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By Nagahiro Saito, Takahiro Ishizaki, Daisuke Yata, Akio Fuwa

"Ternary compound-semiconductor, CuInTe2, film was deposited cathodically under potentiostatic conditions on titanium substrate from aqueous solution containing CuCl2, InCl3, TeO and HCI in this study.The deposition parameters such as electrolytic solution composition, potential and temperature were optimized· for electrodeposition of CulnTe2. Structural characterization of the: deposited film was also carried out using XRD and SEM. Electrodeposited films Were prepared and analyzed for their chemical composition using ICP. The ICP analyses showed that the stoichiometry of the films could be controlled by (1) the deposition potential and/or by (2) the electrolytic bath composition.1. IntroductionThe ternary chalcopyrite type compound semiconductors exhibit such electrical, chemical and optical properties that make them promising for photovoltaic devices (Kazmerski and Wagner 1985)(1). Many researches have been devoted to the characterization of these materials for over one and a half decades. High efficiency solar cells based on p-CulnSe2/n-CdS have been reported (Mickelson and Chen 1983)(2).The electrodeposited fil ns of semiconductors have more advantage than other physical and chemical deposition techniques; it is relatively easy and economic technique and the semiconducting properties such as band-gap variation, concentration of dopant stoichiometric composition and so on can be controlled with some accuracy. The electrodepositions of the ternary CuInS2, CulnSe2 have been reported by many workers (Hodes and Cahen 1986, Bhattachaya 1983, Singh et al 1986, Lokhande and can be prepared as both p-type and n-type. Therefore, its potential for application in optical and photovoltaic devices is one of the great interests. Bhattacharaya and Rajeshwar (1986)(9) reported the electrodeposition of CuInTe2 from an acidic bath· on indium tin oxide (ITO) and Mo substrate. Triethanolamine (TEA) was used as a complexing agent for indium. The electrodeposited CuInTe2 films were non-stoichiometric in composition under all their experimental conditions by electron-probe micro analysis (EPMA) and Auger depth profile analysis. In this paper, we report our results on the behavior .of Cu-In-Te electrodeposition from ·acidic baths; the preparation of CulnTe2 and the effect of bath composition on electrodeposited films obtained."

Jan 1, 2000

US 4,201,749-In the Bayer process production of alumina wherein aluminum hydroxide is precipitated from a sodium aluminate solution for use as seed, sodium oxalate and caustic components are removed from the precipitate by washing it first with a washing liquor which is saturated with sodium oxalate but has little content of caustic, and secondly with hot water. Substantially no sodium oxalate is recycled, yet loss of sodium aluminate is minimal. K. Yamada, T Harato, and H Kato, assigned to Sumitomo Aluminum Smelting Co Ltd May 6, 1980 8 pp. (423-127). Filed. 5-8-79 (37,145) Priority. Japan, 5-8-78 (53/54,803). Same¬British 2,020,642, dated Nov. 21, 1979.

Jan 1, 1982

By K. Sallmann

Spurred by a variety of factors, coal flotation is making headway among the preparation plants of West Germany. Mr. Sallmann provides a general view of flotation practices being employed in his country, with special emphasis on the many-sided problems that confront German coal preparation engineers.

Jan 9, 1961

By Ehsan Moradabadi, Debra F. Laefer

"To more rigorously address tunneling risks to above-ground structures, vulnerability evaluation of all structures along a tunnel route is required. This multi-block area along the route can be considered a district. To fully assess each structure within a tunnel’s zone of influence, a multi-block or district-level model may provide new insights as to risk evaluation and mitigation strategies. However populating such a model with the existing geometry of the built environment poses a major challenge as measured drawings are not readily available for all structures along a tunnel’s route. Cost-effective population of such a model could arguably involve remote sensing data in the form of laser scanning or photogramme-try. However even for unreinforced masonry structures, where external, above-ground geometries can be captured, without a prohibitively expensive building-by-building, in person survey many factors would remain unknown. To consider these uncertainties in an automatic way, a performance assess-ment framework is proposed. Such a framework allows a more rigorous, initial, risk quantification than is currently possible within the simple empirical models generally being used in industry when tunneling risk is initially assessed. This paper introduces (within the allowable space limits of this format) consider-ations for auto-population and application of a district-level, tunnel-risk screening tool. INTRODUCTION Challenging topography, intense urbanization and infrastructure development, combined with limited land availability and a growing awareness of environmental issues have lead to increasing usage of un-derground spaces to control aboveground traffic and provide essential services in metropolitan areas. Tunneling, however, is not without its own risks, especially with respect to aboveground structures whether it be widespread minor damage (Burland et al. 2001) or the more notable, although less fre-quent, large-scale collapses such as the 2003 Shanghai (Allianz 2015) or 2004 Singapore (Magnus et al. 2005) events."

