Search Documents

By C. Díaz

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulfur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is heated in a sulfuric acid plant, and the low sulfur calcine is reduction smelted with coke in an electric furnace to yield a sulfur-deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulfur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries are obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1993

By J. Lehmann, H. Gaye

A brief review of Computational Thermodynamics software concerning the modeling and prediction of reactions involving metals, slags and fluxes is presented. Their application for various steelmaking treatments is discussed. Examples concern phosphorus removal in BOF and EAF, ladle steel desulfurization, and specific treatments for inclusions control in semi-killed or Al-killed carbon and stainless steels.

The pressure of low commodity prices forced the design process for the second lift of Northparkes E26 Mine to adopt a continuous improvement philosophy. The emphasis was to minimise capital expenditure while still maintaining the excellent low operating costs achieved on Lift 1. Although the first block cave lift at Northparkes is the most productive underground mine in the world and is held up as a benchmark for the use of technology in mining, areas for improvement were identified. Every area was critically assessed and investigated for the possible application of new techniques and technologies. Key learnings from the construction and production phases of Lift 1 were captured, documented and used as the starting point for the Lift 2 design. This paper shows how and why the design parameters initially used onLift 1 were changed to become the current E26 Lift 2 developmentproposal. The main differences between the two block caves arehighlighted. The alternative techniques and equipment that wereconsidered are also discussed. * Originally published in the Proceedings of MassMin 2000,published by The AusIMM.

Jan 1, 2001

By Congcong Yang, Jian Pan, Deqing Zhu, Yang Zhong

A study of pelletization of one imported chromite concentrate with coarse site, poor ballability and refractory roasting performance was conducted in small scale tests, and high pressure grinding rollers (HPGR) was used to improve the pelletization. The mechanism of HPGR was revealed by means of SEM images and optical microscopy. Compared with the ball milling pretreatment, HPGR pretreatment can not only enhance the ballability of pellet feed but also drop the roasting temperature. Fired pellets, containing proper chemical compositions with high compressive strength of 2917N/pellet and good metallurgical performances, have been manufactured. The mechanism of HPGR reveals that chromite particle surface turns to more irregular after HPGR treatment and more new surface being formed because of more cracks, sharp corners and edges appearing, resulting in higher surface chemical activity, all of which improve the ballability of the chromite concentrate and contribute to the consolidation of fired pellets.

Jan 1, 2015

By P. Koh

A novel approach incorporating computational fluid dynamics (CFD) and flotation modelling has been used for investigating flotation cell designs. CFD modelling has increasingly been employed to enhance understanding of the cell hydrodynamics in mineral and coal flotation. Opportunities for improving the flotation cell performance can be identify by modelling. The CFD-flotation model from CSIRO incorporates cell hydrodynamics that affect particle-bubble interactions. Information from the model includes velocities, turbulent dissipation rates, gas hold-up, particle-bubble attachment and detachment rates. The attachment and detachment rates have been found to be effective measures of cell performance for cell design.

Jan 1, 2011

By A. J. Rigby

Refractory linings in converters or anode furnaces used to over-oxidize the blister copper will suffer rapid deterioration, due to prolonged contact with copper oxide-rich slag. Nitrogen stirring with COP KIN porous plugs and use of SEMTECH OPC in converters and anode refining vessels can considerably reduce both refractory wear and processing times. In addition, careful control of the vessel atmosphere and the use of real-time optical process control minimize both slag volume and contact time with the vessel refractory.

