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By C. -T. Mutale, A. S. Tuling

Titanium can exist in three different oxidation states. Its oxides are numerous and in presence of iron and oxygen, iron-titanium oxide compounds can also form. Some of the oxides are non-stoichiometric, making the determination of the thermodynamic properties of titanium and its oxides in molten steel and in slag difficult. Therefore, for the assessment of titanium activity in molten steel using the electrochemical measurements of oxygen partial pressure, the identification of oxides in equilibrium with titanium is important. This paper reports on an investigation of solid titanium oxide inclusions, which have been identified by combining different methods of analysis on quenched samples. These samples were taken from a Fe-Ti-melt at 1600°C, quenched in cold water then mounted and polished for optical microscopy. The oxide inclusions were analysed using transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS). Both single crystal and polycrystalline diffraction patterns were used to identify the oxides by comparing the d spacings with those in the ICDD X-Ray Diffraction (XRD) database. XRD was used to analyse the oxide particles on the top of slow cooled samples. It was found in the TEM study that the similarity of the diffraction patterns of the various phases meant that unique identification was difficult to achieve in some of the diffraction patterns. However, TiO, Ti2O3, Ti3O5, Ti4O7were identified in quenched samples, while TiO2, FeO.TiO2and iron oxides were seen in slow cooled samples. It was also confirmed that the type of oxides is related to titanium content of the samples. Keywords: Titanium, Titanium Oxides, Iron, TEM, XRD, thermodynamic.

Jan 1, 2004

By W. M. Cross

Bubble attachment time measurements for the rare-earth phosphate minerals monazite and xenotime were made as a function of oleate concentration, sodium fluoride addition, and temperature. Results indicate that the rare-earth phosphates behave similarly to other phosphate minerals, notably collophanlte and fluorapatite, which have been studied previously. The addition of sodium fluoride yielded a modest decrease in bubble attachment time with fluoride additions below the apparent fluoride surface precipitation point, while at fluoride additions greater than the apparent precipitation point a significant decrease in attachment time occurs. Increasing the temperature or the system gave a slight decrease in bubble attachment time in the absence or sodium fluoride. With sodium fluoride addition and below the apparent fluoride surface precipitation point, an increase in temperature actually increased the attachment time. For sodium fluoride additions above the apparent fluoride surface precipitation point, a temperature increase significantly decreased the attachment time.

Jan 1, 1989

By George Hope, Brigitte Lacouture

"The Red Dog Mine has increased mill throughput for most years since startup. Although flotation equipment has been added over the last 10 years, the Red Dog metallurgical performance has been restricted by a lack of adequate flotation capacity. Two reduced tonnage trials conducted in 1997 as well as numerous SAG relines have consistently indicated the potential to significantly increase both zinc concentrate recovery and grade with additional flotation capacity. Late in 1999, a new circuit was designed with increased flotation capacity while simplifylng the current circuit, providing for three stages of dilution cleaning, and creating a retreat section. The purpose of the retreat section is to target the more complex particles and allow the chemical environment to be fine tuned for improved iron depression. In total, twentyone (21) Outokumpu OK50 mechanical flotation cells and four (4) 3.66m dia. column cells will be added to the current flotation circuit. The VIP (Value Improvement Program) Mill Optimization project is also addressing thickening, water treatment and power issues and has a total budget of $US105 M. Startup of equipment will be phased in to minimize the impact on current operations and is expected to be complete by the end of Q3-2001.INTRODUCTIONRed Dog Operations started production in November 1989. The mine is located above the arctic circle in northwest Alaska. It is linked by an 80 km road to a port-site facility where the concentrate is stored. Concentrate is shipped to markets throughout the world during the one hundred (100) days of open seas. Typical of sedimentary exhalative deposits, the metallurgy proved to be challenging and coupled with many mechanical shortcomings, the initial few years were very difficult. The start-up issues were slowly resolved and in 1998, a major grinding expansion, the PRI (Production Rate Increase) project, was completed. The project was designed to allow a 40% increase over the 1995 throughput. In 2000 mill throughput was 3,050,000 tonnes to produce a total of 960,000 and 140,000 dry tonnes of zinc and lead concentrates respectively, making Red Dog the largest zinc concentrate producer in the world. To address a shortage of flotation capacity remaining from the PRI grinding expansion, a project designated as the VIP (Value Improvement Program) Mill Optimization project was initiated. The mill optimization project is targeted to produce 1,100,000 tonnes of zinc concentrate at 56% zinc grade and 87% zinc recovery. The project will add twenty-one (21) Outokumpu OK50 (50m3) flotation cells, four (4) 3.66mO column cells and address water treatment, thickening and power generation capacities."

