral discoveries will be made and mines and plants built in them during the next decades. Developments must be accompanied by increased activities in education, research and technology transfer in mining and processing, particularly those which are computer based. Malaysia is a developing country with the objective of achieving developed status by 2020. It has a short history of tertiary education and industrial research and a growing mineral industry. It is now building the education and research programs which will give strong support to its mineral industry. The progress which is being made in the computer based components of these pro- grams, and the factors which influence them, are discussed.

Jan 1, 1996

By M. I. Brasileiro

The use of experimental design to the study of mixtures has found a wide range of applications, even in laboratory scale or in industrial development works. The aim of this work was to maximize granite sawing waste content in ceramic tiles using experimental design. Based on the raw materials, specific formulations were developed using the experimental design. The raw materials were mixed and sample bodies were produced using uniaxial pressing. The sample bodies were fired and characterized in terms of water absorption, mechanical strength and X-ray diffraction. Regression models were adjusted relating the water absorption and mechanical strength with the amount of raw materials. The results showed that the methodology of experimental design maximize the content of wastes incorporated in ceramic tiles formulations. Formulations containing up to 40% of waste can be used for the production of ceramic tiles.

Jan 1, 2009

Dragline performance drops considerably when chop-down and double handling of material is needed due to increasing overburden thick- ness or total pit depth. Beyond a certain pit depth the dragline needs support by a pre- stripping system in the upper portion of the overburden. In soft to medium hard ground the bucket wheel excavator can be used for pre- stripping, whereby several methods of material transport are investigated. Conveyor transport around the pit and dumping by stackers is the best solution from the technical point of view. Cross pit transport and dumping by means of a conveying bridge is the method with the lowest costs per volume moved. Cross pit transport by use of a beltwagon with overlong discharge boom is both, poor from the technical point of view and high in overall costs.

Jan 1, 1981

By Fiona M. Doyle Garner

Hydrolytic stripping is the process whereby metal ions in a loaded solvent extractant are hydrolyzed by water, typically at 130°-200°C. Equilibrium hydrolytic stripping tests were done on Versatic 10 solutions of various metals, singly and in mixtures. Single solutions of Fe, Xi, Cu, Mg, and tin precipitated aFe2O3, Ni(OH)2, Cu2O, Mg(OH) 2 and ?Mn203 respectively during hydrolytic stripping. Several mixtures containing iron precipitated magnetic spinel ferrites, MFe20k. No other combinations formed mixed oxides. It is proposed that the mechanisms for hydrolysis and precipitation of iron in loaded Versa- tic solutions are similar to those for iron hydrolysis in aqueous solutions. Infrared spec- troscopy and thin-layer chromatography of mixed iron-nickel Versatic solutions indicated that mixed Fe-Ni carboxylate complexes are present. Magnetic interactions between mixed complexes are thought to be responsible for the homogeneous nucleation of magnetic mixed oxides in preference to single oxides.

Jan 1, 1984