Jan 1, 2005

By Y. Shiraishi, Y. Sakurai

A new method, the gliding cylinder method, was proposed as a wide range viscometer for the measurements of molten salts, slags, and glasses. The method consists of two coaxial cylinders, cylindrical bob and a vessel containing a liquid sample. There is a narrow gap between bob and vessel. When the vessel moves against the bob, the generated force on the bob consists of three types of resistance: (1) Stokes’s resistance on the bob, (2) a capillary flow resistance though an annular gap between vessel and bob, and (3) lubricating resistance in a gap. The last two can be calculated on a theoretical basis but the first cannot be estimated by a simple calculation since a wall effect did not calculate easily. However, it can be assumed that the generated force depends on both the viscosity of a liquid and velocity of the vessel. Thus, the relation between viscosity and a force at desired velocity of the vessel was measured using several standard reference materials including glycerol aqueous solutions and standard reference oils. The results depended on the magnitude of the gap between the bob and the vessel. For the wider gap, it was shown that the viscosity is a linear function of a gradient of force with respect to a vessel velocity. In contrast, if the gap is small, the viscosity depends on the gradient (of force with respect to velocity). This implies that the non-linear phenomena would occur in Stokes resistance. Though detailed analysis is in a further investigation, a calibration method can be applied to determine the viscosity by this method, because good correlation was obtained among these quantities. Viscosity of molten salts, such as NaNO3and ZnCl2was measured by this method as high temperature demonstration. Keywords: viscometer, viscosity, sphere pull-up method, fused salts, molten slags, glass melts

Jan 1, 2004

By B B. Beamish, J Theiler

Current spontaneous combustion index parameters such as SHT, CPT/RIT and R70 self-heating rate all have deficiencies that need clarifying from a risk management perspective. In some instances they can produce a false negative evaluation and in others they can produce a false positive evaluation. These tests all use a relative rating scheme that does not provide any indication of the time it takes for a spontaneous combustion event to develop, nor do they consider the moderating influence of moisture present in the coal on self-heating rate in the low temperature oxidation region. This is viewed as a major deficiency since the true self-heating behaviour of broken coal is primarily a function of time that is governed by the interaction of the initial boundary conditions (initial ambient temperature and moisture state) with the reactivity of the coal (both intrinsic coal reactivity and accelerated self-heating from reactive pyrite if present). The current index tests are also not appropriate for assessment of coalmine immediate roof and floor rocks.CITATION:Beamish, B B and Theiler, J, 2017. Recognising the deficiencies of current spontaneous combustion propensity index parameters, in Proceedings Australian Mine Vent Conference 2017, pp 113–118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

Neither the copper orebodies nor the zinc-lead-silver orebodies at Mount Isa were formed syntectonically as has been claimed for the last 20 and 10 years respectively. Both orebody types were cogenetic, coeval, and formed early during the sedimentation and diagenesis of the host formation. The copper orebodies are interpreted as having formed diagenetically at hand specimen scale, syngenetically at formation scale. The zinc-lead-silver orebodies are interpreted as having formed primarily by sedimentary means at both hand specimen and formation scales.

Jan 1, 2000

By H. Urata, K. Ishii

To determine the effect of F ions in the molten alkali silicate systems on their structures, quenched Na2O-SiO2-NaF systems were investigated by Raman spectroscopy and molecular dynamics simulation. The systematic increase of 1100 cm-1band intensity in the Raman spectra of the silicate melts accompanying the replacement of F for O provides the evidence for concomitant polymerization of melts. From the molecular dynamics simulation, it was confirmed that most of substituted F was mainly coordinated to Na+ ions but not Si4+ions. These results were consistent with the mechanism in which F associated with otherwise network-modifying Na rather than with network-forming Si. Since F was associated to Na+ ions, the replace of O ion by two F ions promote the polymerization of silicate melts. Keywords: fluorine; molten flux; slag structure; molecular dynamics simulation; Raman spectroscopy.