Jan 1, 2002

By James D. Noll, Eileen Birch

In a previous study, the e?cacy of commercial and prototype impactors for sampling diesel particulate matter (DPM) in coal mines was investigated. Laboratory and ?eld samples were collected on quartz-?ber ?lters and analyzed for organic and elemental carbon. Coal dust contributed a minimal amount of elemental carbon when commercial cascade impactors and prototype impactors, designed by the University of Minnesota (UMN) and the US Bureau of Mines (BOM), were used to collect submicrometer dust fractions. Other impactors were not as e?ective at excluding coal dust. The impactors evaluated in that study were either not commercially available or were multi-stage, expensive, and di?cult to use for personal measurements. A commercial version of the BOM impactor, called the DPM Cassette, was recently introduced by SKCs. Tests were conducted to evaluate the performance of the DPM Cassette for measuring diesel-source elemental carbon in the presence of coal dust. Bituminous coals from three mines in two di?erent coal provinces were examined. The dust particle diameters were small and the coal dust contained a high percentage of carbon, there by giving a worst-case condition for non-anthracite coal mines. Results for the DPM Cassette were essentially identical to those obtained by the BOM impactors in a previous study. At a respirable coal dust concentration of 5.46mg m3, which is 3.8 times the regulatory limit, the DPM Cassette collected only 34µg m3 of coal-source elemental carbon.

By Susumu Uchiyama

This machine was manufactured for excavation of the Roppongi station of the Tokyo Metro Line 12. This machine can excavate both the platform and the rail track at the same time in locations where the traffic is congested and has following features: A multi-centered TBM of the size of 7.06(H) x 13.18(W) m The world first H&V TBM, with right and left machine parts articulated vertically and separately for position control A large erector for simultaneous erection of column and central segments of special shape to construct a highly reliable tunnel This paper reports the design concept, construction, and work record.

Jan 1, 1999

By Qingwei Wang

Heavy metal-containing wastewater from hydrometallurgical processes of lead-zinc was treated by biologics in a 200 m3/h industrial scale experiment. The result shows that Zn concentration declined from 50.28 mg/L~240.81 mg/L to 0.21 mg/L~1.98 mg/L, Pb from 1.00 mg/L~13.47 mg/L to 0.083 mg/L~0.71 mg/L, Cu from 0.24 mg/L~2.38 mg/L to 0.059 mg/L~0.40 mg/L, Cd from 2.12 mg/L~23.47 mg/L to 0.011 mg/L~0.071 mg/L and As from 0.50 mg/L~6.00 mg/L to 0.005 mg/L~0.10 mg/L. The concentrations of the above heavy metals in the treated water were lower than that in Integrated Wastewater Discharge Standard (GB8978~1996) in China. Furthermore, the treated wastewater was recycled and reused in smelter plant. Zinc content in hydrolytic sludge reached up to 34.04%, which indicates that this sludge can be used to recover valuable metals.

Jan 1, 2010

The Effect of Non-Toxic Depressants in Chalcopyrite Flotation

Sep 13, 2010

By C. W. Davis

Before listing the laboratories and the work performed there, it is proper to make clear what is done and what is not done by Federal bureaus, States, and Territories, as well as by countries to the north and south of the United States. FEDERAL Bureau of Mines. - The Bureau of Mines does not make assays or analyses for individuals or firms unless the samples are part of the ore-testing and ore-dressing investigations of the Metallurgical Division on representative ores from mining districts and of possible benefit to the entire mineral industry through published reports. All significant results obtained in this way are made public. Any mineral sample sent to this Bureau for simple identification will be examined.

Jan 1, 1938

By Albert L. Toenges

The purpose of this paper is to describe some of the methods and practices of mining coal mechanically where more than one shift is worked, with the view of determining the advantages and disadvantages of various types of equipment and mining systems now in use. This paper is in the nature of a progress report, and, as the number of mines discussed in it is limited, the conclusions drawn in the comparison of various systems are not final but may be revised after subsequent investigations. Physical conditions vary in different and in the same mining districts and determine, more

Jan 1, 1938

By Long Meng, Yaodong Yi, Kuiyuan Chen, Zhancheng Guo, Yu Li

Blast furnace slag is the main by-product discharged in the iron and steel industry and contains considerable waste heat at dischargeing temperature between 1450 and 1550 °C. To fully utilize waste heat and slag, this study directly converted high temperature liquid Ti-bearing blast furnace slag into glass-ceramics via the “Petrurgic” method. Samples at different crystallization temperature were prepared and its influence on crystal phases, pore structure, and compressive strength were investigated via SEM, XRD techniques, and compressive strength measurements. Results showed that all glass-ceramic samples contained main crystals of perovskite, diopside and gehlenite and had a qualified mechanical performance with compressive strength above 100 Mpa, which meets the requirement of Chinese national standard for natural granite stone. With increasing crystallization temperature, pore size decreased, while the size of the perovskite phase firstly decreased and then increased with decreasing crystallization temperature. Samples had an optimum crystallization temperature of 1215 °C, maximum grain size and a densified structure with minimal pore defect.

