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By C. R. Kuhn

From 1968 to 1975, most work in surface modification of inorganic materials involved silane coupling agents. A silane coupling agent can be described simply as an oganosilicon chemical having a general formula RSi-X3 wherein the R group is attached to a silicon in a thermally and hydrolytically stable manner, and X is a hydrolyzable group usually having an alkoxy functionality. About 1975, Kenrich Petrochemicals brought into the market place titanate coupling agents. Titanate coupling agents usually consist of one alkoxy group and three functional groups attached to a central titanium atom. Zircoaluminates became available in about 1982. Zircoaluminate organometallic coupling agents, which vary principally in their respective organofunctionalities, arise from a basic technology in which two different types of organic ligands are selectively bound to a low-molecular weight zircoaluminate backbone.

Jan 1, 1995

By AIME AIME

COMMITTEE No. 2 of the Iron and Steel Institute b f Great. Britain has presented its first report, of 27 printed pages, on blast-furnace plant and practice. This report outlines the various features of modern blast-furnace practice with brief comments thereon, and with references to some of the more recent methods devised for applying the principles and attaining the purposes aimed at' under these headings.. In general, the trend in the United States is in the direction of larger and larger furnaces with ever increasing capacity from which, with improved details in methods and equipment, and attention to details of management, considerable progress in. economy of production has been attained, in fuel consumption and in other items of production cost.

Jan 1, 1929

By W. K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/AgCl reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrode to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 1994

By Paul Richardson

This paper discusses the drilling techniques and equipment used by Loffland Brothers Company to drill the AEC's UC-3 large diameter shaft in Nevada. Included are pictures and illustrations of the drilling-mud circulating system, the surface and downhole drill-string and the special heavy-duty mast and hoisting equipment required to do the job. The purpose and method of lining the large diameter holes along with the technique and materials used to backfill the lining to hole annulus are discussed briefly. Areas requiring improvement in both equipment design and technology for large diameter shaft drilling are discussed briefly. Shafts as large as 140 inches in diameter to depths of 5,000 feet can be drilled with existing equipment and technology.

Jan 1, 1969

By J. W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and, from the data developed, to determine: (a) Which coals, either as mined or after beneficiation by conventional preparation, are suitable chemically under present standards for producing metallurgical coke. (b) Which coals require special and more intensive treatment in preparation than is now practiced. (c) Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation. This report is one in a county series and describes the preparation characteristics of the coals of Logan County, W. Va. According to present-day standards for metallurgical coal, many believe that the sulfur content of the coal should not exceed 1.25 percent? Coal with more than this amount has been used for making metallurgical coke, especially when blended with coal containing less sulfur. In this series of reports 1.25 percent sulfur is used as a gage to determine whether or not a coal will be suited for metallurgical coke.

Jan 1, 1957

By Manuel Calderón

Chile is responsible for 30% of the global copper production; the world ́s largest. However, significant challenges are faced in this industry; declining grades (1.13% in 2002 to 0.61% in 2015), high cost of energy, scarcity of water, and environmental concerns. Mining trends suggest the future of the industry will be focused in the underground space, specifically due to the depletion of economically viable surface mineral deposits. For example, the largest block cave mineat Codelco ́s Chuquicamata mine is expected to reduce energy costs by 50% and dust emissions by 97%compared to the open cut mine. To access these underground deposits, critical infrastructure is required; horizontal tunnel developments, extraction levels, vertical raises, and ore passes with the on-time delivery of the highest quality outcomes being a requisite for successful project delivery (Lift 1 of 3 at Chuquicamata Underground has over 1000drawbells).One aspect that makes this scenario even more challenging for deeper underground operations is the increased risk profile (people, equipment, and geotechnical) that forms part of the general environment. Furthermore geotechnical risks should be considered and they include rock burst and windblast. The safe interaction with this environment must be sustainable throughout the full life of the project. This paper presents the Enaex group approach to addressing the blasting challenges and outlines the solutions created. Aspects such as rock mass damage occurrence as a function of blast vibration frequency content has been studied, as well as the development of blasting methodologies for guaranteeing the full 100% extraction of all infrastructure blasts, including the all-important draw bell volumes. The development of such infrastructure volumes in one single event using electronic detonators and the associated achievement of ambitious productivity goals, are described as a critical part of the successful construction of one of the most ambitious UG projects currently present on the world.