Jan 1, 2016

By Robert C. Bates

Is the value of rock sealant on radon control destroyed by changes in barometric pressure? While an article by Dr. Gerald Schroeder in the June 1977 issue of MINING ENGINEERING suggests this, it should be noted this is not necessarily true as the ensuing discussion reveals. Before analyzing the data leading to Dr. Schroeder's conclusions, some comments on their source are needed. The figures were collected during a 1973 US Bureau of Mines test of radon barrier coatings in the Dakota uranium mine near Grants, N.M. Results of that test were reported by Franklin, et al 3,4 in 1975. The mine is essentially dry and ore occurrence is within a lightly cemented, porous medium-to coarse-grained sandstone of high permeability and radon emanation rate.

Jan 12, 1977

By Luigi P. Gonano, John C. Sharp

The Drakensberg Pumped Storage Scheme in South Africa with an operating head of 500m is located in sedimentary rocks containing relatively weak argillaceous strata. The paper describes design and construction aspects of the high pressure concrete-lined tunnels, and the associated investigation techniques and construction controls.

Jan 1, 1983

By J. O. Marsden

The Candelaria copper-gold mine is located approximately 25 km south and east of Copiapo in Region III, Chile. The original concentrator was designed to treat 28,000 t/d (30,800 stpd) of chalcopyrite-bearing ore through a circuit consisting of a single 11.0 m (36 ft) diameter SAG mill, two ball mills, conventional rougher and scavenger flotation, column cell cleaner flotation, and ceramic disc filtration. The plant was commissioned in August 1994 and quickly reached capacity and expected levels of metallurgical performance. In May 1996, a decision was made to double the capacity of the concentrator by the addition of a second line of equipment. The expanded facilities were commissioned in October 1997, less than 18 months after the decision to proceed, and well within the budget. The original concentrator facilities were replicated or duplicated as much as possible, however, a number of important equipment changes were made to take advantage of industry developments since the original concentrator was designed. These included the use of Eimco 120 m3 (4,200 ft3) cells for rougher and scavenger flotation and the installation of a Svedala VTM -800 Vertimill for regrinding. This paper describes the rationale behind these changes and explores the reasons for the success of the project.

Jan 1, 1999

By A. Luszczkiewicz

An innovative hybrid technology for beneficiation of difficult-to-process sedimentary copper ores comprising acidic leaching stage of the feed combined with subsequent flotation has been presented. Acidic leaching, preceding the flotation process, plays a beneficial role of efficient chemical grinding for liberation of copper sulphide minerals finely disseminated in the copper-bearing carbonate-shale rocks. The process was applied on a fully industrial scale. Flotation results were analysed for both chemically modified and unmodified flotation feeds. After several months of industrial scale operation, it was found that both metals recovery and concentrate grade remarkably increased as a result of application of chemical modification of the flotation feed. Beneficial effects of chemical pre-treatment of flotation middlings on selectivity at a comparable concentrate yield in industrial flotation scale, revealed a considerable increase of the total copper recovery by 3.5percent. Based on the industrial and laboratory investigations we consider a further development of the process and introduction of hydrometallurgy for better recovering of metals from low-grade copper concentrates

Sep 1, 2012

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By C. D. Peters

The Bureau of Mines has been researching remote sensing analysis of an underground coal mining area in Utah and computer-aided methods of defining ground control hazards in this mining area. As a result of these studies, a preliminary potential hazards map was developed for the test site. This map is based primarily upon a lineament (linear feature) analysis of Landsat satellite data. Other data used were paleochannel location data, resistivity data, and information from surface and underground field checking of the lineaments and ground control problems in the mine. Lineaments proved to be reliable indicators of hazardous areas, although the type and degree of hazard varies with different lineament trends and the presence of other conditions such as lineament intersections and intersections with other geologic structures or with paleochannels. Lineaments were observed to match faults, joints, and/or joint trends in the area. The paleochannel data, derived from drill hole data, provided basic information about potentially hazardous areas in the mine by suggesting where paleochannels could cause instability in the roof rock. The ground control problem data served largely to define the relative degree of hazard associated with lineaments and the types of hazards encountered in the mine. Resistivity data helped confirm the presence of fractures where they were expected to occur both from surface geology and from the lineament data.