Mar 1, 2018

By Stuart D. Miller, Clayton L. Rumble

"A field net acid generation (NAG) test procedure has been utilized on-site to identify, classify and map potentially acid forming overburden at the PT Kaltim Prima Coal (K.PC) mining operation situated in the tropical equatorial region of East Kalimantan, Indonesia. The field procedure involves routine use of a calibrated, site specific NAG test (rapid oxidation test using hydrogen peroxide) which has a tum-around time of less than 24 hours and requires minimal sample preparation. It is used on geological drill-hole samples, for forward planning and overburden management; blast-hole samples, for day-to-day operational control and overburden scheduling; and final dump surface samples, for verification testing. This operational monitoring program has been in use at KPC for the past four years.Calibration and implementation of the field procedure has involved validating the NAG test using conventional acid-base accounting techniques, producing an overburden geochemical classification scheme, optimizing laboratory and sample preparation procedures, and ongoing quality management. This paper presents background theory and practical application in a case study format."

Jan 1, 1999

By James A. Jessop

The Bureau of Mines is investigating the use of geophysical methods to determine rock mass characteristics, particularly rock quality, lithology, and fracture parameters that are important for determining the feasibility of in situ leaching operations. As part of this research, two Bureau-developed crosshole geophysical systems are described that can be used for site investigation and rock mass characterization. Results are given for performance tests at field sites in Arizona and Texas and for correlations between the crosshole seismic data with fracture frequency, rock quality, and lithologic variation. Recommendations are made for using elastic waveform propagation characteristics and dynamic elastic properties for improving rock mass characterization in the geomechanical assessment of in situ leaching deposits.

Jan 1, 1990

By J. M. Riley

This report summarizes Bureau of Mines experiments in purifying sulfate leach liquors, which were prepared from low-tenor beryl concentrates by modifying the Degussa process. The leach liquor was prepared from a beryl concentrate containing 2.7 percent BeO by (1) sintering the beryl concentrate with limestone in a rotary kiln at about 1,150° C. and by (2) treating the sinter first with sulfuric acid and then with water to form and extract beryllium sulfate. About 80 percent of the beryllium was dissolved. The resulting leach liquor contained 2.4 grams of BeO, 20 grams of Al203, and 6 grams of Fe203 per liter. The laboratory solution contained much more aluminum and iron than a solution derived from treating 10 percent BeO concentrate, which is the standard raw material used by industry. Tests were made to determine the behavior of the solution toward alum purification and limestone neutralization both of which were employed industrially in conventional Degussa procedure.

Jan 1, 1962

By J. J. Carlson

Studies were carried out to determine whether filtration rate changes observed in an iron ore concentrator were due to variations in particle shape. It was confirmed that ores mined from different locations differed in filtration rates by as much as 60%. However, when image analysis was used to quantify the shapes of the individual particles in the filtration feed, it was found that the particle shapes showed almost no variation, and the shapes did not correlate with the filtration rate. It was also determined that the filtration rate variations were not caused by changes in particle size distribution. These results suggest that the differences in filtration rate are due to factors other than size and shape, such as surface chemistry.

Jan 1, 2008

By H. Mitri

A new monitoring device called SAFEBOLT (Stress And Force Evaluator in BOLTs) has been recently developed at McGill University. The device is essentially an alternative to the load cell, it permits the monitoring of bolt axial load in the field. The SAFEBOLT system consists of a portable readout unit, a connecting cable and the SAFEBOLT device, which is installed in the bolt head. The new device can be installed on any industry standard rockbolt or rebar. The device is completely encapsulated in the bolt head, which makes it resistant to corrosion, rugged, and free of any electric wires. Pilot tests at two underground Quebec mines were carried out and helped improve the initial design of the device head.

Jan 1, 2002

By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at Inca Ltd.&apos;s J. Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper-nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be affected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high-grade nickel concentrate as the residue. Sodium cyanide was added to the froth product 10 depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition . The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high-grade nickel concentrate (29.5% Ni, .26% Cu) and copper concentrate (<0.5% Ni, 30% Cu) were all realized.IntroductionLaboratory test work undertaken at Inco and described previously(1) has demonstrated the importance of low xanthate concentrations on the mineral surfaces in the copper-nickel separation at the Copper Cliff mill.It was determined that oxidation of the separator feed (a cleaned bulk concentrate, grading about 11% Cu and 11% Ni) to lower the xanthate concentration on the mineral surfaces prior to separation significantly improved the quality of the separation (CI 4)*, particularly when no cyanide is used, but also when cyanide is added. As well, it was found that the oxidation permitted a pentlandite-pyrrhotite separation - the oxidation step brought about a decrease in the flotation-rate of pentlandite leaving pyrrhotite and chalcopyrite largely unaffected. Consequently, it was possible to produce a highgrade pentlandite product (30% Ni, 0.3% Cu) at ~83% Ni recovery , as well as a high-grade copper concentrate (0.5% Ni, 30% Cu at -96% Cu recovery)."