By Ian G. H. du Preez

It is illustrated how differences in the basic chemistry of individual metal ions can be exploited to develop new or improved separating agents. Factors like coordination number preferred by the specific metal ion, the degree of coordinate saturation reached by the metal ion and its relation to the phase transferability of the complex species, kinetic factors as opposed to thermodynamic factors controlling the success of the separation, the nature and type of the donor atom employed in a separating agent in relation to the preferences of the metal ion, the significance of stereochemical factors and the hydrophobicity of the media are some of the important factors which are discussed and applied for the development of pa1ladiwn(TI) and nickel(TI) specific separating agents, respectively.

Jan 1, 1999

By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By Esther Carrera Martinez

Caraiba Metals is the sole brazilian copper custom smelter. The sulfur present in the various concentrates processed is recovered as sulfuric acid and oleum ,which are sold in the local market For quality assurance purposes, a study was carried out in order to determine how to control the arsenic content in the acid, allowing the continuous processing of concentrates with high levels impurity, The study was based on the process parameters of the washing towers and mist precipitators, Others process variables were investigated and their effects were used in support to confirm the results, After many analyses performed some interventions to improve the quality of the acid were implemented in the plant, which proved to be successful even by using a conventional purification system,

Jan 1, 1996

By W. R. Bull

This paper examines water-only cyclone performance for the cleaning of fine coal, and the effects of changes in feed flow rate, feed pulp density, and vortex finder diameter. A model is presented for performance simulation which can be used to predict products obtained based on feed washability data.

Jan 1, 1987

By Richard G. Almes

Since the failure of a major coal refuse disposal embankment and impoundment in the Buffalo Creek watershed near Man, West Virginia in early 1972, there have been extensive changes in the design and construction requirements for coal refuse disposal facilities located throughout the United States. The primary emphasis has been on improving the safety of these facilities, particularly for impoundments which are capable of storing millions of gallons of process water and storm runoff. The Mine Safety and Health Administration (MSHA) of the U.S. Department of Labor (formerly the Mining Enforcement and Safety Administration, U.S. Department of interior) has been the lead federal agency in promulgating regulations pertaining to coal waste disposal. In 1974 and 1975, studies were undertaken by our firm under contract to the Mining Enforcement and Safety Administration to prepare a comprehensive engineering and design manual to be used by operators and engineers in the planning and design of coal refuse disposal facilities with the intent ion of avoiding any more Buffalo Creek failures. The resultant 800-page document addresses major subjects such as safety, environmental controls, and cost. Specific topics include characterization of coal refuse, classification of disposal facilities, project planning, geotechnical investigations, testing and design requirements, hydraulic and hydrologic design, environmental factors, operations, and monitoring, instrumentation, and maintenance.

Jan 1, 1980

By Shawn McWilliams, Aini Sun, Mike Lichte, Greg Colzani

The Allegheny County Sanitary Authority (ALCOSAN) adopted its Clean Water Plan (CWP) in May 2020, as part of a federal consent decree to comply with the USEPA’s Combined Sewer Overflow (CSO) Control Policy. Planned improvements include constructing a new regional storage/conveyance tunnel system, promoting green infrastructure/ source control, and expanding the treatment plant. Preliminary planning for the tunnel system was completed in October 2020. The Ohio River Tunnel (ORT) project is the first of three tunnel projects that make up the regional tunnel system. The ORT project began final design in 2021. This paper discusses the advancements made to the ORT preliminary planning concepts considering property availability, alignment optimization, tunnel boring machine evaluation, contract packaging and delivery schedules.

Jun 13, 2023

By Atta B. Yiadom, A. David Miller, Robert C. Kirby, Sean M. Todaro

"San Pablo Dam is a 170-foot (52-meter)-high earthfill embankment, located approximately 10 miles (16 kilometers) north of downtown Oakland, California, that impounds a 38,600 acre-feet (47.6 million m3) reservoir for customers in the East Bay Municipal Utility District's (EBMUD's) service area. Seismic upgrades were designed and constructed in 2008 through 2010. Work included removal of an existing 140,000 cubic-yard (107,000 m3) downstream buttress, which was replaced with an enlarged 300,000 cubic-yard (230,000 m3) buttress founded on alluvium and colluvium that were improved in-place using Cement Deep Soil Mixing (CDSM) technology. The site characterization for the project, design of CDSM, reuse of CDSM spoils as construction materials, and environmental permitting have been described in five previously published professional papers.This paper provides a brief summary of the design of the seismic upgrades and presents the results of measurements made during and/or after construction including the variation of CDSM strengths with time, piezometric levels within the dam and foundation soils, and seepage flow rates. These measured values are compared to the values estimated during design of the seismic upgrades.INTRODUCTIONSan Pablo Reservoir is located approximately 10 miles (16 kilometers) north of downtown Oakland, California, as shown in Fig 1. As many as 50 million gallons (200,000 m3) per day pass through the reservoir for treatment and distribution to a portion of the 1.3 million customers served by EBMUD. The dam is founded mainly on alluvium and was originally built in 1920 using materials excavated from the left and right abutments consisting of siltstone, claystone, fine-grained sandstone, mudstone, and shale that were excavated and placed using hydraulic fill methods. The dam is located within two miles (three kilometers) of the Hayward Fault which is capable of a moment magnitude 7.25 earthquake.Because of the foundation materials, construction method, and proximity to the Hayward Fault, the dam has undergone a series of seismic improvements, including the placement of a downstream compacted earth buttress in 1967 and an upstream compacted earth buttress in 1979. In 2002, the State of California Division of Safety of Dams (DSOD) requested that EBMUD evaluate the seismic stability of San Pablo Dam, following the results of a study that same year that indicated a 62 percent chance of a greater than 6.7 magnitude earthquake striking the San Francisco Bay region between 2003 and 2032. The dam was evaluated and it was concluded that portions of the underlying foundation soils may liquefy during the maximum credible earthquake which could cause the dam to become unstable."