Jan 1, 1986

By B. E. Parsons

Curtailment of production of crude oil, to the extent of effecting an approximate balance in supply and demand, was a problem confronting the oil industry in California throughout the year 1930. At the beginning of the year, with drilling operations only slightly checked, the California industry faced a steadily increasing potential production, an actual production in excess of market requirements and stocks of crude oil and refined products which had reached staggering proportions. During the year, the intensive development of the Playa Del Rey field and extensions to several oil fields, together with flush production from numerous large wells from both new and old fields, caused a steady increase in the state's potential production to a record peak in November of 1,186,000 bbl. daily. Despite the burden of this steady stream of flush production and the handicap of incomplete cooperation in several fields, curtailment successfully lowered the trend of crude oil production in California, except for the period of an open-flow test to determine actual potential production in several important fields in February. Under the curtailment programs in effect, the state's production of crude oil for the year was reduced 22 per cent. under the production of 1929 and even slightly under the production for the years 1927 and 1928. The total stocks of crude oil and refined products were reduced 2.7 per cent. during 1930, as compared to an increase of 30 per cent. in total stocks of all products during 1929. Drilling operations were reduced 28 per cent. as compared to drilling activities during 1929. Voluntary curtailment of drilling programs by many operators, particularly the major companies, accounts for the greatest portion of the reduction in drilling activity. The decline in drilling activity at Santa Fe Springs and in the east-side fields of the San Joaquin Valley was more than offset by development in new fields and extensions to deeper zones of old fields. There were 755 new wells completed during 1930, as compared to 910 completions in 1929. At the close of the year, 220 wells were drilling in the oil fields of California, 9 of which were being drilled in search of deeper producing horizons.

Jan 1, 1931

By Dave Proudfoot, Mike van Wyk

"There has akvays been plenty of discussion around the ‘accuracy of pyrotechnic detonators withmost recognised manufacturers claiming a variability of arourid 1% or less for their ‘superaccurate’ pyrotechnic based detonators. It is only now being understood that this 1% variabilitycan have serious adverse effects on blast performance. For example a 1% accurate 500millisecond shock tube detonator can fire anywhere between 485ms and 515ms. When wecouple these rather inaccurate ‘accurate’ detonators with short delays on surface, such as a 17millisecond connector, the probability of delay crowding and even out of sequence firing is quitehigh."

Jan 1, 1998

Reduce shaft sinking costs and workers exposure to mechanical hazards, drill dust, blast dangers, and fumes. Approach Replace drilling and blasting by using a large, cab-mounted impact breaker suspended from the bottom work deck of the galloway. How It Works The pneumatically actuated impact breaker is positioned by an articulated boom con-trolled from an operators cab. The breaker delivers 2,000 ft-lb blows that fragment the rock at the shaft bottom. Mucking is accomplished by a backhoe bucket on an articulated boom mounted on the cab. See photograph. The mucked material can be removed either by dumping into a previously drilled borehole or by being lifted out in a muck bucket as shown in the drawing. Positioning of the breaker, rotating the cab around its vertical axis, and moving the cab support frame around the perimeter of the shaft are all controlled by one joystick. Separate controls position the mucker boom, which can be swung horizontally through a 180° degree arc towards either side of the cab. Because the cab can be rotated to any position around its vertical axis, and can also be moved in a horizontal circle around the shaft, virtually any position on the bottom of the shaft can be reached by the breaker and mucker.

Jan 1, 1981

By Mann LD

The Haveluck gold deposit, located 2.5km north of Meekatharra, contained 1,284,000 tonnes at an average grade of 1.8 g/t gold of drill delineated proved and probable ore prior to commencement of production. Following successful laboratory and pilot scale testing a decision was made to establish a 300,000 tonnes per year heap leaching operation. The ore, crushed to minus 100mm was stacked on an impermeable membrane and irrigated with a dilute cyanide solution. Gold was recovered from the resulting pregnant solutions by adsorption onto activated carbon and gold bullion produced in a modified Zadra process desorption plant. From the commencement of mining it was obvious that a high percentage of fine material was being produced which would adversely affect the percolation of the cyanide solution-through the leach heaps. A screening plant was incorporated into the crushing circuit which provided an oversize product satisfactory for heap leaching and an undersize for carbon-in-pulp treatment. Plant design provided for the slurrying of minus 0.8mm ore before feeding to the pachuca tanks. Initial practice was to use four tanks for gold dissolution and two for carbon contact. Vibrating screens were used through- out for the carbon-ore separation and the loaded carbon was stripped in the existing desorption plant.

Jan 1, 1982

The estimation of local recoveries, such as the local recovered tonnage of ore and its corresponding grade at a given cutoff grade, is an important problem in a selective mining operation. Multigaussian kriging provides a simple solution to this specific problem. The solution is also complete in the sense that local recoveries are estimated together with their estimation variances. It is thus possible to assess confidence limit intervals on the estimated recoveries. Multigaussian kriging has been applied to the Jerritt Canyon deposit in a most realistic situation. The various steps of the estimation procedure are presented in detail and the potential of the method is demonstrated in view of the results. The obtained results show that the estimated recoveries are in good agreement with the actual recoveries and the actual estimation errors are correctly predicted by the estimation variances. Multigaussian kriging thus appears as a useful and fully operationable tool for the mining industry.