Jan 1, 1985

By J. R. Patts, A. B. Cecala

"After industrial sand has been mined and processed, the finished product is typically loaded into small bags of 45 kg (100 lb) or less, large bulk bags of 454 to 1,361 kg (1,000 to 3,000 lb), or vehicles such as trucks or trains for transport to end users. As the sand is being transferred and loaded, dust can be released into the work environment, potentially exposing workers to respirable crystalline silica. A number of control technologies have been developed and utilized in an effort to reduce dust liberation during loading operations. For bulk loading into trucks or trains, the U.S. National Institute for Occupational Safety and Health (NIOSH) evaluated one of these technologies, the Dust Suppression Hopper (DSH), at two industrial sand processing plants. Results from these case studies show that the DSH reduced airborne respirable dust levels by 39 to 88 percent, depending upon the product size being loaded.IntroductionInhalation of respirable crystalline silica dust can lead to the development of silicosis, a disabling and potentially fatal lung disease. Once contracted, there is no cure for silicosis, so the goal is to prevent the development of the disease by limiting exposure to respirable dust containing crystalline silica at or below the exposure limit of 50 µg/ m3 recommended by the U.S. National Institute for Occupational Safety and Health (NIOSH, 2002). At industrial silica sand operations, the product contains high levels of crystalline silica, so effective control technologies are needed to minimize the respirable dust exposure of workers.NIOSH, in partnership with the Industrial Minerals Association–North America, published a dust control handbook (NIOSH, 2012) focused upon control technologies for industrial- mineral mining and processing operations. One chapter in this handbook discussed technologies for controlling dust liberated during bulk loading, including telescoping loading spouts, dust collection systems for loading spouts, enclosures for load-out areas and a newer technology known as Dust Suppression Hopper (DSH)."

Jan 9, 2018

By Tom Setterfield

Conclusions ?Canada is a prospective place to explore for IOCG deposits ?Time distribution of IOCG mineralization in Canada mimics that in the rest of the world ?Canada may have been the first country to start mining IOCG deposits ?Production from newly discovered IOCG deposits in Canada may start soon

May 1, 2006

By Carolina Passanante

Aços Inoxidáveis Supermartensíticos surgiram na indústria petroquímica como um material alternativo para confecção de dutos, devido principalmente ao sinergismo de suas propriedades mecânicas e de corrosão. Com esta nova demanda, tornou-se necessária a caracterização deste material em suas diversas propriedades, destacando-se neste trabalho o efeito da microestrutura na resistência à corrosão. Objetivou-se, portanto, o estudo da resistência à corrosão por pite de um aço inoxidável supermartensítico 13Cr-5Ni-2Mo-Nb em função da fração volumétrica de ferrita-delta (d) presente na microestrutura. A variação da ferrita-delta foi alcançada através de tratamentos de recozimento, a 1.050°C, durante diferentes tempos (de 0,5h a 48h). As amostras foram submetidas a ensaios de polarização potenciodinâmica em eletrólito contendo 3,5% NaCl, naturalmente aerado. Quantificou-se, ainda, a porcentagem de ferrita em cada uma das condições através de ataque eletrolítico com solução 20% NaOH. Os resultados obtidos evidenciaram a diminuição desta fase com o aumento do tempo de recozimento, chegando praticamente à sua eliminação com tratamento de 48h. Paralelamente, a resistência à corrosão por pite deste aço foi melhorada de modo proporcional à diminuição da fase ferrita, resultando em um aumento de aproximadamente 115 mV da pior para a melhor condição, comprovando que, de fato, a presença de ferrita-delta prejudica as propriedades de resistência à corrosão localizada.

Aug 7, 2018

By Hani Henein

Recent innovations in atomization of molten metals have occurred in the area of single fluid atomization. Impulse Atomization (IA), one of the single fluid techniques, provides unique capabilities to study different regimes of atomization in a controlled environment. By changing processing variables, a mono-dispersed distribution of droplets above one millimeter in diameter can be produced. This is accomplished through proper characterization of the forces influencing the process and in particular the flow of melt through the orifice. This paper will discuss the approach and illustrate results with molten aluminum and cobalt.

Jan 1, 2006