Jan 1, 2015

By Edwin Dudley Martin

DURING the past twelve years the iron and steel industry has made a major advance through the development of the continuous wide strip rolling mill. So far-reaching have been the results that not only has a better product been sold at a lower price but this improvement in quality has permitted manufacturers of products using steel to make important savings in the cost of fabrication. The net result has been a better product at lower cost to the consumer without reduction in either employment or of wages paid within the industry. That is why the iron and steel industry is proud of its attainment. Being a basic industry of strategic importance, such an advance in technology has had its effects on our internal economy, our standard of living, and our industrial power as a nation in both peace and wartime.

Jan 1, 1939

By Shigehisa Endoh, Hitoshi Ohya, Atsushi Inaba, Shigeki Koyanaka

"Recycling should be promoted to keep the global environment. However, it is difficult to detennine the quantitative impact. A life cycle assessment is one of the most reliable methods to estimate the global environment impact.Exergy is useful like entropy when considering the sustainable development. All of our activities have been obtained exergy resources and/or energy itself and throw away waste and/or waste heat. We are trying to use exergy to estimate the quantity of energy and matter for resource accounting. For recycling plastic, plastic has two aspects; material and energy source.The environmental assessment of plastic recycling suggests that the exergy reduction of the entire system is estimated by the yield of matter and the process efficiency. The material recycling is better than the thennal recycling when the process efficiency is high. However, the thennal recycling is much better for the low efficiency. The transition point is able to be decided by the efficiency of the manufacturing and the electric power generation.IntroductionRecently, many of the global environmental problems have become conspicuous like global wanning, ozone layer depletion and acid rain. Some of the methods like life cycle assessment for solving these problems have been presented. Anxiety concerning the proble1ns of energy and resources has led to a rapid increase in the interest in describing and understanding the conversion processes of energy and other resources in today's society. All human activity is supported by obtaining power and products of high exergy from the environment and throwing away the waste material and the waste heat of low exergy back the environment. However, the total exergy in the whole system becomes absolutely smaller than before.The rate of obtaining high exergy products and energy itself by human activity and the speed, by which waste and waste heat having low exergy are thrown away are too fast to attribute to environmental problems [1-3].A material's use by recycling was often common in a circulating society mainly. A significant amount of energy is consumed during circulation. An environmental impact assessment method for the process or the system has not been devised when both of them are taken into consideration. Even if the life cycle assessment evaluation, which has been correctly used up to now, is applied, it is not sufficient for an overall evaluation concerning matter and energy.The real sustainable development is that the exergy reduction value by all human activities on the earth is kept within the range of the exergy reduction in order to consider the earth as closed stationary system. It is important to evaluate the process or the system by using the exergy, and design them so that the exergy loss may decrease as much as possible. We have to consider what process improvement is the most effective."

Jan 1, 2000

By Y K. Ji, B J. Chung

In recent years, the utilisation of ultra-fine ore in ironmaking has gradually increased due to the depletion of high-quality iron ore. The use of ultra-fine ore in the ironmaking process is typically energy intensive and leads to high CO2 emissions. The improvement of sinter reducibility is one of the methods used to reduce the environmental impact of using fine ore.In this study, a high-strength and high-reducibility sinter manufacturing process was investigated by controlling the sintering reaction. The key technology used in this method is the manufacture of mini-pellets by selective granulation equipment. The mini-pellets consist of iron ore, limestone and burnt lime and are designed to melt at temperatures below 1200°C. The molar ratio of CaO to Fe2O3 of the mini-pellets is 0.25~0.75. The 2~5 mm diameter mini-pellets are manufactured with burnt lime as the binding material.During the sintering of mini-pellets, goethite, which has relatively high reducibility, should be retained as residual ore in the sinter cake. The strength of the sinter cake was kept by the bonding reaction of the mini-pellets, which have a low melting temperature. This is the main principle of the reaction-controlled sintering method.The reaction-controlled sintering method manufactures a high-strength and high-reducibility sinter cake and increases sinter productivity by around 15 per cent using ultra-fine iron ore.CITATION:Chung, B J and Ji, Y K, 2015. Production of high-quality sinter by controlling the sintering reaction, in Proceedings Iron Ore 2015, pp 21–28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Xu-ling Chen, Qian Li, Yong-bin Yang, Zhao Jing, Tao Jiang, Guang-hui Li