Jan 1, 2004

By Larry Meinert

Most large skarn deposits are zoned in both space and time relative to associated intrusions, and this zonation can be used to guide exploration. Zonation occurs on scales from km to, and reflects infiltrative fluid flow, wallrock reaction, temperature variations, and fluid mixing. In most skarn systems, there is a general zonation pattern of proximal garnet, distal pyroxene, and vesuvianite (or a pyroxenoid such as wollastonite, bustamite, or rhodonite) at the marble front. In addition, individual skarn minerals may display systematic color or compositional variations within the larger zonation pattern. Such patterns are reviewed for several well-studied examples of Cu, W, Au, and Zn-Pb-Ag skarns. In addition, many deposits have endoskarn or other alteration of the associated intrusion and recrystallization or other subtle changes in the surrounding wallrocks.

Apr 24, 2001

By A. Normanton, B. Harris, V. Ludlow, S. Riaz

Why does a continuous casting mould powder, which works successfully on a particular caster with respect to semi quality, fail to perform on a caster of a similar design utilizing liquid steel from a similar route for an identical product without some tuning of its make-up and composition? In casting sequences of the same steel grade, why do some apparent random heats produce poor surface quality with respect to cracking when otherwise good surface quality is realized? The answer to these questions lies in the interaction of the mould powder, the casting hardware, and the casting process variables. Using, as examples, data collected from within Corus UK and during collaborative work on the assessment of mould powder performance and its effects on surface quality, the interaction of the mould powder, the casting hardware and the casting process variables is explored. The steelmaking route and its associated alumina load, unexpected changes to slag chemistry, infiltration of the slag into the mould strand gap, and the nature of the slag film are all shown to affect powder performance. Keywords: continuous casting, mould powders, alumina, slag films

Jan 1, 2004

By P. T. Allsman

INTRODUCTION The honor of being the recipient of the Mining Society's Daniel C. Jackling Award for 1966 imposes on me the responsibility to search for the subject that I would be best qualified to discuss. It seems that my experience in the mineral industry — nearly 15 years in private and 30 years in public employment — should uniquely qualify me to comment upon the relationships between the mining industry, mineral engineering as a profession, and government, and the changing economic, technologic, political and social changes that dictate their relationships. Such conditions, the increasing knowledge of the world mineral resource base, the greater demands of an expanding population with a rising standard of living, shall be evaluated with respect to our profession — mineral engineering. In all of these forty or so years, I have been in close touch with many phases of the mineral and energy resource industries, especially those of the United States. Particularly during the past 10 years, I have had a ringside seat at the "goings on" in Washington. During all of this period I have observed and analyzed many of the problems of the industry and its relations with the government. During the past few years, I have had increased opportunity for doing research and have found a need to learn something about the mathematical techniques that are undergoing such a revival since electronic computers were developed. One of these techniques is multivariate analysis, which is a system for correlating a large number of complex variables. By applying this technique to the seemingly chaotic present-day situation, there emerges a course of steady improvement in the minerals resource industries that wars, depressions, and political strife have failed to obstruct for long. In short, I advocate a need for new concepts in mineral engineering to cope with the changes, pos- sibly adding many more specialized areas on one end of the spectrum, and broad engineer-generalist approaches at the other. The meeting place shall be where the intricate mineral resource problems at the frontier of knowledge merge into the socio-techno-logical problems of the world. HISTORICAL INVOLVEMENT OF GOVERNMENT IN MINERAL RESOURCE PROBLEMS Involvement of government in mineral resource problems undoubtedly is as old as government itself. But passage of the Mining Act of 1866, superseded by the Act of 1872, was the first major entry of our Federal Government into the problems of mining. Passage of the law was necessary to resolve many conflicting claims and disputes in mining. The General Mining Law of 1872 and the Mineral Leasing Laws of 1920 apply to millions of acres of public lands and to certain privately owned land on which the mineral rights have been reserved to the Federal Government. The extensive involvement of government in the mineral industry business today often comes as a shock to the mineral engineer who has begun to climb the ladder to the top in his company. He is often poorly prepared to cope with the situation and becomes frustrated and even hostile. Better knowledge of the role of government perhaps would ease his situation. In our political system, private industry is responsible for producing minerals. To make certain that the production is adequate for a peace-time economy, and to guarantee the Nation's security in an emergency, the Federal Government finds it expedient to develop policy and engage in regulatory, educational, and research activities. A few examples will illustrate the varied role of government in relation to mineral problems. In varying degrees many agencies of the Executive Branch of Government have responsibilities that influence the functioning of the mineral and energy industries. In addition, of course, Congress, the Judiciary, and State and local governments exercise great influence. The Department of the Interior is primarily responsible for activities to promote the development and conservation of mineral and fuel resources, and the