Jan 1, 1986

By D David

Geometallurgy is often a misunderstood and poorly defined concept. The first thing the paper will attempt is to provide a definition of geometallurgy. Ultimately this paper has been written to provide guidance to geologists, mining engineers and processing professionals as to what geometallurgy means in the crucial early phases of a potential mining project between the time of discovery and the time of commencing construction, should this occur. The paper covers the options available for conducting a geometallurgical study of a resource or orebody, appropriate to the level of definition required in the projectÆs development cycle. The paper will then describe how the geometallurgical information generated is subsequently used in calculations, planning and preparation of reports designed to inform and reassure stakeholders, such as the market. Ultimately in a successful project, appropriate options adopted in the development phase will form the basis of an ongoing geometallurgical program that links the major site disciplines for the good of the operation.CITATION:David, D, 2013. Geometallurgical guidelines for miners, geologists and process engineers - discovery to design, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 129-132 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By Larry Rayburn

In the spring of 1999, construction commenced on the new Steelers Football Stadium in downtown Pittsburgh, Pennsylvania. Richard Goettle, Inc. (RGI) was the successful bidder to install the specified augercast piles for the foundation package. Description - Pittsburgh Steelers Stadium The new stadium will house the Pittsburgh Steelers Professional Football Team. It is widely believed that if a team is provided with a modern playing facility, that a winning season will ensue (Not always the case). The new stadium location is on the north side of Pittsburgh on the Ohio River, and just downstream of the confluence of the Monongahela and Allegheny Rivers. The site is west of existing Three Rivers Stadium. The Three Rivers Stadium was built during the late sixties and housed both the Pirates Baseball and Steelers Football Teams. The Public Auditorium Authority elected to replace this outdated stadium with two new stadiums, one for each professional team. The landmark stadium was imploded in February of 2001.

Jan 1, 2001

By Antonieta Middea, Rupen Adamian, Fernando F. Lins

This work presents the results obtained with aggregation of fine talc (-19 m), a naturally hydrophobic mineral, in the presence of KC1 solutions. The classical DLVO theory describes well the aggregation of talc in dilute KC1 solutions. Beyond 1 M KCI we have found indications that a non-DLVO interparticles force is operative, say an hydration (repulsive) force. This structural force could be responsible for the unexpected re-dispersion of talc suspension. However, no repulsive force (depression) has been observed in salt flotation of talc at higher ionic strength, up to 3 MKCI.

Jan 1, 1995

By Jack A. Simon, M. E. Hopkins

Coal is defined as a combustible rock that originated in the accumulation and physical and chemical alteration of vegetation. Coal can be ignited and burned like the wood that was man's earliest fuel, but coal gives more heat than the same amount of wood and has many industrial uses. Unlike wood, coal is not generally found on the surface of the ground but is mined from the solid rock of the earth. Before taking up the occurrence, formation, and the unique character of coal in the rock sequence, let us briefly consider the general character of all rocks in the crust of the earth. Relatively little is known about the very earliest history of the earth, although a number of logical theories have been developed. Manned exploration of the moon and the rocks returned to earth continue to provide some answers to questions concerning the earth's origin and history. The period of earth history with which we concern ourselves here begins after great areas of water had evolved on earth and substantial land areas of once molten (igneous) rock existed. Weathering and other processes that attacked the surface of the rocks reduced them to small particles. Water provided by rainfall transported this material, ultimately, to large bodies of water where it was deposited. Thus was initiated the geologic sequence of sedimentary rocks that lie above the once molten igneous rocks. The crust and upper mantle of the earth are made up of several large plates along which differential movement (primarily horizontal) takes place. Such movements, although small, are occurring today. These horizontal movements are accompanied by vertical movements causing important changes in the relative position of the continents and oceans. Low-lying coastal swamps with favorable climates are ideal locations for coal accumulation and burial by river-borne sediments, and large areas

Jan 1, 1981

By W. Barthel, B. A. Dippenaar, J. Malan

In its most basic form, the process of sintering is very simple, and has been in use since the turn of the previous century. However, while the basic process is simple, control of the process relies on a number of extremely complex interdependent process parameters and requires a thorough understanding of the effect of these parameters on production capacity and product quality. Further, as with many other processes, the process parameters and hence design details of visually similar installations are highly dependant on the specific feed materials. While the industry trend has been towards an increase of capacity in order to lower unit production cost, typically in Iron ore sintering plants, this approach is not always possible for other commodities because of the scale of operation. This paper seeks firstly to describe some design considerations of sinter plants; secondly, to report on results from testwork performed with a specific series Manganese ore blends; and last, to relate these results to the design of new small-scale Manganese ore sinter plants.

Jan 1, 2004