"It is generally known that alkali metals are harmful to blast furnace production resulting in aggravating RDI of sinters, abnormal expansion of pellets, deteriorating blast furnace lining, etc. Sinters regarded as dominating burden of blast furnace are determined as the main source of alkali metals. In this study, the removal behavior of potassium and sodium oxides by pre-reduction sintering during the sintering process was studied. The removal ratio ofK20 and Na20 was greatly influenced by coke powder content, carbon species, coke powder adding ways, additive and so on. Under the conditions of carbon rate 12% and 5% dosage of CO supplied in the sintering process, the corresponding removal ratio ofK20, Na20 was 69.00% and 32.79%, and metallization ratio could reach 4.65%. This technology provided a novel process for reducing the content of alkali metals in sinters and dramatically improving the quality of blast furnace burden.IntroductionSinter is the main iron-bearing charge of blast furnace for iron-making in China, making up about 80% of the total burden; therefore, its quality has a significant influence on the quality of pig iron and blast furnace operation. Research and practice of numerous years prove that potassium and sodium coming from ores are brought into blast furnace and upgraded, which is one of the essential reasons that lead to blast furnace nodulation and influences its strength. Currently, effective flow sheet to remove potassium and sodium is weak magnetic separation-intensive magnetic separation-flotation [l], while iron ore concentrate is still ofhigh levels of potassium and sodium. As sintering process is also not effective to remove potassium and sodium, blast furnace in China is of high alkali burden, e.g. it reaches 5.6-6.2kg/tFe in Baotou iron making plant, which is greater than international tolerated level of2.55kgltFe [l]."

Jan 1, 2013

By L. A. Baker

The presence of goethite in a hematite ore has been shown to strongly affect the time of heating to the firing temperature. The investigation of spalling of single pellets and of packed beds has enabled free water and goethite spalling to be identified as separate phenomena. In addition, it has been shown that even for an 18 inch deep bed of green balls the free water and goethite drying periods can be considered separately. Based on this observation, a method of predicting production rate and hood temperature profile is presented. The method required knowledge of the ore goethite content, ore grind and the green pellet bulk density. Laboratory results were found to be in good agreement with actual plant practice and have led to improved process performance.

Jan 1, 1972

By F. G. Miller, E. B. Wilson

In 1972, coal mine productivity was in steady decline and labor and maintenance costs were spiralling upward. Yet, despite this sad state of affairs, nowhere in the US at that time was there a comprehensive and coordinated coal research and development plan in the offing. The Bureau of Mines had not yet been charged with such a responsibility, and industry was content to rely on machinery manufacturers for innovations. It was during this period that Bethlehem Steel Corp. determined that a new approach to coal mining research was needed for the industry as well as for the company itself. After studying Bethlehem's own mining practices, the state-of-the-art of mining research elsewhere, and development work by manufacturers, a comprehensive research package was presented to company management in late 1972. The ideas and experience of many operating and management personnel in the company contributed to the formulation of the final plan as approved.

Jan 10, 1976

By J. J. McClelland

The face area of a continuous mining section of an underground coal mine is the most dangerous area in the mine. Workers there are at nearly twice the risk of death or disabling injury than those in other parts of the mine. Despite extensive training of miners and improved equipment and mining methods, fatality and injury rates have remained constant during the past few years. It is clear that advanced research is necessary to apply new technologies or modify work procedures to solve the continuing problem of the loss of lives and the numerous injuries at the mine face. A U.S. Bureau of Mines research program is developing a Reduced-Exposure Mining System (REMS) that relocates personnel operating the mining machinery at the face away from the hazards to a nearby haven of relative safety. REMS uses proven technologies of computer automation and robotics to help control the operation of the mining machines at the face, while personnel are moved away to a nearby, safe control room. In this protected, well-ventilated environment, they can supervise or control the operation of the machines while viewing what the machine is doing using video and graphic display monitors.

Jan 1, 1994