Jan 1, 1967

By I Mason, A Wellington, J Hargreaves

Many people are familiar with the use of marine echo sounders which are used by fishermen to monitor water depth and locate schools of fish. Similar technology has recently been used in some West Australian mines to provide detailed maps of ore contacts and other geological structures. Whilst drillhole intersections provide details of the location of a contact at a point, echo sounding can be used to obtain a continuous profile of the contact. A series of profiles together with drillhole intersection data can be used to build a more accurate geological model than can be inferred from drillhole intersections alone. The benefits of this are more complete ore extraction, less dilution and the ability to make more informed financial decisions. This paper presents a case history which demonstrates the successful application of the technology.

Jan 1, 2000

By G R. Dickens, N H. S Oliver

Deformed regions of the Hamersley Province, Western Australia, contain several major iron ore deposits where banded iron-formation (BIF) of the Dales Gorge Member was converted to martite-microplaty hematite. The genesis of these ores remains controversial, in part because no study has systematically documented how stratigraphically equivalent rocks change chemically from undeformed regions into the deposits. Profound chemical and mineralogical differences do occur between rocks in the undeformed north and mineralised south. BIF and shale can be classified into three types: BIF, altered BIF and iron ore, and black shale, altered black shale and red shale. A series of low temperature (20 to 250¦C) chemical reactions can explain the observed differences in chemistry and mineralogy. The inferred reaction paths indicate that no single process could have produced all of the altered rocks at Mt Whaleback. Recently described carbonate-rich, silica-poor rocks at Mt Tom Price (Taylor et al, 2001) suggest this alteration sequence is even more complex. Our favoured explanation for the genesis of hematite ores is one that can explain deposits at Mt Whaleback and Mt Tom Price: following regional metamorphism, hydrothermal fluids locally formed carbonate-rich, silica-poor BIF with magnetite and carbonate-rich altered black shale. Subsequent surface derived fluids oxidised this magnetite, crystallised microplaty hematite (mpl) and eventually dissolved carbonates and silicates leaving high-grade ore. Either during or sometime after mineralisation, acidic, oxygenated fluids converted altered black shale to red shale and unaltered BIF to martite-rich BIF without carbonates across the southeast of the province.

Jan 1, 2002

By S. E. Olsen, K. Tang

Slag-metal and slag-metal-gas heterogeneous equilibria involving MnO-containing slags have been simulated using recently developed Mn-based alloy and IRSID oxide thermochemical databases. A large number of experimental equilibrium data have been used to verify the calculation results. The experimental slag-metal and slag-metal-gas equilibria in MnO-SiO2binary, MnO-SiO2-CaO and MnO-SiO2-Al2O3ternary, MnO-SiO2-CaO-Al2O3quaternary andMnO-SiO2-CaO-Al2O3-MgO higher-order system can be reproduced within experimental uncertainties. The influence of temperature, CO partial pressure and slag chemistry on the Mn-and Si-distribution equilibria have been quantitatively evaluated. This leads to a sound basis for optimizing the manganese ferroalloy production processes. Key words: MnO-containing slag, manganese ferroalloy, equilibrium simulation, thermochemical database

Jan 1, 2004

By Wilfrid Comeau

While researching for a theme lecture (Comeau, 1993l) on: 'The Mechanics and Physics Explosives', the author of Energy Transfer in Rock Fragmentaion by was confronted with many conflicting concepts regarding: the current explosive rock fragmentation theories, the physical principles governing energy transfers, the mechanical properties of rocks, and observations and data from full scale rock blasting.

Jan 1, 1995

By Marco Antonio Falquete

A novel spark-generating tube, containing no explosive in its composition, is evaluated and compared with conventional shock tube. The product overcomes a series of problems found in conventional shock tube technology. The technologic development had multiple aims: to avoid transport and storage costs associated with explosives, to be more environmental-friendly, to obtain a high-velocity, hightemperature spark whose thermal performance could overcome poor heat transfer to the delay charge by gas convection at shock tube end, and that could cross barriers such as tight kinks, close knots, cuts, extreme environmental conditions, and long-term hot explosive emulsion exposure. The product of this development is evaluated and compared with conventional shock tube in a series of aspects and performance tests, including spark thermal performance (ignition of tougher, low sensitive delay columns, spark gap test), propagation in critical conditions of use (kinks, knots, cuttings), extreme environmental conditions (long-term exposure to hot emulsion explosive, extremes of cold, heat, moisture, underwater exposure), safety features (ignition through flame, open fire), and security against terrorist acts. Due to the safe characteristics of the tube, a series of demonstrations will be performed during the presentation. In nearly all tests and aspects, the spark-generating tube exceeds conventional shock tube, and in the rest equals shock tube, making it a more reliable alternative.

Jan 1, 2005

By Robert McClure, Carlton Lehman

Rendering safe explosives in an urban environment presents a unique challenge due to the safety concerns and disruption to the general public. Potential damage to the surrounding homes, businesses, utilities and transportation infrastructure are some of the major concerns when planning the render-safe operation. Engineering controls to mitigate blast effects, such as damaging air over pressure levels, material ejection and ground borne vibration, need to be implemented as part of the operation. Monitoring of seismic and air overpressure during these operations are needed to protect against potential claims when controlled or unplanned detonations occur. Two recent render-safe operations conducted in and around urban environments dealt with deteriorated, sensitive dynamite and damaged blasting caps. Utilizing innovative neutralization chemicals and processes to render-safe the deteriorated dynamite, while protecting the general public, proved to be the safest, most environmentally responsible and cost-effective way to approach the problem. In both cases, the explosives, old dynamite and detonators were found in abandoned, unlocked magazines. The dynamite was in a significantly deteriorated state, which was evident due to the nitroglycerine found leaking in,around and under the dynamite cartridges. Iron wire permissible electric blasting caps were also found in a corroded condition with exposed explosives and un-shunted lead wires. With occupied buildings within 180 feet (54.86 meters) of the magazines, any procedure (e.g. transporting, countercharging, burning) that could potentially cause a detonation was not an option. In the event of an unplanned detonation during neutralization operations, several blast mitigation methods were employed to safeguard the site. This operation and a similar one with over 1,000 pounds of crushed and buried leaky dynamite were unique since all the explosives were rendered-safe and neutralized on site. The use of advanced neutralization products and filtering processes allowed for a safer, more environmentally responsible way to resolve the problem. The magazines and all residual solids and fluids were tested and confirmed by independent labs to have no explosives residues. The effluents were treated on site, tested and met safe levels, so they were disposed of at a local municipal wastewater facility.

Experimental studies on viscosity of titanium bearing slags have been reviewed and the assessed data were used in extending the capability of the structurally related viscosity model for silicate melts, developed by the present authors. Experimental data on ternary and higher order systems containing CaO, MgO, MnO, FeO, Al2O3, TiO2, Ti2O3, SiO2were assessed and used. The newly extended viscosity model represented the viscosity behaviour over broad temperature and composition ranges. The structural role played by TiO2and Ti2O3in silicate network structure is discussed with respect to their effect on viscosity of melts. Keywords: viscosity model, TiOx containing silicate melts, silicate network structure.

Jan 1, 2004